Verfügbarkeit: Theory of atomic spectra

Theory of atomic spectra:

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Vorheriger Titel:	Sobel'man, Igor' I. Atomic spectra and radiative transitions
1. Verfasser:	Sobel'man, Igor' I. 1927- (VerfasserIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	Oxford, UK Alpha Science Internat. 2006
Schlagworte:	Strahlungsübergang Atomspektrum
Online-Zugang:	Inhaltsverzeichnis
Beschreibung:	XII, 366 S. graph. Darst.
ISBN:	9781842652039 1842652036

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Datensatz im Suchindex

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adam_text	Contents Preface Parti Elementary Information on Atomic Spectra Chapter 1 The Hydrogen Spectrum 1.1 Schrödinger s Equation for the Hydrogen Atom .................... 3 1.1.1 Energy Levels ............................................. 3 1.1.2 Wave Functions ........................................... 5 1.2 Series Regularities ............................................... 7 1.2.1 Radiative Transition Selection Rules ......................... 7 1.2.2 Spectral Series of the Hydrogen Atom ....................... 8 1.2.3 Hydrogenlike Ions ......................................... 9 1.3 Fine Structure .................................................. 10 1.3.1 Velocity Dependence of Electron Mass ....................... 10 1.3.2 Spin-Orbit Interaction ...................................... 11 1.3.3 Fine Structure. Selection Rules .............................. 12 1.3.4 Lamb Shift ............................................... 15 Chapter 2 Systematics of the Spectra of Multielectron Atoms 2.1 Central Field ................................................... 16 2.1.1 Central Field Approximation ................................ 16 2.1.2 Parity of States ............................................ 18 2.1.3 Systematics of Electron States in a Central Field .............. 19 2.2 Electrostatic and Spin-Orbit Splitting in the LS Coupling Approximation ................................................. 20 2.2.1 Spectral Terms. LS Quantum Numbers ....................... 20 2.2.2 Fine Structure of Terms .................................... 21 2.2.3 Finding the Terms of Multielectron Configurations ............ 23 2.2.4 Radiative Transitions ....................................... 26 2.3 j j Coupling Approximation ...................................... 27 2.3.1 Various Coupling Schemes .................................. 27 2.3.2 Systematics of Electron States with j j Coupling ............... 29 viii Contents Chapter 3 Spectra of Multielectron Atoms 3.1 Periodic System of Elements ..................................... 32 3.2 Spectra of the Alkali Elements .................................... 34 3.2.1 Term Scheme ............................................. 34 3.2.2 Series Regularities ......................................... 37 3.2.3 Fine Structure ............................................. 37 3.2.4 Copper, Silver, and Gold Spectra ............................ 38 3.3 Spectra of the Alkaline Earth Elements ............................ 39 3.3.1 He Spectrum ..............!............................... 39 3.3.2 Spectra of the Alkaline Earth Elements ....................... 40 3.3.3 Zinc, Cadmium, and Mercury Spectra ........................ 42 3.4 Spectra of Elements with ρ Valence Electrons ...................... 42 3.4.1 One ρ Electron Outside Filled Shells ......................... 42 3.4.2 Configuration p2 .......................................... 43 3.4.3 Configuration рг .......................................... 44 3.4.4 Configuration p* .......................................... 45 3.4.5 Configuration p5 .......................................... 46 3.4.6 Configuration p6 .......................................... 46 3.5 Spectra of Elements with Unfilled d and f Shells .................... 48 3.5.1 Elements with Unfilled d Shells .............................. 48 3.5.2 Elements with Unfilled ƒ Shells .............................. 49 Partii Theory of Atomic Spectra Chapter 4 Angular Momenta 4.1 Angular Momentum Operator. Addition of Angular Momenta ....... 53 4.1.1 Angular Momentum Operator ............................... 53 4.1.2 Orbital Angular Momentum ................................ 54 4.1.3 Electron Spin ............................................. 54 4.1.4 Addition of Two Angular Momenta ......................... 55 4.1.5 Addition of Three or More Angular Momenta ................ 57 4.2 Angular Momentum Vector Addition Coefficients ................... 60 4.2.1 Clebsch-Gordan and Associated Coefficients .................. 60 4.2.2 Summary of Formulas for 3j Symbols ....................... 62 4.2.3 Racah W Coefficients and 6y Symbols ....................... 66 4.2.4 Summary of Formulas for 6y Symbols ....................... 70 4.2.5 9y Symbols ............................................... 72 4.3 Irreducible Tensor Operators ..................................... 74 Contents ix 4.3.1 Spherical Tensors.......................................... 74 4.3.2 Matrix Elements........................................... 76 4.3.3 Some Examples of Calculation of Reduced Matrix Elements ___ 78 4.3.4 Tensor Product of Operators ................................ 80 4.3.5 Matrix Elements with Coupled Angular Momenta ............. 84 4.3.6 Direct Product of Operators ................................ 86 Chapter 5 Systematics of the States of Multielectron Atoms 5.1 Wave Functions ................................................ 89 5.1.1 Central Field Approximation ................................ 89 5.1.2 Two-Electron Wave Functions in LSMLMS Representation ..... 90 5.1.3 Two-Electron Wave Functions in mm SMg Representation ..... 93 5.1.4 Multielectron Wave Functions in a Parentage Scheme Approximation ............................................ 96 5.1.5 Fractional Parentage Coefficients ............................ 96 5.1.6 Classification of Identical Terms of / Configuration According to Seniority (Seniority Number) ............................. 98 5.2 Matrix Elements of Symmetric Operators .......................... 106 5.2.1 Statement of the Problem .................................. 106 5.2.2 F Matrix Elements. Parentage Scheme Approximation .......... 108 5.2.3 F Matrix Elements. Equivalent Electrons ..................... 109 5.2.4 Q Matrix Elements. Parentage Scheme Approximation ......... Ill 5.2.5 Q Matrix Elements. Equivalent Electrons ..................... 113 5.2.6 Summary of Results ....................................... 115 5.3 Electrostatic Interaction in LS Coupling. Two-Electron Configuration . 115 5.3.1 Coulomb and Exchange Integrals ............................. 115 5.3.2 Configuration Mixing ...................................... 118 5.4 Electrostatic Interaction in LS Coupling. Multielectron Configuration . 120 5.4.1 Configurations / and / / .................................. 120 5.4.2 More Than Half Filled Shells ............................... 123 5.4.3 Filled (Closed) Shells ....................................... 123 5.4.4 Applicability of the Single-Configuration Approximation ....... 124 5.5 Multiplet Splitting in LS Coupling ................................ 126 5.5.1 Preliminary Remarks ....................................... 126 5.5.2 Lande Interval Rule ........................................ 126 5.5.3 One Electron Outside Closed Shells .......................... 128 5.5.4 Configuration / ........................................... 130 5.5.5 Parentage Scheme Approximation ........................... 132 5.5.6 Fine-Structure Splitting of Levels of He ...................... 133 5.5.7 Spin-Spin and Spin-Other Orbit Interactions .................. 139 5.6 jj Coupling .................................................... 141 5.6.1 Wave Functions ........................................... 141 5.6.2 Spin-Orbit and Electrostatic Interactions ...................... 143 x Contents 5.7 Intermediate Coupling and Other Types of Coupling ................ 144 5.7.1 Transformations Between LS and j j Coupling Schemes ......... 144 5.7.2 Intermediate Coupling ...................................... 147 5.7.3 jl Coupling ............................................... 152 5.7.4 Experimental Date ......................................... 153 5.7.5 Other Types of Coupling ................................... 154 Chapter 6 Hyperfine Structure of Spectral Lines 6.1 Nuclear Magnetic Dipole and Electric Quadrupole Moments .......... 156 6.1.1 Magnetic Moments ........................................ 156 6.1.2 Quadrupole Moments ...................................... 157 6.2 Hyperfine Splitting .............................................. 159 6.2.1 General Character of the Splitting ........................... 159 6.2.2 Calculation of the Hyperfine Splitting Constant A ............. 162 6.2.3 Calculation of the Hyperfine Splitting Constant В ............. 168 6.2.4 Radiative Transitions Between Hyperfine-Structure Components. 170 6.2.5 Isotope Shift of the Atomic Levels ........................... 170 Chapter 7 The Atom in an External Electric Field 7.1 Quadratic Stark Effect ........................................... 173 7.2 Hydrogenlike Levels. Linear Stark Effect .......................... 177 7.3 Inhomogeneous Field. Quadrupole Splitting ........................ 181 7.4 Time-Dependent Field ........................................... 183 7.4.1 Amplitude Modulation ..................................... 183 7.4.2 The Hydrogen Atom in a Rotating Electric Field .............. 187 Chapter 8 The Atom in an External Magnetic Field 8.1 Zeeman Effect .................................................. 189 8.2 Paschen-Back Effect ............................................ 194 8.2.1 Strong Field .............................................. 194 8.2.2 Splitting of Hyperfine Structure Components in a Magnetic Field 198 Chapter 9 Radiative Transitions 9.1 Electromagnetic Radiation ....................................... 200 9.1.1 Quantization of the Radiation Field ___,..................... 200 9.1.2 Radiative Transition Probabilities ............................ 201 9.1.3 Correspondence Principle for Spontaneous Emission ........... 202 9.1.4 Dipole Radiation .......................................... 203 Contents xi 9.1.5 Stimulated Emission and Absorption......................... 203 9.1.6 Effective Cross Sections of Absorption and Stimulated Emission 205 9.2 Electric Dipole Radiation ........................................ 205 9.2.1 Selection Rules, Polarization and Angular Distribution ......... 205 9.2.2 Oscillator Strengths and Line Strengths ....................... 208 9.2.3 LS Coupling Approximation. Relative Intensities of Multiplet Components .............................................. 211 9.2.4 One Electron Outside Closed Shell ........................... 213 9.2.5 Multielectron Configurations. Different Coupling Schemes ...... 214 9.2.6 Relative Intensities of Zeeman and Stark Components of Lines. . 215 9.3 Multipole Radiation ............................................. 216 9.3.1 Fields of Electric and Magnetic Multipole Moments ............ 216 9.3.2 Intensity of Multipole Radiation ............................. 220 9.3.3 Selection Rules ............................................ 222 9.3.4 Electric Multipole Radiation ................................ 223 9.3.5 Magnetic Dipole Radiation .................................. 225 9.3.6 Transitions Between Hyperfine Structure Components. Radio Emission from Hydrogen ................................... 227 9.4 Calculation of Radiative Transition Probabilities .................... 229 9.4.1 Approximate Methods ...................................... 229 9.4.2 Three Ways of Writing Formulas for Transition Probabilities ... 230 9.4.3 Theorems for Sums of Oscillator Strengths ................... 232 9.4.4 Semiempirical Methods of Calculating Oscillator Strengths ...... 235 9.4.5 Electric Dipole Transition Probabilities in the Coulomb Approximation ............................................ 236 9.4.6 Intercombination Transitions ................................ 237 9.5 Continuous Spectrum ............................................ 239 9.5.1 Classification of Processes ....................:............. 239 9.5.2 Photorecombination and Photoionization: General Expressions for Effective Cross Sections ................................. 239 9.5.3 Bremsstrahlung: General Expressions for Effective Cross Sections .................................................. 245 9.5.4 Radiation and Absorption Coefficients ....................... 248 9.5.5 Photorecombination and Photoionization: Hydrogenlike Atoms . 251 9.5.6 Photorecombination and Photoionization: Nonhydrogenlike Atoms .................................................... 255 9.5.7 Bremsstrahlung in a Coulomb Field .......................... 257 9.6 Formulas for Q Factors .......................................... 274 9.6.1 Symmetry and Sum Rules .................................. 274 9.6.2 LS Coupling. Allowed Transitions ........................... 275 9.6.3 jl Coupling ............................................... 279 9.7 Tables of Oscillator Strengths and Radiative Transition Probabilities .. 281 9.7.1 Transition Probabilities for the Hydrogen Atom ............... 281 9.7.2 Radiative Transition Probabilities in the Bates-Damgaard Approximation ............................................ 283 x» Contents 9.7.3 Oscillator Strengths and Probabilities of Some Selected Transitions .............................................. 284 9.7.4 Effective Cross Sections and Rates of Photorecombination ... 284 Chapter 10 Relativistic Corrections in the Spectroscopy of Multkharged Ions 10.1 Dirac Equation. Pauli Equation ................................. 303 10.1.1 Dirac Equation .......................................... 303 10.1.2 Electron Spin ........................................... 305 10.1.3 Non-Relativistic Approximation. Pauli Equation ............. 308 10.2 Central Field .................................................. 310 10.2.1 Non-Relativistic Approximation ........................... 310 10.2.2 Second Approximation with Respect to v/c. Fine Splitting ----- 313 10.2.3 Dirac Equation for a Central Field ........................ 316 10.2.4 Coulomb Field. Energy Levels, Fine Splitting ............... 319 10.2.5 Coulomb Field. Radial Functions .......................... 322 10.3 Relativistic Corrections ......................................... 325 10.3.1 Calculation of Some Radial Integrals ....................... 325 10.3.2 Hyperfine Splitting Constant A ............................ 326 10.3.3 Hyperfine Splitting Constant В ............................ 330 10.3.4 Nucleus Finite-Size Correction ............................. 331 10.3.5 Radiative Corrections. Lamb Shift ......................... 333 Chapter 11 Spectra of Multicharged Ions 11.1 Energy Levels ................................................. 339 11.2 Forbidden Transitions .......................................... 341 11.2.1 Н -like Ions ............................................. 342 11.2.2 He-like Ions ............................................ 342 11.3 Satellite Structure .............................................. 346 Chapter 12 The Negative Ion H . 12.1 Negative Ion ВГ. Electron Affinity ............................................................350 12.2 Photoabsorption by H~ .................................................... 35I Appendix ............................................................. References ............................................................ 3^j List of Symbols ....................................................... 363 Subject Index ......................................................... 365
adam_txt	Contents Preface Parti Elementary Information on Atomic Spectra Chapter 1 The Hydrogen Spectrum 1.1 Schrödinger's Equation for the Hydrogen Atom . 3 1.1.1 Energy Levels . 3 1.1.2 Wave Functions . 5 1.2 Series Regularities . 7 1.2.1 Radiative Transition Selection Rules . 7 1.2.2 Spectral Series of the Hydrogen Atom . 8 1.2.3 Hydrogenlike Ions . 9 1.3 Fine Structure . 10 1.3.1 Velocity Dependence of Electron Mass . 10 1.3.2 Spin-Orbit Interaction . 11 1.3.3 Fine Structure. Selection Rules . 12 1.3.4 Lamb Shift . 15 Chapter 2 Systematics of the Spectra of Multielectron Atoms 2.1 Central Field . 16 2.1.1 Central Field Approximation . 16 2.1.2 Parity of States . 18 2.1.3 Systematics of Electron States in a Central Field . 19 2.2 Electrostatic and Spin-Orbit Splitting in the LS Coupling Approximation . 20 2.2.1 Spectral Terms. LS Quantum Numbers . 20 2.2.2 Fine Structure of Terms . 21 2.2.3 Finding the Terms of Multielectron Configurations . 23 2.2.4 Radiative Transitions . 26 2.3 j j Coupling Approximation . 27 2.3.1 Various Coupling Schemes . 27 2.3.2 Systematics of Electron States with j j Coupling . 29 viii Contents Chapter 3 Spectra of Multielectron Atoms 3.1 Periodic System of Elements . 32 3.2 Spectra of the Alkali Elements . 34 3.2.1 Term Scheme . 34 3.2.2 Series Regularities . 37 3.2.3 Fine Structure . 37 3.2.4 Copper, Silver, and Gold Spectra . 38 3.3 Spectra of the Alkaline Earth Elements . 39 3.3.1 He Spectrum .!. 39 3.3.2 Spectra of the Alkaline Earth Elements . 40 3.3.3 Zinc, Cadmium, and Mercury Spectra . 42 3.4 Spectra of Elements with ρ Valence Electrons . 42 3.4.1 One ρ Electron Outside Filled Shells . 42 3.4.2 Configuration p2 . 43 3.4.3 Configuration рг . 44 3.4.4 Configuration p* . 45 3.4.5 Configuration p5 . 46 3.4.6 Configuration p6 . 46 3.5 Spectra of Elements with Unfilled d and f Shells . 48 3.5.1 Elements with Unfilled d Shells . 48 3.5.2 Elements with Unfilled ƒ Shells . 49 Partii Theory of Atomic Spectra Chapter 4 Angular Momenta 4.1 Angular Momentum Operator. Addition of Angular Momenta . 53 4.1.1 Angular Momentum Operator . 53 4.1.2 Orbital Angular Momentum . 54 4.1.3 Electron Spin . 54 4.1.4 Addition of Two Angular Momenta . 55 4.1.5 Addition of Three or More Angular Momenta . 57 4.2 Angular Momentum Vector Addition Coefficients . 60 4.2.1 Clebsch-Gordan and Associated Coefficients . 60 4.2.2 Summary of Formulas for 3j Symbols . 62 4.2.3 Racah W Coefficients and 6y Symbols . 66 4.2.4 Summary of Formulas for 6y Symbols . 70 4.2.5 9y Symbols . 72 4.3 Irreducible Tensor Operators . 74 Contents ix 4.3.1 Spherical Tensors. 74 4.3.2 Matrix Elements. 76 4.3.3 Some Examples of Calculation of Reduced Matrix Elements _ 78 4.3.4 Tensor Product of Operators . 80 4.3.5 Matrix Elements with Coupled Angular Momenta . 84 4.3.6 Direct Product of Operators . 86 Chapter 5 Systematics of the States of Multielectron Atoms 5.1 Wave Functions . 89 5.1.1 Central Field Approximation . 89 5.1.2 Two-Electron Wave Functions in LSMLMS Representation . 90 5.1.3 Two-Electron Wave Functions in mm'SMg Representation . 93 5.1.4 Multielectron Wave Functions in a Parentage Scheme Approximation . 96 5.1.5 Fractional Parentage Coefficients . 96 5.1.6 Classification of Identical Terms of /" Configuration According to Seniority (Seniority Number) . 98 5.2 Matrix Elements of Symmetric Operators . 106 5.2.1 Statement of the Problem . 106 5.2.2 F Matrix Elements. Parentage Scheme Approximation . 108 5.2.3 F Matrix Elements. Equivalent Electrons . 109 5.2.4 Q Matrix Elements. Parentage Scheme Approximation . Ill 5.2.5 Q Matrix Elements. Equivalent Electrons . 113 5.2.6 Summary of Results . 115 5.3 Electrostatic Interaction in LS Coupling. Two-Electron Configuration . 115 5.3.1 Coulomb and Exchange Integrals . 115 5.3.2 Configuration Mixing . 118 5.4 Electrostatic Interaction in LS Coupling. Multielectron Configuration . 120 5.4.1 Configurations /" and /"/'. 120 5.4.2 More Than Half Filled Shells . 123 5.4.3 Filled (Closed) Shells . 123 5.4.4 Applicability of the Single-Configuration Approximation . 124 5.5 Multiplet Splitting in LS Coupling . 126 5.5.1 Preliminary Remarks . 126 5.5.2 Lande Interval Rule . 126 5.5.3 One Electron Outside Closed Shells . 128 5.5.4 Configuration /". 130 5.5.5 Parentage Scheme Approximation . 132 5.5.6 Fine-Structure Splitting of Levels of He . 133 5.5.7 Spin-Spin and Spin-Other Orbit Interactions . 139 5.6 jj Coupling . 141 5.6.1 Wave Functions . 141 5.6.2 Spin-Orbit and Electrostatic Interactions . 143 x Contents 5.7 Intermediate Coupling and Other Types of Coupling . 144 5.7.1 Transformations Between LS and j j Coupling Schemes . 144 5.7.2 Intermediate Coupling . 147 5.7.3 jl Coupling . 152 5.7.4 Experimental Date . 153 5.7.5 Other Types of Coupling . 154 Chapter 6 Hyperfine Structure of Spectral Lines 6.1 Nuclear Magnetic Dipole and Electric Quadrupole Moments . 156 6.1.1 Magnetic Moments . 156 6.1.2 Quadrupole Moments . 157 6.2 Hyperfine Splitting . 159 6.2.1 General Character of the Splitting . 159 6.2.2 Calculation of the Hyperfine Splitting Constant A . 162 6.2.3 Calculation of the Hyperfine Splitting Constant В . 168 6.2.4 Radiative Transitions Between Hyperfine-Structure Components. 170 6.2.5 Isotope Shift of the Atomic Levels . 170 Chapter 7 The Atom in an External Electric Field 7.1 Quadratic Stark Effect . 173 7.2 Hydrogenlike Levels. Linear Stark Effect . 177 7.3 Inhomogeneous Field. Quadrupole Splitting . 181 7.4 Time-Dependent Field . 183 7.4.1 Amplitude Modulation . 183 7.4.2 The Hydrogen Atom in a Rotating Electric Field . 187 Chapter 8 The Atom in an External Magnetic Field 8.1 Zeeman Effect . 189 8.2 Paschen-Back Effect . 194 8.2.1 Strong Field . 194 8.2.2 Splitting of Hyperfine Structure Components in a Magnetic Field 198 Chapter 9 Radiative Transitions 9.1 Electromagnetic Radiation . 200 9.1.1 Quantization of the Radiation Field _,. 200 9.1.2 Radiative Transition Probabilities . 201 9.1.3 Correspondence Principle for Spontaneous Emission . 202 9.1.4 Dipole Radiation . 203 Contents xi 9.1.5 Stimulated Emission and Absorption. 203 9.1.6 Effective Cross Sections of Absorption and Stimulated Emission 205 9.2 Electric Dipole Radiation . 205 9.2.1 Selection Rules, Polarization and Angular Distribution . 205 9.2.2 Oscillator Strengths and Line Strengths . 208 9.2.3 LS Coupling Approximation. Relative Intensities of Multiplet Components . 211 9.2.4 One Electron Outside Closed Shell . 213 9.2.5 Multielectron Configurations. Different Coupling Schemes . 214 9.2.6 Relative Intensities of Zeeman and Stark Components of Lines. . 215 9.3 Multipole Radiation . 216 9.3.1 Fields of Electric and Magnetic Multipole Moments . 216 9.3.2 Intensity of Multipole Radiation . 220 9.3.3 Selection Rules . 222 9.3.4 Electric Multipole Radiation . 223 9.3.5 Magnetic Dipole Radiation . 225 9.3.6 Transitions Between Hyperfine Structure Components. Radio Emission from Hydrogen . 227 9.4 Calculation of Radiative Transition Probabilities . 229 9.4.1 Approximate Methods . 229 9.4.2 Three Ways of Writing Formulas for Transition Probabilities . 230 9.4.3 Theorems for Sums of Oscillator Strengths . 232 9.4.4 Semiempirical Methods of Calculating Oscillator Strengths . 235 9.4.5 Electric Dipole Transition Probabilities in the Coulomb Approximation . 236 9.4.6 Intercombination Transitions . 237 9.5 Continuous Spectrum . 239 9.5.1 Classification of Processes .:. 239 9.5.2 Photorecombination and Photoionization: General Expressions for Effective Cross Sections . 239 9.5.3 Bremsstrahlung: General Expressions for Effective Cross Sections . 245 9.5.4 Radiation and Absorption Coefficients . 248 9.5.5 Photorecombination and Photoionization: Hydrogenlike Atoms . 251 9.5.6 Photorecombination and Photoionization: Nonhydrogenlike Atoms . 255 9.5.7 Bremsstrahlung in a Coulomb Field . 257 9.6 Formulas for Q Factors . 274 9.6.1 Symmetry and Sum Rules . 274 9.6.2 LS Coupling. Allowed Transitions . 275 9.6.3 jl Coupling . 279 9.7 Tables of Oscillator Strengths and Radiative Transition Probabilities . 281 9.7.1 Transition Probabilities for the Hydrogen Atom . 281 9.7.2 Radiative Transition Probabilities in the Bates-Damgaard Approximation . 283 x» Contents 9.7.3 Oscillator Strengths and Probabilities of Some Selected Transitions . 284 9.7.4 Effective Cross Sections and Rates of Photorecombination . 284 Chapter 10 Relativistic Corrections in the Spectroscopy of Multkharged Ions 10.1 Dirac Equation. Pauli Equation . 303 10.1.1 Dirac Equation . 303 10.1.2 Electron Spin . 305 10.1.3 Non-Relativistic Approximation. Pauli Equation . 308 10.2 Central Field . 310 10.2.1 Non-Relativistic Approximation . 310 10.2.2 Second Approximation with Respect to v/c. Fine Splitting ----- 313 10.2.3 Dirac Equation for a Central Field . 316 10.2.4 Coulomb Field. Energy Levels, Fine Splitting . 319 10.2.5 Coulomb Field. Radial Functions . 322 10.3 Relativistic Corrections . 325 10.3.1 Calculation of Some Radial Integrals . 325 10.3.2 Hyperfine Splitting Constant A . 326 10.3.3 Hyperfine Splitting Constant В . 330 10.3.4 Nucleus Finite-Size Correction . 331 10.3.5' Radiative Corrections. Lamb Shift . 333 Chapter 11 Spectra of Multicharged Ions 11.1 Energy Levels . 339 11.2 Forbidden Transitions . 341 11.2.1 Н -like Ions . 342 11.2.2 He-like Ions . 342 11.3 Satellite Structure . 346 Chapter 12 The Negative Ion H". 12.1 Negative Ion ВГ. Electron Affinity .350 12.2 Photoabsorption by H~ . 35I Appendix . References . 3^j List of Symbols . 363 Subject Index . 365
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id	DE-604.BV035050545
illustrated	Illustrated
index_date	2024-07-02T21:56:22Z
indexdate	2024-07-09T21:21:04Z
institution	BVB
isbn	9781842652039 1842652036
language	English
oai_aleph_id	oai:aleph.bib-bvb.de:BVB01-016719234
oclc_num	255211967
open_access_boolean
owner	DE-91G DE-BY-TUM DE-703 DE-11
owner_facet	DE-91G DE-BY-TUM DE-703 DE-11
physical	XII, 366 S. graph. Darst.
publishDate	2006
publishDateSearch	2006
publishDateSort	2006
publisher	Alpha Science Internat.
record_format	marc
spelling	Sobel'man, Igor' I. 1927- Verfasser (DE-588)104311924 aut Theory of atomic spectra Igor I. Sobelman Oxford, UK Alpha Science Internat. 2006 XII, 366 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Strahlungsübergang (DE-588)4183547-5 gnd rswk-swf Atomspektrum (DE-588)4143334-8 gnd rswk-swf Atomspektrum (DE-588)4143334-8 s DE-604 Strahlungsübergang (DE-588)4183547-5 s Früher u.d.T. Sobel'man, Igor' I. Atomic spectra and radiative transitions Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016719234&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Sobel'man, Igor' I. 1927- Theory of atomic spectra Strahlungsübergang (DE-588)4183547-5 gnd Atomspektrum (DE-588)4143334-8 gnd
subject_GND	(DE-588)4183547-5 (DE-588)4143334-8
title	Theory of atomic spectra
title_auth	Theory of atomic spectra
title_exact_search	Theory of atomic spectra
title_exact_search_txtP	Theory of atomic spectra
title_full	Theory of atomic spectra Igor I. Sobelman
title_fullStr	Theory of atomic spectra Igor I. Sobelman
title_full_unstemmed	Theory of atomic spectra Igor I. Sobelman
title_old	Sobel'man, Igor' I. Atomic spectra and radiative transitions
title_short	Theory of atomic spectra
title_sort	theory of atomic spectra
topic	Strahlungsübergang (DE-588)4183547-5 gnd Atomspektrum (DE-588)4143334-8 gnd
topic_facet	Strahlungsübergang Atomspektrum
url	http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016719234&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT sobelmanigori theoryofatomicspectra

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