Cereal straw as a resource for sustainable biomaterials and biofuels: chemistry, extractives, lignins, hemicelluloses and cellulose
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
2010
|
| Ausgabe: | 1. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index Erscheinungsjahr in Vorlageform:2010 |
| Beschreibung: | IX, 292 S. Ill., graph. Darst. |
| ISBN: | 9780444532343 |
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| 245 | 1 | 0 | |a Cereal straw as a resource for sustainable biomaterials and biofuels |b chemistry, extractives, lignins, hemicelluloses and cellulose |c Run-Cang Sun |
| 250 | |a 1. ed. | ||
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Datensatz im Suchindex
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IMAGE 1
CONTENTS
PREFACE IX 4. HEMICELLULOSES
JUN-LI REN AND RUN-CANG SUN
4.1 INTRODUCTION 73
1. INTRODUCTION 4.2 OCCURRENCE, NATURE, AND CLASSIFICATION 73
TONG-QI YUAN AND RUN-CANG SUN
4.2.1 OCCURRENCE, NATURE, AND CLASSIFICATION OF HEMICELLULOSES 74
REFERENCES 5 4.2.2 OCCURRENCE, NATURE, AND
CLASSIFICATION OF STRAW
2. STRUCTURE, ULTRASTRUCTURE, AND CHEMICAL HEMICELLULOSES 76
COMPOSITION 4.3 ISOLATION, ANALYSIS, AND STRUCTURE 77
4.3.1 ISOLATION 77
FENG XU 4.3 2 STRUCTURAL ANALYSIS OF STRAW
2.1 ANATOMICAL STRUCTURE 9 HEMICELLULOSES 85
2.2 ULTRASTRUCTURE 10 4 3.3 STRUCTURE 89
2.2.1 ULTRASTRUCTURE OF WOOD 10 4.4 PHYSICOCHEMICAL PROPERTIES 96
2.2.2 ULTRASTRUCTURE OF CRASS 15 4.4.1 SOLUBILITY 96
2.3 DISTRIBUTION OF POLYSACCHARIDES AND LIGNIN 18 4.4.2 MW AND MW
DISTRIBUTION 96
2.3.1 POLYSACCHARIDES DISTRIBUTION 18 4.4.3 RHEOLOGICAL BEHAVIOR 97
2.3.2 LIGNIN DISTRIBUTION 21 4.4.4 SURFACE TENSION 98
2.4 CHEMICAL COMPOSITION 29 4.4.5 THERMAL BEHAVIOR 99
2.41 CELLULOSE 31 4.4.6 BIOLOGICAL ACTIVITY 100
2.4 2 HEMICELLULOSES 34 4.5 INTERACTIONS WITH CELLULOSE 100
2.4.3 LIGNIN 37 4 5.1 INTERACTION OF HEMICELLULOSES
2.4 4 PECTIC SUBSTANCES 39 WITH CELLULOSES IN PRODUCTION
2.4.5 PROTEINS 40 OF CELLULOSES 101
2 4.6 CUTINS, SUBERMS, WAXES AND 45 2 INTERACTION OF HEMICELLULOSES
OTHER EXTRACTS 40 WITH CELLULOSES IN PAPERMAKING
2.4 7 ASH 43 PROCESS 103
REFERENCES 43 45 3 EFFECT OF INTERACTION OF
HEMICELLULOSES WITH CELLULOSES
3. EXTRACTIVES ON THE BIOETHANOL PRODUCTION 104
PAI PENG, JING BIAN AND RUN-CANG SUN
4 5 4 THE ASSEMBLY CHARACTERISTICS OF HEMICELLULOSES ON CELLULOSE 105
3.1 ISOLATION AND PURIFICATION 50 4.6 MODIFICATION OF HEMICELLULOSES AND
3.1.1 PROCEDURES FOR ISOLATION OF ITS APPLICATION 105
EXTRACTIVES 50 461 THE POTENTIAL MODIFICATION OF
312 PURIFICATION OF EXTRACTIVES 51 HEMICELLULOSES 105
3.2 STRUCTURAL CHARACTERIZATION 52 46 2 CHEMICAL MODIFICATION AND ITS
3.2.1 CHEMICAL COMPOSITION OF APPLICATION 106
EXTRACTIVES 52 4 6.3 STRAW HEMICELLULOSES AND
3 22 SPECTROSCOPIC AND THERMAL THEIR APPLICATION 117
CHARACTERIZATION 62 4.7 SUMMARY 118
REFERENCES 70 REFERENCES 119
V
IMAGE 2
VI CONTENTS
5. CELLULOSE
CHUAN-FU LIU AND RUN-CANG SUN 5.1 OCCURRENCE 131
5.2 ISOLATION
5.2.1 DELIGNIFICATION AND ALKALI
132
EXTRACTION 132
5.2.2 STEAM EXPLOSION 134
5.2.3 ALKALINE PEROXIDE EXTRACTION 135
5.2.4 ORGANIC SOLVENT EXTRACTION 135
5.2.5 OTHER ISOLATION METHODS 136
5.3 STRUCTURE AND THE CRYSTALLINE LATTICE OF CELLULOSE I 138
5.3.1 SUPERMOLECULAR STRUCTURE 138
5.3.2 CELLULOSE LATTICE I 138
5.3.3 CONVERSION OF CELLULOSE I TO
CELLULOSE II 142
5.4 PHYSICO-CHEMICAL PROPERTIES 143
5.4.1 STRUCTURAL PROPERTIES 143
5.4.2 DISSOLUTION OF CELLULOSE 146
5.4.3 REGENERATION OF CELLULOSE 151
5.4.4 HYDROLYSIS OF CELLULOSE 153
5.5 CHEMICAL MODIFICATION AND
ITS UTILIZATION 154
5.5.1 ACETYLATION 155
5.5.2 ACYLATION WITH OTHER LINEAR ANHYDRIDES OR CHLORIDES 157
5.5.3 ESTERIFICATION WITH CYCLIC ANHYDRIDES 157
5.5.4 CARBOXYMETHYLATION 158
5.5.5 OTHER CHEMICAL MODIFICATION 161 5.6 CONCLUDING REMARKS 162
REFERENCES 162
6. LIGNIN
FACHUANG LU AND JOHN RALPH
6.1 INTRODUCTION 169
6.2 MONOLIGNOLS, AND LIGNIFICATION IN GRASS CELL WALLS 170
6.2.1 BIOSYNTHESIS OF MONOL IGNOLS 170 6.2.2 LIGNIN DEPOSITION AND
TOPOCHEMISTRY 171
6.2.3 LIGNIFICATION - POLYMERIZATION OF MONOLIGNOLS U3
6.3 ISOLATION AND PURIFICATION OF LIGNINS 174
6.3.1 MILLED WOOD LIGNIN 175
6.3.2 ENZYME LIGNIN 177
6.3.3 ALKALI LIGNINS 178
6.3.4 ORGANOSOLV LIGNIN 180
6.3.5 PURIFICATION OF LIGNINS 182
6.4 ANALYTICAL METHODS FOR LIGNIN CHARACTERIZATION 183
6.4.1 THIOACIDOLYSIS 183
6.4.2 DFRC METHOD 184
6.4.3 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY 185
6.5 STRUCTURAL CHARACTERISTICS OF STRAW LIGNINS 187 6.5.1 FERULATES IN
CRASS LIGNINS 188
6.5.2 P-COUMARATES IN GRASS LIGNINS 192 6.5.3 LIGNIN-CARBOHYDRATE
COMPLEXES IN GRASSES 193
6.6 UTILIZATION OF LIGNINS 194
6.6.1 WOOD ADHESIVES MADE
FROM LIGNINS 195
6.6.2 BIOCHEMICALS/BIOFUEL FROM LIGNINS 196 6.7 CONCLUDING REMARKS 197
REFERENCES 198
7. CHEMICAL MODIFICATION OF STRAW AS NOVEL MATERIALS FOR INDUSTRIES
7.1 CHEMICAL MODIFICATION OF CEREAL STRAWS
AS NATURAL SORBENTS IN OIL SPILL CLEANUP 209 DIAO SHE, RUN-CANG SUN AND
GWYNN LLOYDJONES
7.2
7.1.1 HAZARD OF OIL SPILL 209
7.1.2 METHODS FOR CONTROLLING OIL SPILLS 209
7.1.3 CLASSIFICATION OF OIL SORBENTS 209 7.1.4 PRINCIPLES OF SORBENCY
210
7.1.5 INFLUENCE OF SORPTIVE CAPACITY 210 7.1.6 CHEMICAL MODIFICATION OF
CEREAL
STRAWS AS OIL SORBENTS 211
7.1.7 TYPES OF CATALYSTS IN CHEMICAL MODIFICATION 212
7.1.8 AGRO-BASED SORBENT APPLICATION 213
REFERENCES 216
MODIFICATION OF CEREAL STRAWS AS NATURAL SORBENTS FOR REMOVING METAL
IONS FROM INDUSTRIAL WASTE WATER
FENG PENG AND RUN-CANG SUN
7.2.1 INTRODUCTION 219
7.2.2 MECHANISM OF METAL BIOSORPTION 220 7.2.3 ADSORPTION MODELS 220
7.2.4 METHODS OF CHEMICAL MODIFICATION 221 7.2.4.1 THE METHODS OF DIRECT
CHEMICAL MODIFICATION 222 7.2.4.2 CHEMICAL GRAFTING MODIFICATION 223
7.2.5 CHEMICALLY MODIFIED STRAW 227
7.2.5.1 SUGARCANE BAGASSE 227
7.2.5.2 RICE STRAW/HUSKS/HULLS 230 7.2.5.3 WHEAT STRAWAA/HEAT BRAN 231
7.2.5.4 CORNCOBS 231
IMAGE 3
CONTENTS VU
7.2.5.5 SOYBEAN STRAW/HULL 7.2.5.6 OTHER STRAW/HULLS
7.2.6 SUMMARY REFERENCES
7.3 MODIFICATION OF STRAW FOR ACTIVATED
CARBON PREPARATION AND APPLICATION FOR THE REMOVAL OF DYES FROM AQUEOUS
SOLUTIONS TONG-QI YUAN AND RUN-CANG SUN
73A INTRODUCTION 7.3.2 TECHNOLOGIES AVAILABLE FOR
DYE REMOVAL 7.3.2.1 BIOLOGICAL TREATMENTS 7.3.2.2 CHEMICAL METHODS
7.3.2.3 PHYSICAL METHODS 7.3.3 DYE REMOVAL USING COMMERCIAL ACTIVATED
CARBONS
7.3.4 DYE REMOVAL USING AGRICULTURAL WASTES OR BYPRODUCTS 7.3.5
PRODUCTION OF ACS FROM AGRICULTURAL
BYPRODUCTS 7.3.5.1 PHYSICAL ACTIVATION 7.3.5.2 CHEMICAL ACTIVATION
7.3.5.3 DYE REMOVAL USING ACS FROM AGRICULTURAL BYPRODUCTS
23 7.3.6 SUMMARY 247
233 REFERENCES 248
233 234 7.4 LIQUEFACTION AND GASIFICATION OF CEREAL STRAWS MING-FEI LI
AND RUN-CANG SUN
7.4.1 HYDROTHERMAL LIQUEFACTION 253
7.4.2 SOLVOLYTIC LIQUEFACTION 256
7.4.3 THERMAL GASIFICATION 259
7.4.4 HYDROTHERMAL GASIFICATION 261
REFERENCES 263
239
245
245
7.5 BIOREFINERY STRAW FOR BIOETHANOL 239 240 KUN WANG AND RUN-CANG SUN
240 7.5.1 INTRODUCTION 267
240 7.5.2 LIGNOCELLULOSIC BIOMASS
RECALCITRANCE 268
241 7.5.3 BIOREFINERY STRAW FOR BIOETHANOL
PRODUCTION 270
242 7.5.3.1 ACID HYDROLYSIS 270
7.5.3.2 ENZYMATIC HYDROLYSIS 272
244 7.5.4 SUMMARY 282
245
REFERENCES 283
INDEX 289 |
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| edition | 1. ed. |
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| isbn | 9780444532343 |
| language | English |
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| spelling | Sun, Run-Cang Verfasser aut Cereal straw as a resource for sustainable biomaterials and biofuels chemistry, extractives, lignins, hemicelluloses and cellulose Run-Cang Sun 1. ed. Amsterdam [u.a.] Elsevier 2010 IX, 292 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Erscheinungsjahr in Vorlageform:2010 Chemische Analyse (DE-588)4009840-0 gnd rswk-swf Stroh (DE-588)4183724-1 gnd rswk-swf Biomasseverarbeitung (DE-588)4400055-8 gnd rswk-swf Stroh (DE-588)4183724-1 s Chemische Analyse (DE-588)4009840-0 s DE-604 Biomasseverarbeitung (DE-588)4400055-8 s OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020201124&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Sun, Run-Cang Cereal straw as a resource for sustainable biomaterials and biofuels chemistry, extractives, lignins, hemicelluloses and cellulose Chemische Analyse (DE-588)4009840-0 gnd Stroh (DE-588)4183724-1 gnd Biomasseverarbeitung (DE-588)4400055-8 gnd |
| subject_GND | (DE-588)4009840-0 (DE-588)4183724-1 (DE-588)4400055-8 |
| title | Cereal straw as a resource for sustainable biomaterials and biofuels chemistry, extractives, lignins, hemicelluloses and cellulose |
| title_auth | Cereal straw as a resource for sustainable biomaterials and biofuels chemistry, extractives, lignins, hemicelluloses and cellulose |
| title_exact_search | Cereal straw as a resource for sustainable biomaterials and biofuels chemistry, extractives, lignins, hemicelluloses and cellulose |
| title_full | Cereal straw as a resource for sustainable biomaterials and biofuels chemistry, extractives, lignins, hemicelluloses and cellulose Run-Cang Sun |
| title_fullStr | Cereal straw as a resource for sustainable biomaterials and biofuels chemistry, extractives, lignins, hemicelluloses and cellulose Run-Cang Sun |
| title_full_unstemmed | Cereal straw as a resource for sustainable biomaterials and biofuels chemistry, extractives, lignins, hemicelluloses and cellulose Run-Cang Sun |
| title_short | Cereal straw as a resource for sustainable biomaterials and biofuels |
| title_sort | cereal straw as a resource for sustainable biomaterials and biofuels chemistry extractives lignins hemicelluloses and cellulose |
| title_sub | chemistry, extractives, lignins, hemicelluloses and cellulose |
| topic | Chemische Analyse (DE-588)4009840-0 gnd Stroh (DE-588)4183724-1 gnd Biomasseverarbeitung (DE-588)4400055-8 gnd |
| topic_facet | Chemische Analyse Stroh Biomasseverarbeitung |
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