Chemical energy and exergy: an introduction to chemical thermodynamics for engineers
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
2004
|
| Ausgabe: | 1. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Inhaltsverzeichnis |
| Beschreibung: | IX, 149 S. Ill., graph. Darst. |
| ISBN: | 044451645X |
Internformat
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| 100 | 1 | |a Sato, Norio |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Chemical energy and exergy |b an introduction to chemical thermodynamics for engineers |c Norio Sato |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 2004 | |
| 300 | |a IX, 149 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 650 | 4 | |a Processus irréversibles | |
| 650 | 7 | |a Termoquímica |2 larpcal | |
| 650 | 4 | |a Thermochimie | |
| 650 | 4 | |a Exergy | |
| 650 | 4 | |a Irreversible processes | |
| 650 | 4 | |a Thermochemistry | |
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Datensatz im Suchindex
| _version_ | 1804138997164802048 |
|---|---|
| adam_text | Titel: Chemical energy and exergy
Autor: Sato, Norio
Jahr: 2004
CONTENTS
PREFACE
CHAPTER 1. THERMODYNAMIC STATE VARIABLES--................-------------------------1
1.1. Thermodynamic systems.................................................................................? 1
1.2. Variables of the state....................................-----..........?..........-----------------------2
1.3. Extensive and intensive variables..................----------------------------------------------------3
1.4. Partial molar quantities........................---------...........-..................---------------------3
1.5. The extent of a chemical reaction ?..............----...............................-------------------5
CHAPTER 2. CONSERVATION OF ENERGY------------....................-...........-------------9
2.1. Energy as a physical quantity of the state-------------------------------------------------------------9
2.2. Conservation of energy.....................-----------------------------------------------------------10
2.3. Internal energy U with independent variables T, V, and £ ...............---------------------------11
2.4. Enthalpy H with independent variables T, p, and £----------...................--------------------12
2.5. Enthalpy and heat of reaction...................------------------------------------------------------15
2.6. Enthalpy of pure substances........---------------..............-.....................------------------16
CHAPTER 3. ENTROPY AS A STATE PROPERTY -.....-?...............-...........-----------19
3.1. Introduction to entropy..........-.......................-...........-------------------------------------19
3.2. Reversible and irreversible processes----------------------------------------------------------------21
3.3. The creation of entropy and uncompensated heat---------------------------------------------------23
3.4. The creation of entropy and thermodynamic potentials------............---------------------------25
3.5. Affinity of irreversible processes..................-...............-................................------26
3.6. Entropy of pure substances........-------------------------------------------------------------------30
3.7. Entropy of heat transfer...........................................--------------------------.....--------31
3.8. Entropy of gas expansion...........-------------------------------------------------------------------33
3.9. Entropy of mixing.............................................................----------------------------34
CHAPTER 4. AFFINITY IN IRREVERSIBLE PROCESSES-------------------------------------37
4.1. Affinity in chemical reactions...........-..................-------------------------------------------37
4.2. Affinity and heat of reaction...................-------------------------------------------------------38
4.3. The average heat of reaction..................--------------------------------------------------------40
4.4. The average affinity of reaction----...................................--------------------------------41
viii CONTENTS
CHAPTER 5. CHEMICAL POTENTIAL-------------------------------------------------------------45
5.1. Thermodynamic potentials in open systems---------------------------------------------------------45
5.2. The partial molar quantity of energy and the chemical potential-----------------------------------46
5.3. Chemical potentials and the affinity of reaction-----------------------------------------------------47
5.4. Chemical potentials and thermodynamic energy functions-----------------------------------------48
5.5. Chemical potentials in homogeneous mixtures: the Gibbs-Duhem equation----------------------49
5.6. Chemical potentials of substances in ideal mixtures-------------------------------------------------49
5.7. Activity and activity coefficient---------------------..............-------------------------------------51
5.8. Chemical potentials of pure substances-.......--------------------------------------------------------52
5.9. Thermodynamic potentials in ideal mixtures ?.........---------------------------------------------53
5.10. The unitary and mixing terms of thermodynamic potentials---------------------------------------54
CHAPTER 6. UNITARY AFFINITY AND EQUILIBRIUM---------------------------------------57
6.1. Affinity and equilibrium in chemical reactions-------------------------------------------------------57
6.2. The unitary affinity-------------------------------------------------------------------------------------58
6.3. Equilibrium constants and concentration units-------------------------------------------------------59
6.4. Equilibrium constants as a function of pressure and temperature-----------------------------------60
CHAPTER 7. GASES, LIQUIDS, AND SOLIDS-----------------------------------------------------63
7.1. Perfect and ideal gases---------------------------------------------------------------------------------63
7.2. Non-ideal gases-----------------------------------------------------------------------------------------65
7.3. Liquids and solids--------------------------------------------------------------------------------------66
7.4. The state equation and thermodynamic functions of condensed substances----------------------67
CHAPTER 8. SOLUTIONS.................---------------------------------------------------------------71
8.1. Ideal and non-ideal solutions---------------------------------------------------------------------------71
8.2. Perfect solutions and ideal solutions------------------------------------------------------------------72
8.3. Reference systems for thermodynamic unitary quantity--------------------------------------------75
8.4. Thermodynamic excess functions in non-ideal solutions-------------------------------------------76
8.5. Units of the concentration-----------------------------------------------------------------------------77
8.6. Osmotic pressure---------------------------------------------------------------------------------------78
8.7. Electrolytic solutions-----------------------------------------------------------------------------------80
CHAPTER 9. ELECTROCHEMICAL ENERGY----------------------------------------------------83
9.1. Electrochemical potential of charged particles-------------------------------------------------------83
9.2. Transfer of charged particles between two condensed phases---------------------------------------85
9.3. Electrode and electrode potential----------------------------------------------------------------------86
9.4. Electrochemical cells-----------------------------------------------------------------------------------89
9.5. Equilibrium electrode potential of electronic transfer reactions-------------------------------------92
9.6. Equilibrium electrode potential of ionic transfer reactions-----------------------------------------94
9.7. Chemical potential of hydrated ions------------------------------------------------------------------95
CONTENTS ix
CHAPTER 10. EXERGY........................................................----------------------------97
10.1. The concept of exergy----------..............-...................-....................-----------------97
10.2. Exergy and heat-------------------------------------------------------------------------------------99
10.3. Exergy and pressure--------------------------------------------------------------------------------100
10.4. Thermal exergy of high temperature substances--------------------------------------------------101
10.5. Thermal exergy of low temperature substances---------------------------------------------------104
10.6. Exergy in mixing substances.............----------------------------------------------------------105
10.7. Chemical exergy of substances-...................................?...........-.....................-107
10.8. Standard chemical exergy of substances.........................................--------------------110
10.9. Total exergy of substances...............----------------...................-........-----------------112
10.10. Exergy and affinity.............................................--------------------------------------112
CHAPTER 11. EXERGY DIAGRAM --........-..................?...........-----------------------115
11.1. Efficiency in the use of energy-...........----...................................-.------------------115
11.2. Exergy balance diagram-----------...........---------------------------------...........------------117
11.3. Exergy vector diagram-------------..........-.....................----------------------------------120
11.4. Principles in exergy vector diagrams--------------------------------------------------------------123
11.5. Exergy transfer between two processes-----------------------------------------------------------125
11.6. Exergy vectors of heating-cooling processes-------------------------------...........------------126
11.7. Exergy vectors of compression-expansion processes--------------------------------------------128
11.8. Exergy vectors of separating-mixing processes---------------------------------------------------129
11.9. Exergy vectors of chemical reactions-------------------------------------------------------------129
11.10. Exergy transfer in chemical reactions-..........--------------------------------------------------131
11.11. Exergy vector diagrams of methanol synthesis.................-............-----------------------134
11.12. Exergy vectors for electrochemical reactions-------------..................------------------------137
LIST OF SYMBOLS--------------------------------------------------........--------------------------141
REFERENCES ?........................---------------------------------...........-------------------145
INDEX----------------------------------------------------------------------------------------------------147
|
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| spelling | Sato, Norio Verfasser aut Chemical energy and exergy an introduction to chemical thermodynamics for engineers Norio Sato 1. ed. Amsterdam [u.a.] Elsevier 2004 IX, 149 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Processus irréversibles Termoquímica larpcal Thermochimie Exergy Irreversible processes Thermochemistry Thermochemie (DE-588)4078260-8 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Thermochemie (DE-588)4078260-8 s DE-604 http://www.loc.gov/catdir/toc/fy0607/2006273151.html Inhaltsverzeichnis HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017441805&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Sato, Norio Chemical energy and exergy an introduction to chemical thermodynamics for engineers Processus irréversibles Termoquímica larpcal Thermochimie Exergy Irreversible processes Thermochemistry Thermochemie (DE-588)4078260-8 gnd |
| subject_GND | (DE-588)4078260-8 (DE-588)4123623-3 |
| title | Chemical energy and exergy an introduction to chemical thermodynamics for engineers |
| title_auth | Chemical energy and exergy an introduction to chemical thermodynamics for engineers |
| title_exact_search | Chemical energy and exergy an introduction to chemical thermodynamics for engineers |
| title_full | Chemical energy and exergy an introduction to chemical thermodynamics for engineers Norio Sato |
| title_fullStr | Chemical energy and exergy an introduction to chemical thermodynamics for engineers Norio Sato |
| title_full_unstemmed | Chemical energy and exergy an introduction to chemical thermodynamics for engineers Norio Sato |
| title_short | Chemical energy and exergy |
| title_sort | chemical energy and exergy an introduction to chemical thermodynamics for engineers |
| title_sub | an introduction to chemical thermodynamics for engineers |
| topic | Processus irréversibles Termoquímica larpcal Thermochimie Exergy Irreversible processes Thermochemistry Thermochemie (DE-588)4078260-8 gnd |
| topic_facet | Processus irréversibles Termoquímica Thermochimie Exergy Irreversible processes Thermochemistry Thermochemie Lehrbuch |
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