Phase transitions in polymers: the role of metastable states
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
2008
|
| Ausgabe: | 1. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | xv, 307 p. Ill., graph. Darst. |
| ISBN: | 9780444519115 |
Internformat
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV035158569 | ||
| 003 | DE-604 | ||
| 005 | 20090304 | ||
| 007 | t | ||
| 008 | 081113s2008 ad|| |||| 00||| eng d | ||
| 020 | |a 9780444519115 |c (hbk.) : £100.00 |9 978-0-444-51911-5 | ||
| 035 | |a (OCoLC)184827849 | ||
| 035 | |a (DE-599)GBV574386378 | ||
| 040 | |a DE-604 |b ger |e aacr | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-703 | ||
| 050 | 0 | |a QC173.4.P65 | |
| 082 | 0 | |a 620.192 |2 22 | |
| 084 | |a UV 3300 |0 (DE-625)146892: |2 rvk | ||
| 100 | 1 | |a Cheng, Stephen Z. D. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Phase transitions in polymers |b the role of metastable states |c Stephen Z. D. Cheng |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 2008 | |
| 300 | |a xv, 307 p. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and index | ||
| 650 | 4 | |a Polymères | |
| 650 | 4 | |a Polymères - Propriétés thermiques | |
| 650 | 7 | |a Polymères |2 ram | |
| 650 | 4 | |a Transitions de phase | |
| 650 | 7 | |a Transitions de phases |2 ram | |
| 650 | 4 | |a États métastables (Chimie) | |
| 650 | 7 | |a États métastables (physique) |2 ram | |
| 650 | 4 | |a Nonequilibrium thermodynamics | |
| 650 | 4 | |a Phase transformations (Statistical physics) | |
| 650 | 4 | |a Polymers | |
| 650 | 0 | 7 | |a Polymere |0 (DE-588)4046699-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Phasenumwandlung |0 (DE-588)4132140-6 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Polymere |0 (DE-588)4046699-1 |D s |
| 689 | 0 | 1 | |a Phasenumwandlung |0 (DE-588)4132140-6 |D s |
| 689 | 0 | |5 DE-604 | |
| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016965724&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-016965724 | ||
Datensatz im Suchindex
| _version_ | 1804138320566943744 |
|---|---|
| adam_text | Contents
Foreword
ix
Preface and Acknowledgments
xiii
ι.
Introduction
ι
1. Phases in Single-Component Systems
ι
1.1. Macroscopic description of phases
ι
1.2.
Microscopic description of phases
3
1.3.
Connection between microscopic descriptions and
macroscopic properties
7
2.
Phase Transitions in Single-Component Systems
10
2.1.
Definitions of phase transitions
10
2.2.
Phase equilibrium and stability
12
2.
Thermodynamics and Kinetics of Phase Transitions
17
1.
Thermodynamics of Phase Transitions in Single Component Systems
18
1.1.
An example of liquid-gas transitions: van
der Waals
gas 18
1.2.
General descriptions of liquid-gas and crystalline
solid-liquid transitions
20
1.3.
Crystalline solid-solid transitions
24
1.4.
Transitions involving mesophases
25
2.
Kinetic Aspects of Phase Transitions in Single Component Systems
31
2.1.
Crystallization
31
2.2.
Crystal melting kinetics
35
2.3.
Transition kinetics involving mesophases
37
3.
Phases and Phase Transitions in Multiple Component Systems
39
3.1.
Gibbs phase rule
39
3.2.
General thermodynamics of binary mixing
40
3.3.
Liquid-liquid phase separation in binary mixtures
42
3.4.
Kinetics of liquid-liquid phase separation in binary mixtures
45
3.5.
Crystalline solid-liquid transitions in binary mixtures
51
3.6.
Mesophase-liquid transitions in binary mixtures
52
3.
Concepts of Metastable States
61
1.
Ostwald s Stage Rule and Definition of a Metastable State
61
2.
Examples of Metastable States in Phase Transitions
63
2.1.
Metastable states in liquid-gas transitions
63
2.2.
Metastable states in crystalline solid-liquid transitions
65
vi
Contents
3.
Appearance of Metastable States Controlled by Competing Kinetics
67
4.
What are the Limitations of the Current Understanding of
Metastable States?
71
5.
Concept of Metastability
73
4.
Metastable States in Phase Transitions of Polymers
77
1.
Supercooled Liquids and Crystallization
78
1.1.
Supercooled liquids
78
1.2.
Comments on polymer crystallization theories
81
1.3.
Primary nucleation process in polymer crystallization
91
1.4.
Structure of the
interfacial
liquid near the crystal growth front
94
1.5.
What is the nucleation barrier?
96
2.
Superheated Crystals and Crystal Melting
106
2.1.
Superheated crystals
106
2.2.
Irreversible polymer crystal melting
110
2.3.
Determining crystal metastability
111
2.4.
Ensuring constant metastability during heating
117
2.5.
Polymer crystal melting at elevated pressures
120
2.6.
Polymer crystal melting kinetics
122
3.
Metastable States in Phase-Separated Polymer Blends and Copotymers
124
3.1.
Metastable states in phase-separated polymer blends
124
3.2.
Kinetics of liquid-liquid phase-separation in polymer blends
127
3.3.
Metastable states in phase-separated block copolymers
130
3.4.
Polymer crystallization in nano-confined environments
using diblock copolymers as templates
136
5.
Metastable States Observed Due to Phase Transformation Kinetics
in Polymers
157
1.
Appearance of Metastable States Based on Their Crystal
Nucleation Barrier
158
1.1.
Crystal growth rates along different growth planes
158
1.2.
Initial transient state in polymer crystallization
168
1.3.
Nucleation and growth rates affected by chain conformation
173
2.
Polymorphs and Competing Formation Kinetics
176
2.1.
Phase stability changes in polymorphs at atmospheric pressure
176
2.2.
Phase stability changes in polymorphs at high pressures and temperatures
186
2.3.
External field-induced polymorphs
193
3.
Monotropic Phase Transitions in Polymers
195
3.1.
Crystallization kinetics enhanced by a preordered mesophase
195
3.2.
Change of phase transition sequence due to existence of a
preordered state
199
4.
Surface- and Interface-Induced Metastable Phases
203
4.1.
Surface-induced metastable polymorphs
203
4.2.
Metastable states introduced by unbalanced surface
stresses caused by chain folding
213
Contents
vii
6. Interdependence
of Metastable
States
on Different Length Scales
237
1.
Combining Phase Size Effects with Polymorphs
238
1.1.
Phase-stability changes in polymorphs based on phase sizes
238
1.2.
Examples of phase inversion by crossing over the
phase-stability boundaries
245
1.3.
Examples of phase inversion without crossing the
phase-stability boundaries
256
2.
Liquid-Liquid Phase Separation Coupled with Vitrification
260
3.
Liquid-Liquid Phase Separation Coupled with Crystallization
266
3.1.
Liquid-liquid phase separation intervened
by crystallization in solution
266
3.2.
Sequential liquid-liquid phase separation and
crystallization in solution
270
3.3.
Liquid-liquid phase separation intersected by
crystallization in polymer blends
274
3.4.
Sequential liquid-liquid phase separation and
crystallization in polymer blends
281
4.
Liquid-Liquid Phase Separation Associated with Gelation and Crystallization
286
7.
Outlook: A Personal View
299
Index
303
|
| adam_txt |
Contents
Foreword
ix
Preface and Acknowledgments
xiii
ι.
Introduction
ι
1. Phases in Single-Component Systems
ι
1.1. Macroscopic description of phases
ι
1.2.
Microscopic description of phases
3
1.3.
Connection between microscopic descriptions and
macroscopic properties
7
2.
Phase Transitions in Single-Component Systems
10
2.1.
Definitions of phase transitions
10
2.2.
Phase equilibrium and stability
12
2.
Thermodynamics and Kinetics of Phase Transitions
17
1.
Thermodynamics of Phase Transitions in Single Component Systems
18
1.1.
An example of liquid-gas transitions: van
der Waals
gas 18
1.2.
General descriptions of liquid-gas and crystalline
solid-liquid transitions
20
1.3.
Crystalline solid-solid transitions
24
1.4.
Transitions involving mesophases
25
2.
Kinetic Aspects of Phase Transitions in Single Component Systems
31
2.1.
Crystallization
31
2.2.
Crystal melting kinetics
35
2.3.
Transition kinetics involving mesophases
37
3.
Phases and Phase Transitions in Multiple Component Systems
39
3.1.
Gibbs phase rule
39
3.2.
General thermodynamics of binary mixing
40
3.3.
Liquid-liquid phase separation in binary mixtures
42
3.4.
Kinetics of liquid-liquid phase separation in binary mixtures
45
3.5.
Crystalline solid-liquid transitions in binary mixtures
51
3.6.
Mesophase-liquid transitions in binary mixtures
52
3.
Concepts of Metastable States
61
1.
Ostwald's Stage Rule and Definition of a Metastable State
61
2.
Examples of Metastable States in Phase Transitions
63
2.1.
Metastable states in liquid-gas transitions
63
2.2.
Metastable states in crystalline solid-liquid transitions
65
vi
Contents
3.
Appearance of Metastable States Controlled by Competing Kinetics
67
4.
What are the Limitations of the Current Understanding of
Metastable States?
71
5.
Concept of Metastability
73
4.
Metastable States in Phase Transitions of Polymers
77
1.
Supercooled Liquids and Crystallization
78
1.1.
Supercooled liquids
78
1.2.
Comments on polymer crystallization theories
81
1.3.
Primary nucleation process in polymer crystallization
91
1.4.
Structure of the
interfacial
liquid near the crystal growth front
94
1.5.
What is the nucleation barrier?
96
2.
Superheated Crystals and Crystal Melting
106
2.1.
Superheated crystals
106
2.2.
Irreversible polymer crystal melting
110
2.3.
Determining crystal metastability
111
2.4.
Ensuring constant metastability during heating
117
2.5.
Polymer crystal melting at elevated pressures
120
2.6.
Polymer crystal melting kinetics
122
3.
Metastable States in Phase-Separated Polymer Blends and Copotymers
124
3.1.
Metastable states in phase-separated polymer blends
124
3.2.
Kinetics of liquid-liquid phase-separation in polymer blends
127
3.3.
Metastable states in phase-separated block copolymers
130
3.4.
Polymer crystallization in nano-confined environments
using diblock copolymers as templates
136
5.
Metastable States Observed Due to Phase Transformation Kinetics
in Polymers
157
1.
Appearance of Metastable States Based on Their Crystal
Nucleation Barrier
158
1.1.
Crystal growth rates along different growth planes
158
1.2.
Initial transient state in polymer crystallization
168
1.3.
Nucleation and growth rates affected by chain conformation
173
2.
Polymorphs and Competing Formation Kinetics
176
2.1.
Phase stability changes in polymorphs at atmospheric pressure
176
2.2.
Phase stability changes in polymorphs at high pressures and temperatures
186
2.3.
External field-induced polymorphs
193
3.
Monotropic Phase Transitions in Polymers
195
3.1.
Crystallization kinetics enhanced by a preordered mesophase
195
3.2.
Change of phase transition sequence due to existence of a
preordered state
199
4.
Surface- and Interface-Induced Metastable Phases
203
4.1.
Surface-induced metastable polymorphs
203
4.2.
Metastable states introduced by unbalanced surface
stresses caused by chain folding
213
Contents
vii
6. Interdependence
of Metastable
States
on Different Length Scales
237
1.
Combining Phase Size Effects with Polymorphs
238
1.1.
Phase-stability changes in polymorphs based on phase sizes
238
1.2.
Examples of phase inversion by crossing over the
phase-stability boundaries
245
1.3.
Examples of phase inversion without crossing the
phase-stability boundaries
256
2.
Liquid-Liquid Phase Separation Coupled with Vitrification
260
3.
Liquid-Liquid Phase Separation Coupled with Crystallization
266
3.1.
Liquid-liquid phase separation intervened
by crystallization in solution
266
3.2.
Sequential liquid-liquid phase separation and
crystallization in solution
270
3.3.
Liquid-liquid phase separation intersected by
crystallization in polymer blends
274
3.4.
Sequential liquid-liquid phase separation and
crystallization in polymer blends
281
4.
Liquid-Liquid Phase Separation Associated with Gelation and Crystallization
286
7.
Outlook: A Personal View
299
Index
303 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Cheng, Stephen Z. D. |
| author_facet | Cheng, Stephen Z. D. |
| author_role | aut |
| author_sort | Cheng, Stephen Z. D. |
| author_variant | s z d c szd szdc |
| building | Verbundindex |
| bvnumber | BV035158569 |
| callnumber-first | Q - Science |
| callnumber-label | QC173 |
| callnumber-raw | QC173.4.P65 |
| callnumber-search | QC173.4.P65 |
| callnumber-sort | QC 3173.4 P65 |
| callnumber-subject | QC - Physics |
| classification_rvk | UV 3300 |
| ctrlnum | (OCoLC)184827849 (DE-599)GBV574386378 |
| dewey-full | 620.192 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 620 - Engineering and allied operations |
| dewey-raw | 620.192 |
| dewey-search | 620.192 |
| dewey-sort | 3620.192 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Physik |
| discipline_str_mv | Physik |
| edition | 1. ed. |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01884nam a2200505 c 4500</leader><controlfield tag="001">BV035158569</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20090304 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">081113s2008 ad|| |||| 00||| eng d</controlfield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">9780444519115</subfield><subfield code="c">(hbk.) : £100.00</subfield><subfield code="9">978-0-444-51911-5</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)184827849</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBV574386378</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">aacr</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-703</subfield></datafield><datafield tag="050" ind1=" " ind2="0"><subfield code="a">QC173.4.P65</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">620.192</subfield><subfield code="2">22</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">UV 3300</subfield><subfield code="0">(DE-625)146892:</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Cheng, Stephen Z. D.</subfield><subfield code="e">Verfasser</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Phase transitions in polymers</subfield><subfield code="b">the role of metastable states</subfield><subfield code="c">Stephen Z. D. Cheng</subfield></datafield><datafield tag="250" ind1=" " ind2=" "><subfield code="a">1. ed.</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Amsterdam [u.a.]</subfield><subfield code="b">Elsevier</subfield><subfield code="c">2008</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">xv, 307 p.</subfield><subfield code="b">Ill., graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">Includes bibliographical references and index</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polymères</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polymères - Propriétés thermiques</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Polymères</subfield><subfield code="2">ram</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Transitions de phase</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">Transitions de phases</subfield><subfield code="2">ram</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">États métastables (Chimie)</subfield></datafield><datafield tag="650" ind1=" " ind2="7"><subfield code="a">États métastables (physique)</subfield><subfield code="2">ram</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nonequilibrium thermodynamics</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Phase transformations (Statistical physics)</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Polymers</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Polymere</subfield><subfield code="0">(DE-588)4046699-1</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Phasenumwandlung</subfield><subfield code="0">(DE-588)4132140-6</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Polymere</subfield><subfield code="0">(DE-588)4046699-1</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="1"><subfield code="a">Phasenumwandlung</subfield><subfield code="0">(DE-588)4132140-6</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">Digitalisierung UB Bayreuth</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016965724&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-016965724</subfield></datafield></record></collection> |
| id | DE-604.BV035158569 |
| illustrated | Illustrated |
| index_date | 2024-07-02T22:49:43Z |
| indexdate | 2024-07-09T21:26:19Z |
| institution | BVB |
| isbn | 9780444519115 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016965724 |
| oclc_num | 184827849 |
| open_access_boolean | |
| owner | DE-703 |
| owner_facet | DE-703 |
| physical | xv, 307 p. Ill., graph. Darst. |
| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | Elsevier |
| record_format | marc |
| spelling | Cheng, Stephen Z. D. Verfasser aut Phase transitions in polymers the role of metastable states Stephen Z. D. Cheng 1. ed. Amsterdam [u.a.] Elsevier 2008 xv, 307 p. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Polymères Polymères - Propriétés thermiques Polymères ram Transitions de phase Transitions de phases ram États métastables (Chimie) États métastables (physique) ram Nonequilibrium thermodynamics Phase transformations (Statistical physics) Polymers Polymere (DE-588)4046699-1 gnd rswk-swf Phasenumwandlung (DE-588)4132140-6 gnd rswk-swf Polymere (DE-588)4046699-1 s Phasenumwandlung (DE-588)4132140-6 s DE-604 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016965724&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Cheng, Stephen Z. D. Phase transitions in polymers the role of metastable states Polymères Polymères - Propriétés thermiques Polymères ram Transitions de phase Transitions de phases ram États métastables (Chimie) États métastables (physique) ram Nonequilibrium thermodynamics Phase transformations (Statistical physics) Polymers Polymere (DE-588)4046699-1 gnd Phasenumwandlung (DE-588)4132140-6 gnd |
| subject_GND | (DE-588)4046699-1 (DE-588)4132140-6 |
| title | Phase transitions in polymers the role of metastable states |
| title_auth | Phase transitions in polymers the role of metastable states |
| title_exact_search | Phase transitions in polymers the role of metastable states |
| title_exact_search_txtP | Phase transitions in polymers the role of metastable states |
| title_full | Phase transitions in polymers the role of metastable states Stephen Z. D. Cheng |
| title_fullStr | Phase transitions in polymers the role of metastable states Stephen Z. D. Cheng |
| title_full_unstemmed | Phase transitions in polymers the role of metastable states Stephen Z. D. Cheng |
| title_short | Phase transitions in polymers |
| title_sort | phase transitions in polymers the role of metastable states |
| title_sub | the role of metastable states |
| topic | Polymères Polymères - Propriétés thermiques Polymères ram Transitions de phase Transitions de phases ram États métastables (Chimie) États métastables (physique) ram Nonequilibrium thermodynamics Phase transformations (Statistical physics) Polymers Polymere (DE-588)4046699-1 gnd Phasenumwandlung (DE-588)4132140-6 gnd |
| topic_facet | Polymères Polymères - Propriétés thermiques Transitions de phase Transitions de phases États métastables (Chimie) États métastables (physique) Nonequilibrium thermodynamics Phase transformations (Statistical physics) Polymers Polymere Phasenumwandlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016965724&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT chengstephenzd phasetransitionsinpolymerstheroleofmetastablestates |