Fundamentals of sustainable chemical science:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Boca Raton [u.a.]
CRC Press
2009
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 376 S. graph. Darst. |
| ISBN: | 1439802394 9781439802397 |
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Datensatz im Suchindex
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| adam_text | Titel: Fundamentals of sustainable chemical science
Autor: Manahan, Stanley E.
Jahr: 2009
CONTENTS
PREFACE XIII
AUTHOR XV
1. INTRODUCTION TO CHEMISTRY AND
GREEN CHEMISTRY 1
1.1. IF WE DO NOT CHANGE DIRECTION 1
1.2. THE ESSENTIAL ROLE OF CHEMISTRY 2
1.3. ENVIRONMENTAL CHEMISTRY AND GREEN CHEMISTRY 3
1.4. A MINI-COURSE IN CHEMISTRY 5
1.5. THE BUILDING BLOCKS OF MATTER 5
Subatomic Particles and Atoms 5
Atoms and Elements 6
The Periodic Table 7
1.6. CHEMICAL BONDS AND COMPOUNDS 8
Chemical Compounds 9
Ionic Bonds 10
Summary of Chemical Compounds and the Chemical Bond 11
Molecular Mass 11
1.7. CHEMICAL REACTIONS AND EQUATIONS 12
1.8. NUMBERS IN CHEMISTRY: EXPONENTIAL NOTATION 12
Addition and Subtraction of Exponential Numbers 13
Multiplication and Division of Exponential Numbers 14
1.9. SIGNIFICANT FIGURES AND UNCERTAINTIES IN NUMBERS 15
Significant Figures in Calculations 15
Rounding Numbers 17
Use of Three Significant Digits 17
1.10. MEASUREMENTS AND SYSTEMS OF MEASUREMENT 18
SI Units of Measurement 18
Multiples of Units 18
Metric and English Systems of Measurement 18
1.11. UNITS OF MASS 20
1.12. UNITS OF LENGTH 21
1.13. UNITS OF VOLUME 22
vi Contents
1.14. TEMPERATURE, HEAT, AND ENERGY 23
Temperature Scales 23
Melting Point and Boiling Point 26
Heat and Energy 27
1.15. PRESSURE 27
1.16. UNITS AND THEIR USE IN CALCULATIONS 28
Unit Conversion Factors 28
CHAPTER SUMMARY 31
Answers to Chapter Summary 33
LITERATURE CITED 36
QUESTIONS AND PROBLEMS 37
2. MATTER AND MATERIALS 45
2.1. WHAT IS MATTER AND WHY DOES IT MATTER
FOR SUSTAINABELITY AND GREEN CHEMISTRY? 45
2.2. CLASSIFICATION OF MATTER 46
Some General Types of Matter 47
Mixtures and Pure Substances 48
Summary of the Classification of Matter 49
2.3. QUANTITY OF MATTER: THE MOLE 49
The Mole and Avogadro s Number 50
2.4. PHYSICAL PROPERTIES OF MATTER 50
Density 51
Specific Gravity 52
Color 53
Electromagnetic Radiation and Green Chemistry 54
2.5. STATES OF MATTER 55
2.6. GASES 56
The Gas Laws 57
Gas Law Calculations 59
2.7. LIQUIDS AND SOLUTIONS 62
Evaporation and Condensation of Liquids 2
Vapor Pressure
Solutions 63
2.8. SOLIDS 6S
2.9. THERMAL PROPERTEES W
Melting Point 6°
Boiling Point 66
Specific Heat ^
Heat of Vaporization 68
Heat of Fusion 6^
Phase Change Materials in Green Technology
2.10. SEPARATION AND CHARACTERIZATION OF MATTER 70
Distillation 7®
Separation in Waste Treatment
2.11. THE GREEN CHEMISTRY OF MATTER 7*
CHAPTER SUMMARY 75
QUESTIONS AND PROBLEMS 81
Contents vii
3. ATOMS AND ELEMENTS 87
3.1. ATOMS AND ELEMENTS 87
3.2. THE ATOMIC THEORY 87
Laws That Are Explained by Dalton s Atomic Theory 87
Small Size of Atoms 89
Atomic Mass 90
3.3. SUBATOMIC PARTICLES 90
3.4. THE BASIC STRUCTURE OF THE ATOM 91
Atomic Number, Isotopes, and Mass Number of Isotopes 91
Electrons in Atoms 92
3.5. DEVELOPMENT OF THE PERIODIC TABLE 93
3.6. HYDROGEN, THE SIMPLEST ATOM 93
Designation of Hydrogen in the Periodic Table 94
Showing Electrons in Hydrogen Atoms and Molecules 94
Properties of Elemental Hydrogen 94
Production and Uses of Elemental Hydrogen 95
3.7. HELIUM, THE FIRST ATOM WITH A FILLED ELECTRON SHELL 95
Occurrence and Uses of Helium 96
3.8. LITHIUM, THE FIRST ATOM WITH BOTH INNER
AND OUTER ELECTRONS 97
Uses of Lithium 97
Lithium, a Key Material in Green Technology 99
3.9. THE SECOND PERIOD, ELEMENTS 4-10 99
Beryllium, Atomic Number 4 99
Boron, Atomic Number 5 100
Carbon, Atomic Number 6 101
Nitrogen, Atomic Number 7 101
Oxygen, Atomic Number 8 102
Fluorine, Atomic Number 9 103
Neon, Atomic Number 10 103
3.10. ELEMENTS 11-20, AND BEYOND 104
The Elements Beyond Calcium 106
3.11. A MORE DETAHJED LOOK AT ATOMIC STRUCTURE 107
Electromagnetic Radiation 107
3.12. QUANTUM AND WAVE MECHANICAL MODELS OF
ELECTRONS IN ATOMS 108
The Wave Mechanical Model of Atomic Structure 109
Multielectron Atoms and Quantum Numbers 111
3.13. ENERGY LEVELS OF ATOMIC ORBITALS 113
Hund s Rule of Maximum Multiplicity 115
3.14. SHAPES OF ATOMIC ORBITALS 116
3.15. ELECTRON CONFIGURATION 117
3.16. ELECTRONS IN THE FIRST 20 ELEMENTS 118
Electron Configuration of Hydrogen 118
Electron Configuration of Helium 119
Electron Configurations of Elements 2—20 119
Lithium 119
Valence Electrons 119
viii Contents
Beryllium 120
Filling the 2p Orbitals 120
Filling the 3s, 3p, and 4s Orbitals 121
3.17. ELECTRON CONFIGURATIONS AND THE PERIODIC TABLE 122
CHAPTER SUMMARY 126
Answers to Chapter Summary 128
QUESTIONS AND PROBLEMS 131
4. CHEMICAL BONDS, MOLECULES,
AND COMPOUNDS 139
4.1. CHEMICAL BONDS AND COMPOUND FORMATION 139
Chemical Bonds and Valence Electrons 140
4.2. CHEMICAL BONDING AND THE OCTET RULE 141
The Octet Rule for Some Diatomic Gases 141
The Octet Rule for Chemical Compounds 141
4.3. IONIC BONDING 142
Electron Configurations of Ions from a Single Atom 142
Sodium Chloride as an Ionic Compound 143
Energetics in Ionic Bonding 145
Energy of Ion Attraction 146
Lattice Energy 147
Ion Size 147
Formation of Some Example Ionic Compounds 149
4.4. FUNDAMENTALS OF COVALENT BONDING 150
Chemical Bonds and Energy 150
Covalent Bonding 150
4.5. COVALENT BONDS IN COMPOUNDS 152
4.6. SOME OTHER ASPECTS OF COVALENT BONDING 154
Multiple Bonds and Bond Order 154
Lengths and Strengths of Multiple Bonds 155
Electronegativity and Covalent Bonding 156
Sharing Electrons—Unequally 157
Coordinate Covalent Bonds 158
Compounds That Do Not Conform to the Octet Rule 159
Resonance Structures 160
4.7. CHEMICAL FORMULAS OF COMPOUNDS i61
What a Chemical Formula States 161
Percentage Composition from Chemical Formulas 162
Calculation of Chemical Formulas 163
Empirical Formula from Percentage Composition 164
4.8. THE NAMES OF CHEMICAL COMPOUNDS l(n
Binary Molecular Compounds 167
Names of Ionic Compounds 168
4.9. ACn)S, BASES, AND SALTS I70
Acids 170
Bases 1?1
Salts m
CHAPTER SUMMARY in
Answers to Chapter Summary 173
QUESTIONS AND PROBLEMS 175
Contents ix
5. CHEMICAL REACTIONS, EQUATIONS,
AND STOICHIOMETRY 181
5.1. THE SENTENCES OF CHEMISTRY 181
Chemical Reactions and Equations: The Sentences of the Chemical Language 181
Quantitative Calculations from Chemical Equations 182
5.2. THE INFORMATION IN A CHEMICAL EQUATION 182
Chemical Reactions 182
Expressing a Chemical Reaction as a Chemical Equation 182
Symbols Used in Chemical Equations 183
5.3. BALANCING CHEMICAL EQUATIONS 184
Balancing the Equation for the Reaction of Hydrogen Sulfide
with Sulfur Dioxide 184
Some Other Examples of Balancing Equations 185
Summary of Steps in Balancing an Equation 187
5.4. WILL A REACTION OCCUR? 188
5.5. HOW FAST DOES A REACTION GO? 190
5.6. CLASSIFICATION OF CHEMICAL REACTIONS 190
5.7. QUANTITATIVE INFORMATION FROM CHEMICAL REACTIONS 193
Review of Quantitative Chemical Terms 193
Calcination of Limestone 194
5.8. WHAT IS STOICHIOMETRY AND WHY IS IT IMPORTANT? 195
The Mole Ratio Method of Stoichiometric Calculations 196
CHAPTER SUMMARY 200
Answers to Chapter Summary 202
QUESTIONS AND PROBLEMS 203
6. ACIDS, BASES, AND SALTS 209
6.1. THE IMPORTANCE OF ACn)S, BASES, AND SALTS 209
6.2. THE NATURE OF ACH)S, BASES, AND SALTS 210
Hydrogen Ion and Hydroxide Ion 210
Acids 210
Bases 211
Salts 211
Amphoteric Substances 212
Metal Ions as Acids 212
Salts That Act as Bases 213
Salts That Act as Acids 213
6.3. CONDUCTANCE OF ELECTRICITY BY ACIDS, BASES,
AND SALTS IN SOLUTION 214
Electrolytes 215
6.4. DISSOCIATION OF ACIDS AND BASES IN WATER 216
6.5. THE HYDROGEN ION CONCENTRATION AND BUFFERS 218
Buffers 219
6.6. pH AND THE RELATIONSHIP BETWEEN HYDROGEN ION
AND HYDROXIDE ION CONCENTRATIONS 219
Acid-Base Equilibria 221
6.7. PREPARATION OF ACn)S 222
6.8. PREPARATION OF BASES 223
6.9. PREPARATION OF SALTS 225
x Contents
6.10. ACID SALTS AND BASIC SALTS 227
Acid Salts 227
Basic Salts 227
6.11. WATER OF HYDRATION 227
6.12. NAMES OF ACIDS, BASES, AND SALTS 228
Acids 228
Bases 228
Salts 229
CHAPTER SUMMARY 232
Answers to Chapter Summary 233
QUESTIONS AND PROBLEMS 236
7. SOLUTIONS AND SOLVENTS 243
7.1. WHAT ARE SOLUTIONS? WHY ARE THEY IMPORTANT? 243
Reactions in Solution 244
Solutions in Living Systems 245
Solutions in the Environment 245
Industrial Uses of Solutions 246
7.2. SOLVENTS 246
7.3. WATER—A UNIQUE SOLVENT 247
7.4. THE SOLUTION PROCESS AND SOLUBILITY 249
7.5. SOLUTION CONCENTRATIONS 251
Molar Concentration 252
Diluting Solutions 254
Molar Concentration of H+ Ion and pH 255
Solubility 256
7.6. STANDARD SOLUTIONS AND TITRATIONS 257
7.7. PHYSICAL PROPERTIES OF SOLUTIONS 259
Freezing Point Depression 259
Boiling Point Elevation 259
Osmosis 259
7.8. SOLUTION EQUILIBRIA 261
Solution Equilibria 261
Solubilities of Gases 263
7.9. COLLOIDAL SUSPENSIONS 26S
Kinds of Colloidal Particles 265
Colloid Stability 266
Coagulation and Flocculation of Colloidal Particles 268
CHAPTER SUMMARY 268
Answers to Chapter Summary 270
QUESTIONS AND PROBLEMS 272
8. CHEMISTRY AND ELECTRICITY 275
8.1. CHEMISTRY AND ELECTRICITY 275
8.2. OXIDATION AND REDUCTION 276
8.3. OXIDATION-REDUCTION IN SOLUTION 279
8.4. THE DRY CELL 2SL
8.5. STORAGE BATTERIES 2»3
Contents xi
8.6. USING ELECTRICITY TO MAKE CHEMICAL REACTIONS OCCUR 286
Electrolysis of Water: A Green Technology 286
Electrolytic Manufacture of Chemicals 288
8.7. ELECTROPLATING 289
8.8. FUEL CELLS 290
8.9. SOLAR CELLS 291
8.10. REACTION TENDENCY 292
Measurement of E° 293
E° Values and Reaction Tendency 294
8.11. EFFECT OF CONCENTRATION: NERNST EQUATION 296
8.12. POTENTIOMETRY 297
8.13. CORROSION 299
CHAPTER SUMMARY 300
Answers to Chapter Summary 302
QUESTIONS AND PROBLEMS 304
9. ORGANIC CHEMISTRY 307
9.1. ORGANIC CHEMISTRY 307
Molecular Geometry in Organic Chemistry 307
9.2. HYDROCARBONS 308
Alkanes 308
Alkenes and Alkynes 314
Alkenes and Cis—Trans Isomerism 315
Condensed Structural Formulas 315
Aromatic Hydrocarbons 316
9.3. ORGANIC FUNCTIONAL GROUPS AND CLASSES
OF ORGANIC COMPOUNDS 318
Organo-Oxygen Compounds 319
Organonitrogen Compounds 321
Organohalide Compounds 322
Organosulfur Compounds 326
Organophosphorus Compounds 328
9.4. SYNTHETIC POLYMERS 330
CHAPTER SUMMARY 332
Answers to Chapter Summary 334
SUPPLEMENTARY REFERENCES 335
QUESTIONS AND PROBLEMS 336
10. BIOLOGICAL CHEMISTRY 339
10.1. BIOCHEMISTRY 339
Biomolecules 340
10.2. BIOCHEMISTRY AND THE CELL 340
Major Cell Features 340
10.3. PROTEINS 342
Protein Structure 344
Denaturation of Proteins 346
10.4. CARBOHYDRATES 347
10.5. LIPIDS 349
xii Contents
10.6. ENZYMES 351
10.7. NUCLEIC ACroS 355
Nucleic Acids in Protein Synthesis 358
Modified DNA 359
10.8. RECOMBINANT DNA AND GENETIC ENGINEERING 359
10.9. METABOLIC PROCESSES 360
Energy-Yielding Processes 360
CHAPTER SUMMARY 361
Answers to Chapter Summary 362
LITERATURE CITED 363
SUPPLEMENTARY REFERENCES 364
QUESTIONS AND PROBLEMS 364
INDEX 367
|
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| spelling | Manahan, Stanley E. 1937- Verfasser (DE-588)172247438 aut Fundamentals of sustainable chemical science Stanley E. Manahan Boca Raton [u.a.] CRC Press 2009 XII, 376 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Grüne Chemie (DE-588)7563215-9 gnd rswk-swf Chemie (DE-588)4009816-3 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Chemie (DE-588)4009816-3 s DE-604 Grüne Chemie (DE-588)7563215-9 s HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020190077&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
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| title | Fundamentals of sustainable chemical science |
| title_auth | Fundamentals of sustainable chemical science |
| title_exact_search | Fundamentals of sustainable chemical science |
| title_full | Fundamentals of sustainable chemical science Stanley E. Manahan |
| title_fullStr | Fundamentals of sustainable chemical science Stanley E. Manahan |
| title_full_unstemmed | Fundamentals of sustainable chemical science Stanley E. Manahan |
| title_short | Fundamentals of sustainable chemical science |
| title_sort | fundamentals of sustainable chemical science |
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