Emission inventory of the German Baltic Sea catchment area: research report 297 25 527
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Berlin
Umweltbundesamt
2000
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| Schriftenreihe: | Texte / Umweltbundesamt
2000,34 Environmental research of the Federal Ministry of the Environment, Nature Conversation and Nuclear Safety : Research project water |
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| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XII, 168 S. graph. Darst. 30 cm |
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Datensatz im Suchindex
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| adam_text | Titel: Emission inventory of the German Baltic Sea catchment area
Autor: Gluschke, Michael
Jahr: 2000
Table of contents Page
Table of contents I
List of tables.........................................................................................................................V
List of diagrams IX
List of abbreviations XT
1. Introduction 1
1.1 State of knowledge 1
1.2 Objective of the work........................................._.........................................................3
1.3 Formulation and path to solution 4
2. Material and Methods _ 5
2.1 Selection of monitoring stations 5
2.2 Selection of test parameters 7
2.3 Determination of concentration levels 10
2.3.1 Sampling....................................................................................................................1.0
2.3.2 Analysis.....................................................................................................................10
2.3.2.1 Heavy metals ._.....................................................................................................12
2.3.2.2 Volatile halogen hydrocarbons..............................................................................13
2.3.2.3 Non-volatile halogen hydrocarbons _ _ 14
2.3.2.4 Nonylphenolethoxylates : 16
2.3.2.5 Sum parameter AOX.............................................................................................17
2.3.2.6 Polycyclic aromatic hydrocarbons 18
2.3.2.7 Nitrogen and phosphorus based pesticides 18
2.4 Determination of discharges and wastewater quantities 19
2.5. Methodology of load calculation..............................................................................20
2.6. Influence of the limits of quantitation .............................................................22
II
3. Results.........................................................................................................................23
3.1 Heavy metals................................................................................................................23
3.1.1 Introduction.......................................................................................[.......................23
3.1.2 Bases of parameters...................................•..............................................................23
3.1.3 Test results..........;......................................................................................................28
3.1.3.1 Heavy metal loads in wastewater..........................................................................28
3.1.3.2 Heavy metal loads in the rivers............................................................................30
3.2. Volatile halogen hydrocarbons...................................................................................34
3.2.1 Introduction...............................................................................................................34
3.2.2 Bases of parameters..................................................................................................34
3.2.3 Test results.................................................................................................................37
3.2.3.1 VHHC loads in wastewater...................................................................................37
3.2.3.2 VHHC loads in the rivers..,..................................................................................39
3.3. Non-volatile halogen hydrocarbons .........................................41
3.3.1 Introduction _............................41
3.3.2 Bases of parameters .........41
3.3.3 Test results................................................................................................44
3.3.3.1 Non-volatile halogen hydrocarbon loads in wastewater .44
3.3.3.2 Non-volatile halogen hydrocarbon loads in the rivers ......46
3.4.Nonylphenolethoxylates 47
3.4.1 Introduction 47
3.4.2 Bases of parameters 47
3.4.3 Test results 48
3.4.3.1 Nonylphenolethoxylate loads in wastewater 48
3.4.3.2 Nonylphenolethoxylate loads in the rivers 50
3.5. AOX _ 52
Ill
3.5.1 Introduction...............................................................................................................52
3.5.2 Bases of sum parameter AOX . 52
3.5.3 Test results.................................:...............................................................................53
3.5.3.1 AOX loads in wastewater......................................................................................53
3.5.3.2 AOX loads in the rivers 55
3.6. Polycyclic aromatic hydrocarbons (PAH) 57
3.6.1 Introduction............................................................................................._.................57
3.6.2 Bases of sum parameter PAH 57
3.6.3 Test results.................................................................................................................58
3.6.3.1 PAH loads in wastewater 58
3.6.3.2 PAH loads in the rivers - 59
3.7. Pesticides (PSM).........................................................................................._..............61
3.7.1 Introduction...............................................................................................................61
3.7.2 Bases of parameters 61
3.7.3 Test results.................................................................................................................63
3.7.3.1 Pesticide loads in wastewater................................................................................63
3.7.3.2 Pesticide loads in the rivers...................................................................................67
3.8 Emission inventory of the German Oder catchment area 69
3.8.1 Introduction...............................................................................................................69
3.8.2 Approach.............................................................../...................................................70
3.8.3 Test results.................................................................................................................71
3.9 Emission inventory of the German Baltic Sea catchment area 74
3.9.1 Introduction...............................................................................................................74
3.9.2 Approach..................................................................................................................74
.3.9.3 Test results.......................................................;.........................................................77
3.10 Special measurement programme 1999..............._...............................................;... 81
IV
3.10.1 Introductory remarks..............................................................................................81
3.10.2 Pharmacological residue in WWTP discharges 82
3.10.2.1 Introduction..........................................................................................................82
3.10.2.2 Bases of parameters............................................................................................82
3.10.2.3 Test results,...........................................................................................................83
3.10.3 Organotin compounds in WWTP discharges........................................................86
3.10.3.1 Introduction......................................................................................._._.................86
3.10.3.2 Bases of parameters.............................................................................................86
3.10.3.3 Test results.........................................................................................._................88
3.10.4 Nonylphenol in WWTP discharges ...............................91
3.10.4.1 Test results...........................................................................................................91
4. Summary ^ ............................... .........93
5. Bibliography .........................................................................................99
6. Appendix 105
Appendix 1: Pollution loads at monitoring stations 107
Appendix 2: Pollution concentrations at monitoring stations 111
Appendix 3: Special measurement programme 1999 ..163
V
List of Tables Page
Tab. 2.3-1: Limits of quantitation of some parameters in comparison 11
Tab. 2.3-2: Analysis of heavy metals................................................................................13
Tab. 2.3-3: Analysis of volatile halogen hydrocarbons 13
Tab. 2.3-4: Analysis of non-volatile halogen hydrocarbons 14
Tab. 2.3-5: AOX analysis..................................................................................................17
Tab. 2.3-6: PAH analysis..................................................................................................18
Tab. 2.3-7: Analysis of nitrogen and phosphorus based pesticides 19
Tab. 3.1-1: Heavy metal loads in the rivers 31
Tab. 3.5-1: MWWTP AOX loads in comparison............................................................54
Tab. 3.5-2: AOX loads of the rivers Warnow and Trave 56
Tab. 3.8-1: Wastewater quantities in German Oder catchment area 70
Tab. 3.8-2: Emission inventory of German Oder catchment area 72
Tab. 3.9-1: Wastewater quantities in German Baltic Sea catchment area 76
Tab. 3.9-2: Emission inventory of German Baltic Sea catchment area 79
Tab. 4-1: Pollutant emissions in the entire German Baltic Sea
catchment area _ 94
Appendix 1
Tab. A. 1-1 Pollution loads of monitored industrial companies 1998 107
Tab. A. 1-2: Pollution loads of monitored municipal wastewater treatment
plants 1998........................................................................................................................108
Tab. A. 1-3 Pollution loads of monitored wastewater discharges 1998 109
Tab. A. 1-4: Pollution loads of monitored river measurement points 1998 _ 110
Appendix 2
Tab. A.2-1: Monitoring station (MS) 1 (EKO Stahl VEO / Brandenburg)..................111
Tab. A.2-2:MS 2 (Haindl Papier GmbH / Brandenburg)...............................................112
Tab. A.2-3: MS 3 (PCK GmbH Schwedt/Brandenburg).............................................113
VI
Tab. A.2-4: MS 4 (Schwedter Papier und Karton GmbH / Brandenburg)....................114
Tab. A.2-5: MS 5 (Energiewerke Nord / Mecklenburg-Western Pomerania)..............115
Tab. A.2-6: MS 5 (thermal power station Rostock / MV).............................................1.16
Tab. A.2-7: MS 7 (Hydro Agri AG / Mecklenburg-Western Pomerania)....................117
Tab. A.2-8: MS 8 (hard coal power station Rostock /
Mecklenburg-Western Pomerania).................................................................................H8
Tab. A.2-9: MS 9 (Feinpapier Bad Muskau / Saxony)..................................................119
Tab. A.2-10: MS 10 (Telux Spezialglas Neuwerk / Saxony)........................................120
Tab. A.2-11: MS 11 (Gliicksklee GmbH Neustadt / Schleswig-Holstein)...................121
Tab. A.2-12: MS 12 (Pomosinwerke Grossenbrode / Schleswig-Holstein).................122
Tab. A.2-13: MS 13 (Sugar factory Schleswig / Schleswig-Holstein)..........................123
Tab. A.2-14: MS 14 (municipal WWTP Frankrurt/O. /
Brandenburg)..................................................................................._................................125
Tab. A.2-14 (cont): MS 14 (municipal WWTP Frankfurt/O. /
Brandenburg) _ ......... ....................-..J?6
Tab. A.2-15: MS 15 (municipal WWTP Eisenhiittenstadt /
Brandenburg)........................................_____.......................................................................127
Tab. A.2-15 (cont.): MS 15 (municipal WWTP Eisenhuttenstadt /
Brandenburg) _ 128
Tab. A.2-16: MS 16 (municipal WWTP Schwedt/O. /
Brandenburg) _ 129
Tab. A.2-16 (cont.): MS 16 (municipal WWTP Schwedt/O. /
Brandenburg) ..130
Tab. A.2-17: MS 17 (municipal WWTP Altfriedland /
Brandenburg) 131
Tab. A.2-17 (cont.): MS 17 (municipal WWTP Altfriedland /
Brandenburg) 132
Tab. A.2-18: MS 18 (municipal WWTP Rostock/
Mecklenburg-Western Pomerania) 133
Tab. A.2-18 (cont.): MS 18 (municipal WWTP Rostock /
Mecklenburg-Western Pomerania) 134
Tab. A.2-19: MS 19 (municipal WWTP Stralsund /
Mecklenburg-Western Pomerania) 135
Tab. A.2-19 (cont.): MS 19 (municipal WWTP Stralsund /
VII
Mecklenburg-Western Pomerania) 136
Tab. A.2-20: MS 20 (municipal WWTP Wismar /
Mecklenburg-Western Pomerania) 137
Tab. A.2-20 (cont): MS 20 (municipal WWTP Wismar /
Mecklenburg-Western Pomerania)...........................; _ -138
Tab. A.2-21: MS 21 (municipal WWTP Gustrow /
Mecklenburg-Western Pomerania) _ 139
Tab. A.2-21 (cont.): MS 21 (municipal WWTP Gustrow /
Mecklenburg-Western Pomerania)..................................................................................140
Tab. A.2-22: MS 22 (municipal WWTP Gorlitz Nord /
Saxony) ..........................................................................................................................141
Tab. A.2-22 (cont.): MS 22 (municipal WWTP Gorlitz Nord /
Saxony}142
Tab. A.2-23: MS 23 (municipal WWTP Zittau /
Saxony)143
Tab. A.2-23 (cont.): MS 23 (municipal WWTP Zittau /
Saxony)..........................................................................................._ 144
Tab. A.2-24: MS 24 (municipal WWTP Rothenburg /
Saxony).............................................................................................................................145
Tab. A.2-24 (cont.): MS 24 (municipal WWTP Rothenburg /
Saxony)..............................................................................................................................146
Tab. A.2-25: MS 25 (municipal WWTP Kiel / .
Schleswig-Holstein).........................................................................................................147
Tab. A.2-25 (cont.): MS 25 (municipal WWTP Kiel /
Schleswig-Holstein)..........................................................................................................148
Tab. A.2-26: MS 26 (municipal WWTP Osterby /
Schleswig-Holstein)............. .............................................................................................149
Tab. A.2-26 (cont.): MS 26 (municipal WWTP Osterby /
Schleswig-Holstein)..............................;..........................................................................150
Tab. A.2-27: MS 27 / river MS 1
(Lausitz Neisse 3-country region)....................................................................................151
Tab. A.2-27 (cont.): MS 27 / river MS 1
(Lausitz Neisse 3-country region)..................................................................................152
Tab. A.2-28: MS 28 / river MS 2
(Lausitz Neisse at Ratzdorf)...................................................................153
VIII
Tab. A.2-28 (cont): MS 28 / river MS 2
(Lausitz Neisse at Ratzdorf)....._.......................................................................................154
Tab. A.2-29: MS 29 / river MS 3 (Oder at Frankfurt/O.)...............................................155
Tab. A.2-29 (cont): MS 29 / river MS 3 (Oder at Frankfiirt/O.)..................................156
Tab. A.2-30: MS 30 / river MS 4 (Oder at Hohenwutzen)............................................157
Tab. A.2-30 (cont): MS 30 / river MS 4 (Oder at Hohenwutzen)................................158
Tab. A.2-31: MS 31 /river MS 5 (Warnowat Kessin)...........:................................;.....159
Tab. A.2-31. (cont): MS 31 / river MS 5 (Warnow at Kessin).. ...................................160
Tab. A.2-32: MS 32 / river MS 6 (Trave at Sehmsdorf)..............................161
Tab. A.2-32 (cont.): MS 32 /river MS 6 (Trave at Sehmsdorf)....................................162
Appendix 3 *
Tab. A.3-1: Pharmacological residues in the municipal WWTP s of Rostock,
Stralsund und Wismar 163
Tab. A.3-2: Organotin substances in the municipal WWTP s of Rostock,
Stralsund und Wismar _ 165
Tab. A.3-2 (cont.): Organotin substances in the municipal WWTP s of Rostock,
Stralsund und Wismar . 166
Tab. A.3-3: Nonylphenol in the municipal WWTP s of Rostock,
Stralsund und Wismar 167
IX
List of diagrams Page
Diag. 2.1-1: List of monitoring stations for the research project 6
Diag. 2.2-1: HELCOM list of priority harmful substances as modified
for the research project 9
Diag. 2.2-2: Additionally tested parameters in the research project 9
Diag. 2.3-1: Gas-chromatogram of apure water sample contaminated with
various environmentally relevant NVHH s (GC/ECD)_ 15
Diag. 2.3-2: Actual sample with positive NP1EO and NP2EO results 16
Diag. 2.5-1: Calculation of copper load 1998 for the Oder/Hohenwutzen 21
Diag. 3.1-1: Total heavy metal loads for the monitored wastewater sources 29
Diag. 3.1-2: Heavy metal loads for the Oder at Frankfurt/O.
and at Hohenwutzen ; • 32
Diag. 3.2-1: VHHC loads of the monitored wastewater sources _ 38
Diag. 3.2-2: Riverine VHHC loads ; 39
Diag. 3.3-1: NVHH loads of the monitored wastewater sources 45
Diag. 3.4-1: Nonylphenolethoxylate loads of the monitored wastewater sources 49
Diag. 3.5-1: AOX loads of the monitored wastewater sources 53
Diag. 3.5-2: AOX loads in the rivers........._..........;...........................................................55
Diag. 3.6-1: PAH loads of the monitored wastewater sources 58
Diag. 3.6-2: PAH loads in the rivers.............................-................................................60
Diag. 3.7-1: Pesticide loads of the MWWTP s................................................................64
Diag. 3.7-2: Share of simazine emission from the rural WWTP s of the monitored
MWWTP s ......................_........................................................................................66
Diag. 3.7-3: Pesticide loads in the rivers 67
Diag. 3.8-1: Border Oder segment....................................................................................69
Diag. 3.9-1: German Baltic Sea catchment area with FuE project monitoring
stations.................................................................................................................................75
Diag. 3.10-1: Drug residues in the municipal WWTP s of Rostock, Stralsund
and Wismar.........................................................................................................................84
Diag. 3.10-2: Monobutyltin in the discharges of the MWWTP s of Rostock,
Stralsund and Wismar ............90
X
Diag. 3.10-3: n-Butyltin compounds in sludge of MWWTP at
Stralsund......................................................................; 90
Diag. 3.10.-4: Nonylphenolethoxylates and nonylphenol at
the Wismar MWWTP . 92
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| geographic | Ostsee (DE-588)4044107-6 gnd Deutschland (DE-588)4011882-4 gnd Ostseeraum West (DE-588)4301272-3 gnd |
| geographic_facet | Ostsee Deutschland Ostseeraum West |
| id | DE-604.BV023837103 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:37:44Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017479217 |
| oclc_num | 76210210 |
| open_access_boolean | |
| owner | DE-634 |
| owner_facet | DE-634 |
| physical | XII, 168 S. graph. Darst. 30 cm |
| publishDate | 2000 |
| publishDateSearch | 2000 |
| publishDateSort | 2000 |
| publisher | Umweltbundesamt |
| record_format | marc |
| series2 | Texte / Umweltbundesamt Environmental research of the Federal Ministry of the Environment, Nature Conversation and Nuclear Safety : Research project water |
| spelling | Gluschke, Michael 1966- Verfasser (DE-588)115848509 aut Emission inventory of the German Baltic Sea catchment area research report 297 25 527 by Michael Gluschke Berlin Umweltbundesamt 2000 XII, 168 S. graph. Darst. 30 cm txt rdacontent n rdamedia nc rdacarrier Texte / Umweltbundesamt 2000,34 Environmental research of the Federal Ministry of the Environment, Nature Conversation and Nuclear Safety : Research project water Einzugsgebiet (DE-588)4151469-5 gnd rswk-swf Schadstoffeintrag (DE-588)4510651-4 gnd rswk-swf Emissionsüberwachung (DE-588)4377075-7 gnd rswk-swf Umweltchemikalie rswk-swf Fließgewässer (DE-588)4017551-0 gnd rswk-swf Schadstoffemission (DE-588)4179312-2 gnd rswk-swf Wasserverschmutzung (DE-588)4189299-9 gnd rswk-swf Ostsee (DE-588)4044107-6 gnd rswk-swf Deutschland (DE-588)4011882-4 gnd rswk-swf Ostseeraum West (DE-588)4301272-3 gnd rswk-swf Ostseeraum West (DE-588)4301272-3 g Emissionsüberwachung (DE-588)4377075-7 s DE-604 Deutschland (DE-588)4011882-4 g Ostsee (DE-588)4044107-6 g Einzugsgebiet (DE-588)4151469-5 s Fließgewässer (DE-588)4017551-0 s Wasserverschmutzung (DE-588)4189299-9 s Schadstoffeintrag (DE-588)4510651-4 s Umweltchemikalie s Schadstoffemission (DE-588)4179312-2 s 1\p DE-604 Paralle Sprachausgabe deutsch Gluschke, Michael Emissionsinventar deutsches Ostsee-Einzugsgebiet Umweltbundesamt Texte 2000,34 (DE-604)BV005532599 2000,34 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017479217&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Gluschke, Michael 1966- Emission inventory of the German Baltic Sea catchment area research report 297 25 527 Einzugsgebiet (DE-588)4151469-5 gnd Schadstoffeintrag (DE-588)4510651-4 gnd Emissionsüberwachung (DE-588)4377075-7 gnd Umweltchemikalie Fließgewässer (DE-588)4017551-0 gnd Schadstoffemission (DE-588)4179312-2 gnd Wasserverschmutzung (DE-588)4189299-9 gnd |
| subject_GND | (DE-588)4151469-5 (DE-588)4510651-4 (DE-588)4377075-7 (DE-588)4017551-0 (DE-588)4179312-2 (DE-588)4189299-9 (DE-588)4044107-6 (DE-588)4011882-4 (DE-588)4301272-3 |
| title | Emission inventory of the German Baltic Sea catchment area research report 297 25 527 |
| title_auth | Emission inventory of the German Baltic Sea catchment area research report 297 25 527 |
| title_exact_search | Emission inventory of the German Baltic Sea catchment area research report 297 25 527 |
| title_full | Emission inventory of the German Baltic Sea catchment area research report 297 25 527 by Michael Gluschke |
| title_fullStr | Emission inventory of the German Baltic Sea catchment area research report 297 25 527 by Michael Gluschke |
| title_full_unstemmed | Emission inventory of the German Baltic Sea catchment area research report 297 25 527 by Michael Gluschke |
| title_short | Emission inventory of the German Baltic Sea catchment area |
| title_sort | emission inventory of the german baltic sea catchment area research report 297 25 527 |
| title_sub | research report 297 25 527 |
| topic | Einzugsgebiet (DE-588)4151469-5 gnd Schadstoffeintrag (DE-588)4510651-4 gnd Emissionsüberwachung (DE-588)4377075-7 gnd Umweltchemikalie Fließgewässer (DE-588)4017551-0 gnd Schadstoffemission (DE-588)4179312-2 gnd Wasserverschmutzung (DE-588)4189299-9 gnd |
| topic_facet | Einzugsgebiet Schadstoffeintrag Emissionsüberwachung Umweltchemikalie Fließgewässer Schadstoffemission Wasserverschmutzung Ostsee Deutschland Ostseeraum West |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017479217&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV005532599 |
| work_keys_str_mv | AT gluschkemichael emissioninventoryofthegermanbalticseacatchmentarearesearchreport29725527 |