Theory of atomic spectra:
Gespeichert in:
| Vorheriger Titel: | Sobel'man, Igor' I. Atomic spectra and radiative transitions |
|---|---|
| 1. Verfasser: | |
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Oxford, UK
Alpha Science Internat.
2006
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 366 S. graph. Darst. |
| ISBN: | 9781842652039 1842652036 |
Internformat
MARC
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| 020 | |a 9781842652039 |c hbk. |9 978-1-84265-203-9 | ||
| 020 | |a 1842652036 |9 1-84265-203-6 | ||
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| 084 | |a PHY 511f |2 stub | ||
| 100 | 1 | |a Sobelʹman, I. I. |d 1927-2005 |e Verfasser |0 (DE-588)104311924 |4 aut | |
| 245 | 1 | 0 | |a Theory of atomic spectra |c Igor I. Sobelman |
| 264 | 1 | |a Oxford, UK |b Alpha Science Internat. |c 2006 | |
| 300 | |a XII, 366 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Strahlungsübergang |0 (DE-588)4183547-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Atomspektrum |0 (DE-588)4143334-8 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Atomspektrum |0 (DE-588)4143334-8 |D s |
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| 689 | 1 | 0 | |a Strahlungsübergang |0 (DE-588)4183547-5 |D s |
| 689 | 1 | |5 DE-604 | |
| 780 | 0 | 0 | |i Früher u.d.T. |a Sobel'man, Igor' I. |t Atomic spectra and radiative transitions |
| 856 | 4 | 2 | |m Digitalisierung UB Bayreuth |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016719234&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-016719234 | |
Datensatz im Suchindex
| _version_ | 1827193633187561472 |
|---|---|
| adam_text |
Contents
Preface
Parti
Elementary
Information on
Atomic Spectra
Chapter
1
The Hydrogen Spectrum
1.1 Schrödinger's
Equation for the Hydrogen Atom
. 3
1.1.1
Energy Levels
. 3
1.1.2
Wave Functions
. 5
1.2
Series Regularities
. 7
1.2.1
Radiative Transition Selection Rules
. 7
1.2.2
Spectral Series of the Hydrogen Atom
. 8
1.2.3
Hydrogenlike Ions
. 9
1.3
Fine Structure
. 10
1.3.1
Velocity Dependence of Electron Mass
. 10
1.3.2
Spin-Orbit Interaction
. 11
1.3.3
Fine Structure. Selection Rules
. 12
1.3.4
Lamb Shift
. 15
Chapter
2
Systematics of the Spectra of Multielectron Atoms
2.1
Central Field
. 16
2.1.1
Central Field Approximation
. 16
2.1.2
Parity of States
. 18
2.1.3
Systematics of Electron States in a Central Field
. 19
2.2
Electrostatic and Spin-Orbit Splitting in the LS Coupling
Approximation
. 20
2.2.1
Spectral Terms. LS Quantum Numbers
. 20
2.2.2
Fine Structure of Terms
. 21
2.2.3
Finding the Terms of Multielectron Configurations
. 23
2.2.4
Radiative Transitions
. 26
2.3
j j
Coupling Approximation
. 27
2.3.1
Various Coupling Schemes
. 27
2.3.2
Systematics of Electron States with
j j
Coupling
. 29
viii Contents
Chapter
3
Spectra of Multielectron Atoms
3.1
Periodic System of Elements
. 32
3.2
Spectra of the Alkali Elements
. 34
3.2.1
Term Scheme
. 34
3.2.2
Series Regularities
. 37
3.2.3
Fine Structure
. 37
3.2.4
Copper, Silver, and Gold Spectra
. 38
3.3
Spectra of the Alkaline Earth Elements
. 39
3.3.1
He Spectrum
.!. 39
3.3.2
Spectra of the Alkaline Earth Elements
. 40
3.3.3
Zinc, Cadmium, and Mercury Spectra
. 42
3.4
Spectra of Elements with
ρ
Valence Electrons
. 42
3.4.1
One
ρ
Electron Outside Filled Shells
. 42
3.4.2
Configuration p2
. 43
3.4.3
Configuration
рг
. 44
3.4.4
Configuration p*
. 45
3.4.5
Configuration p5
. 46
3.4.6
Configuration p6
. 46
3.5
Spectra of Elements with Unfilled
d
and
f
Shells
. 48
3.5.1
Elements with Unfilled
d
Shells
. 48
3.5.2
Elements with Unfilled
ƒ
Shells
. 49
Partii
Theory of Atomic Spectra
Chapter
4
Angular Momenta
4.1
Angular Momentum Operator. Addition of Angular Momenta
. 53
4.1.1
Angular Momentum Operator
. 53
4.1.2
Orbital Angular Momentum
. 54
4.1.3
Electron Spin
. 54
4.1.4
Addition of Two Angular Momenta
. 55
4.1.5
Addition of Three or More Angular Momenta
. 57
4.2
Angular Momentum Vector Addition Coefficients
. 60
4.2.1
Clebsch-Gordan and Associated Coefficients
. 60
4.2.2
Summary of Formulas for 3j Symbols
. 62
4.2.3
Racah
W
Coefficients and 6y Symbols
. 66
4.2.4
Summary of Formulas for 6y Symbols
. 70
4.2.5
9y Symbols
. 72
4.3
Irreducible Tensor Operators
. 74
Contents ix
4.3.1
Spherical
Tensors. 74
4.3.2 Matrix Elements. 76
4.3.3
Some Examples of Calculation of Reduced Matrix Elements
_ 78
4.3.4
Tensor Product of Operators
. 80
4.3.5
Matrix Elements with Coupled Angular Momenta
. 84
4.3.6
Direct Product of Operators
. 86
Chapter
5
Systematics of the States of Multielectron Atoms
5.1
Wave Functions
. 89
5.1.1
Central Field Approximation
. 89
5.1.2
Two-Electron Wave Functions in LSMLMS Representation
. 90
5.1.3
Two-Electron Wave Functions in mm'SMg Representation
. 93
5.1.4
Multielectron Wave Functions in a Parentage Scheme
Approximation
. 96
5.1.5
Fractional Parentage Coefficients
. 96
5.1.6
Classification of Identical Terms of
/"
Configuration According
to Seniority (Seniority Number)
. 98
5.2
Matrix Elements of Symmetric Operators
. 106
5.2.1
Statement of the Problem
. 106
5.2.2
F
Matrix Elements. Parentage Scheme Approximation
. 108
5.2.3
F
Matrix Elements. Equivalent Electrons
. 109
5.2.4
Q
Matrix Elements. Parentage Scheme Approximation
.
Ill
5.2.5
Q
Matrix Elements. Equivalent Electrons
. 113
5.2.6
Summary of Results
. 115
5.3
Electrostatic Interaction in LS Coupling. Two-Electron Configuration
. 115
5.3.1
Coulomb and Exchange Integrals
. 115
5.3.2
Configuration Mixing
. 118
5.4
Electrostatic Interaction in LS Coupling. Multielectron Configuration
. 120
5.4.1
Configurations
/"
and
/"/'. 120
5.4.2
More Than Half Filled Shells
. 123
5.4.3
Filled (Closed) Shells
. 123
5.4.4
Applicability of the Single-Configuration Approximation
. 124
5.5
Multiplet
Splitting in LS Coupling
. 126
5.5.1
Preliminary Remarks
. 126
5.5.2 Lande
Interval Rule
. 126
5.5.3
One Electron Outside Closed Shells
. 128
5.5.4
Configuration
/". 130
5.5.5
Parentage Scheme Approximation
. 132
5.5.6
Fine-Structure Splitting of Levels of He
. 133
5.5.7
Spin-Spin and Spin-Other Orbit Interactions
. 139
5.6
jj Coupling
. 141
5.6.1
Wave Functions
. 141
5.6.2
Spin-Orbit and Electrostatic Interactions
. 143
x
Contents
5.7
Intermediate
Coupling and Other Types of Coupling
. 144
5.7.1
Transformations Between LS and
j j
Coupling Schemes
. 144
5.7.2
Intermediate Coupling
. 147
5.7.3
jl Coupling
. 152
5.7.4
Experimental Date
. 153
5.7.5
Other Types of Coupling
. 154
Chapter
6
Hyperfine Structure of Spectral Lines
6.1
Nuclear Magnetic
Dipole
and Electric Quadrupole Moments
. 156
6.1.1
Magnetic Moments
. 156
6.1.2
Quadrupole Moments
. 157
6.2
Hyperfine Splitting
. 159
6.2.1
General Character of the Splitting
. 159
6.2.2
Calculation of the Hyperfine Splitting Constant A
. 162
6.2.3
Calculation of the Hyperfine Splitting Constant
В
. 168
6.2.4
Radiative Transitions Between Hyperfine-Structure Components.
170
6.2.5
Isotope Shift of the Atomic Levels
. 170
Chapter
7
The Atom in an External Electric Field
7.1
Quadratic Stark Effect
. 173
7.2
Hydrogenlike Levels. Linear Stark Effect
. 177
7.3
Inhomogeneous Field. Quadrupole Splitting
. 181
7.4
Time-Dependent Field
. 183
7.4.1
Amplitude Modulation
. 183
7.4.2
The Hydrogen Atom in a Rotating Electric Field
. 187
Chapter
8
The Atom in an External Magnetic Field
8.1
Zeeman
Effect
. 189
8.2
Paschen-Back Effect
. 194
8.2.1
Strong Field
. 194
8.2.2
Splitting of Hyperfine Structure Components in a Magnetic Field
198
Chapter
9
Radiative Transitions
9.1
Electromagnetic Radiation
. 200
9.1.1
Quantization of the Radiation Field
_,. 200
9.1.2
Radiative Transition Probabilities
. 201
9.1.3
Correspondence Principle for Spontaneous Emission
. 202
9.1.4 Dipole
Radiation
. 203
Contents xi
9.1.5
Stimulated
Emission and Absorption. 203
9.1.6
Effective Cross Sections of Absorption and Stimulated Emission
205
9.2
Electric
Dipole
Radiation
. 205
9.2.1
Selection Rules, Polarization and Angular Distribution
. 205
9.2.2
Oscillator Strengths and Line Strengths
. 208
9.2.3
LS Coupling Approximation. Relative Intensities of
Multiplet
Components
. 211
9.2.4
One Electron Outside Closed Shell
. 213
9.2.5
Multielectron Configurations. Different Coupling Schemes
. 214
9.2.6
Relative Intensities of
Zeeman
and Stark Components of Lines.
. 215
9.3
Multipole Radiation
. 216
9.3.1
Fields of Electric and Magnetic Multipole Moments
. 216
9.3.2
Intensity of Multipole Radiation
. 220
9.3.3
Selection Rules
. 222
9.3.4
Electric Multipole Radiation
. 223
9.3.5
Magnetic
Dipole
Radiation
. 225
9.3.6
Transitions Between Hyperfine Structure Components. Radio
Emission from Hydrogen
. 227
9.4
Calculation of Radiative Transition Probabilities
. 229
9.4.1
Approximate Methods
. 229
9.4.2
Three Ways of Writing Formulas for Transition Probabilities
. 230
9.4.3
Theorems for Sums of Oscillator Strengths
. 232
9.4.4
Semiempirical Methods of Calculating Oscillator Strengths
. 235
9.4.5
Electric
Dipole
Transition Probabilities in the Coulomb
Approximation
. 236
9.4.6
Intercombination Transitions
. 237
9.5
Continuous Spectrum
. 239
9.5.1
Classification of Processes
.:. 239
9.5.2
Photorecombination and Photoionization: General Expressions
for Effective Cross Sections
. 239
9.5.3 Bremsstrahlung:
General Expressions for Effective Cross
Sections
. 245
9.5.4
Radiation and Absorption Coefficients
. 248
9.5.5
Photorecombination and Photoionization: Hydrogenlike Atoms
. 251
9.5.6
Photorecombination and Photoionization: Nonhydrogenlike
Atoms
. 255
9.5.7 Bremsstrahlung
in a Coulomb Field
. 257
9.6
Formulas for
Q
Factors
. 274
9.6.1
Symmetry and Sum Rules
. 274
9.6.2
LS Coupling. Allowed Transitions
. 275
9.6.3
jl Coupling
. 279
9.7
Tables of Oscillator Strengths and Radiative Transition Probabilities
. 281
9.7.1
Transition Probabilities for the Hydrogen Atom
. 281
9.7.2
Radiative Transition Probabilities in the Bates-Damgaard
Approximation
. 283
x»
Contents
9.7.3
Oscillator Strengths and Probabilities of Some Selected
Transitions
. 284
9.7.4
Effective Cross Sections and Rates of Photorecombination
. 284
Chapter
10
Relativistic Corrections in the Spectroscopy of Multkharged Ions
10.1
Dirac Equation.
Pauli
Equation
. 303
10.1.1
Dirac Equation
. 303
10.1.2
Electron Spin
. 305
10.1.3
Non-Relativistic Approximation.
Pauli
Equation
. 308
10.2
Central Field
. 310
10.2.1
Non-Relativistic Approximation
. 310
10.2.2
Second Approximation with Respect to v/c. Fine Splitting
----- 313
10.2.3
Dirac Equation for a Central Field
. 316
10.2.4
Coulomb Field. Energy Levels, Fine Splitting
. 319
10.2.5
Coulomb Field. Radial Functions
. 322
10.3
Relativistic Corrections
. 325
10.3.1
Calculation of Some Radial Integrals
. 325
10.3.2
Hyperfine Splitting Constant A
. 326
10.3.3
Hyperfine Splitting Constant
В
. 330
10.3.4
Nucleus Finite-Size Correction
. 331
10.3.5'
Radiative Corrections. Lamb Shift
. 333
Chapter
11
Spectra of Multicharged Ions
11.1
Energy Levels
. 339
11.2
Forbidden Transitions
. 341
11.2.1
Н
-like
Ions
. 342
11.2.2
He-like Ions
. 342
11.3
Satellite Structure
. 346
Chapter
12
The Negative Ion H".
12.1
Negative Ion
ВГ.
Electron Affinity
.350
12.2
Photoabsorption
by H~
.
35I
Appendix
.
References
.
3^j
List of Symbols
.
363
Subject Index
.
365 |
| adam_txt |
Contents
Preface
Parti
Elementary
Information on
Atomic Spectra
Chapter
1
The Hydrogen Spectrum
1.1 Schrödinger's
Equation for the Hydrogen Atom
. 3
1.1.1
Energy Levels
. 3
1.1.2
Wave Functions
. 5
1.2
Series Regularities
. 7
1.2.1
Radiative Transition Selection Rules
. 7
1.2.2
Spectral Series of the Hydrogen Atom
. 8
1.2.3
Hydrogenlike Ions
. 9
1.3
Fine Structure
. 10
1.3.1
Velocity Dependence of Electron Mass
. 10
1.3.2
Spin-Orbit Interaction
. 11
1.3.3
Fine Structure. Selection Rules
. 12
1.3.4
Lamb Shift
. 15
Chapter
2
Systematics of the Spectra of Multielectron Atoms
2.1
Central Field
. 16
2.1.1
Central Field Approximation
. 16
2.1.2
Parity of States
. 18
2.1.3
Systematics of Electron States in a Central Field
. 19
2.2
Electrostatic and Spin-Orbit Splitting in the LS Coupling
Approximation
. 20
2.2.1
Spectral Terms. LS Quantum Numbers
. 20
2.2.2
Fine Structure of Terms
. 21
2.2.3
Finding the Terms of Multielectron Configurations
. 23
2.2.4
Radiative Transitions
. 26
2.3
j j
Coupling Approximation
. 27
2.3.1
Various Coupling Schemes
. 27
2.3.2
Systematics of Electron States with
j j
Coupling
. 29
viii Contents
Chapter
3
Spectra of Multielectron Atoms
3.1
Periodic System of Elements
. 32
3.2
Spectra of the Alkali Elements
. 34
3.2.1
Term Scheme
. 34
3.2.2
Series Regularities
. 37
3.2.3
Fine Structure
. 37
3.2.4
Copper, Silver, and Gold Spectra
. 38
3.3
Spectra of the Alkaline Earth Elements
. 39
3.3.1
He Spectrum
.!. 39
3.3.2
Spectra of the Alkaline Earth Elements
. 40
3.3.3
Zinc, Cadmium, and Mercury Spectra
. 42
3.4
Spectra of Elements with
ρ
Valence Electrons
. 42
3.4.1
One
ρ
Electron Outside Filled Shells
. 42
3.4.2
Configuration p2
. 43
3.4.3
Configuration
рг
. 44
3.4.4
Configuration p*
. 45
3.4.5
Configuration p5
. 46
3.4.6
Configuration p6
. 46
3.5
Spectra of Elements with Unfilled
d
and
f
Shells
. 48
3.5.1
Elements with Unfilled
d
Shells
. 48
3.5.2
Elements with Unfilled
ƒ
Shells
. 49
Partii
Theory of Atomic Spectra
Chapter
4
Angular Momenta
4.1
Angular Momentum Operator. Addition of Angular Momenta
. 53
4.1.1
Angular Momentum Operator
. 53
4.1.2
Orbital Angular Momentum
. 54
4.1.3
Electron Spin
. 54
4.1.4
Addition of Two Angular Momenta
. 55
4.1.5
Addition of Three or More Angular Momenta
. 57
4.2
Angular Momentum Vector Addition Coefficients
. 60
4.2.1
Clebsch-Gordan and Associated Coefficients
. 60
4.2.2
Summary of Formulas for 3j Symbols
. 62
4.2.3
Racah
W
Coefficients and 6y Symbols
. 66
4.2.4
Summary of Formulas for 6y Symbols
. 70
4.2.5
9y Symbols
. 72
4.3
Irreducible Tensor Operators
. 74
Contents ix
4.3.1
Spherical
Tensors. 74
4.3.2 Matrix Elements. 76
4.3.3
Some Examples of Calculation of Reduced Matrix Elements
_ 78
4.3.4
Tensor Product of Operators
. 80
4.3.5
Matrix Elements with Coupled Angular Momenta
. 84
4.3.6
Direct Product of Operators
. 86
Chapter
5
Systematics of the States of Multielectron Atoms
5.1
Wave Functions
. 89
5.1.1
Central Field Approximation
. 89
5.1.2
Two-Electron Wave Functions in LSMLMS Representation
. 90
5.1.3
Two-Electron Wave Functions in mm'SMg Representation
. 93
5.1.4
Multielectron Wave Functions in a Parentage Scheme
Approximation
. 96
5.1.5
Fractional Parentage Coefficients
. 96
5.1.6
Classification of Identical Terms of
/"
Configuration According
to Seniority (Seniority Number)
. 98
5.2
Matrix Elements of Symmetric Operators
. 106
5.2.1
Statement of the Problem
. 106
5.2.2
F
Matrix Elements. Parentage Scheme Approximation
. 108
5.2.3
F
Matrix Elements. Equivalent Electrons
. 109
5.2.4
Q
Matrix Elements. Parentage Scheme Approximation
.
Ill
5.2.5
Q
Matrix Elements. Equivalent Electrons
. 113
5.2.6
Summary of Results
. 115
5.3
Electrostatic Interaction in LS Coupling. Two-Electron Configuration
. 115
5.3.1
Coulomb and Exchange Integrals
. 115
5.3.2
Configuration Mixing
. 118
5.4
Electrostatic Interaction in LS Coupling. Multielectron Configuration
. 120
5.4.1
Configurations
/"
and
/"/'. 120
5.4.2
More Than Half Filled Shells
. 123
5.4.3
Filled (Closed) Shells
. 123
5.4.4
Applicability of the Single-Configuration Approximation
. 124
5.5
Multiplet
Splitting in LS Coupling
. 126
5.5.1
Preliminary Remarks
. 126
5.5.2 Lande
Interval Rule
. 126
5.5.3
One Electron Outside Closed Shells
. 128
5.5.4
Configuration
/". 130
5.5.5
Parentage Scheme Approximation
. 132
5.5.6
Fine-Structure Splitting of Levels of He
. 133
5.5.7
Spin-Spin and Spin-Other Orbit Interactions
. 139
5.6
jj Coupling
. 141
5.6.1
Wave Functions
. 141
5.6.2
Spin-Orbit and Electrostatic Interactions
. 143
x
Contents
5.7
Intermediate
Coupling and Other Types of Coupling
. 144
5.7.1
Transformations Between LS and
j j
Coupling Schemes
. 144
5.7.2
Intermediate Coupling
. 147
5.7.3
jl Coupling
. 152
5.7.4
Experimental Date
. 153
5.7.5
Other Types of Coupling
. 154
Chapter
6
Hyperfine Structure of Spectral Lines
6.1
Nuclear Magnetic
Dipole
and Electric Quadrupole Moments
. 156
6.1.1
Magnetic Moments
. 156
6.1.2
Quadrupole Moments
. 157
6.2
Hyperfine Splitting
. 159
6.2.1
General Character of the Splitting
. 159
6.2.2
Calculation of the Hyperfine Splitting Constant A
. 162
6.2.3
Calculation of the Hyperfine Splitting Constant
В
. 168
6.2.4
Radiative Transitions Between Hyperfine-Structure Components.
170
6.2.5
Isotope Shift of the Atomic Levels
. 170
Chapter
7
The Atom in an External Electric Field
7.1
Quadratic Stark Effect
. 173
7.2
Hydrogenlike Levels. Linear Stark Effect
. 177
7.3
Inhomogeneous Field. Quadrupole Splitting
. 181
7.4
Time-Dependent Field
. 183
7.4.1
Amplitude Modulation
. 183
7.4.2
The Hydrogen Atom in a Rotating Electric Field
. 187
Chapter
8
The Atom in an External Magnetic Field
8.1
Zeeman
Effect
. 189
8.2
Paschen-Back Effect
. 194
8.2.1
Strong Field
. 194
8.2.2
Splitting of Hyperfine Structure Components in a Magnetic Field
198
Chapter
9
Radiative Transitions
9.1
Electromagnetic Radiation
. 200
9.1.1
Quantization of the Radiation Field
_,. 200
9.1.2
Radiative Transition Probabilities
. 201
9.1.3
Correspondence Principle for Spontaneous Emission
. 202
9.1.4 Dipole
Radiation
. 203
Contents xi
9.1.5
Stimulated
Emission and Absorption. 203
9.1.6
Effective Cross Sections of Absorption and Stimulated Emission
205
9.2
Electric
Dipole
Radiation
. 205
9.2.1
Selection Rules, Polarization and Angular Distribution
. 205
9.2.2
Oscillator Strengths and Line Strengths
. 208
9.2.3
LS Coupling Approximation. Relative Intensities of
Multiplet
Components
. 211
9.2.4
One Electron Outside Closed Shell
. 213
9.2.5
Multielectron Configurations. Different Coupling Schemes
. 214
9.2.6
Relative Intensities of
Zeeman
and Stark Components of Lines.
. 215
9.3
Multipole Radiation
. 216
9.3.1
Fields of Electric and Magnetic Multipole Moments
. 216
9.3.2
Intensity of Multipole Radiation
. 220
9.3.3
Selection Rules
. 222
9.3.4
Electric Multipole Radiation
. 223
9.3.5
Magnetic
Dipole
Radiation
. 225
9.3.6
Transitions Between Hyperfine Structure Components. Radio
Emission from Hydrogen
. 227
9.4
Calculation of Radiative Transition Probabilities
. 229
9.4.1
Approximate Methods
. 229
9.4.2
Three Ways of Writing Formulas for Transition Probabilities
. 230
9.4.3
Theorems for Sums of Oscillator Strengths
. 232
9.4.4
Semiempirical Methods of Calculating Oscillator Strengths
. 235
9.4.5
Electric
Dipole
Transition Probabilities in the Coulomb
Approximation
. 236
9.4.6
Intercombination Transitions
. 237
9.5
Continuous Spectrum
. 239
9.5.1
Classification of Processes
.:. 239
9.5.2
Photorecombination and Photoionization: General Expressions
for Effective Cross Sections
. 239
9.5.3 Bremsstrahlung:
General Expressions for Effective Cross
Sections
. 245
9.5.4
Radiation and Absorption Coefficients
. 248
9.5.5
Photorecombination and Photoionization: Hydrogenlike Atoms
. 251
9.5.6
Photorecombination and Photoionization: Nonhydrogenlike
Atoms
. 255
9.5.7 Bremsstrahlung
in a Coulomb Field
. 257
9.6
Formulas for
Q
Factors
. 274
9.6.1
Symmetry and Sum Rules
. 274
9.6.2
LS Coupling. Allowed Transitions
. 275
9.6.3
jl Coupling
. 279
9.7
Tables of Oscillator Strengths and Radiative Transition Probabilities
. 281
9.7.1
Transition Probabilities for the Hydrogen Atom
. 281
9.7.2
Radiative Transition Probabilities in the Bates-Damgaard
Approximation
. 283
x»
Contents
9.7.3
Oscillator Strengths and Probabilities of Some Selected
Transitions
. 284
9.7.4
Effective Cross Sections and Rates of Photorecombination
. 284
Chapter
10
Relativistic Corrections in the Spectroscopy of Multkharged Ions
10.1
Dirac Equation.
Pauli
Equation
. 303
10.1.1
Dirac Equation
. 303
10.1.2
Electron Spin
. 305
10.1.3
Non-Relativistic Approximation.
Pauli
Equation
. 308
10.2
Central Field
. 310
10.2.1
Non-Relativistic Approximation
. 310
10.2.2
Second Approximation with Respect to v/c. Fine Splitting
----- 313
10.2.3
Dirac Equation for a Central Field
. 316
10.2.4
Coulomb Field. Energy Levels, Fine Splitting
. 319
10.2.5
Coulomb Field. Radial Functions
. 322
10.3
Relativistic Corrections
. 325
10.3.1
Calculation of Some Radial Integrals
. 325
10.3.2
Hyperfine Splitting Constant A
. 326
10.3.3
Hyperfine Splitting Constant
В
. 330
10.3.4
Nucleus Finite-Size Correction
. 331
10.3.5'
Radiative Corrections. Lamb Shift
. 333
Chapter
11
Spectra of Multicharged Ions
11.1
Energy Levels
. 339
11.2
Forbidden Transitions
. 341
11.2.1
Н
-like
Ions
. 342
11.2.2
He-like Ions
. 342
11.3
Satellite Structure
. 346
Chapter
12
The Negative Ion H".
12.1
Negative Ion
ВГ.
Electron Affinity
.350
12.2
Photoabsorption
by H~
.
35I
Appendix
.
References
.
3^j
List of Symbols
.
363
Subject Index
.
365 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Sobelʹman, I. I. 1927-2005 |
| author_GND | (DE-588)104311924 |
| author_facet | Sobelʹman, I. I. 1927-2005 |
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| bvnumber | BV035050545 |
| classification_rvk | UM 2200 |
| classification_tum | PHY 511f |
| ctrlnum | (OCoLC)255211967 (DE-599)GBV511110820 |
| discipline | Physik |
| discipline_str_mv | Physik |
| format | Book |
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| id | DE-604.BV035050545 |
| illustrated | Illustrated |
| index_date | 2024-07-02T21:56:22Z |
| indexdate | 2025-03-21T09:00:39Z |
| institution | BVB |
| isbn | 9781842652039 1842652036 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016719234 |
| oclc_num | 255211967 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-703 DE-11 |
| owner_facet | DE-91G DE-BY-TUM DE-703 DE-11 |
| physical | XII, 366 S. graph. Darst. |
| publishDate | 2006 |
| publishDateSearch | 2006 |
| publishDateSort | 2006 |
| publisher | Alpha Science Internat. |
| record_format | marc |
| spelling | Sobelʹman, I. I. 1927-2005 Verfasser (DE-588)104311924 aut Theory of atomic spectra Igor I. Sobelman Oxford, UK Alpha Science Internat. 2006 XII, 366 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Strahlungsübergang (DE-588)4183547-5 gnd rswk-swf Atomspektrum (DE-588)4143334-8 gnd rswk-swf Atomspektrum (DE-588)4143334-8 s DE-604 Strahlungsübergang (DE-588)4183547-5 s Früher u.d.T. Sobel'man, Igor' I. Atomic spectra and radiative transitions Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016719234&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Sobelʹman, I. I. 1927-2005 Theory of atomic spectra Strahlungsübergang (DE-588)4183547-5 gnd Atomspektrum (DE-588)4143334-8 gnd |
| subject_GND | (DE-588)4183547-5 (DE-588)4143334-8 |
| title | Theory of atomic spectra |
| title_auth | Theory of atomic spectra |
| title_exact_search | Theory of atomic spectra |
| title_exact_search_txtP | Theory of atomic spectra |
| title_full | Theory of atomic spectra Igor I. Sobelman |
| title_fullStr | Theory of atomic spectra Igor I. Sobelman |
| title_full_unstemmed | Theory of atomic spectra Igor I. Sobelman |
| title_old | Sobel'man, Igor' I. Atomic spectra and radiative transitions |
| title_short | Theory of atomic spectra |
| title_sort | theory of atomic spectra |
| topic | Strahlungsübergang (DE-588)4183547-5 gnd Atomspektrum (DE-588)4143334-8 gnd |
| topic_facet | Strahlungsübergang Atomspektrum |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016719234&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT sobelʹmanii theoryofatomicspectra |