Chemical structure and reactivity: an integrated approach
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Oxford [u.a.]
Oxford Univ. Press
2008
|
| Ausgabe: | 1. publ. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XVIII, 925 S. Ill., graph. Darst. 26cm |
| ISBN: | 0199289301 9780199289301 |
Internformat
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| 245 | 1 | 0 | |a Chemical structure and reactivity |b an integrated approach |c James Keeler ; Peter Wothers |
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Datensatz im Suchindex
| _version_ | 1804138116436459520 |
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| adam_text | FULL CONTENTS PREFACE V* ONLINE RESOURCE CENTRE IX* PART I THE
FUNDAMENTALS 1 MOLECULAR STRUCTURES AND THE STATES OF MATTER 3* 1.1
TYPES OF BONDING 4* 1.2 WEAKER NON-BONDED INTERACTIONS 6* 1.3 SOLIDS 9*
1.4 STRUCTURE DETERMINATION BY X-RAY DIFFRACTION 10* 1.5 WHERE ARE THE
BONDS? 13* 1.6 HOW TO DRAW MOLECULES 15* 1.7 COMMON NAMES AND
ABBREVIATIONS 17* 1.8 PREDICTING THE SHAPES OF MOLECULES USING VSEPR 18*
1.9 THE IDEAL GAS 22* 1.10 MOLECULAR ENERGY LEVELS 26* 1.11 MOVING ON
29* QUESTIONS 29* 2 ELECTRONS IN ATOMS 35* 2.1 INTRODUCING QUANTUM
MECHANICS 36* 2.2 INTRODUCING ORBITALS 39* 2.3 HYDROGEN ATOMIC ORBITALS
44* 2.4 SPIN 63* 2.5 HYDROGEN-LIKE ATOMS 65* 2.6 MULTI-ELECTRON ATOMS
65* 2.7 LONIZATION ENERGIES 80* 2.8 MOVING ON 85* FURTHER READING 86*
QUESTIONS 86* 3 ELECTRONS IN MOLECULES: DIATORNICS 91* 3.1 INTRODUCING
MOLECULAR ORBITALS 92* 3.2 H2. HE2 AND THEIR IONS 104* 3.3 HOMONUCLEAR
DIATOMICS OF THE SECOND PERIOD 105* 3.4 PHOTOELECTRON SPECTRA 125* 3.5
HETERONUCLEAR DIATOMICS 126* 3.6 MOVING ON 134* FURTHER READING 135* XIV
CONTENTS OUESTIONS 135* 4 ELECTRONS IN RNOLECULES: POLYATORNICS 137* 4.1
THE SIMPLEST TRIATOMIC: H; 138* 4.2 MORE COMPLEX LINEAR TRIATOMICS 144*
4.3 MOS OF WATER AND METHANE 146* 4.4 HYBRID ATOMIC ORBITALS 150* 4.5
COMPARING THE HYBRID AND FULL MO APPROACHES 156* 4.6 EXTENDING THE
HYBRID CONCEPT 159* 4.7* BONDING IN ORGANIC MOLECULES 162* 4.8
DELOCALIZED BONDING 165* 4.9 DELOCALIZED STRUCTURES INCLUDING
HETEROATOMS 173* 4.10 MOVING ON 176* FURTHER READING 176* OUESTIONS 176*
5 BONDING IN SOLIDS 179* 5.1 METALLIC BONDING: INTRODUCING BANDS 180*
5.2 LONIC SOLIDS 189* 5.3 MOVING ON 197* FURTHER READING 197* OUESTIONS
198* 6 THERMODYNAMICS AND THE SECOND LAW 201* 6.1 SPONTANEOUS PROCESSES
202* 6.2 PROPERTIES OF MATTER: STATE FUNCTIONS 204* 6.3 ENTROPY AND THE
SECOND LAW 205* 6.4 HEAT, INTERNAL ENERGY AND ENTHALPY 212* 6.5 ENTROPY
IN TERMS OF HEAT 214* 6.6 CALCULATING THE ENTROPY CHANGE OF THE UNIVERSE
217* 6.7 GIBBS ENERGY 220* 6.8 CHEMICAL EQUILIBRIUM 222* 6.9 FINDING THE
STANDARD GIBBS ENERGY CHANGE 227* 6.10 INTERPRETING THE VALUE OF ~RGO
233* 6.11 ~RHO AND ~RS FOR REACTIONS NOT INVOLVING IONS 235* 6.12
~RHO AND ~RSO FOR REACTIONS INVOLVING IONS IN SOLUTION 238* 6.13
APPLICATIONS 241* 6.14 ACIDITY, BASICITY AND PK A 245* 6.15 HOW MUCH
PRODUCT IS THERE AT EQUILIBRIUM? 252* 6.16 MOVING ON 257* FURTHER
READING 257* OUESTIONS 258* CONTENTS XV* 7 TRENDS IN BONDING 261* 7.1
ELECTRONIC CONFIGURATION AND THE PERIODIC TABLE 262* 7.2 ORBITAL
ENERGIES AND EFFECTIVE NUCLEAR CHARGES 265* 7.3 ATOMIC SIZES ACROSS THE
PERIODIC TABLE 273* 7.4 LONIZATION ENERGIES AND ELECTRON AFFINITIES 276*
7.5 SUMMARY OF THE TRENDS IN ORBITAL ENERGIES AND SIZES 281* 7.6 BONDING
IN THE ELEMENTS - NON-METALS 281* 7.7 METALLIC STRUCTURES 289* 7.8 THE
TRANSITION FROM METALS TO NON-METALS 294* 7.9 BONDING BETWEEN THE
ELEMENTS 297* 7.10 OXIDATION STATES 303* 7.11 MOVING ON 306* FURTHER
READING 306* OUESTIONS 306* 8 DESCRIBING REACTIONS USING ORBITALS 311*
8.1 THE REDISTRIBUTION OF ELECTRONS IN AREACTION 311* 8.2 HOMO-LUMO
INTERACTIONS 315* 8.3 INTERACTIONS INVOLVING NONBONDING LUMOS 318* 8.4
INTERACTIONS INVOLVING 1F ANTIBONDING LUMOS 323* 8.5 INTERACTIONS
INVOLVING ER ANTIBONDING LUMOS 326* 8.6 SUMMARY OF THE EFFECTS OF
DIFFERENT HOMO-LUMO INTERACTIONS 328* 8.7 THE ROLE OF PROTONATION IN
REACTIONS 329* 8.8 INTRAMOLECULAR ORBITAL INTERACTIONS 331* 8.9
REARRANGEMENT REACTIONS 333* 8.10 MOVING ON 335* OUESTIONS 336* 9
ORGANIC CHEMISTRY 1: FUNCTIONAL GROUPS 339* 9.1 FUNCTIONAL GROUPS 340*
9.2 CHANGING FUNCTIONAL GROUP LEVEL 345* 9.3 LEVEL TWO TO LEVEL ONE -
CARBONYL ADDITION REACTIONS 350* 9.4 TRANSFORMATIONS WITHIN FUNCTIONAL
GROUP LEVEL TWO 355* 9.5 TRANSFORMATIONS WITHIN FUNCTIONAL GROUP LEVEL
THREE 365* 9.6 MOVING DOWN FROM FUNCTIONAL GROUP LEVEL THREE 382* 9.7
TRANSFORMATIONS WITHIN LEVEL ONE 390* FURTHER READING 403* OUESTIONS
403* 10 THE RATES OF REACTIONS 409* 10.1 THE RATE OF AREACTION 410* 10.2
RATE LAWS 412* 10.3 TEMPERATURE DEPENDENCE 415* 10.4 THE ENERGY BARRIER
TO REACTION 416* 10.5 ELEMENTARY REACTIONS AND REACTION MECHANISMS 419*
10.6 REACTIONS IN SOLUTION 421* XVI CONTENTS 10.7 SEQUENTIAL REACTIONS
422* 10.8 ANALYSING THE KINETICS OF COMPLEX MECHANISMS 428* 10.9 CHAIN
REACTIONS 434* FURTHER READING 439* OUESTIONS 440* PART 11 GOING FURTHER
11 SPECTROSCOPY 447* 11 .1 MASS SPECTROMETRY 448* 11.2 SPECTROSCOPY AND
ENERGY LEVELS 458* 11.3 IR SPECTROSCOPY - INTRODUCTION 461* 11.4
INTERPRETING IR SPECTRA 469* 11.5 NUCLEAR MAGNETIC RESONANCE (F LMR)
477* 11.6 COUPLING IN NMR 487* 11.7 MORE COMPLICATED COUPLING PATTERNS -
PROTON NMR 499* FURTHER READING 5OE9* OUESTIONS 509* 12 ORGANIC CHEMISTRY
2: THREE-DIRNENSIONAL SHAPES 519* 12.1 THE RELATIONSHIPS BETWEEN ISOMERS
520* 12.2 THE EFFECT OF ROTATIONS ABOUT BONDS 523* 12.3 ISOMERISM IN
ALKENES 528* 12.4 ENANTIOMERS AND CHIRALITY 530* 12.5 SYMMETRY AND
CHIRALITY 539* 12.6 THE CONFORMATION OF CYCLIC MOLECULES 542* 12.7
MOVING ON 553* FURTHER READING 553* OUESTIONS 554* 13 ORGANIC CHEMISTRY
3: REACTIONS OF 1F SYSTEMS 557* 13.1 ELIMINATION REACTIONS - THE
FORMATION OF ALKENES 559* 13.2 ELECTROPHILIC ADDITION TO ALKENES 568*
13.3 ENOLS AND ENOLATES 580* 13.4 THE REACTIONS OF ENOLS AND ENOLATES
586* 13.5 INTRODUCTION TO AROMATIC SYSTEMS 593* FURTHER READING 607*
OUESTIONS 607* 14 MAIN-GROUP CHEMISTRY 611* 14.1 OVERVIEW 612* 14.2 KEY
CONCEPTS IN MAIN-GROUP CHEMISTRY 614* 14.3 HYDROLYSIS OF CHLORIDES 622*
14.4 OXIDES 630* 14.5 BRIEF SURVEY OF THE CHEMISTRY OF EACH GROUP 631*
CONTENTS XVII* 14.6 MOVING ON* 644* FURTHER READING* 644* QUESTIONS*
645* 15* TRANSITION METALS 649* 15.1 ORBITAL ENERGIES AND OXIDATION
STATES 651* 15.2 COMPLEXES 654* 15.3 BONDING IN OETAHEDRAL EOMPLEXES
656* 15.4 HIGH-SPIN AND LOW-SPIN OETAHEDRAL EOMPLEXES 663* 15.5 MAGNETIE
AND SPEETROSEOPIE PROPERTIES OF EOMPLEXES 666* 15.6 CONSEQUENEES OF THE
SPLITTING OF THE D ORBITALS 669* 15.7 TETRAHEDRAL AND SQUARE-PLANAR
EOMPLEXES 672* 15.8 CRYSTAL-FIE!D THEORY 674* 15.9 ORGANOMETALLIE
EOMPLEXES 675* 15.10 AQUEOUS EHEMISTRY AND OXOANIONS 681* 15.11 MOVING
ON 684* FURTHER READING 684* QUESTIONS 685* 16 QUANTUM MECHANICS AND
SPECTROSCOPY* 689* 16.1 THE POSTULATES OF QUANTUM MEEHANIES* 691* 16.2 A
FREE PARTICLE MOVING IN ONE DIMENSION* 697* 16.3 PARTICLE IN A BOX* 701*
16.4 PARTICLE IN A TWO-DIMENSIONAL SQUARE WEIL* 710* 16.5 THE HARMONIE
OSEILLATOR* 711* 16.6 SPEETROSEOPY AND ENERGY LEVELS* 719* 16.7 THE IR
SPEETRUM OF A DIATOMIE* 722* 16.8 VIBRATIONS OF LARGER MOLEEULES* 731*
16.9 RAMAN SPEETROSEOPY* 733* 16.10 SUMMARY OF THE FEATURES OF
VIBRATIONAL SPEETROSEOPY 735* 16.11 THE RIGID ROTOR* 736* 16.12 THE
MIEROWAVE SPEETNIM OF A DIATOMIE* 737* 16.13 VIBRATION-ROTATION SPEETRUM
OF A DIATOMIE* 743* 16.14 THE HYDROGEN ATOM* 747* 16.15 ELEETRONIE
TRANSITIONS 749* FURTHER READING 751* QUESTIONS 751* 17 CHEMICAL
THERMODYNAMICS* 755* 17.1 THEFIRSTLAW* 756* 17.2 WORK OF GAS EXPANSIONS*
759* 17.3 INTERNAL ENERGY, ENTHALPY AND HEAT EAPAEITY* 766* 17.4 THE
GIBBS ENERGY* 771* 17.5 THE MIXING OF IDEAL GASES* 774* 17.6 CHEMIEAL
EQUILIBRIUM* 776* 17.7 EQUILIBRIA INVOLVING OTHER THAN GASES* 783* XVIII
CONTENTS 17.8 DETERMINATION OT THE STANDARD GIBBS ENERGY CHANGE 785*
17.9 THE TEMPERATURE DEPENDENEE OT THE EQUILIBRIUM EONSTANT 788* 17.10
DETERMINATION OT ABSOLUTE ENTROPIES 792* FURTHER READING 793* OUESTIONS
793* 18 CHEMICAL KINETICS 797* 18.1 MEASURING EONEENTRATION 798* 18.2
INTEGRATED RATE LAWS 805* 18.3 OTHER METHODS OT ANALYSING KINETIE DATA
814* 18.4 COLLISION THEORY 814* 18.5 POTENTIAL ENERGY SURFAEES 819* 18.6
TRANSITION STATE THEORY 821* FURTHER READING 825* OUESTIONS 825* 19
ELECTROCHEMISTRY 831* 19.1 ELEETROEHEMIEAL EELLS 832* 19.2 THERMODYNAMIE
PARAMETERS FROM EELL POTENTIALS 836* 19.3 THE NERNST EQUATION AND
STANDARD EELL POTENTIALS 839* 19.4 THE SPONTANEOUS EELL REAETION 846*
19.5 SUMMARY 846* 19.6 TYPES OF HALF EELLS 848* 19.7 ASSESSING REDOX
STABILITY USING ELEETRODE POTENTIALS 851* 19.8 THE LIMITS OF STABILITY
IN AQUEOUS SOLUTION 854* 19.9 USING EELL POTENTIALS TO DETERMINE
THERMODYNAMIE PARAMETERS 856* 19.10 OXIDATION STATE DIAGRAMS 861* 19.11
MEASUREMENT OF EONEENTRATION 866* FURTHER READING 869* OUESTIONS 870* 20
DIMENSIONS, UNITS AND SOME KEY MATHEMATICAL IDEAS 875* 20.1 DIMENSIONAL
ANALYSIS 876* ~2 U~ ~ 20.3 TRIGONOMETRIE FUNETIONS 890* 20.4 THE
EXPONENTIAL FUNETION 895* 20.5 CALEULUS: DIFFERENTIATION 900* 20.6
CALEULUS: INTEGRATION 905* 20.7 DIFFERENTIAL EQUATIONS 910* FURTHER
READING 912* ANSWERS TO SEIT TEST EXEREISES 912* OUESTIONS 913* INDEX
917* ORBITAL ENERGIES 925*
|
| adam_txt |
FULL CONTENTS PREFACE V* ONLINE RESOURCE CENTRE IX* PART I THE
FUNDAMENTALS 1 MOLECULAR STRUCTURES AND THE STATES OF MATTER 3* 1.1
TYPES OF BONDING 4* 1.2 WEAKER NON-BONDED INTERACTIONS 6* 1.3 SOLIDS 9*
1.4 STRUCTURE DETERMINATION BY X-RAY DIFFRACTION 10* 1.5 WHERE ARE THE
BONDS? 13* 1.6 HOW TO DRAW MOLECULES 15* 1.7 COMMON NAMES AND
ABBREVIATIONS 17* 1.8 PREDICTING THE SHAPES OF MOLECULES USING VSEPR 18*
1.9 THE IDEAL GAS 22* 1.10 MOLECULAR ENERGY LEVELS 26* 1.11 MOVING ON
29* QUESTIONS 29* 2 ELECTRONS IN ATOMS 35* 2.1 INTRODUCING QUANTUM
MECHANICS 36* 2.2 INTRODUCING ORBITALS 39* 2.3 HYDROGEN ATOMIC ORBITALS
44* 2.4 SPIN 63* 2.5 HYDROGEN-LIKE ATOMS 65* 2.6 MULTI-ELECTRON ATOMS
65* 2.7 LONIZATION ENERGIES 80* 2.8 MOVING ON 85* FURTHER READING 86*
QUESTIONS 86* 3 ELECTRONS IN MOLECULES: DIATORNICS 91* 3.1 INTRODUCING
MOLECULAR ORBITALS 92* 3.2 H2. HE2 AND THEIR IONS 104* 3.3 HOMONUCLEAR
DIATOMICS OF THE SECOND PERIOD 105* 3.4 PHOTOELECTRON SPECTRA 125* 3.5
HETERONUCLEAR DIATOMICS 126* 3.6 MOVING ON 134* FURTHER READING 135* XIV
CONTENTS OUESTIONS 135* 4 ELECTRONS IN RNOLECULES: POLYATORNICS 137* 4.1
THE SIMPLEST TRIATOMIC: H; 138* 4.2 MORE COMPLEX LINEAR TRIATOMICS 144*
4.3 MOS OF WATER AND METHANE 146* 4.4 HYBRID ATOMIC ORBITALS 150* 4.5
COMPARING THE HYBRID AND FULL MO APPROACHES 156* 4.6 EXTENDING THE
HYBRID CONCEPT 159* 4.7* BONDING IN ORGANIC MOLECULES 162* 4.8
DELOCALIZED BONDING 165* 4.9 DELOCALIZED STRUCTURES INCLUDING
HETEROATOMS 173* 4.10 MOVING ON 176* FURTHER READING 176* OUESTIONS 176*
5 BONDING IN SOLIDS 179* 5.1 METALLIC BONDING: INTRODUCING BANDS 180*
5.2 LONIC SOLIDS 189* 5.3 MOVING ON 197* FURTHER READING 197* OUESTIONS
198* 6 THERMODYNAMICS AND THE SECOND LAW 201* 6.1 SPONTANEOUS PROCESSES
202* 6.2 PROPERTIES OF MATTER: STATE FUNCTIONS 204* 6.3 ENTROPY AND THE
SECOND LAW 205* 6.4 HEAT, INTERNAL ENERGY AND ENTHALPY 212* 6.5 ENTROPY
IN TERMS OF HEAT 214* 6.6 CALCULATING THE ENTROPY CHANGE OF THE UNIVERSE
217* 6.7 GIBBS ENERGY 220* 6.8 CHEMICAL EQUILIBRIUM 222* 6.9 FINDING THE
STANDARD GIBBS ENERGY CHANGE 227* 6.10 INTERPRETING THE VALUE OF ~RGO
233* 6.11 ~RHO AND ~RS' FOR REACTIONS NOT INVOLVING IONS 235* 6.12
~RHO AND ~RSO FOR REACTIONS INVOLVING IONS IN SOLUTION 238* 6.13
APPLICATIONS 241* 6.14 ACIDITY, BASICITY AND PK A 245* 6.15 HOW MUCH
PRODUCT IS THERE AT EQUILIBRIUM? 252* 6.16 MOVING ON 257* FURTHER
READING 257* OUESTIONS 258* CONTENTS XV* 7 TRENDS IN BONDING 261* 7.1
ELECTRONIC CONFIGURATION AND THE PERIODIC TABLE 262* 7.2 ORBITAL
ENERGIES AND EFFECTIVE NUCLEAR CHARGES 265* 7.3 ATOMIC SIZES ACROSS THE
PERIODIC TABLE 273* 7.4 LONIZATION ENERGIES AND ELECTRON AFFINITIES 276*
7.5 SUMMARY OF THE TRENDS IN ORBITAL ENERGIES AND SIZES 281* 7.6 BONDING
IN THE ELEMENTS - NON-METALS 281* 7.7 METALLIC STRUCTURES 289* 7.8 THE
TRANSITION FROM METALS TO NON-METALS 294* 7.9 BONDING BETWEEN THE
ELEMENTS 297* 7.10 OXIDATION STATES 303* 7.11 MOVING ON 306* FURTHER
READING 306* OUESTIONS 306* 8 DESCRIBING REACTIONS USING ORBITALS 311*
8.1 THE REDISTRIBUTION OF ELECTRONS IN AREACTION 311* 8.2 HOMO-LUMO
INTERACTIONS 315* 8.3 INTERACTIONS INVOLVING NONBONDING LUMOS 318* 8.4
INTERACTIONS INVOLVING 1F ANTIBONDING LUMOS 323* 8.5 INTERACTIONS
INVOLVING ER ANTIBONDING LUMOS 326* 8.6 SUMMARY OF THE EFFECTS OF
DIFFERENT HOMO-LUMO INTERACTIONS 328* 8.7 THE ROLE OF PROTONATION IN
REACTIONS 329* 8.8 INTRAMOLECULAR ORBITAL INTERACTIONS 331* 8.9
REARRANGEMENT REACTIONS 333* 8.10 MOVING ON 335* OUESTIONS 336* 9
ORGANIC CHEMISTRY 1: FUNCTIONAL GROUPS 339* 9.1 FUNCTIONAL GROUPS 340*
9.2 CHANGING FUNCTIONAL GROUP LEVEL 345* 9.3 LEVEL TWO TO LEVEL ONE -
CARBONYL ADDITION REACTIONS 350* 9.4 TRANSFORMATIONS WITHIN FUNCTIONAL
GROUP LEVEL TWO 355* 9.5 TRANSFORMATIONS WITHIN FUNCTIONAL GROUP LEVEL
THREE 365* 9.6 MOVING DOWN FROM FUNCTIONAL GROUP LEVEL THREE 382* 9.7
TRANSFORMATIONS WITHIN LEVEL ONE 390* FURTHER READING 403* OUESTIONS
403* 10 THE RATES OF REACTIONS 409* 10.1 THE RATE OF AREACTION 410* 10.2
RATE LAWS 412* 10.3 TEMPERATURE DEPENDENCE 415* 10.4 THE ENERGY BARRIER
TO REACTION 416* 10.5 ELEMENTARY REACTIONS AND REACTION MECHANISMS 419*
10.6 REACTIONS IN SOLUTION 421* XVI CONTENTS 10.7 SEQUENTIAL REACTIONS
422* 10.8 ANALYSING THE KINETICS OF COMPLEX MECHANISMS 428* 10.9 CHAIN
REACTIONS 434* FURTHER READING 439* OUESTIONS 440* PART 11 GOING FURTHER
11 SPECTROSCOPY 447* 11 .1 MASS SPECTROMETRY 448* 11.2 SPECTROSCOPY AND
ENERGY LEVELS 458* 11.3 IR SPECTROSCOPY - INTRODUCTION 461* 11.4
INTERPRETING IR SPECTRA 469* 11.5 NUCLEAR MAGNETIC RESONANCE (F\LMR)
477* 11.6 COUPLING IN NMR 487* 11.7 MORE COMPLICATED COUPLING PATTERNS -
PROTON NMR 499* FURTHER READING 5OE9* OUESTIONS 509* 12 ORGANIC CHEMISTRY
2: THREE-DIRNENSIONAL SHAPES 519* 12.1 THE RELATIONSHIPS BETWEEN ISOMERS
520* 12.2 THE EFFECT OF ROTATIONS ABOUT BONDS 523* 12.3 ISOMERISM IN
ALKENES 528* 12.4 ENANTIOMERS AND CHIRALITY 530* 12.5 SYMMETRY AND
CHIRALITY 539* 12.6 THE CONFORMATION OF CYCLIC MOLECULES 542* 12.7
MOVING ON 553* FURTHER READING 553* OUESTIONS 554* 13 ORGANIC CHEMISTRY
3: REACTIONS OF 1F SYSTEMS 557* 13.1 ELIMINATION REACTIONS - THE
FORMATION OF ALKENES 559* 13.2 ELECTROPHILIC ADDITION TO ALKENES 568*
13.3 ENOLS AND ENOLATES 580* 13.4 THE REACTIONS OF ENOLS AND ENOLATES
586* 13.5 INTRODUCTION TO AROMATIC SYSTEMS 593* FURTHER READING 607*
OUESTIONS 607* 14 MAIN-GROUP CHEMISTRY 611* 14.1 OVERVIEW 612* 14.2 KEY
CONCEPTS IN MAIN-GROUP CHEMISTRY 614* 14.3 HYDROLYSIS OF CHLORIDES 622*
14.4 OXIDES 630* 14.5 BRIEF SURVEY OF THE CHEMISTRY OF EACH GROUP 631*
CONTENTS XVII* 14.6 MOVING ON* 644* FURTHER READING* 644* QUESTIONS*
645* 15* TRANSITION METALS 649* 15.1 ORBITAL ENERGIES AND OXIDATION
STATES 651* 15.2 COMPLEXES 654* 15.3 BONDING IN OETAHEDRAL EOMPLEXES
656* 15.4 HIGH-SPIN AND LOW-SPIN OETAHEDRAL EOMPLEXES 663* 15.5 MAGNETIE
AND SPEETROSEOPIE PROPERTIES OF EOMPLEXES 666* 15.6 CONSEQUENEES OF THE
SPLITTING OF THE D ORBITALS 669* 15.7 TETRAHEDRAL AND SQUARE-PLANAR
EOMPLEXES 672* 15.8 CRYSTAL-FIE!D THEORY 674* 15.9 ORGANOMETALLIE
EOMPLEXES 675* 15.10 AQUEOUS EHEMISTRY AND OXOANIONS 681* 15.11 MOVING
ON 684* FURTHER READING 684* QUESTIONS 685* 16 QUANTUM MECHANICS AND
SPECTROSCOPY* 689* 16.1 THE POSTULATES OF QUANTUM MEEHANIES* 691* 16.2 A
FREE PARTICLE MOVING IN ONE DIMENSION* 697* 16.3 PARTICLE IN A BOX* 701*
16.4 PARTICLE IN A TWO-DIMENSIONAL SQUARE WEIL* 710* 16.5 THE HARMONIE
OSEILLATOR* 711* 16.6 SPEETROSEOPY AND ENERGY LEVELS* 719* 16.7 THE IR
SPEETRUM OF A DIATOMIE* 722* 16.8 VIBRATIONS OF LARGER MOLEEULES* 731*
16.9 RAMAN SPEETROSEOPY* 733* 16.10 SUMMARY OF THE FEATURES OF
VIBRATIONAL SPEETROSEOPY 735* 16.11 THE RIGID ROTOR* 736* 16.12 THE
MIEROWAVE SPEETNIM OF A DIATOMIE* 737* 16.13 VIBRATION-ROTATION SPEETRUM
OF A DIATOMIE* 743* 16.14 THE HYDROGEN ATOM* 747* 16.15 ELEETRONIE
TRANSITIONS 749* FURTHER READING 751* QUESTIONS 751* 17 CHEMICAL
THERMODYNAMICS* 755* 17.1 THEFIRSTLAW* 756* 17.2 WORK OF GAS EXPANSIONS*
759* 17.3 INTERNAL ENERGY, ENTHALPY AND HEAT EAPAEITY* 766* 17.4 THE
GIBBS ENERGY* 771* 17.5 THE MIXING OF IDEAL GASES* 774* 17.6 CHEMIEAL
EQUILIBRIUM* 776* 17.7 EQUILIBRIA INVOLVING OTHER THAN GASES* 783* XVIII
CONTENTS 17.8 DETERMINATION OT THE STANDARD GIBBS ENERGY CHANGE 785*
17.9 THE TEMPERATURE DEPENDENEE OT THE EQUILIBRIUM EONSTANT 788* 17.10
DETERMINATION OT ABSOLUTE ENTROPIES 792* FURTHER READING 793* OUESTIONS
793* 18 CHEMICAL KINETICS 797* 18.1 MEASURING EONEENTRATION 798* 18.2
INTEGRATED RATE LAWS 805* 18.3 OTHER METHODS OT ANALYSING KINETIE DATA
814* 18.4 COLLISION THEORY 814* 18.5 POTENTIAL ENERGY SURFAEES 819* 18.6
TRANSITION STATE THEORY 821* FURTHER READING 825* OUESTIONS 825* 19
ELECTROCHEMISTRY 831* 19.1 ELEETROEHEMIEAL EELLS 832* 19.2 THERMODYNAMIE
PARAMETERS FROM EELL POTENTIALS 836* 19.3 THE NERNST EQUATION AND
STANDARD EELL POTENTIALS 839* 19.4 THE SPONTANEOUS EELL REAETION 846*
19.5 SUMMARY 846* 19.6 TYPES OF HALF EELLS 848* 19.7 ASSESSING REDOX
STABILITY USING ELEETRODE POTENTIALS 851* 19.8 THE LIMITS OF STABILITY
IN AQUEOUS SOLUTION 854* 19.9 USING EELL POTENTIALS TO DETERMINE
THERMODYNAMIE PARAMETERS 856* 19.10 OXIDATION STATE DIAGRAMS 861* 19.11
MEASUREMENT OF EONEENTRATION 866* FURTHER READING 869* OUESTIONS 870* 20
DIMENSIONS, UNITS AND SOME KEY MATHEMATICAL IDEAS 875* 20.1 DIMENSIONAL
ANALYSIS 876* ~2 U~ ~ 20.3 TRIGONOMETRIE FUNETIONS 890* 20.4 THE
EXPONENTIAL FUNETION 895* 20.5 CALEULUS: DIFFERENTIATION 900* 20.6
CALEULUS: INTEGRATION 905* 20.7 DIFFERENTIAL EQUATIONS 910* FURTHER
READING 912* ANSWERS TO SEIT TEST EXEREISES 912* OUESTIONS 913* INDEX
917* ORBITAL ENERGIES 925* |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Keeler, James Wothers, Peter |
| author_GND | (DE-588)137339577 |
| author_facet | Keeler, James Wothers, Peter |
| author_role | aut aut |
| author_sort | Keeler, James |
| author_variant | j k jk p w pw |
| building | Verbundindex |
| bvnumber | BV035133448 |
| classification_rvk | VC 5010 VE 5300 |
| classification_tum | CHE 600f |
| ctrlnum | (OCoLC)644277612 (DE-599)GBV56344973X |
| discipline | Chemie / Pharmazie Chemie |
| discipline_str_mv | Chemie / Pharmazie Chemie |
| edition | 1. publ. |
| format | Book |
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| genre | (DE-588)4123623-3 Lehrbuch gnd-content |
| genre_facet | Lehrbuch |
| id | DE-604.BV035133448 |
| illustrated | Illustrated |
| index_date | 2024-07-02T22:25:13Z |
| indexdate | 2024-07-09T21:23:04Z |
| institution | BVB |
| isbn | 0199289301 9780199289301 |
| language | English |
| lccn | 2008299730 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016800928 |
| oclc_num | 644277612 |
| open_access_boolean | |
| owner | DE-703 DE-91G DE-BY-TUM DE-11 DE-12 DE-188 DE-210 |
| owner_facet | DE-703 DE-91G DE-BY-TUM DE-11 DE-12 DE-188 DE-210 |
| physical | XVIII, 925 S. Ill., graph. Darst. 26cm |
| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | Oxford Univ. Press |
| record_format | marc |
| spelling | Keeler, James Verfasser aut Chemical structure and reactivity an integrated approach James Keeler ; Peter Wothers 1. publ. Oxford [u.a.] Oxford Univ. Press 2008 XVIII, 925 S. Ill., graph. Darst. 26cm txt rdacontent n rdamedia nc rdacarrier Literaturangaben Chemical structure Reactivity (Chemistry) Chemical structure - LCSH Reactivity (Chemistry) - LCSH Chemische Reaktion (DE-588)4009853-9 gnd rswk-swf Chemische Struktur (DE-588)4009857-6 gnd rswk-swf Thermochemie (DE-588)4078260-8 gnd rswk-swf Chemische Bindung (DE-588)4009843-6 gnd rswk-swf Reaktivität (DE-588)4208182-8 gnd rswk-swf Organische Chemie (DE-588)4043793-0 gnd rswk-swf Physikalische Chemie (DE-588)4045959-7 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Organische Chemie (DE-588)4043793-0 s Physikalische Chemie (DE-588)4045959-7 s DE-604 Chemische Struktur (DE-588)4009857-6 s Chemische Bindung (DE-588)4009843-6 s Reaktivität (DE-588)4208182-8 s Thermochemie (DE-588)4078260-8 s Chemische Reaktion (DE-588)4009853-9 s Wothers, Peter Verfasser (DE-588)137339577 aut OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016800928&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Keeler, James Wothers, Peter Chemical structure and reactivity an integrated approach Chemical structure Reactivity (Chemistry) Chemical structure - LCSH Reactivity (Chemistry) - LCSH Chemische Reaktion (DE-588)4009853-9 gnd Chemische Struktur (DE-588)4009857-6 gnd Thermochemie (DE-588)4078260-8 gnd Chemische Bindung (DE-588)4009843-6 gnd Reaktivität (DE-588)4208182-8 gnd Organische Chemie (DE-588)4043793-0 gnd Physikalische Chemie (DE-588)4045959-7 gnd |
| subject_GND | (DE-588)4009853-9 (DE-588)4009857-6 (DE-588)4078260-8 (DE-588)4009843-6 (DE-588)4208182-8 (DE-588)4043793-0 (DE-588)4045959-7 (DE-588)4123623-3 |
| title | Chemical structure and reactivity an integrated approach |
| title_auth | Chemical structure and reactivity an integrated approach |
| title_exact_search | Chemical structure and reactivity an integrated approach |
| title_exact_search_txtP | Chemical structure and reactivity an integrated approach |
| title_full | Chemical structure and reactivity an integrated approach James Keeler ; Peter Wothers |
| title_fullStr | Chemical structure and reactivity an integrated approach James Keeler ; Peter Wothers |
| title_full_unstemmed | Chemical structure and reactivity an integrated approach James Keeler ; Peter Wothers |
| title_short | Chemical structure and reactivity |
| title_sort | chemical structure and reactivity an integrated approach |
| title_sub | an integrated approach |
| topic | Chemical structure Reactivity (Chemistry) Chemical structure - LCSH Reactivity (Chemistry) - LCSH Chemische Reaktion (DE-588)4009853-9 gnd Chemische Struktur (DE-588)4009857-6 gnd Thermochemie (DE-588)4078260-8 gnd Chemische Bindung (DE-588)4009843-6 gnd Reaktivität (DE-588)4208182-8 gnd Organische Chemie (DE-588)4043793-0 gnd Physikalische Chemie (DE-588)4045959-7 gnd |
| topic_facet | Chemical structure Reactivity (Chemistry) Chemical structure - LCSH Reactivity (Chemistry) - LCSH Chemische Reaktion Chemische Struktur Thermochemie Chemische Bindung Reaktivität Organische Chemie Physikalische Chemie Lehrbuch |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016800928&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT keelerjames chemicalstructureandreactivityanintegratedapproach AT wotherspeter chemicalstructureandreactivityanintegratedapproach |