Verfügbarkeit: Materials for engineers

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Bibliographische Detailangaben
1. Verfasser:	Hosford, William F. 1928- (VerfasserIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	Cambridge [u.a.] Cambridge Univ. Press 2008
Schlagworte:	Matériaux Matériaux - Propriétés mécaniques Matériaux - Propriétés électriques Materials > Textbooks Werkstoffkunde
Online-Zugang:	Contributor biographical information Publisher description Table of contents only Inhaltsverzeichnis
Beschreibung:	Includes bibliographical references and index
Beschreibung:	XV, 278 S. Ill., graph. Darst.
ISBN:	9780521899970

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Datensatz im Suchindex

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adam_text	Contents Preface page xv 1 Introduction ........................................1 Properties 1 Bonding 2 Types of Materials 3 Crystalline Materials 4 Amorphous Materials 6 Note of Interest 7 Problems 7 2 Phases ............................................8 What Is a Phase? 8 Phase Diagrams 8 Lever Law 9 Intermediate Phases 11 Invariant Reactions 12 Effects of Pressure 12 Solid Solutions 13 Grain Structure 14 Grain Size 14 Notes of Interest 15 Problems 16 3 Diffusion .........................................18 Fick s First Law 18 Fick s Second Law 18 Solutions of Fick s Second Law 19 Junction of Two Solid Solutions 20 Temperature Dependence of Diffusivity 21 Contents Diffusion in Systems with More than One Phase 22 Notes of Interest 26 Problems 26 4 Mechanical Behavior .................................28 Stress and Strain 28 Elasticity 28 Variation of Young s Modulus 30 Plastic Deformation 31 Strength Dependence on Grain Size 35 Solid Solution Strengthening 36 Cold Work 36 Hardness 38 Slip 38 Notes of Interest 39 Problems 40 5 Mechanical Failure ...................................42 Fracture 42 Creep 46 Fatigue 47 Toughness 53 Fracture Mechanics 54 Thermal Shock 55 Delayed Fracture 56 Notes of Interest 57 Problems 58 6 Annealing ........................................60 Stages of Annealing 60 Recovery 60 Recrystallization 60 Grain Growth 64 Note of Interest 66 Problems 66 7 Iron and Steel ......................................68 Steels 68 Pearlite Formation 69 Alloying Elements in Steel 70 Martensite Formation 71 Nature of Martensite 72 Hardenability 73 Quenching 76 Contents vii Tempering 77 Special Heat Treatments 78 Steel Classification System 79 Low-carbon Steels 80 Stainless Steels 81 Cast Iron 81 Notes of Interest 82 Problems 83 8 Nonferrous Metals ...................................85 Aluminum 85 Copper and Copper Alloys 89 Magnesium 91 Titanium 91 Nickel-base Alloys 92 Zinc 93 Notes of Interest 93 Problems 94 9 Casting and Welding ..................................95 Casting 95 Macrostructure of Castings 95 Dendrite Formation 96 Liquid-to-solid Shrinkage 96 Solid-state Shrinkage 98 Segregation 98 Gas Evolution 100 Casting Processes 100 Fusion Welding 101 Solid-state Welding 102 Notes of Interest 102 Problems 104 10 Solid Shaping ..................................------105 Bulk Forming 105 Hot Working vs. Cold Working 106 Sheet Forming 107 Note of Interest 109 Problems 109 11 Polymers .........................................110 Thermoplastics 110 Degree of Polymerization 110 Molecular Weight 111 viu Contents Branching ИЗ Cross-linking ИЗ Stereoisomerism 113 Copolymers 114 Molecular Configuration 115 Thermosetting Polymers 115 Addition Polymerization 116 Condensation Polymerization 117 Common Polymers 118 Glass Transition 118 Additives 120 Degradation 121 Properties and Uses of Polymers 121 Epoxies 124 Silicones 124 Notes of Interest 124 Problems 124 12 Polymer Processing ..................................125 Cooling 125 Injection Molding 125 Compression Molding 126 Transfer Molding 126 Bulk Extrusion 127 Blown Films and Blow Molding 128 Fiber Drawing and Rolling 128 Thermoforming 128 Foaming 129 Notes of Interest 129 Problems 129 13 Glasses .......................................... 130 Structure of Silicate Glasses 130 Chemical Compositions 131 Bridging and Non-bridging Oxygen Ions 131 Glass Viscosity 132 Thermally Induced Stresses 133 Vycor® 135 Devitrificaton 136 Photosensitive Glass 136 Other Inorganic Glasses 136 Residual Stresses 137 Contents ix Strength of Glasses 138 Shaping Glass 138 Metallic Glasses 139 Notes of Interest 141 Problems 141 14 Crystalline Ceramics .................................142 Ceramics 142 Slip Systems 142 Ionic Bonding 143 Hardness 143 Porosity 145 Variability of Strength 146 Toughening of Ceramics 147 Growth of Single Crystals 149 Notes of Interest 150 Problems 150 15 Powder Processing ..................................151 Powder Compaction 151 Sintering 151 Intermediate and Final Stages of Sintering 153 Loss of Surface Area 154 Particle Size Effect 154 Grain Growth 155 Activated Sintering 156 Liquid Phase Sintering 157 Hot Isostatic Pressing 158 Note of Interest 158 Problems 158 16 Pottery and Concrete ................................160 Clay 160 Processing of Clay Products 160 Forms of Pottery 162 Hydration Reactions 162 Portland Cement 163 Concrete Mixes 164 Asphalt Concrete 165 Notes of Interest 165 Problems 165 Contents 17 Composites .......................................166 Fiber-reinforced Composites 166 Elastic Behavior of Fiber-reinforced Composites 166 Strength of Fiber-reinforced Composites 170 Volume Fraction Fibers 171 Fiber Length 172 Failures with Discontinuous Fibers 172 Typical Properties 173 Particulate Composites 173 Lamellar Composites 175 Notes of Interest 176 Problems 176 18 Carbon ..........................................178 Diamond 178 Graphite 179 Carbon Fibers 180 Amorphous Carbon 180 Fullerenes 181 Nanotubes 181 Notes of Interest 182 Problems 183 19 Fibers, Foams, and Porous Materials ......................184 Fibers 184 Fabrication of Porous Foams 185 Morphology of Foams 185 Mechanical Properties of Foams 186 Honeycombs 187 Application of Porous Materials 187 Notes of Interest 187 Problems 188 20 Electrical Properties .................................189 Conductivity 189 Metallic Conduction 190 Ionic Conduction 192 Energy Bands 193 Intrinsic Semiconduction 194 Extrinsic Semiconduction 196 III-V Semiconductors 198 п -p Rectifiers 199 Transistors 200 Dielectric Properties 200 Contents xi Piezoelectric Behavior 203 Notes of Interest 204 Problems 205 21 Optical and Thermal Properties .........................206 Spectrum of Electomagnetic Radiation 206 Index of Refraction 207 Reflectivity 209 Absorption 209 Opacity 210 Luminescence 210 Light-emitting Diodes (LEDs) 211 Photovoltaic Cells 211 Lasers 211 Fiber Optics 211 Thermal Expansion 212 Thermal Conductivity 212 Specific Heats 214 Latent Heats of Transformation 214 Thermocouples 214 Notes of Interest 215 Problems 215 22 Magnetic Materials ..................................216 Ferromagnetism 216 Domains 216 Saturation Magnetization 217 Ceramic Magnets 218 The B -Н Curve 219 Soft Magnetic Materials 220 Hard Magnetic Materials 220 Curie Temperature 221 Magnetic Memory Storage 221 Notes of Interest 222 Problems 222 23 Corrosion ........................................224 Aqueous Corrosion 224 Passivity 227 Corrosion Protection 227 Rust 228 Direct Oxidation 228 Notes of Interest 229 Problems 230 xii Contents 24 Modem Manufacturing Techniques, Surface Treatments, and Recycling .....................................231 Two-dimensional Photolithography 231 Photo-stereolithography 232 Laser Beams 232 Electron Beams 233 Electrical Discharge Machining 233 Plasma Coating 233 Ion Implantation 234 Recycling of Metals 234 Recycling Plastics 235 Recycling Glass and Paper 236 Notes of Interest 237 Problems 237 APPENDIX 1: Wood .........................................239 Structure 239 Dimensional Changes with Moisture 240 Anisotropy of Properties 242 Plywood 242 Notes of Interest 242 Problems 243 APPENDIX 2: Miller Indices for Planes and Directions ...................244 Planar Indices 244 Direction Indices 244 Families of Planes and Directions 245 Notes of Interest 245 Problem 246 APPENDIX 3: X-ray Diffraction ..................................247 Note of Interest 247 Problem 248 APPENDIX 4: Surfaces ........................................249 Relation of Surface Energy to Bonding 249 Grain Boundaries 250 Segregation to Surfaces 250 Measurements of Relative Surface Energies 251 Surfaces of Amorphous Materials 252 Note of Interest 252 Problems 253 APPENDIX 5: Dislocations .....................................254 Edge and Screw Dislocations 254 Stress Fields 256 Contents xiii Note of Interest 257 Problems 257 APPENDIX 6: Avrami Kinetics ..................................258 Avrami Kinetics 258 Note of Interest 260 Problems 260 APPENDIX 7: Organic Chemistry .................................261 Bonds 261 Bond Energies 261 Bond Angles 262 Note of Interest 263 Problems 264 APPENDIX 8: Average Molecular Weight ...........................265 Molecular Weights 265 Note of Interest 266 Problems 266 APPENDIX 9: Bond Geometry in Compounds ........................267 Coordination 267 Ionic Radii 269 Note of Interest 270 Problems 270 APPENDIX 10: Weibull Analysis .................................271 Weibull Analysis 271 Note of Interest 273 Problem 273 Index 275
adam_txt	Contents Preface page xv 1 Introduction .1 Properties 1 Bonding 2 Types of Materials 3 Crystalline Materials 4 Amorphous Materials 6 Note of Interest 7 Problems 7 2 Phases .8 What Is a Phase? 8 Phase Diagrams 8 Lever Law 9 Intermediate Phases 11 Invariant Reactions 12 Effects of Pressure 12 Solid Solutions 13 Grain Structure 14 Grain Size 14 Notes of Interest 15 Problems 16 3 Diffusion .18 Fick's First Law 18 Fick's Second Law 18 Solutions of Fick's Second Law 19 Junction of Two Solid Solutions 20 Temperature Dependence of Diffusivity 21 Contents Diffusion in Systems with More than One Phase 22 Notes of Interest 26 Problems 26 4 Mechanical Behavior .28 Stress and Strain 28 Elasticity 28 Variation of Young's Modulus 30 Plastic Deformation 31 Strength Dependence on Grain Size 35 Solid Solution Strengthening 36 Cold Work 36 Hardness 38 Slip 38 Notes of Interest 39 Problems 40 5 Mechanical Failure .42 Fracture 42 Creep 46 Fatigue 47 Toughness 53 Fracture Mechanics 54 Thermal Shock 55 Delayed Fracture 56 Notes of Interest 57 Problems 58 6 Annealing .60 Stages of Annealing 60 Recovery 60 Recrystallization 60 Grain Growth 64 Note of Interest 66 Problems 66 7 Iron and Steel .68 Steels 68 Pearlite Formation 69 Alloying Elements in Steel 70 Martensite Formation 71 Nature of Martensite 72 Hardenability 73 Quenching 76 Contents vii Tempering 77 Special Heat Treatments 78 Steel Classification System 79 Low-carbon Steels 80 Stainless Steels 81 Cast Iron 81 Notes of Interest 82 Problems 83 8 Nonferrous Metals .85 Aluminum 85 Copper and Copper Alloys 89 Magnesium 91 Titanium 91 Nickel-base Alloys 92 Zinc 93 Notes of Interest 93 Problems 94 9 Casting and Welding .95 Casting 95 Macrostructure of Castings 95 Dendrite Formation 96 Liquid-to-solid Shrinkage 96 Solid-state Shrinkage 98 Segregation 98 Gas Evolution 100 Casting Processes 100 Fusion Welding 101 Solid-state Welding 102 Notes of Interest 102 Problems 104 10 Solid Shaping .------105 Bulk Forming 105 Hot Working vs. Cold Working 106 Sheet Forming 107 Note of Interest 109 Problems 109 11 Polymers .110 Thermoplastics 110 Degree of Polymerization 110 Molecular Weight 111 viu Contents Branching ИЗ Cross-linking ИЗ Stereoisomerism 113 Copolymers 114 Molecular Configuration 115 Thermosetting Polymers 115 Addition Polymerization 116 Condensation Polymerization 117 Common Polymers 118 Glass Transition 118 Additives 120 Degradation 121 Properties and Uses of Polymers 121 Epoxies 124 Silicones 124 Notes of Interest 124 Problems 124 12 Polymer Processing .125 Cooling 125 Injection Molding 125 Compression Molding 126 Transfer Molding 126 Bulk Extrusion 127 Blown Films and Blow Molding 128 Fiber Drawing and Rolling 128 Thermoforming 128 Foaming 129 Notes of Interest 129 Problems 129 13 Glasses . 130 Structure of Silicate Glasses 130 Chemical Compositions 131 Bridging and Non-bridging Oxygen Ions 131 Glass Viscosity 132 Thermally Induced Stresses 133 Vycor® 135 Devitrificaton 136 Photosensitive Glass 136 Other Inorganic Glasses 136 Residual Stresses 137 Contents ix Strength of Glasses 138 Shaping Glass 138 Metallic Glasses 139 Notes of Interest 141 Problems 141 14 Crystalline Ceramics .142 Ceramics 142 Slip Systems 142 Ionic Bonding 143 Hardness 143 Porosity 145 Variability of Strength 146 Toughening of Ceramics 147 Growth of Single Crystals 149 Notes of Interest 150 Problems 150 15 Powder Processing .151 Powder Compaction 151 Sintering 151 Intermediate and Final Stages of Sintering 153 Loss of Surface Area 154 Particle Size Effect 154 Grain Growth 155 Activated Sintering 156 Liquid Phase Sintering 157 Hot Isostatic Pressing 158 Note of Interest 158 Problems 158 16 Pottery and Concrete .160 Clay 160 Processing of Clay Products 160 Forms of Pottery 162 Hydration Reactions 162 Portland Cement 163 Concrete Mixes 164 Asphalt Concrete 165 Notes of Interest 165 Problems 165 Contents 17 Composites .166 Fiber-reinforced Composites 166 Elastic Behavior of Fiber-reinforced Composites 166 Strength of Fiber-reinforced Composites 170 Volume Fraction Fibers 171 Fiber Length 172 Failures with Discontinuous Fibers 172 Typical Properties 173 Particulate Composites 173 Lamellar Composites 175 Notes of Interest 176 Problems 176 18 Carbon .178 Diamond 178 Graphite 179 Carbon Fibers 180 Amorphous Carbon 180 Fullerenes 181 Nanotubes 181 Notes of Interest 182 Problems 183 19 Fibers, Foams, and Porous Materials .184 Fibers 184 Fabrication of Porous Foams 185 Morphology of Foams 185 Mechanical Properties of Foams 186 Honeycombs 187 Application of Porous Materials 187 Notes of Interest 187 Problems 188 20 Electrical Properties .189 Conductivity 189 Metallic Conduction 190 Ionic Conduction 192 Energy Bands 193 Intrinsic Semiconduction 194 Extrinsic Semiconduction 196 III-V Semiconductors 198 п -p Rectifiers 199 Transistors 200 Dielectric Properties 200 Contents xi Piezoelectric Behavior 203 Notes of Interest 204 Problems 205 21 Optical and Thermal Properties .206 Spectrum of Electomagnetic Radiation 206 Index of Refraction 207 Reflectivity 209 Absorption 209 Opacity 210 Luminescence 210 Light-emitting Diodes (LEDs) 211 Photovoltaic Cells 211 Lasers 211 Fiber Optics 211 Thermal Expansion 212 Thermal Conductivity 212 Specific Heats 214 Latent Heats of Transformation 214 Thermocouples 214 Notes of Interest 215 Problems 215 22 Magnetic Materials .216 Ferromagnetism 216 Domains 216 Saturation Magnetization 217 Ceramic Magnets 218 The B -Н Curve 219 Soft Magnetic Materials 220 Hard Magnetic Materials 220 Curie Temperature 221 Magnetic Memory Storage 221 Notes of Interest 222 Problems 222 23 Corrosion .224 Aqueous Corrosion 224 Passivity 227 Corrosion Protection 227 Rust 228 Direct Oxidation 228 Notes of Interest 229 Problems 230 xii Contents 24 Modem Manufacturing Techniques, Surface Treatments, and Recycling .231 Two-dimensional Photolithography 231 Photo-stereolithography 232 Laser Beams 232 Electron Beams 233 Electrical Discharge Machining 233 Plasma Coating 233 Ion Implantation 234 Recycling of Metals 234 Recycling Plastics 235 Recycling Glass and Paper 236 Notes of Interest 237 Problems 237 APPENDIX 1: Wood .239 Structure 239 Dimensional Changes with Moisture 240 Anisotropy of Properties 242 Plywood 242 Notes of Interest 242 Problems 243 APPENDIX 2: Miller Indices for Planes and Directions .244 Planar Indices 244 Direction Indices 244 Families of Planes and Directions 245 Notes of Interest 245 Problem 246 APPENDIX 3: X-ray Diffraction .247 Note of Interest 247 Problem 248 APPENDIX 4: Surfaces .249 Relation of Surface Energy to Bonding 249 Grain Boundaries 250 Segregation to Surfaces 250 Measurements of Relative Surface Energies 251 Surfaces of Amorphous Materials 252 Note of Interest 252 Problems 253 APPENDIX 5: Dislocations .254 Edge and Screw Dislocations 254 Stress Fields 256 Contents xiii Note of Interest 257 Problems 257 APPENDIX 6: Avrami Kinetics .258 Avrami Kinetics 258 Note of Interest 260 Problems 260 APPENDIX 7: Organic Chemistry .261 Bonds 261 Bond Energies 261 Bond Angles 262 Note of Interest 263 Problems 264 APPENDIX 8: Average Molecular Weight .265 Molecular Weights 265 Note of Interest 266 Problems 266 APPENDIX 9: Bond Geometry in Compounds .267 Coordination 267 Ionic Radii 269 Note of Interest 270 Problems 270 APPENDIX 10: Weibull Analysis .271 Weibull Analysis 271 Note of Interest 273 Problem 273 Index 275
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