High energy materials: propellants, explosives and pyrotechnics
Gespeichert in:
1. Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Weinheim
Wiley-VCH
2010
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Schlagworte: | |
Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
Beschreibung: | XXXIV, 464 S. Ill., graph. Darst. |
ISBN: | 9783527326105 |
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IX CONTENTS PREFACE XIX ACKNOWLEDGMENTS XXI ABBREVIATIONS XXIII 1
SALIENT FEATURES OF EXPLOSIVES 1 1.1 INTRODUCTION 1 1.2 DEFINITION 2
1.2.1 EVOLUTION OF HEAT 3 1.2.2 RAPIDITY OF REACTION 3 1.3
CLASSIFICATION 4 1.3.1 MILITARY EXPLOSIVES 6 1.3.1.1 DETONATING OR HIGH
EXPLOSIVES 6 1.3.1.2 DEFLAGRATING OR LOW EXPLOSIVES 7 1.3.1.3
PYROTECHNICS 9 1.3.2 CIVIL EXPLOSIVES 9 1.3.2.1 PERMITTED OR PERMISSIBLE
EXPLOSIVES 9 1.3.2.2 NON-PERMITTED EXPLOSIVES 11 1.4 FUNDAMENTAL
FEATURES 14 1.4.1 COMPATIBILITY AND STABILITY 14 1.4.2 OXYGEN BALANCE
(OB) 17 1.4.3 SENSITIVITY AND SENSITIVENESS 39 1.4.3.1 SENSITIVITY TO
IMPACT 20 1.4.3.2 SENSITIVITY TO FRICTION 20 1.4.3.3 SENSITIVITY TO
SHOCK 20 1.4.3.4 SENSITIVITY TO SPARK 20 1.4.3.5 SENSITIVITY TO HEAT 20
1.4.4 HEAT OF FORMATION 24 1.4.5 HEAT OF EXPLOSION AND GASEOUS PRODUCTS
27 1.4.6 VELOCITY OF DETONATION (VOD) 30 BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/994011180 DIGITALISIERT DURCH X CONTENTS 1.5 ADDITIONAL
REQUIREMENTS FOR MILITARY EXPLOSIVES 33 1.5.1 VOLATILITY 34 1.5.2
TOXICITY 34 1.5.3 HYGROSCOPICITY 34 1.5.4 DENSITY 35 1.5.5 LIFE 35 1.5.6
AVAILABILITY, COST AND DEMILITARIZATION OR RECYCLING 35 1.5.7
ECO-FRIENDLINESS 36 1.6 APPLICATIONS OF EXPLOSIVES 37 1.6.1 MILITARY
APPLICATIONS 38 1.6.1.1 SHELLS 39 1.6.1.2 BOMBS 40 1.6.1.3 GRENADES 40
1.6.1.4 TORPEDOES 40 1.6.1.5 SHAPED CHARGES 41 1.6.1.6 WARHEADS 41 1.6.2
COMMERCIAL APPLICATIONS 43 1.6.2.1 COAL MINING 43 1.6.2.2 TUNNELING 44
1.6.2.3 QUARRYING 44 1.6.2.4 OTHER MINING 45 1.6.3 MILITARY EXPLOSIVES
AND DEVICES FOR COMMERCIAL APPLICATIONS 45 1.6.3.1 DETONATORS 45 1.6.3.2
PILOT SEAT EJECTION SYSTEM 45 1.6.3.3 HIGH ALTITUDE FUEL 46 1.6.3.4 AIR
RE-GENERATING COMPOSITION 46 1.6.3.5 METAL CLADDING AND WELDING 47
1.6.3. CONTENTS XI 1.6.6.6 OIL AND GAS INDUSTRY 62 REFERENCES 63 2
STATUS OF EXPLOSIVES 69 2.1 HISTORICAL ASPECTS 69 2.2 STATUS OF CURRENT
AND FUTURE EXPLOSIVES 70 2.2.1 BLACK POWDER 71 2.2.2 TRINITROTOLUENE 71
2.2.3 TETRYL 72 2.2.4 NITROGLYCERINE 72 2.2.5 DYNAMITE 73 2.2.6
PENTAERYTHRITOL TETRANITRATE 73 2.2.7 NITROCELLULOSE 74 2.2.8 POLYVINYL
NITRATE 75 2.2.9 MERCURY FULMINATE 76 2.2.10 LEAD AZIDE 76 2.2.11 PICRIC
ACID, LEAD PICRATE AND AMMONIUM PICRATE 78 2.2.12 LEAD STYPHNATE
(LEAD-2,4,6-TRINITRORESORCINATE) 79 2.2.13 DIAZODINITROPHENOL 79 2.2.14
TETRAZENE 80 2.2.15 MERCURIC-S-NITROTETRAZOLE 81 2.2.16 RESEARCH
DEPARTMENT EXPLOSIVE 81 2.2.17 HIGH MELTING EXPLOSIVE (OR HER MAJESTY'S
EXPLOSIVE) 82 2.2.18 'HEAT-RESISTANT' OR 'THERMALLY STABLE' EXPLOSIVES
83 XII CONTENTS 2.2.19.2 1,3,4,6-TETRANITROGLYCOLURIL 106 2.2.19.3
TETRANITROPROPANEDIUREA 106 2.2.19.4
1,3,5,5-TETRANITROHEXAHYDROPYRIMIDINE 107 2.2.20 MELT-CASTABLE
EXPLOSIVES 108 2.2.20.1 TRIS-X AND METHYL TRIS-X 108 2.2.20.2
1,3,3-TRINITROAZETIDINE 109 2.2.20.3 4,4'-DINITRO-3,3'-BIFURAZAN 120
2.2.21 INSENSITIVE HIGH EXPLOSIVES 110 2.2.21.1 OXYNITROTRIAZOLE OR
NITROTRIAZOLONE 112 2.2.21.2 DINITROGLYCOLURIL 113 2.2.21.3
AMINONITROTRIAZOLE 114 2.2.21.4
TRANS-L,4,5,8-TETRANITRO-L,4,5,8-TETRAAZADECALIN 114 2.2.22 ENERGETIC
BINDERS AND PLASTICIZERS 225 2.2.22.1 ENERGETIC BINDERS 125 2.2.22.2
ENERGETIC PLASTICIZERS 227 2.2.23 ENERGETIC MATERIALS SYNTHESIZED USING
DINITROGEN PENTOXIDE 117 2.2.24 NEWLY REPORTED EXPLOSIVES 128 2.2.25
IMPORTANT FORMULATIONS BASED ON TATB, CL-20 AND NTO 220 2.2.25.1
TATB-BASED FORMULATIONS 120 2.2.25.2 CL-20-BASED FORMULATIONS 122
2.2.25.3 NTO-BASED FORMULATIONS 124 2.2.26 INSENSITIVE MUNITIONS AND
SOME NEW INSENSITIVE EXPLOSIVES/ FORMULATION CONTENTS XIII 3 PROCESSING
AND ASSESSMENT TECHNIQUES FOR EXPLOSIVES 263 3.1 PROCESSING TECHNIQUES
FOR EXPLOSIVES 263 3.1.1 CASTING 164 3.1.1.1 MELT-CASTING 164 3.1.1.2
NORMAL CASTING 265 3.1.1.3 VIBRATION OR SEDIMENTATION CASTING 166
3.1.1.4 SQUEEZE OR PRESSURE CASTING 266 3.1.2 EXTRUSION 166 3.1.3
PRESSING 166 3.1.3.1 UNIDIRECTIONAL PRESSING 167 3.1.3.2 DOUBLE ACTION
PRESSING 167 3.1.3.3 INCREMENTAL PRESSING 167 3.1.3.4 HYDROSTATIC
PRESSING 268 3.1.3.5 ISOSTATIC PRESSING 168 3.2 FORMULATION FUNDAMENTALS
270 3.2.1 CURRENT FORMULATIONS 170 3.2.2 ALUMINIZED EXPLOSIVE
FORMULATIONS 272 3.2.3 SHEET EXPLOSIVES 272 3.2.4 PLASTIC BONDED
EXPLOSIVES 173 3.3 ASSESSMENT OF EXPLOSIVES 275 3.3.1 DETERMINATION OF
COMPATIBILITY AND STABILITY OF EXPLOSIVES 176 3.3.1.1 VACUUM STABILITY
TEST 277 3.3.1.2 HEAT TEST 179 3.3.1.3 IMPACT SENSITIVITY TEST 279 3.3.2
SENSITIVITY OF EXPLOSIVES TO HEAT, IMPACT, FRICTION, SPARK AND SHOCK 180
3.3.2.1 DETERMINATION OF HEAT SENSITIVITY 180 XIV CONTENTS 4.3 SOLID
PROPELLANTS 213 4.3.1 HOMOGENEOUS PROPELLANTS 223 4.3.1.1 SINGLE-BASE
PROPELLANTS 213 4.3.1.2 DOUBLE-BASE PROPELLANTS 224 4.3.1.3 TRIPLE-BASE
PROPELLANTS 214 4.3.2 HETEROGENEOUS PROPELLANTS 224 4.3.2.1 COMPOSITE
PROPELLANTS 224 4.3.2.2 COMPOSITE MODIFIED DOUBLE-BASE PROPELLANTS 225
4.3.2.3 FUEL-RICH PROPELLANTS 225 4.4 HYBRID PROPELLANTS 227 4.5
THIXOTROPIC PROPELLANTS 217 4.6 PERFORMANCE OF PROPELLANTS 228 4.6.1 GUN
PROPELLANTS 218 4.6.1.1 FORCE CONSTANT 218 4.6.1.2 BURNING RATE
COEFFICIENTS 229 4.6.1.3 VIVACITY 229 4.6.1.4 MUZZLE VELOCITY 229
4.6.1.5 EFFICIENCIES OF GUN SYSTEM AND CHARGE 220 4.6.2 ROCKET
PROPELLANTS 220 4.6.2.1 BURN RATE 221 4.6.2.2 THRUST 222 4.6.2.3
SPECIFIC IMPULSE (J SP ) 222 4.6.2.4 CHAMBER PRESSURE 223 4.6.2.5
CHARACTERISTIC VELOCITY (C*) 223 4.6.2.6 TEMPERATURE SENSITIVITY 224 4.7
FORMULATION OF GUN PROPELLANTS 226 CONTENTS XV 4.9.4.1 CLASSIFICATION OF
PLASTICIZERS 267 4.9.4.2 CHARACTERISTICS OF PLASTICIZERS 268 4.9.4.3
FUNCTIONS OF PLASTICIZERS 268 4.9.4.4 MIGRATION OF PLASTICIZERS 268
4.9.4.5 NOVEL PLASTICIZERS 271 NITROXYETHYL NITRAMINE PLASTICIZERS 272
POLYNITRO ALIPHATIC PLASTICIZERS 272 ROWANITE 8001 OR K-10 PLASTICIZER
273 AZIDO PLASTICIZERS 273 ENERGETIC OLIGOMERIC PLASTICIZERS 274 NITRATE
ESTER PLASTICIZERS 275 4.9.5 BONDING AGENTS 275 4.9.6 STABILIZERS 277
4.9.7 BURN-RATE MODIFIERS 280 4.9.7.1 BURN-RATE MODIFIERS FOR DB
PROPELLANTS 282 4.9.7.2 LESS TOXIC AND NON-TOXIC BURN-RATE MODIFIERS FOR
DB PROPELLANTS 284 4.9.7.3 BURN-RATE MODIFIERS FOR CMDB PROPELLANTS 284
4.9.7'.4 BURN-RATE MODIFIERS FOR COMPOSITE PROPELLANTS 284 METALLIC
OXIDES 284 FERROCENE DERIVATIVES 287 BUTACENE 287 4.10 INHIBITION OF
ROCKET PROPELLANTS 289 XVI CONTENTS 4.11 INSULATION OF ROCKET MOTORS 323
4.11.1 CHARACTERISTICS OF INSULATORS OR INSULATING MATERIALS 313 4.11.2
MATERIALS FOR INSULATION 314 4.11.3 PROCESS FOR INSULATION OF MOTORS 315
4.11.4 FUTURE MATERIALS FOR INSULATION 325 REFERENCES 326 5 PYROTECHNICS
331 5.1 INTRODUCTION 331 5.2 GENERAL FEATURES OF PYROTECHNICS 332 5.3
INGREDIENTS OF PYROTECHNIC FORMULATIONS 333 5.3.1 FUELS 333 5.3.2
OXIDIZERS 334 5.3.3 BINDERS 334 5.3.4 COOLANTS 335 5.3.5 RETARDANTS 335
5.3.6 DYES 335 5.3.7 COLOR INTENSIFIES 335 5.3.8 MODERATORS 335 5.4
IMPORTANT CHARACTERISTICS OF INGREDIENTS FOR PYROTECHNIC FORMULATIONS
336 5.4.1 DENSITY 336 5.4.2 HYGROSCOPICITY 337 5.4.3 MELTING AND BOILING
POINTS AND DECOMPOSITION TEMPERATURES 338 5.4.4 OXYGEN CONTENT OF
OXIDIZERS 339 5.4.5 THERMAL CONDUCTIVITY OF FUELS AND CONTAINERS 339
CONTENTS XVII 5.5.3 SMOKE FORMULATIONS 358 5.5.3.1 REQUIREMENTS FOR
SMOKES 359 5.5.3.2 CLASSIFICATION OF SMOKES 359 5.5.3.3 TYPES OF SMOKE
AGENTS 360 5.5.3.4 COLORED SMOKES 362 5.5.3.5 LACHRYMATORY SMOKES 364
5.5.3.6 NON-TOXIC AND ECO-FRIENDLY SMOKES 364 5.5.3.7 INFRARED SCREENING
SMOKES 365 5.5.3.8 CHEMISTRY OF PHOSPHORUS 367 STABILITY OF RED
PHOSPHORUS 369 APPLICATIONS FOR RED PHOSPHORUS 370 5.5.4 INCENDIARY
FORMULATIONS 373 5.5.4.1 CHARACTERISTICS OF INCENDIARY MATERIALS 374
ESSENTIAL CHARACTERISTICS 374 DESIRABLE CHARACTERISTICS 374 5.5.4.2
LIQUID INCENDIARIES 375 5.5.4.3 SOLID INCENDIARIES 376 5.5.4.4 CHEMISTRY
OF NAPALM 379 5.6 PERFORMANCE ASSESSMENT OF PYROTECHNIC FORMULATIONS 382
5.6.1 IGNITION TEMPERATURE 382 5.6.2 MECHANICAL PROPERTIES 382 5.6.3
MOISTURE ABSORPTION 382 5.6.4 HEAT OUTPUT AND GAS VOLUME 382 5.6. XVIII
CONTENTS 5.8.8 NANOMATERIALS FOR EXPLOSIVE FORMULATIONS 402 5.9 RECENT
AND FUTURE TRENDS IN PYROTECHNICS 401 5.9.1 ENERGETIC BINDERS,
PLASTICIZERS AND OXIDIZERS 402 5.9.2 EXOTIC SALTS OF LITHIUM, RUBIDIUM
AND CAESIUM AND THEIR FORMULATIONS 402 5.9.3 DINITRAMIDE SALTS OF ALKALI
METALS AND THEIR FORMULATIONS 403 5.9.4 MOISTURE RESISTANT COATINGS FOR
METAL POWDERS 404 5.9.5 NEW FUELS AS SUBSTITUTE FOR CHARCOAL 405 5.9.6
HIGH NITROGEN CONTENT-HIGH ENERGY MATERIALS FOR PYROTECHNIC FORMULATIONS
406 REFERENCES 406 6 EXPLOSIVE AND CHEMICAL SAFETY 423 6.1 SAFETY 413
6.2 EXPLOSIVE SAFETY 424 6.2.1 UN CLASSIFICATION OF DANGEROUS GOODS AND
HAZARDOUS CHEMICALS 416 6.2.1.1 HAZARD DIVISIONS 417 6.2.1.2
COMPATIBILITY GROUPS FOR EXPLOSIVES AND AMMUNITION 420 6.2.1.3 HAZARD
CLASSIFICATION 422 6.3 FIRE SAFETY 422 6.3.1 FIRE DIVISIONS 423 6.3.2
CLASSES OF FIRES, FIRE EXTINGUISHERS AND FIRE FIGHTING 424 6.3.2.1
CLASSES OF FIRES 425 6.3.2. |
any_adam_object | 1 |
author | Agrawal, Jai Prakash |
author_facet | Agrawal, Jai Prakash |
author_role | aut |
author_sort | Agrawal, Jai Prakash |
author_variant | j p a jp jpa |
building | Verbundindex |
bvnumber | BV025605967 |
classification_rvk | VN 5470 VN 5480 |
ctrlnum | (OCoLC)574874924 (DE-599)BVBBV025605967 |
dewey-full | 662.2 |
dewey-hundreds | 600 - Technology (Applied sciences) |
dewey-ones | 662 - Explosives, fuels & related products |
dewey-raw | 662.2 |
dewey-search | 662.2 |
dewey-sort | 3662.2 |
dewey-tens | 660 - Chemical engineering |
discipline | Chemie / Pharmazie |
format | Book |
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id | DE-604.BV025605967 |
illustrated | Illustrated |
indexdate | 2024-07-20T10:34:59Z |
institution | BVB |
isbn | 9783527326105 |
language | English |
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oclc_num | 574874924 |
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physical | XXXIV, 464 S. Ill., graph. Darst. |
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publisher | Wiley-VCH |
record_format | marc |
spelling | Agrawal, Jai Prakash Verfasser aut High energy materials propellants, explosives and pyrotechnics Jai Prakash Agrawal Weinheim Wiley-VCH 2010 XXXIV, 464 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Pyrotechnik (DE-588)4047927-4 gnd rswk-swf Kraftstoff (DE-588)4073754-8 gnd rswk-swf Energetisches Material (DE-588)7643045-5 gnd rswk-swf Explosivstoff (DE-588)4016013-0 gnd rswk-swf Energetisches Material (DE-588)7643045-5 s Explosivstoff (DE-588)4016013-0 s Pyrotechnik (DE-588)4047927-4 s Kraftstoff (DE-588)4073754-8 s 1\p DE-604 text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3294534&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020201083&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
spellingShingle | Agrawal, Jai Prakash High energy materials propellants, explosives and pyrotechnics Pyrotechnik (DE-588)4047927-4 gnd Kraftstoff (DE-588)4073754-8 gnd Energetisches Material (DE-588)7643045-5 gnd Explosivstoff (DE-588)4016013-0 gnd |
subject_GND | (DE-588)4047927-4 (DE-588)4073754-8 (DE-588)7643045-5 (DE-588)4016013-0 |
title | High energy materials propellants, explosives and pyrotechnics |
title_auth | High energy materials propellants, explosives and pyrotechnics |
title_exact_search | High energy materials propellants, explosives and pyrotechnics |
title_full | High energy materials propellants, explosives and pyrotechnics Jai Prakash Agrawal |
title_fullStr | High energy materials propellants, explosives and pyrotechnics Jai Prakash Agrawal |
title_full_unstemmed | High energy materials propellants, explosives and pyrotechnics Jai Prakash Agrawal |
title_short | High energy materials |
title_sort | high energy materials propellants explosives and pyrotechnics |
title_sub | propellants, explosives and pyrotechnics |
topic | Pyrotechnik (DE-588)4047927-4 gnd Kraftstoff (DE-588)4073754-8 gnd Energetisches Material (DE-588)7643045-5 gnd Explosivstoff (DE-588)4016013-0 gnd |
topic_facet | Pyrotechnik Kraftstoff Energetisches Material Explosivstoff |
url | http://deposit.dnb.de/cgi-bin/dokserv?id=3294534&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020201083&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT agrawaljaiprakash highenergymaterialspropellantsexplosivesandpyrotechnics |