Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Dordrecht [u.a.]
Kluwer
2002
|
| Schriftenreihe: | Understanding chemical reactivity
23 |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | VII, 186 S. graph. Darst. |
| ISBN: | 1402010931 |
Internformat
MARC
| LEADER | 00000nam a2200000 cb4500 | ||
|---|---|---|---|
| 001 | BV025295223 | ||
| 003 | DE-604 | ||
| 005 | 20130917 | ||
| 007 | t | ||
| 008 | 100417s2002 d||| |||| 00||| eng d | ||
| 020 | |a 1402010931 |9 1-4020-1093-1 | ||
| 035 | |a (OCoLC)730961695 | ||
| 035 | |a (DE-599)BVBBV025295223 | ||
| 040 | |a DE-604 |b ger |e rakwb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-11 | ||
| 082 | 0 | |a 541.226 | |
| 084 | |a UH 5710 |0 (DE-625)145690: |2 rvk | ||
| 084 | |a UH 6030 |0 (DE-625)145737: |2 rvk | ||
| 084 | |a UM 3260 |0 (DE-625)145885: |2 rvk | ||
| 245 | 1 | 0 | |a Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase |c ed. by Thomas Elsaesser ... |
| 264 | 1 | |a Dordrecht [u.a.] |b Kluwer |c 2002 | |
| 300 | |a VII, 186 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 1 | |a Understanding chemical reactivity |v 23 | |
| 700 | 1 | |a Elsässer, Thomas |d 1957- |0 (DE-588)13920542X |4 edt | |
| 830 | 0 | |a Understanding chemical reactivity |v 23 |w (DE-604)BV000021931 |9 23 | |
| 856 | 4 | 2 | |m HBZ Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019927947&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-019927947 | ||
Datensatz im Suchindex
| _version_ | 1804142364338421760 |
|---|---|
| adam_text | Titel: Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase
Autor: Elsässer, Thomas
Jahr: 2002
Contents
1
Ultrafast Dynamics of Hydrogen Bonding and Proton
Transfer in the Condensed Phase
T Elsaesser and H.J. Bakker
1 Introduction
2 Outline of the Book
2
Infra-Red Spectra of Hydrogen Bonded Systems:
Theory and Experiment
S. Bratos, J-CI. Leicknam, G. Gallot and H. Ratajczak
1 Introduction
2 Classical Infra-Red Spectroscopy
2.1 Phenomenological Description
2.2 Statistical Theory of Band Shapes.
Semi-Emipiral Theories
2.3 Statistical Theory of Band Shapes.
Molecular Dynamics Simulations
2.4 Power and Limits of Classical
Infra-red Spectroscopy
3 Time-Resolved Infra-red Spectroscopy
3.1 Basic Information
3.2 Femtochemistry of Water
3.3 Phenomenological Description
3.4 Statistical Theory of Band Shapes
4 Conclusions
References
3
Femtosecond Mid-Infrared Spectroscopy of Water
H.J. Bakker
1 Introduction
2 Femtosecond Mid-Infrared Spectroscopy
2.1 Generation of Femtosecond Mid-Infrared Pulses
2.2 Nonlinear Vibrational Spectroscopy of Water
2.3 Aqueous Samples
1
1
3
5
5
7
7
10
16
18
19
19
19
21
24
27
28
31
31
32
32
33
36
V
vi
Ultrafast Hydrogen Bonding Dynamics and Proton Transfer
3 Energy Transfer in Liquid Water
3.1 Vibrational Relaxation of HD0:D20
3.2 Vibrational Relaxation of Liquid H20
3.3 Vibrational Relaxation of the O-D Stretch
Vibration of Liquid Water
3.4 Vibrational Relaxation of Water in Aqueous
Solvent Shells
3.5 Resonant Intermolecular Energy Transfer
in Liquid H20
4 Hydrogen-Bond Dynamics of Liquid Water
4.1 Experimental Results
4.2 Brownian Oscillator Model
4.3 Hydrogen-Bond versus Deuterium-Bond
Dynamics
4.4 Hydrogen-Bond Dynamics of Water in Aqueous
Solvent Shells
4.5 Relation between Hydrogen-Bond Length and
Local Liquid Structure
5 Refined Quantum-Mechanical Modeling of the Spectral
Response of Liquid Water
6 Conclusions
References
Proton Transfer Reactions and Hydrogen Bonding in Solution
P.M. Kiefer and J.T. Hynes
1 Introduction
2 Adiabatic Proton Transfer
3 Nonadiabatic Tunneling Proton Transfer
4 Concluding Remarks
References
5
Ab-initio Reaction Paths and Potential-Energy Functions for Excited-
State Intra- and Intermolecular Hydrogen-Transfer Processes
A.L. Sobolewski and W. Domcke
1 Introduction
2 Theoretical Methodology
2.1 Reaction Path Concept
2.2 Electronic-Structure Methods
3 Theoretical Results
3.1 An ESIHT Model System: Malonaldehyde
3.1.1 Hydrogen Transfer
3.1.2 Hydrogen Detachment
3.2 Real ESIHT Systems
38
38
41
44
44
48
51
52
55
58
60
64
65
69
70
73
73
75
84
87
90
93
94
96
96
96
98
98
100
102
104
Vll
3.3 ESIHT in H-Bonded Molecular Complexes 106
3.4 A Generic Mechanistic Model of the ESIHT
Reaction and Photostability 108
3.5 Photoinduced Hydrogen Transfer to the Solvent 109
Conclusions 114
References 115
6
Ultrafast Excited State Hydrogen Transfer in the Condensed Phase 119
T. Elsaesser
1 Introduction 119
2 Experimental Techniques 123
3 Vibrational Spectroscopy of Ultrafast Hydrogen
Transfer 128
3.1 Resonance Raman Spectroscopy 128
3.2 Femtosecond Infrared Spectroscopy 132
4 Excited State Hydrogen Transfer: Transient
Electronic Spectra 136
5 Vibrational Relaxation and Redistribution Induced by
Hydrogen Transfer 143
6 Conclusions 148
References 151
7
Proton Dissociation and Solute-Solvent Interactions Following
Electronic Excitation of Photoacids 155
E. Pines and D. Pines
1 Introduction 155
1.1 Neutral and Cationic Photoacids 157
1.2 A General Description of Photoacidity 160
1.2.1 Neutral Photoacids 160
1.2.2 Cationic Photoacids 162
2 Kinetic Processes Initiated by Photoacid Proton
Dissociation 163
2.1 Diffusion-Controlled Proton Transfer Reactions 163
2.2 Proton Transfer to Solvent (PTTS) from Photoacids 166
2.3 Proton Transfer in Bulk Water (The Grotthus
Mechanism) 171
3 Hydrogen Bonding Interaction of Photoacids 174
4 Solvation Dynamics and Hydrogen Bonding Interactions
of Photoacids 177
5 Summary 178
References 179
Index 185
|
| any_adam_object | 1 |
| author2 | Elsässer, Thomas 1957- |
| author2_role | edt |
| author2_variant | t e te |
| author_GND | (DE-588)13920542X |
| author_facet | Elsässer, Thomas 1957- |
| building | Verbundindex |
| bvnumber | BV025295223 |
| classification_rvk | UH 5710 UH 6030 UM 3260 |
| ctrlnum | (OCoLC)730961695 (DE-599)BVBBV025295223 |
| dewey-full | 541.226 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.226 |
| dewey-search | 541.226 |
| dewey-sort | 3541.226 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01329nam a2200337 cb4500</leader><controlfield tag="001">BV025295223</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20130917 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">100417s2002 d||| |||| 00||| eng d</controlfield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">1402010931</subfield><subfield code="9">1-4020-1093-1</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)730961695</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV025295223</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-11</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">541.226</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">UH 5710</subfield><subfield code="0">(DE-625)145690:</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">UH 6030</subfield><subfield code="0">(DE-625)145737:</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">UM 3260</subfield><subfield code="0">(DE-625)145885:</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase</subfield><subfield code="c">ed. by Thomas Elsaesser ...</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Dordrecht [u.a.]</subfield><subfield code="b">Kluwer</subfield><subfield code="c">2002</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">VII, 186 S.</subfield><subfield code="b">graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="490" ind1="1" ind2=" "><subfield code="a">Understanding chemical reactivity</subfield><subfield code="v">23</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Elsässer, Thomas</subfield><subfield code="d">1957-</subfield><subfield code="0">(DE-588)13920542X</subfield><subfield code="4">edt</subfield></datafield><datafield tag="830" ind1=" " ind2="0"><subfield code="a">Understanding chemical reactivity</subfield><subfield code="v">23</subfield><subfield code="w">(DE-604)BV000021931</subfield><subfield code="9">23</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">HBZ Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019927947&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-019927947</subfield></datafield></record></collection> |
| id | DE-604.BV025295223 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:30:35Z |
| institution | BVB |
| isbn | 1402010931 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-019927947 |
| oclc_num | 730961695 |
| open_access_boolean | |
| owner | DE-11 |
| owner_facet | DE-11 |
| physical | VII, 186 S. graph. Darst. |
| publishDate | 2002 |
| publishDateSearch | 2002 |
| publishDateSort | 2002 |
| publisher | Kluwer |
| record_format | marc |
| series | Understanding chemical reactivity |
| series2 | Understanding chemical reactivity |
| spelling | Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase ed. by Thomas Elsaesser ... Dordrecht [u.a.] Kluwer 2002 VII, 186 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Understanding chemical reactivity 23 Elsässer, Thomas 1957- (DE-588)13920542X edt Understanding chemical reactivity 23 (DE-604)BV000021931 23 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019927947&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase Understanding chemical reactivity |
| title | Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase |
| title_auth | Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase |
| title_exact_search | Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase |
| title_full | Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase ed. by Thomas Elsaesser ... |
| title_fullStr | Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase ed. by Thomas Elsaesser ... |
| title_full_unstemmed | Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase ed. by Thomas Elsaesser ... |
| title_short | Ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase |
| title_sort | ultrafast hydrogen bonding dynamics and proton transfer processes in the condensed phase |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019927947&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000021931 |
| work_keys_str_mv | AT elsasserthomas ultrafasthydrogenbondingdynamicsandprotontransferprocessesinthecondensedphase |