Environmental chemistry:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York
Freeman
2005
|
| Ausgabe: | 3. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Getr. Zählung Ill., graph. Darst. |
| ISBN: | 0716748770 |
Internformat
MARC
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| 245 | 1 | 0 | |a Environmental chemistry |c Colin Baird ; Michael Cann |
| 250 | |a 3. ed. | ||
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Datensatz im Suchindex
| _version_ | 1804138993767415808 |
|---|---|
| adam_text | Titel: Environmental chemistry
Autor: Baird, Colin
Jahr: 2005
CONTENTS
Preface xvii
Introduction to Green Chemistry xxv
PART I AIR AND ENERGY 1
CHAPTER 1 Stratospheric Chemistry:
The Ozone Layer 3
Introduction 3
Dobson Units for Overhead Ozone • The Annual Ozone Hole Above
Antarctica • Ozone Depletion in Temperate Areas * Regions of
the Atmosphere • Environmental Concentration Units for Atmo-
spheric Gases
The Physics and Chemistry of the Ozone Layer 9
Absorption of Light by Molecules • Filtering of Sunlight s UV Compo-
nent by Atmospheric O2 and O3 • Biological Consequences of
Ozone Depletion • Variation in Light s Energy with Wavelength
• Creation of Ozone in the Stratosphere • Destruction of Strato-
spheric Ozone
The Steady State in Atmospheric Reactions 21
The Steady-State Approximation • Steady-State Analysis of the
Chapman Mechanism
Catalytic Processes of Ozone Destruction 27
Catalytic Destruction of Ozone by Nitric Oxide • Box 1 -1: The
Rates of Free-Radical Reactions • Destruction of Ozone Without
Atomic Oxygen by Other Mechanisms • Atomic Chlorine and
Bromine as X Catalysts
The Ozone Hole and Other Sites of Ozone Depletion 36
The Activation of Catalytically Inactive Chlorine • Reactions
That Create the Ozone Hole • The Size of the Antarctic Ozone
Hole • Stratospheric Ozone Destruction over the Arctic Region
vi Contents
• Increases in UV at Ground Level • Box 1-2: The Chemistry
Behind Mid-Latitude Decreases in Stratospheric Ozone
The Chemicals That Cause Ozone Destruction 48
CFC Decomposition Increases Atmospheric Chlorine • Box 1-3: For-
mulas and Codes for Carbon Compounds (Including CFCs) • Other
Chlorine-Containing, Ozone-Depleting Substances • Green Chem-
istry: The Replacement of CFC and Hydrocarbon Blowing Agents with
Carbon Dioxide in Producing Foam Polystyrene • CFC Replacements
• Bromine-Containing, Ozone-Depleting Substances • International
Agreements That Restrict ODSs • Green Chemistry: Harpin Tech-
nology—Eliciting Nature s Own Defenses Against Diseases
chapter 2 Ground-Level Air Pollution—
Outdoors and Indoors 66
Introduction 66
Concentration Units for Atmospheric Pollutants • The Chemical
Fate of Trace Gases in Clean Air • Box 2-1: The Interconversion of
Gas Concentrations
Urban Ozone: The Photochemical Smog Process 72
The Origin and Occurrence of Smog • Nitrogen Oxides Production
During Fuel Combustion • Ground-Level Ozone in Smog • Gov-
ernmental Goals for Reducing Ozone Concentrations • Photochem-
ical Smog Around the World • Limiting VOC and NO Emissions to
Reduce Ground-Level Ozone • Catalytic Converters • Control
of Nitric Oxide Emissions from Power Plants • Future Reductions
of Smog-Producing Emissions • Green Chemistry: Replacement of
Organic Solvents with Supercritical and Liquid Carbon Dioxide;
Development of Surfactants for This Compound
Acid Rain 93
Sulfur Dioxide and Hydrogen Sulfide Sources and Abatement • Clean
Coal: Reducing Sulfur Dioxide Emissions from Power Plants
The Ecological Effects of Acid Rain
and of Photochemical Smog 99
Neutralization of Acid Rain by Soil • Release of Aluminum into
Soil and Water Bodies by Acid Rain • Effect on Trees and Crops of
Air Pollution
Contents vii
Particulates in Air Pollution 106
Sources of Coarse Particles • Sources of Fine Particles
Air Quality Indices and Size Characteristics
for Participate Matter 111
The PM Indices • Haze • The Distribution of Particle Sizes
in an Air Sample
The Health Effects of Outdoor Air Pollutants 114
The Human Health Effects of Smogs • Particulates as Health
Risks • Smoke
Indoor Air Pollution 127
Formaldehyde • Benzene • Nitrogen Dioxide • Carbon
Monoxide • Environmental Tobacco Smoke • Asbestos
chapter 3 The Detailed Chemistry
of the Atmosphere 139
Box 3-1 Lewis Structures of Simple Free Radicals
Tropospheric Chemistry 141
The Principles of Reactivity in the Troposphere • The Tropo
spheric Oxidation of Methane • Photochemical Smog: The
Oxidation of Reactive Hydrocarbons • Photochemical
Smog: The Fate of the Free Radicals • Oxidation of
Atmospheric SO2: The Homogeneous Gas-Phase
Mechanism • Oxidation of Atmospheric SO^: The
Aqueous-Phase Mechanism
Systematics of Stratospheric Chemistry 161
Processes Involving Loosely Bound Oxygen Atoms
*C M|Wfe * The Greenhouse Effect
and Global Warming 166
The Mechanism of the Greenhouse Effect 167
The Earth s Energy Balance • Historical Temperature
Trends • Earth s Energy Emissions and the
Greenhouse Effect
viii Contents
Molecular Vibrations: Energy Absorption
by Greenhouse Gases 171
The Major Greenhouse Gases 173
Carbon Dioxide: Absorption of Infrared Light • Carbon Dioxide: Past
Concentration and Emission Trends • Carbon Dioxide: Atmospheric
Lifetime and Fate of Its Emissions • Green Chemistry: Supercritical
Carbon Dioxide in the Production of Computer Chips • Water
Vapor: Its Infrared Absorption and Role in Feedback • The Atmo-
spheric Window
Atmospheric Residence Time 187
Other Greenhouse Gases 191
Methane: Absorption and Sinks • Methane: Emission
Sources • Box 4-1: Determining the Emissions of Old Carbon
Sources of Methane • Methane: Concentration Trend and Possible
Future Increases • Nitrous Oxide • CFCs and Their Replace-
ments • Sulfur Hexafluoride • Tropospheric Ozone
The Climate-Modifying Effects of Aerosols 202
The Interaction of Light with Particles • Aerosols and Global
Warming
Global Warming to Date 206
Earth s Energy Balance • Effective CO2 Concentration • Alloca-
tion of Warming to Natural and Anthropogenic Factors • Global
Wanning: Chronology and Geography • Box 4-2: Cooling over
China from Haze • Global Circulation Models • Other Signs of
Global Warming
OQU f££ $ Climate Change in the Future:
Predictions, Consequences,
and Controls 220
The Potential Consequences of Global Warming 220
Predictions for Climate Change by 2100 • Predictions About Sea
Levels • Climate Predictions for Specific Regions • Predicted
Effects on Human Health
Energy Reserves and Usage 226
Determinants of Growth in Energy Use • Energy Reserves:
Coal • Energy Reserves: Petroleum and Natural Gas • Green
Contents ix
Chemistry: Polylactic Acid—Biodegradable Polymers from Renewable
Resources: Reducing the Need for Petroleum and the Impact on the
Environment • Growth in Energy Use and Its Causes
CO2 Emission Scenarios and Agreements 236
Patterns of Growth in CO2 Concentrations • IPCC Scenarios for
CO2 Emissions and Concentrations • International Agreements on
Greenhouse Gas Emissions
Minimizing Future Emissions
of Greenhouse Gases 241
Carbon Intensity and Carbon Taxes • Sequestration of
CO2 • Removing CO2 from the Atmosphere • Reducing CO?
Emissions by Improving Energy Efficiency • Reducing Methane
Emissions
CHAPTER 6 Renewable Energy, Alternative
Fuels, and the Hydrogen
Economy 252
Renewable Energy 253
Hydroelectric Power • Wind Energy • Biomass • Geothermal
Energy • Wave and Tidal Power • Types of Direct Solar
Energy • Using Thermal Conversion to Produce Electricity
• Limitations on the Conversion of Energy: The Second Law of
Thermodynamics • Solar Cells • Conclusions About Renew-
able Fuels and Solar Energy
Alternative Fuels 267
Gasoline • Octane Enhancers • Natural Gas and Propane
(LPG) • Oxygenated Fuels: Methanol • Oxygenated Fuels:
Ethanol • Alcohols and Ethers as Vehicular Fuels • MTBE as
a Fuel Additive • Biofuels
Hydrogen—Fuel of the Future? 283
Combusting Hydrogen • Generating Electricity by Powering Fuel
Cells with Hydrogen • Obtaining Fuel-Cell Hydrogen from Liquid
Fuels • Electric Cars Powered by Batteries • Other Uses for Fuel
Cells • Storing Hydrogen • Producing Hydrogen • Conclu-
sions Concerning Hydrogen and Other Alternative Fuels
Contents
Environmental Instrumental Analysis 1: Instrumental
Determination of NOX by Chemiluminescence 299
Environmental Instrumental Analysis 2: Instrumental
Determination of Atmospheric Methane 302
PART II TOXIC ORGANIC
CHEMICALS 305
chapter 7 Pesticides 307
Background 307
Types of Pesticides • Traditional Insecticides • Organochlorine
Insecticides • Pesticides in Water
DDT 313
DDT s Structure • Box 7-1: The History of DDT • DDE in Body
Fat • Bans on DDT and Other Persistent Pollutants
The Accumulation of Organochlorines
in Biological Systems 318
Bioconcentration • Biomagnification • Analogs of DDT
Other Organochlorine Insecticides 323
Toxaphene • Hexachlorinated Cyclohexane • Chlorinated
Cyclopentadiene Insecticides
Principles of Toxicology 327
Dose—Response Relationships • Risk Assessment
The Distribution of Environmental
Pollutants 334
An Example of a Fugacity Calculation • Model World Parameters
for Fugacity Calculations
Organophosphate and Carbamate
Insecticides 337
Organophosphate Insecticides • Carbamate Insecticides • Health
Problems of Organophosphates and Carbamates
Contents xi
Natural and Green Insecticides, and Integrated
Pest Management 342
Pesticides from Natural Sources • Integrated Pest Manage-
ment • Green Chemistry: Insecticides That Target Only
Certain Insects • Green Chemistry: A New Method for Controlling
Termites
Herbicides 346
Atrazine and Other Triazines • Chloroacetamides • Glyphosate
• Phenoxy Herbicides
Summary 352
CHAPTER 8 Nonpestic ide Toxic Orqai lie
Compounds of Environmental
Concern 358
Dioxins 359
Dioxin Production in the Preparation of 2,4,5-T • Dioxin
Numbering System • Chlorophenols as Pesticides • Detecting
Dioxins in Food and Water • Box 8-1: Deducing the Probable
Chlorophenolic Origins of a Dioxin
PCBs 365
The Structure of PCB Molecules • The Numbering Systems for
PCBs • Commercial Uses of PCBs • PCBs Cycling Among Air,
Water, and Sediments • PCB Contamination by Furans • Box 8-2:
Predicting the Furans That Will Form from a Given PCB
Other Sources of Dioxins and Furans 376
Pulp and Paper Mills • Green Chemistry: HiO2, an Environmentally
Benign Bleaching Agent for the Production of Paper • Fires and
Incineration as Sources of Dioxins and Furans • Chlorine Content
of Dioxin and Furan Emissions
The Health Effects of Dioxins,
Furans, and PCBs 381
Inadvertent PCB Poisonings • Effects of in Utero Exposure to
PCBs • The Toxicity Patterns of Dioxins, Furans, and PCBs
• The TEQ Scale • Dioxins, Furans, and PCBs in Food • Diox-
ins as Probable Human Carcinogens • Human Exposure to Dioxins,
Furans, and PCBs
xli Contents
Polynudeor Aromatic Hydrocarbons (PAHs) 393
The Molecular Structure of PAHs • PAHs as Air
Pollutants • PAHs as Water Pollutants • Formation of PAHs
During Incomplete Combustion • Carcinogenic Properties of
PAHs • Box 8-3: More on the Mechanism of PAH Carcino-
genesis • Environmental Levels of PAHs and Human Cancer
Other Toxic Organics of Environmental Concern 402
Insect Repellants • PBDEs: A New Persistent Pollutant • Perfluo-
rinated Sulfonates
Environmental Estrogens 405
Mechanism of Action of Environmental Estrogens • The Chemicals
That Operate as Environmental Estrogens • Effects of Environmen-
tal Estrogens on Wildlife • Effects of Environmental Estrogens on
Humans
The Long-Range Transport of Atmospheric
Pollutants 413
Environmental Instrumental Analysis 3: Electron Capture
Detection of Pesticides 420
PART HI WATER 423
CHAPfEfe 9 The Chemistry of Natural Waters 425
Oxidation-Reduction Chemistry in
Natural Waters 426
Dissolved Oxygen • Oxygen Demand • Green Chemistry: Enzy-
matic Preparation of Cotton Textiles • Decomposition of Organic
Matter in Water • The pE Scale • pE-pH Diagrams • Sulfur
Compounds in Natural Waters • Acid Mine Drainage • Nitrogen
Compounds in Natural Waters
Acid-Base Chemistry in Natural Waters:
The Carbonate System 442
The CO2-Carbonate System • Water in Equilibrium with Solid
Calcium Carbonate • Water in Equilibrium with Both CaCO3 and
Atmospheric CO2
Contents xiil
Ion Concentrations in Natural Waters
and Drinking Water 449
The Abundant Ions in Fresh Water • Fluoride Ion in
Water • Bottled Drinking Waters • Seawater • Alkalinity
Indices for Natural Waters • The Hardness Index for Natural
Waters • Aluminum in Natural Waters • Perchlorates
CHAPTER 10 The Pollution and Purification
of Water 463
Water Disinfection 463
Aeration of Water • Removal of Calcium and Magnesium
• Box 10-1: Activated Carbon • Disinfection to Reduce Illnesses
• Filtering of Water • Removal of Colloidal Particles by Precipi-
tation • Disinfection by Membrane Technology • Disinfection
by Ultraviolet Irradiation • Disinfection by Chemical Methods:
Ozone and Chlorine Dioxide • Disinfection by Chlorination: His-
tory • Disinfection by Chlorination: Production of Hypochlorous
Acid • Disinfection by Chlorination: By-Products and Their Health
Effects • Box 10-2: The Mechanism of Chloroform Production in
Drinking Water • Disinfection by Chlorination: Advantages over
Other Methods
Groundwater: Its Supply, Chemical Contamination,
and Remediation 478
The Nature and Supply of Groundwater • The Contamination of
Groundwater • Nitrate Contamination of Groundwater • Nitrates
in Food and Water • Health Hazards of Nitrates in Drinking
Water • Nitrosamines in Food and Water • Groundwater Contami-
nation by Organic Chemicals • The Ultimate Sink for Organic
Contaminants in Groundwater • Decontamination of Groundwater:
Pump-and-Treat • Decontamination of Groundwater: Bioremediation
and Natural Attenuation • Decontamination of Groundwater: In Situ
Remediation
The Chemical Contamination and Treatment
of Wastewater and Sewage 494
Sewage Treatment • The Origin and Removal of Excess
Phosphate • Box 10-3: Time Dependence of Concentrations in
the Two-Step Oxidation of Ammonia • Green Chemistry: Sodium
Iminodisuccinate—A Biodegradable Chelating Agent • Reducing
the Salt Concentration in Water • The Biological Treatment of
xiv Contents
Wastewater and Sewage • Drugs in Wastewater from Sewage Treat-
ment Plants • The Treatment of Cyanides in Wastewater • The
Disposal of Sewage Sludge
Modern Wastewater and Air Purification Techniques 507
The Destruction of Volatile Organic Compounds • Advanced
Oxidation Methods for Water Purification • Photocatalytic
Processes • Other Advanced Oxidation Methods
CHAPTER 11 Toxic Heavy Metals 516
Introduction 516
Speciation and the Toxicity of Heavy Metals • Bioaccumulation of
Heavy Metals
Mercury 519
Mercury Vapor • Mercury Amalgams • Mercury and
the Industrial Chlor-Alkali Process • The 2 + Ion of
Mercury • Methylmercury Toxicity • Methylmercury
Accumulation in the Environment and in the Human
Body • Other Sources of Methylmercury • The Use
of Mercury in Preservatives and as Medications • Safe Levels
of Mercury in the Body
Lead 530
Elemental Lead as an Environmental Risk • Ionic 2+ Lead in
Water and Food as an Environmental Hazard to Humans • Lead
Salts as Glazes and Pigments • Green Chemistry: Replacement of
Lead in Electrodeposition Coatings • Dissolution of Otherwise
Insoluble Lead Salts • Ionic 4+ Lead in Automobile
Batteries • Tetravalent Organic Lead Compounds as Gasoline
Additives • Environmental Lead from Leaded Gasoline • Lead s
Effects on Human Reproduction and Intelligence
Cadmium 542
Environmental Sources of Cadmium • Human Intake of Cadmium
• Protection Against Low Levels of Cadmium
Arsenic 545
Arsenic(HI) Versus Arsenic(V) Toxicity • Anthropogenic Sources
of Arsenic to the Environment • Box 11-1: Organotin Compounds
• Arsenic in Drinking Water • Drinking Water Standards for
Contents xv
Arsenic • Removal of Arsenic from Water • Steady State of
Arsenic in Water • Arsenic in Organic and Other Molecular Forms
Chromium 554
Chromium Contamination of Water • The Wood Preservative
CCA • Green Chemistry: Removing the Arsenic and Chromium
from Pressure-Treated Wood
Environmental Instrumental Analysis 4: Inductively Coupled
Plasma Determination of Lead 562
Environmental Instrumental Analysis 5: Ion Chromatography
of Environmentally Significant Anions 565
PART IV SOME OTHER ENVIRONMENTAL
CONCERNS 569
CHAPTER 12 Hazardous and Municipal
Wastes, and the Contamination
of Soils and Sediments 571
Domestic and Commercial Garbage: Its Disposal
and Minimization 571
Burying Garbage in Landfills • Stages in the Decomposition of
Garbage in a Landfill • Leachate from a Landfill • Incineration
of Garbage • Green Chemistry: Polyaspartate—A Biodegradable
Antiscalant and Dispersing Agent
The Recycling of Household and Commercial Waste 581
The Recycling of Metals and Glass • The Recycling of Paper • The
Recycling of Tires • The Recycling of Plastics • Ways of
Recycling Plastics • Green Chemistry: Development of Recyclable
Carpeting • Life Cycle Assessments
Soils and Sediments 591
Basic Soil Chemistry • The Acidity and Cation-Exchange Capacity
of Soil • Soil Salinity • Sediments • The Binding of Heavy
Metals to Soils and Sediments • Mine Tailings • The Reme-
diation of Contaminated Soil • Box 12-1: The Superfund Program
• The Analysis and Remediation of Contaminated Sediments
xvi Contents
• Bioremediation of Wastes and Soil • Bioremediation of Organo-
chlorine Contamination • Phytoremediation of Soils and Sediments
Hazardous Wastes 614
The Nature of Hazardous Wastes • The Management of Hazardous
Wastes • Toxic Substances • Incineration of Toxic Waste
• Supercritical Fluids • Nonoxidative Processes
CHAPTER 13 Radioactivity, Radon,
and Nuclear Energy 626
Radioactivity and Radon Gas 626
The Nature of Radioactivity • The Health Effects of Ionizing
Radiation • Quantifying the Amount of Radiation Energy Absorbed
• Radioactive Nucleus Decay • Radon from the Uranium-238
Decay Sequence • Measuring the Rate of Disintegration and
Health Threat from Environmental Radiation • Box 13-1: Steady-
State Analysis of the Radioactive Decay Series • The Daughters
of Radon • Measuring the Health Danger from Radon and Its
Daughters • Depleted Uranium • Dirty Bombs
Nuclear Energy 637
Fission Reactors • Environmental Problems of Uranium Mining and
Refining • The Future of Fission-Based Nuclear Power • The
Catastrophe at Chernobyl • The Accident at Three Mile Island
• Plutonium and the Problem of Nuclear Waste • Box 13-2: Radio-
active Contamination by Plutonium Production • Fusion Reactors
• The Energy Released in Nuclear Processes
Appendix: Background Organic
Chemistry AP-1
Answers to Selected Odd-Numbered
Problems AN-1
Index 1-1
|
| any_adam_object | 1 |
| author | Baird, Colin Cann, Michael |
| author_facet | Baird, Colin Cann, Michael |
| author_role | aut aut |
| author_sort | Baird, Colin |
| author_variant | c b cb m c mc |
| building | Verbundindex |
| bvnumber | BV023797319 |
| classification_rvk | VN 9200 |
| ctrlnum | (OCoLC)249341000 (DE-599)BVBBV023797319 |
| dewey-full | 628.50154 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 628 - Sanitary engineering |
| dewey-raw | 628.50154 |
| dewey-search | 628.50154 |
| dewey-sort | 3628.50154 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Chemie / Pharmazie Bauingenieurwesen |
| edition | 3. ed. |
| format | Book |
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| id | DE-604.BV023797319 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:37:01Z |
| institution | BVB |
| isbn | 0716748770 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017439522 |
| oclc_num | 249341000 |
| open_access_boolean | |
| owner | DE-634 DE-83 |
| owner_facet | DE-634 DE-83 |
| physical | Getr. Zählung Ill., graph. Darst. |
| publishDate | 2005 |
| publishDateSearch | 2005 |
| publishDateSort | 2005 |
| publisher | Freeman |
| record_format | marc |
| spelling | Baird, Colin Verfasser aut Environmental chemistry Colin Baird ; Michael Cann 3. ed. New York Freeman 2005 Getr. Zählung Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Lehrbuch (DE-588)4123623-3 gnd rswk-swf Ökologische Chemie (DE-588)4135167-8 gnd rswk-swf Umweltgeochemie (DE-588)4404136-6 gnd rswk-swf Ökologische Chemie (DE-588)4135167-8 s Umweltgeochemie (DE-588)4404136-6 s Lehrbuch (DE-588)4123623-3 s 1\p DE-604 Cann, Michael Verfasser aut HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017439522&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Baird, Colin Cann, Michael Environmental chemistry Lehrbuch (DE-588)4123623-3 gnd Ökologische Chemie (DE-588)4135167-8 gnd Umweltgeochemie (DE-588)4404136-6 gnd |
| subject_GND | (DE-588)4123623-3 (DE-588)4135167-8 (DE-588)4404136-6 |
| title | Environmental chemistry |
| title_auth | Environmental chemistry |
| title_exact_search | Environmental chemistry |
| title_full | Environmental chemistry Colin Baird ; Michael Cann |
| title_fullStr | Environmental chemistry Colin Baird ; Michael Cann |
| title_full_unstemmed | Environmental chemistry Colin Baird ; Michael Cann |
| title_short | Environmental chemistry |
| title_sort | environmental chemistry |
| topic | Lehrbuch (DE-588)4123623-3 gnd Ökologische Chemie (DE-588)4135167-8 gnd Umweltgeochemie (DE-588)4404136-6 gnd |
| topic_facet | Lehrbuch Ökologische Chemie Umweltgeochemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017439522&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT bairdcolin environmentalchemistry AT cannmichael environmentalchemistry |