Ion-pair chromatography and related techniques:
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Boca Raton, Fla.
CRC Press
2010
|
| Series: | Analytical chemistry series
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturangaben |
| Physical Description: | XIII, 201 S. graph. Darst. |
| ISBN: | 9781439800966 |
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MARC
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Record in the Search Index
| _version_ | 1804142788281892864 |
|---|---|
| adam_text | IMAGE 1
CONTENTS PREFAEE XI
THE AUTHOR XIII
CHAPTER 1 INTRODUETION 1
REFERENEE 2
CHAPTER 2 ELEETROLYTE SOLUTIONS AND HISTORIEAL CONEEPT OF ION-PAIRING 3
2.1 PHENOMENOLOGIEAL TREATMENT 3
2.2 ION-SOLVENT INTERAETIONS 4
2.3 ION-ION ASPEEIFIE INTERAETIONS 7
2.4 INTERAETIONS OF IONS WITH NON-ELEETROLYTES 9
2.5 CRITIEAL REVIEW OF HISTORY OF THEORETIEAL TREATMENTS OFION-PAIRING
12
2.5.1 FROM THE BEGINNING TO BJERRUM S MODEL 12
2.5.2 FURTHER DEVELOPMENTS 14
2.5.3 HYDROPHOBIE LON-PAIRING CONEEPT 16
2.6 THERMODYNAMIE PROPERTIES OF ION-PAIRS 18
2.7 TEEHNIQUES FOR STUDYING ION-PAIRING 19
2.7.1 CONDUETOMETRY 19
2.7.2 POTENTIOMETRY 19
2.7.3 SPEETROSEOPIE METHODS 20
2.7.4 AETIVITY MEASUREMENT 20
2.7.5 RELAXATION METHODS 20
2.7.5.1 DIELEETRIE RELAXATION SPEETROSEOPY (DRS) 20
2.7.5.2 ULTRASONIE RELAXATION (UR) 21
2.7.6 SEPARATIVE METHODS 21
REFERENEES 22
CHAPTER 3 RETENTION MODELING AS FUNETION OF MOBILE PHASE COMPOSITION 29
3.1 THEORETIEAL MODELS OF ION-PAIR CHROMATOGRAPHY (IPQ 29 3.1.1
STOIEHIOMETRIE MODELS 30
3.1.2 NON-STOIEHIOMETRIE MODELS 32
3.2 EMPIRIEAL MODELS OF IPC .46
3.2.1 CHEMOMETRIEAL OPTIMIZATION METHODS 46
3.2.2 ARTIFIEIAL NEURAL NETWORK (ANN) MODELS 49 REFERENEES 51
VII
IMAGE 2
CHAPTER 4 MODELING OF RETENTION AS A FUNCTION OF ANALYTE NATURE 57
REFERENCES 59
CHAPTER 5 STATIONARY PHASES 61
5.1 REVERSED PHASE IPC 62
5.1.1 SILICA-BASED STATIONARY PHASES AND SILANOPHILIC INTERACTIONS 62
5.1.2 OTHER REVERSED PHASE STATIONARY PHASES 65 5.2 NORMAL PHASE IPC AND
OTHER STATIONARY PHASES 66
REFERENCES 67
CHAPTER 6 DEVELOPMENTS IN COLUMN TECHNOLOGY AND FAST IPC 71
6.1 ULTRAHIGH PERFORMANCE LIQUID CHROMATOGRAPHY (U-HPLC) 71
6.2 MONOLITHIC COLUMNS 75
REFERENCES 76
CHAPTER 7 ION-PAIR REAGENTS (IPR) 79
7.1 TRADITIONAL IPRS 79
7.2 VOLATILE IPRS 81
7.3 CHAOTROPIC SALTS 82
7.4 IONIC LIQUID-BASED IPRS 84
7.5 UNUSUAL IPRS 88
7.6 IPR COUNTER IONS 88
7.7 CONCLUSIONS 90
REFERENCES 90
CHAPTER 8 ORGANIC MODIFIERS 99
8.1 ORGANIC MODIFIER CONCENTRATION IN ELUENT.. 99
8.2 NATURE OF ORGANIC MODIFIERS 101
8.3 GRADIENT ELUTION 102
REFERENCES 103
CHAPTER 9 ROLE OF ELUENT PH IN IPE. 109
9.1 IPC VERSUS RP-HPLC 109
9.2 PH-DEPENDENT SILANOL IONIZATION 113
REFERENCES 114
CHAPTER 10 TEMPERATURE 117
10.1 INFLUENCE OF TEMPERATURE ON COLUMN EFFICIENCY 117 10.2 INFLUENCE OF
TEMPERATURE ON SELECTIVITY UNDER RP-HPLC AND IPC CONDITIONS 117
REFERENCES 121
IMAGE 3
CHAPTER 11 SPECIAL IPC MODES AND VARIATIONS 125
11.1 MIXTURE OF DIFFERENT IPRS IN MOBILE PHASE 125
11.2 PERMANENTLY COATED COLUMNS 125
11.3 IPRS ADDED ONLY TO SAMPLE SOLUTION AND GHOST PEAKS 127
11.4 SPECIAL ADDITIVES IN MOBILE PHASE 128
11.5 MODIFICATION OF ELUENT IONIC STRENGTH AT CONSTANT IPR CONCENTRATION
128
REFERENCES 131
CHAPTER 12 DETECTION AND HYPHENATION 135
12.1 UV-VIS DETECTORS 136
12.2 FLUORESCENCE DETECTORS 140
12.3 ELECTRICAL CONDUCTIVITY DETECTORS 142
12.4 ELECTROCHEMICAL DETECTORS 142
12.5 EVAPORATIVE LIGHT SCATTERING DETECTORS 145
12.6 UNUSUAL DETECTORS 145
12.7 HYPHENATION TECHNIQUES 146
12.7.1 IPC-MS 146
12.7.2 IPC-ICP AND OTHER UNUSUAL HYPHENATIONS 151 REFERENCES 153
CHAPTER 13 EXAMPLES OF APPLICATIONS 161
13.1 INORGANIC AND ORGANOMETALLIC SPECIES 161
13.2 FOOD ANALYSIS 163
13.3 LIFE SCIENCE AND MEDICINE 163
13.4 PHARMACEUTICAL, TOXICOLOGICAL, AND C1INICAL ANALYSIS 165 13.5
ENVIRONMENTAL ANALYSIS 166
13.6 ENANTIOMERIC SEPARATIONS 168
REFERENCES 169
CHAPTER 14 IPC VERSUS COMPETITIVE TECHNIQUES 179
REFERENCES 180
CHAPTER 15 ION-PAIRING IN DIFFERENT ANALYTICAL TECHNIQUES 183
15.1 CAPILLARY ELECTROPHORESIS (CE) AND RELATED TECHNIQUES 183
15.2 SUPERCRITICAL FLUID CHROMATOGRAPHY (SFC) AND OTHER TECHNIQUES 184
15.3 UV-VISIBLE SPECTROPHOTOMETRY 184
15.4 EXTRACTION AND SAMPLE PREPARATION 185
REFERENCES 186
IMAGE 4
X CONTENTS
CHAPTER 16 NON-SEPARATIVE APPLICATIONS OF IPC 189
REFERENCES 191
CHAPTER 17 CONCLUSIONS AND FUTURE RESEARCH NEEDS 193
INDEX 195
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| discipline | Chemie / Pharmazie |
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| indexdate | 2024-07-09T22:37:20Z |
| institution | BVB |
| isbn | 9781439800966 |
| language | English |
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| spelling | Cecchi, Teresa Verfasser aut Ion-pair chromatography and related techniques Teresa Cecchi Boca Raton, Fla. CRC Press 2010 XIII, 201 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Analytical chemistry series Literaturangaben Ionenpaarchromatographie (DE-588)4224589-8 gnd rswk-swf Ionenpaarchromatographie (DE-588)4224589-8 s DE-604 OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020198916&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Cecchi, Teresa Ion-pair chromatography and related techniques Ionenpaarchromatographie (DE-588)4224589-8 gnd |
| subject_GND | (DE-588)4224589-8 |
| title | Ion-pair chromatography and related techniques |
| title_auth | Ion-pair chromatography and related techniques |
| title_exact_search | Ion-pair chromatography and related techniques |
| title_full | Ion-pair chromatography and related techniques Teresa Cecchi |
| title_fullStr | Ion-pair chromatography and related techniques Teresa Cecchi |
| title_full_unstemmed | Ion-pair chromatography and related techniques Teresa Cecchi |
| title_short | Ion-pair chromatography and related techniques |
| title_sort | ion pair chromatography and related techniques |
| topic | Ionenpaarchromatographie (DE-588)4224589-8 gnd |
| topic_facet | Ionenpaarchromatographie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020198916&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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