Energy dissipation in molecular systems: with 16 tables
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2005
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | IX, 202 S. graph. Darst. 24 cm |
| ISBN: | 3540250506 |
Internformat
MARC
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| 100 | 1 | |a Tramer, André |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Energy dissipation in molecular systems |b with 16 tables |c A. Tramer ; Ch. Jungen ; F. Lahmani |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 2005 | |
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| 700 | 1 | |a Lahmani, Françoise |e Verfasser |4 aut | |
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Datensatz im Suchindex
| _version_ | 1804138994121834496 |
|---|---|
| adam_text | Titel: Energy dissipation in molecular systems
Autor: Tramer, André
Jahr: 2005
Contents
1 The Basic Notions........................................................................................1
1.1 Introductory Remarks..............................................................................1
1.2 Excited Molecular States........................................................................2
1.2.1 Stationary and Quasi-Stationary States....................................2
1.2.2 Zero-Order and Exact Molecular States....................................4
1.3 Coupling Schemes and Level Patterns..................................................6
1.3.1 Small Molecules..........................................................................7
1.3.2 Large Molecule Limit ................................................................10
1.3.3 Sequential-Coupling Model ......................................................11
1.4 The Time Evolution of Excited States....................................................12
1.4.1 Vibrational Wave Packet............................................................12
1.4.2 Coherent and Incoherent Excitation..........................................14
1.4.3 The Time Evolution of the Excited Molecule..........................14
1.5 Summary..................................................................................................21
1.6 Franck-Condon Rule..............................................................................22
1.6.1 Franck-Condon Rule..................................................................22
1.6.2 Energy and Momentum Gap Laws............................................23
2 Experimental Techniques............................................................................29
2.1 Principles of Time-and Energy-Resolved Experiments......................29
2.2 Isolated Molecules ..................................................................................31
2.2.1 Gases and Supersonic Jets..........................................................31
2.2.2 The Spectroscopy of Isolated Molecules..................................32
2.3 Time-Resolved Measurements................................................................36
2.3.1 Light Sources for Time-Resolved Spectroscopy......................36
2.3.2 Monitoring of the Excited-State Evolution..............................36
2.4 Model Systems for Molecular Interaction Studies................................38
2.4.1 Gas-Phase Collisions..................................................................39
2.4.2 Rare-Gas Matrices and Clusters................................................39
2.4.3 AC Complexes and Half-Collisions..........................................40
2.4.4 From the Model to Real Systems..............................................40
VIII Contents
3 Intramolecular Vibrational Redistribution..............................................^
3.1 Introduction......................: :....................................a-x
3.1.1 Vibrational Relaxation and Redistribution................
3.1.2 The Model of Independent Oscillators......................................44
3.2 IVR in Excited Electronic States............................................................4^
3.2.1 Bright and Dark Vibrational Levels..........................................46
3.2.2 Fluorescence Studies..................................................................47
3.3 IVR in Ground Electronic States............................................................53
3.3.1 General Remarks........................................................................53
3.3.2 Emission and Transient Absorption..........................................33
3.3.3 X-H Absorption Spectra............................................................57
3.4 IVR and the Vibrational Predissociation................................................62
3.5 Modelling of the Level Coupling Patterns............................................67
3.5.1 Level Coupling Selection Rules................................................67
3.5.2 The Level Pattern and the Tier Model......................................70
3.6 Conclusions..............................................................................................71
4 Vibrational and Rotational Relaxation......................................................73
4.1 Introduction..............................................................................................73
4.1.1 Intermolecular Potentials............................................................72
4.1.2 Experimental Studies..................................................................76
4.1.3 Main Questions............................................................................80
4.2 Collisional Vibrational and Rotational Relaxation................................80
4.2.1 Rotational and Vibrational Relaxation Rates............................81
4.2.2 Propensity Rules for Rotational Transitions ............................82
4.2.3 Vibrational Relaxation and Up-Relaxation..............................84
4.2.4 Conclusion ..................................................................................86
4.3 Direct and Sequential Paths of the Vibrational Relaxation..................87
4.3.1 Model Notions............................................................................87
4.3.2 The Vibrational Relaxation of Diatomics ................................87
4.3.3 The Vibrational Predissociation
of Complexes of Polyatomic Molecules ........................92
4.3.4 The Vibrational Relaxation in Hydrogen-Bonded Systems .. 95
4.4 The Competition Between Relaxation Channels..................................99
4.4.1 Model Treatment........................................................................99
4.4.2 Experiment...............................................100
5 Electronic Relaxation.........................................107
5.1 Potential-Energy Surfaces ......................................................................107
5.2 Nonintersecting Potential-Energy Surfaces ..........................................112
5.2.1 Large Molecules..........................................................................114
5.2.2 Small-Molecule Properties of Large Molecules......................117
5.2.3 Small Molecules..........................................................................119
5.3 The Environmental Effects on Electronic Relaxation..........................128
5.3.1 Large and Intermediate-Sized Molecules..................................128
Contents IX
5.3.2 Small Molecules..........................................................................128
5.3.3 Pathways of Electronic Relaxation............................................130
5.4 Intersecting Potential-Energy Surfaces..................................................132
5.4.1 Curve Crossing and Predissociation of Diatomics..................132
5.4.2 Coupled Equations Near an Intersection...........................134
5.4.3 Experimental Studies of Predissociation..................................136
5.4.4 Fast Relaxation of Polyatomics..................................................143
5.5 Conclusions..............................................................................................151
6 The Electron and Proton Transfer..............................153
6.1 General Remarks......................................................................................153
6.2 Electron Transfer......................................................................................156
6.2.1 Potential Energy Surfaces..........................................................156
6.2.2 Spectroscopy and Dynamics......................................................160
6.3 Proton/Hydrogen-Atom Transfer............................................................170
6.3.1 General Notions..........................................................................170
6.3.2 Intramolecular Hydrogen Transfer............................................170
6.3.3 Intermolecular Proton Transfer..................................................178
6.4 Final Remarks..........................................................................................179
7 Postface ....................................................181
References......................................................185
Index...........................................................201
|
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| author | Tramer, André Jungen, Christian Lahmani, Françoise |
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| illustrated | Illustrated |
| indexdate | 2024-07-09T21:37:01Z |
| institution | BVB |
| isbn | 3540250506 |
| language | English |
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| physical | IX, 202 S. graph. Darst. 24 cm |
| publishDate | 2005 |
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| publisher | Springer |
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| spelling | Tramer, André Verfasser aut Energy dissipation in molecular systems with 16 tables A. Tramer ; Ch. Jungen ; F. Lahmani Berlin [u.a.] Springer 2005 IX, 202 S. graph. Darst. 24 cm txt rdacontent n rdamedia nc rdacarrier Molekülsystem (DE-588)4507233-4 gnd rswk-swf Dissipation (DE-588)4346728-3 gnd rswk-swf Molekülsystem (DE-588)4507233-4 s Dissipation (DE-588)4346728-3 s DE-604 Jungen, Christian Verfasser aut Lahmani, Françoise Verfasser aut HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017439730&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Tramer, André Jungen, Christian Lahmani, Françoise Energy dissipation in molecular systems with 16 tables Molekülsystem (DE-588)4507233-4 gnd Dissipation (DE-588)4346728-3 gnd |
| subject_GND | (DE-588)4507233-4 (DE-588)4346728-3 |
| title | Energy dissipation in molecular systems with 16 tables |
| title_auth | Energy dissipation in molecular systems with 16 tables |
| title_exact_search | Energy dissipation in molecular systems with 16 tables |
| title_full | Energy dissipation in molecular systems with 16 tables A. Tramer ; Ch. Jungen ; F. Lahmani |
| title_fullStr | Energy dissipation in molecular systems with 16 tables A. Tramer ; Ch. Jungen ; F. Lahmani |
| title_full_unstemmed | Energy dissipation in molecular systems with 16 tables A. Tramer ; Ch. Jungen ; F. Lahmani |
| title_short | Energy dissipation in molecular systems |
| title_sort | energy dissipation in molecular systems with 16 tables |
| title_sub | with 16 tables |
| topic | Molekülsystem (DE-588)4507233-4 gnd Dissipation (DE-588)4346728-3 gnd |
| topic_facet | Molekülsystem Dissipation |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017439730&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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