Characterisation of LiAIH4 and complex alanates:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2008
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Zsfassung in dt. Sprache |
| Beschreibung: | V, 130 S. graph. Darst. |
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| adam_text | CHARACTERISATION OF LIAIH 4 AND COMPLEX ALANATES VON DER FAKULTAT
ENERGIE-VERFAHRENS-UND BIOTECHNIK DER UNIVERSITAT STUTTGART ZUR
ERIANGUNG DER WURDE EINES DOKTORINGENIEURS (DR.-LNG.) GENEHMIGTE
ABHANDLUNG VORGELEGT VON MARCIN OSSOWSKI AUS CHORZ6W, POLEN
HAUPTBERICHTER: PROF. DR.-LNG. HABIL. M. GROLL MITBERICHTER: PROF.
DR.-LNG. J. HAPKE TABLE OF CONTENTS TABLE OF CONTENTS NOMENCLATURE
ABSTRACT / KURZFASSUNG V 1. INTRODUCTION 1 1.1. HYDROGEN AS THE FUEL OF
THE FUTURE 1 1.2. HYDROGEN STORAGE METHODS 2 1.3. COMPLEX METAL HYDRIDES
6 1.4. AIM OF PRESENT THESIS 7 2. ALANATES 9 2.1. WHAT ARE ALANATES? 9
2.2. CRYSTAL STRUCTURE 10 2.3. CHEMISTRY (DECOMPOSITION AND SYNTHESIS)
12 2.4. THERMODYNAMIC PROPERTIES 17 2.5. KINETICS PROPERTIES AND
REACTION MECHANICS 17 2.6. METHODS TO IMPROVE KINETICS 19 2.7.
LITERATURE OVERVIEW 21 3. EXPERIMENTATION 25 3.1. EXPERIMENTAL APPARATUS
25 3.1.1. SET-UP 25 3.1.2. REACTORS 26 3.2. MEASUREMENT PROCEDURE AND
MEASUREMENT ACCURACY 27 3.2.1. MEASUREMENT PROCEDURE AND POST PROCESSING
27 3.2.2. MEASUREMENT ACCURACY 28 3.3. EXPERIMENTAL PROGRAM 31
EXPERIMENTAL INVESTIGATION OF LIAIH 4 32 NANO-SCALE STRUCTURING AND
DOPING OF LIAIH 4 32 DESORPTION EXPERIMENTS 34 PURE LIAIH 4 34 UAIH4
DOPED WITH 2 MOLE % PURE TITANIUM 36 IJAIH4 DOPED WITH 2 MOLE % TITANIUM
ORGANIC COMPOUND - TI(OBU) 4 39 LIAIH 4 DOPED WITH 1 MOLE % TITANIUM AND
ZIRCONIUM ORGANIC 43 COMPOUNDS - TI(OBU) 4 AND ZR(OPR) 4 HIGH PRESSURE
EXPERIMENTS 46 EXPERIMENTAL SET-UP 46 EXPERIMENTAL RESULTS { 48 PAGE I
TABLE OF CONTENTS 4.4. SUMMARY 56 5. EXPERIMENTAL INVESTIGATION OF
COMPLEX ALANATES 59 5.1. PRELIMINARY EXPERIMENTS 59 5.1.1. SYNTHESIS AND
CHARACTERISATION OF NAO.SL^.SAIHE 60 5.1.2. SYNTHESIS AND
CHARACTERISATION OF NAU 2 AIH 6 APPLYING LIAIH 4 62 5.1.3. SYNTHESIS AND
CHARACTERISATION OF NALI 2 AIH 6 APPLYING NAAIH 4 64 5.1.4. SYNTHESIS
AND CHARACTERISATION OF NAI. 5 LII.5AIH 6 66 5.2. SYNTHESIS,
CHARACTERISATION AND CATALYSING OF NA 2 LIAIH 6 68 5.2.1. PURE NA 2
LIAIH 6 70 5.2.1.1. PCI - MEASUREMENTS 70 5.2.1.2. KINETICS MEASUREMENTS
77 5.2.2. NA 2 LIAIH 6 DOPED WITH 2 MOLE % PURE ZIRCONIUM 84 5.2.3. NA 2
LIAIH 6 DOPED WITH 2 MOLE % PURE VANADIUM 87 5.2.4. NA 2 LIAIH 6 DOPED
WITH 2 MOLE % ORGANIC COMPOUND - TI(OBU) 4 90 5.2.5. NA 2 LIAIH6 DOPED
WITH 2 MOLE % ORGANIC COMPOUND - ZR(OPR) 4 92 5.3. SUMMARY 94 6. SUMMARY
AND CONCLUSIONS 98 6.1. GENERAL 98 6.2. SUMMARY AND CONCLUSIONS FOR
LIAIH 4 99 6.3. SUMMARY AND CONCLUSIONS FOR COMPLEX ALANATES 100 7.
REFERENCES 102 A. APPENDICES 106 A.1. THE SET-UP AND MEASUREMENT
PROCEDURES 106 A.1.1. THE KINETICS MEASUREMENT DEVICE 106 A. 1.1.1.
SET-UP DESCRIPTION 106 A.1.1.2. MEASURING PROCEDURE 108 A. 1.2. THE PCI
DEVICE 111 A. 1.2.1. SET-UP DESCRIPTION 111 A.1.2.2. MEASURING PROCEDURE
113 A. 1.3. BALL MILL 116 A.1.4. XRD 119 A.1.5. POST PROCESSING -
CALCULATIONS 121 A.1.5.1. CALCULATION OF HYDROGEN STORAGE CAPACITIES -,
121 A.1.5.2. ERROR ESTIMATION 123 A.2. STRESS CALCULATIONS FOR HIGH
PRESSURE VESSEL 126 PAGE I
|
| adam_txt |
CHARACTERISATION OF LIAIH 4 AND COMPLEX ALANATES VON DER FAKULTAT
ENERGIE-VERFAHRENS-UND BIOTECHNIK DER UNIVERSITAT STUTTGART ZUR
ERIANGUNG DER WURDE EINES DOKTORINGENIEURS (DR.-LNG.) GENEHMIGTE
ABHANDLUNG VORGELEGT VON MARCIN OSSOWSKI AUS CHORZ6W, POLEN
HAUPTBERICHTER: PROF. DR.-LNG. HABIL. M. GROLL MITBERICHTER: PROF.
DR.-LNG. J. HAPKE TABLE OF CONTENTS TABLE OF CONTENTS NOMENCLATURE '"
ABSTRACT / KURZFASSUNG V 1. INTRODUCTION 1 1.1. HYDROGEN AS THE FUEL OF
THE FUTURE 1 1.2. HYDROGEN STORAGE METHODS 2 1.3. COMPLEX METAL HYDRIDES
6 1.4. AIM OF PRESENT THESIS 7 2. ALANATES 9 2.1. WHAT ARE ALANATES? 9
2.2. CRYSTAL STRUCTURE 10 2.3. CHEMISTRY (DECOMPOSITION AND SYNTHESIS)
12 2.4. THERMODYNAMIC PROPERTIES 17 2.5. KINETICS PROPERTIES AND
REACTION MECHANICS 17 2.6. METHODS TO IMPROVE KINETICS 19 2.7.
LITERATURE OVERVIEW 21 3. EXPERIMENTATION 25 3.1. EXPERIMENTAL APPARATUS
25 3.1.1. SET-UP 25 3.1.2. REACTORS 26 3.2. MEASUREMENT PROCEDURE AND
MEASUREMENT ACCURACY 27 3.2.1. MEASUREMENT PROCEDURE AND POST PROCESSING
27 3.2.2. MEASUREMENT ACCURACY 28 3.3. EXPERIMENTAL PROGRAM 31
EXPERIMENTAL INVESTIGATION OF LIAIH 4 32 NANO-SCALE STRUCTURING AND
DOPING OF LIAIH 4 32 DESORPTION EXPERIMENTS 34 PURE LIAIH 4 34 UAIH4
DOPED WITH 2 MOLE % PURE TITANIUM 36 IJAIH4 DOPED WITH 2 MOLE % TITANIUM
ORGANIC COMPOUND - TI(OBU) 4 39 LIAIH 4 DOPED WITH 1 MOLE % TITANIUM AND
ZIRCONIUM ORGANIC 43 COMPOUNDS - TI(OBU) 4 AND ZR(OPR) 4 HIGH PRESSURE
EXPERIMENTS 46 EXPERIMENTAL SET-UP 46 EXPERIMENTAL RESULTS { 48 PAGE I
TABLE OF CONTENTS 4.4. SUMMARY 56 5. EXPERIMENTAL INVESTIGATION OF
COMPLEX ALANATES 59 5.1. PRELIMINARY EXPERIMENTS 59 5.1.1. SYNTHESIS AND
CHARACTERISATION OF NAO.SL^.SAIHE 60 5.1.2. SYNTHESIS AND
CHARACTERISATION OF NAU 2 AIH 6 APPLYING LIAIH 4 62 5.1.3. SYNTHESIS AND
CHARACTERISATION OF NALI 2 AIH 6 APPLYING NAAIH 4 64 5.1.4. SYNTHESIS
AND CHARACTERISATION OF NAI. 5 LII.5AIH 6 66 5.2. SYNTHESIS,
CHARACTERISATION AND CATALYSING OF NA 2 LIAIH 6 68 5.2.1. PURE NA 2
LIAIH 6 70 5.2.1.1. PCI - MEASUREMENTS 70 5.2.1.2. KINETICS MEASUREMENTS
77 5.2.2. NA 2 LIAIH 6 DOPED WITH 2 MOLE % PURE ZIRCONIUM 84 5.2.3. NA 2
LIAIH 6 DOPED WITH 2 MOLE % PURE VANADIUM 87 5.2.4. NA 2 LIAIH 6 DOPED
WITH 2 MOLE % ORGANIC COMPOUND - TI(OBU) 4 90 5.2.5. NA 2 LIAIH6 DOPED
WITH 2 MOLE % ORGANIC COMPOUND - ZR(OPR) 4 92 5.3. SUMMARY 94 6. SUMMARY
AND CONCLUSIONS 98 6.1. GENERAL 98 6.2. SUMMARY AND CONCLUSIONS FOR
LIAIH 4 99 6.3. SUMMARY AND CONCLUSIONS FOR COMPLEX ALANATES 100 7.
REFERENCES 102 A. APPENDICES 106 A.1. THE SET-UP AND MEASUREMENT
PROCEDURES 106 A.1.1. THE KINETICS MEASUREMENT DEVICE 106 A. 1.1.1.
SET-UP DESCRIPTION 106 A.1.1.2. MEASURING PROCEDURE 108 A. 1.2. THE PCI
DEVICE 111 A. 1.2.1. SET-UP DESCRIPTION 111 A.1.2.2. MEASURING PROCEDURE
113 A. 1.3. BALL MILL 116 A.1.4. XRD ' 119 A.1.5. POST PROCESSING -
CALCULATIONS 121 A.1.5.1. CALCULATION OF HYDROGEN STORAGE CAPACITIES -,
121 A.1.5.2. ERROR ESTIMATION 123 A.2. STRESS CALCULATIONS FOR HIGH
PRESSURE VESSEL 126 PAGE I |
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| spelling | Ossowski, Marcin Verfasser (DE-588)136551033 aut Characterisation of LiAIH4 and complex alanates von Marcin Ossowski 2008 V, 130 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Zsfassung in dt. Sprache Stuttgart, Univ., Diss., 2008 Alanate ; IND: s Wasserstoffspeicherung ; IND: s (DE-588)4113937-9 Hochschulschrift gnd-content HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016966670&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Ossowski, Marcin Characterisation of LiAIH4 and complex alanates Alanate ; IND: s Wasserstoffspeicherung ; IND: s |
| subject_GND | (DE-588)4113937-9 |
| title | Characterisation of LiAIH4 and complex alanates |
| title_auth | Characterisation of LiAIH4 and complex alanates |
| title_exact_search | Characterisation of LiAIH4 and complex alanates |
| title_exact_search_txtP | Characterisation of LiAIH4 and complex alanates |
| title_full | Characterisation of LiAIH4 and complex alanates von Marcin Ossowski |
| title_fullStr | Characterisation of LiAIH4 and complex alanates von Marcin Ossowski |
| title_full_unstemmed | Characterisation of LiAIH4 and complex alanates von Marcin Ossowski |
| title_short | Characterisation of LiAIH4 and complex alanates |
| title_sort | characterisation of liaih4 and complex alanates |
| topic | Alanate ; IND: s Wasserstoffspeicherung ; IND: s |
| topic_facet | Alanate ; IND: s Wasserstoffspeicherung ; IND: s Hochschulschrift |
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