Verfügbarkeit: Colloid stability and application in pharmacy

Colloid stability and application in pharmacy:

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Format:	Buch
Sprache:	English
Veröffentlicht:	Weinheim [u.a.] WILEY-VCH 2007
Schriftenreihe:	Colloids and interface science series 3
Schlagworte:	Colloids Colloids in medicine Colloids > Stability Pharmaceutical chemistry Kolloidchemie
Online-Zugang:	http://deposit.dnb.de/cgi-bin/dokserv?id=2878101&prov=M&dok_var=1&dok_ext=htm Inhaltsverzeichnis Inhaltsverzeichnis
Beschreibung:	XVIII, 437 S. Ill, graph. Darst. 240 mm x 170 mm
ISBN:	9783527314638

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650		4	\|a Colloids
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Datensatz im Suchindex

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adam_text	COLLOIDS AND INTERFACE SCIENCE SERIES VOLUME 3 COLLOID STABILITY AND APPLICATION IN PHARMACY GDNED BY FHQRWAT F. TADROS WLLEY-VCH VERLAGGMBH &CO. KGAA CONTENTS PREFACE XIII LIST OF CONTRIBUTORS XXV 1 IRON OXIDE NANOPARTICLE DISPERSIONS 1 IGNDC CAPEK 1.1 INTRODUCTION 2 1.2 PREPARATION OF IRON AND IRON OXIDE NANOPARTICLES 5 1.2.1 GENERAL 5 1.2.2 MICROEMULSION 8 1.2.3 PRECIPITATION 11 1.2.3.1 HYDROPHOBICALLY MODIFIED NANOPARTICLES 12 1.2.3.2 HYDROPHILICALLY MODIFIED NANOPARTICLES 21 1.3 METAL-IRON OXIDE NANOPARTICLES 29 1.4 IRON-METAL ALLOYS 38 1.5 POLYMER-IRON OXIDE NANOPARTICLES 39 1.6 OXIDATION OF IRON OXIDE PARTICLES 44 1.7 APPLICATIONS 47 1.8 PARTICLE SIZE ESTIMATIONS 48 1.9 CONCLUSIONS 49 REFERENCES 55 2 SOLUBILIZATION OF A POORLY SOLUBLE AROMATIC DRUG BY MICELLAR SOLUTIONS OF AMPHIPHILIC BLOCK COPOLY(OXYALKYLENE)S 61 DAVID ATTWOOD AND COLIN BOOTH 2.1 INTRODUCTION 61 2.2 COPOLYMERS 64 2.3 MICELLIZATION AND MICELLE PROPERTIES 66 2.4 DRUG SOLUBILIZATION 68 2.4.1 METHOD 1 70 2.4.1.1 EFFECT OF COMPOSITION AND MICELLE CORE SIZE: 25 "C 70 2.4.1.2 EFFECT OF SOLUBILIZATION TEMPERATURE 72 COLLOIDS AND INTERFACE SCIENCE SERIES, VOL. 3 COLLOID STABILITY AND APPLICATION IN PHARMACY. EDITED BY THARWAT F. TADROS COPYRIGHT 2007 WILEY-VCH VERLAG GMBH & CO. KGAA, WEINHEIM ISBN: 978-3-527-31463-8 VI CONTENTS 2.5 METHOD 2 73 2.6 GELATION 74 2.7 CONCLUSION 75 REFERENCES 76 3 CONTROLLING THE PHYSICAL STABILITY OF LIPOSOMAL COLLOIDS 79 FERENC CSEMPESZ AND \STV6N PUSKDS 3.1 INTRODUCTION 79 3.2 EXPERIMENTAL 80 3.2.1 MATERIALS 80 3.2.2 METHODS 81 3.2.2.1 PREPARATION OF LIPOSOMES 81 3.2.2.2 CHARACTERIZATION OF THE PHYSICAL STABILITY OF LIPOSOMES 82 3.3 RESULTS 82 3.3.1 PARTICLE SIZE AND SIZE DISTRIBUTION OF LIPOSOMES 82 3.3.2 KINETIC STABILITY OF LIPOSOME DISPERSIONS 84 3.3.3 EFFECT OF PH ON THE STABILITY OF DMPC LIPOSOMES 85 3.3.4 EFFECT OF DISSOLVED CYDODEXTRINS ON THE STABILITY OF DPPC LIPOSOMES 87 3.4 CONCLUSIONS 88 REFERENCES 89 4 MATHEMATICAL MODELING OF COAGULATION AND FLOCCULATION OF COLLOIDAL SUSPENSIONS INCORPORATING THE INFLUENCE OF SURFACE FORCES 91 VENKATARAMANA RUNKANA AND PONISSERIL SOMASUNDARAN 4.1 INTRODUCTION 91 4.2 MATHEMATICAL MODEL 93 4.2.1 POPULATION BALANCE EQUATION FOR AGGREGATION 94 4.2.2 COLLISION FREQUENCY 96 4.2.3 COLLISION EFFICIENCY 99 4.2.3.1 VAN DER WAALS ATTRACTION 100 4.2.3.2 ELECTRICAL DOUBLE LAYER FORCES 101 4.2.3.3 BRIDGING ATTRACTION/STERIC REPULSION 102 4.2.3.4 HYDRATION REPULSION 103 4.3 RESULTS AND DISCUSSION 104 4.3.1 ELECTROLYTE-INDUCED COAGULATION 105 4.3.1.1 DIFFUSION-LIMITED AGGREGATION 105 4.3.1.2 REACTION-LIMITED AGGREGATION 106 4.3.2 POLYMER-INDUCED FLOCCULATION 109 4.3.2.1 SIMPLE CHARGE NEUTRALIZATION 109 4.3.2.2 BRIDGING FLOCCULATION 111 4.4 CONCLUSIONS 115 REFERENCES 116 CONTENTS VII 5 EMULSION STABILITY AND INTERFACIAL PROPERTIES - APPLICATION TO COMPLEX EMULSIONS OF INDUSTRIAL INTEREST 119 DANIELE CLAUSSE, DELPHINE DANIEL-DAVID, FRANGOIS GOMEZ, LJEPSA KOMUNJER, ISABELLE PEZRON, CHRISTINE DALMAZZONE, AND CHRISTINE NOIK 5.1 INTRODUCTION 120 5.2 MACROSCOPIC CHARACTERIZATION OF COMPLEX EMULSIONS: PROPERTIES AND STABILITY 121 5.2.1 EMULSION DEFINITIONS 121 5.2.2 RELEVANT PARAMETERS 122 5.2.3 EMULSION STABILITY 122 5.2.4 METHODS USED TO CHARACTERIZE EMULSION STABILITY 124 5.3 METHODS USED TO CHARACTERIZE INTERFACIAL PROPERTIES 227 5.3.1 EXPERIMENTAL METHODS 127 5.3.2 ADSORPTION 127 5.3.2.1 STRUCTURE OF ADSORBED LAYERS 127 5.3.2.2 PRINCIPAL SURFACE/INTERFACE PARAMETERS 128 5.4 IMPACT OF INTERFACIAL PHENOMENA ON THE STABILITY OF COMPLEX EMULSIONS 130 5.4.1 OIL-IN-WATER FOOD EMULSIONS 130 5.4.1.1 SURFACE-ACTIVE FOOD EMULSION COMPONENTS 130 5.4.1.2 RELATIONSHIP BETWEEN THE PROPERTIES OF THE PROTEIN INTERFACIAL FILM AND THE STABILITY OF FOOD EMULSIONS 132 5.4.2 WATER-IN-CRUDE OIL EMULSION: FORMATION AND DESTABILIZATION 136 5.4.2.1 CORRELATION BETWEEN WATER-IN-CRUDE OIL EMULSION STABILITY AND PHYSICOCHEMICAL PARAMETERS 137 5.4.2.2 DESTABILIZATION OF WATER-IN-OIL EMULSIONS BY CHEMICAL DEMULSIFIERS 140 5.5 CONCLUSIONS 144 REFERENCES 145 6 WETTING FILM DYNAMICS AND STABILITY 151 BORYAN RADOEV, KLAUS WERNER STOCKELHUBER, ROUMEN TSEKOV, AND PHILIPPE LETOCART 6.1 INTRODUCTION 151 6.2 DYNAMICS OF WETTING FILMS 152 6.2.1 DRAINAGE OF LIQUID FILMS AND DIMPLE RELAXATION 152 6.2.2 ACOUSTICALLY EXCITED SURFACE WAVES 158 6.3 STABILITY OF WETTING FILMS 161 6.3.1 STABLE FILMS 161 6.3.2 RUPTURE OF WETTING FILMS 263 6.3.3 FILM RUPTURE CAUSED BY NANO-BUBBLES 266 REFERENCES 171 VIII CONTENTS 7 MEASURING FORCES IN THE COLLOIDAL REGIME WITH THE ATOMIC FORCE MICROSCOPE 273 J. MIEKE KLEIJN, MARCEL CIESBERS, AND MARTIEN A. COHEN STUART 7.1 INTRODUCTION 173 7.1.1 GENERAL INTRODUCTION 173 7.1.2 MEASURING SURFACE FORCES - A HISTORICAL OVERVIEW 174 7.1.3 THE ATOMIC FORCE MICROSCOPE 279 7.2 FORCE MEASUREMENTS USING THE AFM 183 7.2.1 PRINCIPLES 283 7.2.1.1 DYNAMIC MEASURING METHODS 285 7.2.2 COLLOIDAL PROBE AFM 285 7.2.3 CALIBRATION OF THE PIEZOELECTRIC SCANNER 286 7.2.4 DETERMINATION OF THE CANTILEVER SPRING CONSTANT 187 7.2.5 POINTS OF ATTENTION 290 7.2.5.1 SCANNER PECULIARITIES 290 7.2.5.2 ABSOLUTE DISTANCE 292 7.2.5.3 SURFACE ROUGHNESS 193 7.2.5.4 HYDRODYNAMICS/HYDRODYNAMIC DRAG 294 7.3 FORCES IN THE COLLOIDAL REGIME 294 7.3.1 INTERACTIONS BETWEEN SOLID SURFACES IN AQUEOUS ELECTROLYTE 296 7.3.2 ADHESION 206 7.3.3 FORCES BETWEEN A PROBE PARTICLE AND A FLUID INTERFACE 222 7.3.4 FORCES BETWEEN TWO FLUID INTERFACES 223 7.3.5 SURFACES CARRYING END-GRAFTED OR ADSORBED POLYMERS 213 7.3.6 INTERACTIONS IN THE PRESENCE OF NEGATIVELY ADSORBING POLYMER 228 7.3.7 SINGLE-MOLECULE FORCE SPECTROSCOPY 222 7.4 CONCLUSION AND OUTLOOK 222 REFERENCES 225 8 ION SPECIFICITY IN COLLOIDAL SYSTEMS JOHANNES LYKLEMA AND FRANS A. M. LEERMAKERS 231 8.1 INTRODUCTION 232 8.2 LYOTROPIC OR HOFMEISTER SERIE 233 8.3 SOME LITERATURE EXAMPLES 234 8.3.1 THE SILVER IODIDE SYSTEM 235 8.3.2 OXIDIC SURFACES 242 8.3.3 ANIONIC MONOLAYERS AND ANIONIC MICELLES 245 8.4 MODELING ION SPECIFICITY AT THE ELECTRIFIED SOLID/LIQUID INTERFACE 248 8.4.1 INTRODUCTION 248 8.4.2 OUTLINE OF THE METHOD AND PROCEDURES OF ELABORATION 250 8.4.3 CHOICE OF PARAMETERS 259 8.4.4 RESULTS AND DISCUSSION 260 8.4.5 CONCLUSIONS OF THE MODELING 272 CONTENTS IIX 8.5 OUTLOOK 273 REFERENCES 273 9 STABILIZATION OF THIN FILMS, FOAMS, EMULSIONS AND BIFLUID GELS WITH SURFACE-ACTIVE SOLID PARTICLES 277 KRASSIMIR P. VELIKOV AND ORLIN D. VELEV 9.1 INTRODUCTION 278 9.2 ABSORPTION BEHAVIOR OF PARTICLES AT INTERFACES 278 9.3 MECHANISM OF STABILIZATION OF FOAMS AND EMULSIONS BY SPHERICAL PARTICLES 282 9.3.1 PARTICLES IN LIQUID FILMS 282 9.3.2 EMULSIONS 287 9.3.2.1 EFFECT OF PARTICLE HYDROPHOBICITY 287 9.3.2.2 EFFECT OF PARTICLE SIZE 289 9.3.2.3 EFFECT OF PARTICLE CONCENTRATION 290 9.3.2.4 INTERFACIAL AND BULK RHEOLOGY 292 9.3.3 FOAMS 294 9.4 STABILIZATION BY NON-SPHERICAL PARTICLES 294 9.4.1 FOAMS 295 9.4.2 EMULSIONS 299 9.5 MULTIPLE EMULSIONS STABILIZED WITH PARTICLES 300 9.6 BIFLUID PARTICLE-STABILIZED GELS 302 9.7 CONCLUSIONS AND OUTLOOK 302 REFERENCES 304 10 FORCES IN AQUEOUS NANOFILMS CONTAINING POLYELECTROLYTES 307 DAN QU, KATARZYNA HANNI-CIUNEL, DANIEL RAPOPORT, AND REGINE V. KLITZING 10.1 INTRODUCTION 307 10.2 FORCES IN FILMS 309 10.2.1 DLVO FORCES 309 10.2.2 STRUCTURAL FORCES 309 10.3 METHODS FOR FORCE MEASUREMENTS 320 10.3.1 THIN-ELM PRESSURE BALANCE (TFPB) 320 10.3.1.1 TFPB FOR FLUORESCENCE MEASUREMENTS (FTFPB) 313 10.3.1.2 TFPB OR WETTING FILMS 313 10.3.2 COLLOIDAL PROBE ATOMIC FORCE MICROSCOPE (CP-AFM) 315 10.3.3 SURFACE FORCE APPARATUS (SFA) 316 10.3.4 COMPARISON BETWEEN THE DIFFERENT METHODS: ADVANTAGES AND DISADVANTAGES, FIELDS OF APPLICATION 326 10.4 EFFECT OF CONFINEMENT 318 10.4.1 COMPARISON OF POLYELECTROLYTE STRUCTURING WITHIN BULK AND FILM 318 10.4.2 LOCAL POLYELECTROLYTE CONCENTRATION 322 X CONTENTS 10.5 EFFECT OF DIFFERENT PARAMETERS ON FILM FORCES 323 10.5.1 MOLECULAR ARCHITECTURE 323 10.5.1.1 AMPHIPHILIC DIBLOCK COPOLYMERS 323 10.5.1.2 BRANCHED POLYELECTROLYTES 324 10.5.1.3 RIGIDITY OF THE POLYMER BACKBONE 326 10.5.2 ELECTROSTATICS 326 10.5.2.1 POLYMER CHARGE DENSITY 327 10.5.2.2 IONIC STRENGTH 329 10.6 EFFECT OF FILM INTERFACE PROPERTIES 330 10.6.1 CHARGE OF INTERFACE 330 10.6.1.1 MODIFICATION OF SOLID INTERFACES 330 10.6.1.2 VARIATION OF POLYELECTROLYTE/SURFACTANT COMPOSITION IN FOAM FILMS 330 10.6.2 WETTING FILMS CONTAINING POLYELECTROLYTE SOLUTIONS 333 10.7 SUMMARY AND CONCLUSIONS 333 REFERENCES 334 11 ASSOCIATION BETWEEN POLYELECTROLYTES AND OPPOSITELY CHARGED SURFACTANTS IN BULK AND AT SOLID/LIQUID INTERFACES 337 PER M. CLAESSON, ANDRA DEDINAITE, ROBERT ME'SZDROS, AND IMRE VARGA 11.1 INTRODUCTION 337 11.2 BULK ASSOCIATION 338 11.2.1 DETERMINATION OF BINDING ISOTHERMS 338 11.2.2 THERMODYNAMICS OF ASSOCIATION 340 11.2.2.1 SITE BINDING MODELS 343 11.2.2.2 CLOSED AGGREGATE FORMATION MODELS 347 11.2.2.3 SMALL SYSTEMS THERMODYNAMIC MODEL 351 11.2.2.4 MONOMER BINDING TO POLYELECTROLYTES 356 11.2.3 SIMULATIONS AND ADDITIONAL THEORETICAL APPROACHES 356 11.2.3.1 ONE POLYELECTROLYTE AND ONE MACROION 357 11.2.3.2 SEVERAL POLYELECTROLYTES AND ONE MACROION 358 11.2.3.3 ONE POLYELECTROLYTE AND SEVERAL MACROIONS 358 11.2.3.4 SEVERAL POLYELECTROLYTES AND SEVERAL MACROIONS 359 11.2.4 STABILITY OF POLYELECTROLYTE-SURFACTANT AGGREGATES 360 11.2.5 STRUCTURE OF POLYELECTROLYTE-SURFACTANT COMPLEXES 362 11.3 INTERFACIAL ASSOCIATION 364 11.3.1 ELLIPSOMETRY 365 11.3.1.1 POLYELECTROLYTE ADSORPTION 366 11.3.1.2 POLYELECTROLYTE-SURFACTANT SYSTEMS 368 11.3.2 DUAL POLARIZATION INTERFEROMETRY (DPI) 379 11.3.3 QUARTZ CRYSTAL MICROBALANCE WITH DISSIPATION (QCM-D) 381 11.3.3.1 PREADSORBED POLYELECTROLYTE LAYERS 382 11.3.3.2 ADSORBED LAYERS FORMED BY PREFORMED AGGREGATES 383 11.3.4 NEUTRON REFLECTIVITY 384 CONTENTS XI 11.3.5 SURFACE FORCES 385 11.3.5.1 PREADSORBED POLYELECTROLYTE LAYERS, CLASS (IP) SYSTEMS 385 11.3.5.2 ADSORBED LAYERS FORMED BY PREFORMED AGGREGATES 391 11.4 CONCLUSIONS 392 REFERENCES 392 12 NON-IONIC MICELLE FILMS: THINNING AND STABILITY 397 ALEX D. NIKOLOV AND DARSH T. WASAN 12.1 INTRODUCTION 397 12.2 MICELLAR FILM THINNING PROBED BY CAPILLARY FORCE BALANCE 400 12.3 RESULTS AND DISCUSSION 401 12.4 CONCLUSIONS 407 REFERENCES 408 13 PEGYLATED POLYMER-BASED NANOPARTICLES FOR DRUG DELIVERY TO THE BRAIN 409 HYUN RYOUNG KIM, KARINE ANDRIEUX, AND PATRICK COUVREUR 13.1 INTRODUCTION 409 13.2 BIODEGRADABLE POLYMER-BASED PEGYLATED NANOPARTICLES 422 13.2.1 METHODOLOGY FOR SURFACE MODIFICATION OF NANOPARTICLES BY PEG 412 13.2.1.1 ADSORPTION OF PEG CHAINS ON THE NANOPARTICLE SURFACE 422 13.2.1.2 COVALENT ATTACHMENT OF PEG CHAINS TO THE NANOPARTICLE SURFACE 412 13.2.2 PHYSICOCHEMICAL CHARACTERIZATION OF NANOPARTICLES 414 13.2.3 INTERACTION WITH BLOOD COMPONENTS AND PLASMA PROTEINS 415 13.2.4 APPLICATION OF PEGYLATED NANOPARTICLES TO BRAIN TARGETING 417 13.3 NANOGELS 429 13.4 ACTIVE TARGETING OF PEGYLATED NANOPARTICLES 420 13.4.1 PEG DERIVATIVES FOR PROTEIN ATTACHMENT 420 13.4.2 TARGETING OF TRANSFERRIN RECEPTOR FOR BRAIN DELIVERY 422 13.4.2.1 OX26-CONJUGATED PEGYLATED NANOPARTICLES 422 13.4.2.2 TRANSFERRIN CONJUGATION 423 13.5 CONCLUSIONS 424 REFERENCES 425 SUBJECT INDEX 429
adam_txt	COLLOIDS AND INTERFACE SCIENCE SERIES VOLUME 3 COLLOID STABILITY AND APPLICATION IN PHARMACY GDNED BY FHQRWAT F. TADROS WLLEY-VCH VERLAGGMBH &CO. KGAA CONTENTS PREFACE XIII LIST OF CONTRIBUTORS XXV 1 IRON OXIDE NANOPARTICLE DISPERSIONS 1 IGNDC CAPEK 1.1 INTRODUCTION 2 1.2 PREPARATION OF IRON AND IRON OXIDE NANOPARTICLES 5 1.2.1 GENERAL 5 1.2.2 MICROEMULSION 8 1.2.3 PRECIPITATION 11 1.2.3.1 HYDROPHOBICALLY MODIFIED NANOPARTICLES 12 1.2.3.2 HYDROPHILICALLY MODIFIED NANOPARTICLES 21 1.3 METAL-IRON OXIDE NANOPARTICLES 29 1.4 IRON-METAL ALLOYS 38 1.5 POLYMER-IRON OXIDE NANOPARTICLES 39 1.6 OXIDATION OF IRON OXIDE PARTICLES 44 1.7 APPLICATIONS 47 1.8 PARTICLE SIZE ESTIMATIONS 48 1.9 CONCLUSIONS 49 REFERENCES 55 2 SOLUBILIZATION OF A POORLY SOLUBLE AROMATIC DRUG BY MICELLAR SOLUTIONS OF AMPHIPHILIC BLOCK COPOLY(OXYALKYLENE)S 61 DAVID ATTWOOD AND COLIN BOOTH 2.1 INTRODUCTION 61 2.2 COPOLYMERS 64 2.3 MICELLIZATION AND MICELLE PROPERTIES 66 2.4 DRUG SOLUBILIZATION 68 2.4.1 METHOD 1 70 2.4.1.1 EFFECT OF COMPOSITION AND MICELLE CORE SIZE: 25 "C 70 2.4.1.2 EFFECT OF SOLUBILIZATION TEMPERATURE 72 COLLOIDS AND INTERFACE SCIENCE SERIES, VOL. 3 COLLOID STABILITY AND APPLICATION IN PHARMACY. EDITED BY THARWAT F. TADROS COPYRIGHT 2007 WILEY-VCH VERLAG GMBH & CO. KGAA, WEINHEIM ISBN: 978-3-527-31463-8 VI CONTENTS 2.5 METHOD 2 73 2.6 GELATION 74 2.7 CONCLUSION 75 REFERENCES 76 3 CONTROLLING THE PHYSICAL STABILITY OF LIPOSOMAL COLLOIDS 79 FERENC CSEMPESZ AND \STV6N PUSKDS 3.1 INTRODUCTION 79 3.2 EXPERIMENTAL 80 3.2.1 MATERIALS 80 3.2.2 METHODS 81 3.2.2.1 PREPARATION OF LIPOSOMES 81 3.2.2.2 CHARACTERIZATION OF THE PHYSICAL STABILITY OF LIPOSOMES 82 3.3 RESULTS 82 3.3.1 PARTICLE SIZE AND SIZE DISTRIBUTION OF LIPOSOMES 82 3.3.2 KINETIC STABILITY OF LIPOSOME DISPERSIONS 84 3.3.3 EFFECT OF PH ON THE STABILITY OF DMPC LIPOSOMES 85 3.3.4 EFFECT OF DISSOLVED CYDODEXTRINS ON THE STABILITY OF DPPC LIPOSOMES 87 3.4 CONCLUSIONS 88 REFERENCES 89 4 MATHEMATICAL MODELING OF COAGULATION AND FLOCCULATION OF COLLOIDAL SUSPENSIONS INCORPORATING THE INFLUENCE OF SURFACE FORCES 91 VENKATARAMANA RUNKANA AND PONISSERIL SOMASUNDARAN 4.1 INTRODUCTION 91 4.2 MATHEMATICAL MODEL 93 4.2.1 POPULATION BALANCE EQUATION FOR AGGREGATION 94 4.2.2 COLLISION FREQUENCY 96 4.2.3 COLLISION EFFICIENCY 99 4.2.3.1 VAN DER WAALS ATTRACTION 100 4.2.3.2 ELECTRICAL DOUBLE LAYER FORCES 101 4.2.3.3 BRIDGING ATTRACTION/STERIC REPULSION 102 4.2.3.4 HYDRATION REPULSION 103 4.3 RESULTS AND DISCUSSION 104 4.3.1 ELECTROLYTE-INDUCED COAGULATION 105 4.3.1.1 DIFFUSION-LIMITED AGGREGATION 105 4.3.1.2 REACTION-LIMITED AGGREGATION 106 4.3.2 POLYMER-INDUCED FLOCCULATION 109 4.3.2.1 SIMPLE CHARGE NEUTRALIZATION 109 4.3.2.2 BRIDGING FLOCCULATION 111 4.4 CONCLUSIONS 115 REFERENCES 116 CONTENTS VII 5 EMULSION STABILITY AND INTERFACIAL PROPERTIES - APPLICATION TO COMPLEX EMULSIONS OF INDUSTRIAL INTEREST 119 DANIELE CLAUSSE, DELPHINE DANIEL-DAVID, FRANGOIS GOMEZ, LJEPSA KOMUNJER, ISABELLE PEZRON, CHRISTINE DALMAZZONE, AND CHRISTINE NOIK 5.1 INTRODUCTION 120 5.2 MACROSCOPIC CHARACTERIZATION OF COMPLEX EMULSIONS: PROPERTIES AND STABILITY 121 5.2.1 EMULSION DEFINITIONS 121 5.2.2 RELEVANT PARAMETERS 122 5.2.3 EMULSION STABILITY 122 5.2.4 METHODS USED TO CHARACTERIZE EMULSION STABILITY 124 5.3 METHODS USED TO CHARACTERIZE INTERFACIAL PROPERTIES 227 5.3.1 EXPERIMENTAL METHODS 127 5.3.2 ADSORPTION 127 5.3.2.1 STRUCTURE OF ADSORBED LAYERS 127 5.3.2.2 PRINCIPAL SURFACE/INTERFACE PARAMETERS 128 5.4 IMPACT OF INTERFACIAL PHENOMENA ON THE STABILITY OF COMPLEX EMULSIONS 130 5.4.1 OIL-IN-WATER FOOD EMULSIONS 130 5.4.1.1 SURFACE-ACTIVE FOOD EMULSION COMPONENTS 130 5.4.1.2 RELATIONSHIP BETWEEN THE PROPERTIES OF THE PROTEIN INTERFACIAL FILM AND THE STABILITY OF FOOD EMULSIONS 132 5.4.2 WATER-IN-CRUDE OIL EMULSION: FORMATION AND DESTABILIZATION 136 5.4.2.1 CORRELATION BETWEEN WATER-IN-CRUDE OIL EMULSION STABILITY AND PHYSICOCHEMICAL PARAMETERS 137 5.4.2.2 DESTABILIZATION OF WATER-IN-OIL EMULSIONS BY CHEMICAL DEMULSIFIERS 140 5.5 CONCLUSIONS 144 REFERENCES 145 6 WETTING FILM DYNAMICS AND STABILITY 151 BORYAN RADOEV, KLAUS WERNER STOCKELHUBER, ROUMEN TSEKOV, AND PHILIPPE LETOCART 6.1 INTRODUCTION 151 6.2 DYNAMICS OF WETTING FILMS 152 6.2.1 DRAINAGE OF LIQUID FILMS AND DIMPLE RELAXATION 152 6.2.2 ACOUSTICALLY EXCITED SURFACE WAVES 158 6.3 STABILITY OF WETTING FILMS 161 6.3.1 STABLE FILMS 161 6.3.2 RUPTURE OF WETTING FILMS 263 6.3.3 FILM RUPTURE CAUSED BY NANO-BUBBLES 266 REFERENCES 171 VIII CONTENTS 7 MEASURING FORCES IN THE COLLOIDAL REGIME WITH THE ATOMIC FORCE MICROSCOPE 273 J. MIEKE KLEIJN, MARCEL CIESBERS, AND MARTIEN A. COHEN STUART 7.1 INTRODUCTION 173 7.1.1 GENERAL INTRODUCTION 173 7.1.2 MEASURING SURFACE FORCES - A HISTORICAL OVERVIEW 174 7.1.3 THE ATOMIC FORCE MICROSCOPE 279 7.2 FORCE MEASUREMENTS USING THE AFM 183 7.2.1 PRINCIPLES 283 7.2.1.1 DYNAMIC MEASURING METHODS 285 7.2.2 COLLOIDAL PROBE AFM 285 7.2.3 CALIBRATION OF THE PIEZOELECTRIC SCANNER 286 7.2.4 DETERMINATION OF THE CANTILEVER SPRING CONSTANT 187 7.2.5 POINTS OF ATTENTION 290 7.2.5.1 SCANNER PECULIARITIES 290 7.2.5.2 ABSOLUTE DISTANCE 292 7.2.5.3 SURFACE ROUGHNESS 193 7.2.5.4 HYDRODYNAMICS/HYDRODYNAMIC DRAG 294 7.3 FORCES IN THE COLLOIDAL REGIME 294 7.3.1 INTERACTIONS BETWEEN SOLID SURFACES IN AQUEOUS ELECTROLYTE 296 7.3.2 ADHESION 206 7.3.3 FORCES BETWEEN A PROBE PARTICLE AND A FLUID INTERFACE 222 7.3.4 FORCES BETWEEN TWO FLUID INTERFACES 223 7.3.5 SURFACES CARRYING END-GRAFTED OR ADSORBED POLYMERS 213 7.3.6 INTERACTIONS IN THE PRESENCE OF NEGATIVELY ADSORBING POLYMER 228 7.3.7 SINGLE-MOLECULE FORCE SPECTROSCOPY 222 7.4 CONCLUSION AND OUTLOOK 222 REFERENCES 225 8 ION SPECIFICITY IN COLLOIDAL SYSTEMS JOHANNES LYKLEMA AND FRANS A. M. LEERMAKERS 231 8.1 INTRODUCTION 232 8.2 LYOTROPIC OR HOFMEISTER SERIE 233 8.3 SOME LITERATURE EXAMPLES 234 8.3.1 THE SILVER IODIDE SYSTEM 235 8.3.2 OXIDIC SURFACES 242 8.3.3 ANIONIC MONOLAYERS AND ANIONIC MICELLES 245 8.4 MODELING ION SPECIFICITY AT THE ELECTRIFIED SOLID/LIQUID INTERFACE 248 8.4.1 INTRODUCTION 248 8.4.2 OUTLINE OF THE METHOD AND PROCEDURES OF ELABORATION 250 8.4.3 CHOICE OF PARAMETERS 259 8.4.4 RESULTS AND DISCUSSION 260 8.4.5 CONCLUSIONS OF THE MODELING 272 CONTENTS IIX 8.5 OUTLOOK 273 REFERENCES 273 9 STABILIZATION OF THIN FILMS, FOAMS, EMULSIONS AND BIFLUID GELS WITH SURFACE-ACTIVE SOLID PARTICLES 277 KRASSIMIR P. VELIKOV AND ORLIN D. VELEV 9.1 INTRODUCTION 278 9.2 ABSORPTION BEHAVIOR OF PARTICLES AT INTERFACES 278 9.3 MECHANISM OF STABILIZATION OF FOAMS AND EMULSIONS BY SPHERICAL PARTICLES 282 9.3.1 PARTICLES IN LIQUID FILMS 282 9.3.2 EMULSIONS 287 9.3.2.1 EFFECT OF PARTICLE HYDROPHOBICITY 287 9.3.2.2 EFFECT OF PARTICLE SIZE 289 9.3.2.3 EFFECT OF PARTICLE CONCENTRATION 290 9.3.2.4 INTERFACIAL AND BULK RHEOLOGY 292 9.3.3 FOAMS 294 9.4 STABILIZATION BY NON-SPHERICAL PARTICLES 294 9.4.1 FOAMS 295 9.4.2 EMULSIONS 299 9.5 MULTIPLE EMULSIONS STABILIZED WITH PARTICLES 300 9.6 BIFLUID PARTICLE-STABILIZED GELS 302 9.7 CONCLUSIONS AND OUTLOOK 302 REFERENCES 304 10 FORCES IN AQUEOUS NANOFILMS CONTAINING POLYELECTROLYTES 307 DAN QU, KATARZYNA HANNI-CIUNEL, DANIEL RAPOPORT, AND REGINE V. KLITZING 10.1 INTRODUCTION 307 10.2 FORCES IN FILMS 309 10.2.1 DLVO FORCES 309 10.2.2 STRUCTURAL FORCES 309 10.3 METHODS FOR FORCE MEASUREMENTS 320 10.3.1 THIN-ELM PRESSURE BALANCE (TFPB) 320 10.3.1.1 TFPB FOR FLUORESCENCE MEASUREMENTS (FTFPB) 313 10.3.1.2 TFPB OR WETTING FILMS 313 10.3.2 COLLOIDAL PROBE ATOMIC FORCE MICROSCOPE (CP-AFM) 315 10.3.3 SURFACE FORCE APPARATUS (SFA) 316 10.3.4 COMPARISON BETWEEN THE DIFFERENT METHODS: ADVANTAGES AND DISADVANTAGES, FIELDS OF APPLICATION 326 10.4 EFFECT OF CONFINEMENT 318 10.4.1 COMPARISON OF POLYELECTROLYTE STRUCTURING WITHIN BULK AND FILM 318 10.4.2 LOCAL POLYELECTROLYTE CONCENTRATION 322 X CONTENTS 10.5 EFFECT OF DIFFERENT PARAMETERS ON FILM FORCES 323 10.5.1 MOLECULAR ARCHITECTURE 323 10.5.1.1 AMPHIPHILIC DIBLOCK COPOLYMERS 323 10.5.1.2 BRANCHED POLYELECTROLYTES 324 10.5.1.3 RIGIDITY OF THE POLYMER BACKBONE 326 10.5.2 ELECTROSTATICS 326 10.5.2.1 POLYMER CHARGE DENSITY 327 10.5.2.2 IONIC STRENGTH 329 10.6 EFFECT OF FILM INTERFACE PROPERTIES 330 10.6.1 CHARGE OF INTERFACE 330 10.6.1.1 MODIFICATION OF SOLID INTERFACES 330 10.6.1.2 VARIATION OF POLYELECTROLYTE/SURFACTANT COMPOSITION IN FOAM FILMS 330 10.6.2 WETTING FILMS CONTAINING POLYELECTROLYTE SOLUTIONS 333 10.7 SUMMARY AND CONCLUSIONS 333 REFERENCES 334 11 ASSOCIATION BETWEEN POLYELECTROLYTES AND OPPOSITELY CHARGED SURFACTANTS IN BULK AND AT SOLID/LIQUID INTERFACES 337 PER M. CLAESSON, ANDRA DEDINAITE, ROBERT ME'SZDROS, AND IMRE VARGA 11.1 INTRODUCTION 337 11.2 BULK ASSOCIATION 338 11.2.1 DETERMINATION OF BINDING ISOTHERMS 338 11.2.2 THERMODYNAMICS OF ASSOCIATION 340 11.2.2.1 SITE BINDING MODELS 343 11.2.2.2 CLOSED AGGREGATE FORMATION MODELS 347 11.2.2.3 SMALL SYSTEMS THERMODYNAMIC MODEL 351 11.2.2.4 MONOMER BINDING TO POLYELECTROLYTES 356 11.2.3 SIMULATIONS AND ADDITIONAL THEORETICAL APPROACHES 356 11.2.3.1 ONE POLYELECTROLYTE AND ONE MACROION 357 11.2.3.2 SEVERAL POLYELECTROLYTES AND ONE MACROION 358 11.2.3.3 ONE POLYELECTROLYTE AND SEVERAL MACROIONS 358 11.2.3.4 SEVERAL POLYELECTROLYTES AND SEVERAL MACROIONS 359 11.2.4 STABILITY OF POLYELECTROLYTE-SURFACTANT AGGREGATES 360 11.2.5 STRUCTURE OF POLYELECTROLYTE-SURFACTANT COMPLEXES 362 11.3 INTERFACIAL ASSOCIATION 364 11.3.1 ELLIPSOMETRY 365 11.3.1.1 POLYELECTROLYTE ADSORPTION 366 11.3.1.2 POLYELECTROLYTE-SURFACTANT SYSTEMS 368 11.3.2 DUAL POLARIZATION INTERFEROMETRY (DPI) 379 11.3.3 QUARTZ CRYSTAL MICROBALANCE WITH DISSIPATION (QCM-D) 381 11.3.3.1 PREADSORBED POLYELECTROLYTE LAYERS 382 11.3.3.2 ADSORBED LAYERS FORMED BY PREFORMED AGGREGATES 383 11.3.4 NEUTRON REFLECTIVITY 384 CONTENTS XI 11.3.5 SURFACE FORCES 385 11.3.5.1 PREADSORBED POLYELECTROLYTE LAYERS, CLASS (IP) SYSTEMS 385 11.3.5.2 ADSORBED LAYERS FORMED BY PREFORMED AGGREGATES 391 11.4 CONCLUSIONS 392 REFERENCES 392 12 NON-IONIC MICELLE FILMS: THINNING AND STABILITY 397 ALEX D. NIKOLOV AND DARSH T. WASAN 12.1 INTRODUCTION 397 12.2 MICELLAR FILM THINNING PROBED BY CAPILLARY FORCE BALANCE 400 12.3 RESULTS AND DISCUSSION 401 12.4 CONCLUSIONS 407 REFERENCES 408 13 PEGYLATED POLYMER-BASED NANOPARTICLES FOR DRUG DELIVERY TO THE BRAIN 409 HYUN RYOUNG KIM, KARINE ANDRIEUX, AND PATRICK COUVREUR 13.1 INTRODUCTION 409 13.2 BIODEGRADABLE POLYMER-BASED PEGYLATED NANOPARTICLES 422 13.2.1 METHODOLOGY FOR SURFACE MODIFICATION OF NANOPARTICLES BY PEG 412 13.2.1.1 ADSORPTION OF PEG CHAINS ON THE NANOPARTICLE SURFACE 422 13.2.1.2 COVALENT ATTACHMENT OF PEG CHAINS TO THE NANOPARTICLE SURFACE 412 13.2.2 PHYSICOCHEMICAL CHARACTERIZATION OF NANOPARTICLES 414 13.2.3 INTERACTION WITH BLOOD COMPONENTS AND PLASMA PROTEINS 415 13.2.4 APPLICATION OF PEGYLATED NANOPARTICLES TO BRAIN TARGETING 417 13.3 NANOGELS 429 13.4 ACTIVE TARGETING OF PEGYLATED NANOPARTICLES 420 13.4.1 PEG DERIVATIVES FOR PROTEIN ATTACHMENT 420 13.4.2 TARGETING OF TRANSFERRIN RECEPTOR FOR BRAIN DELIVERY 422 13.4.2.1 OX26-CONJUGATED PEGYLATED NANOPARTICLES 422 13.4.2.2 TRANSFERRIN CONJUGATION 423 13.5 CONCLUSIONS 424 REFERENCES 425 SUBJECT INDEX 429
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spelling	Colloid stability and application in pharmacy ed. by Tharwat F. Tadros Weinheim [u.a.] WILEY-VCH 2007 XVIII, 437 S. Ill, graph. Darst. 240 mm x 170 mm txt rdacontent n rdamedia nc rdacarrier Colloids and interface science series 3 Colloids Colloids in medicine Colloids Stability Pharmaceutical chemistry Kolloidchemie (DE-588)4134420-0 gnd rswk-swf Kolloidchemie (DE-588)4134420-0 s DE-604 Tadros, Tharwat F. 1937-2018 Sonstige (DE-588)129740837 oth Colloids and interface science series 3 (DE-604)BV023312660 3 http://deposit.dnb.de/cgi-bin/dokserv?id=2878101&prov=M&dok_var=1&dok_ext=htm http://www.gbv.de/dms/bs/toc/522156681.pdf lizenzfrei Inhaltsverzeichnis GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016496915&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Colloid stability and application in pharmacy Colloids and interface science series Colloids Colloids in medicine Colloids Stability Pharmaceutical chemistry Kolloidchemie (DE-588)4134420-0 gnd
subject_GND	(DE-588)4134420-0
title	Colloid stability and application in pharmacy
title_auth	Colloid stability and application in pharmacy
title_exact_search	Colloid stability and application in pharmacy
title_exact_search_txtP	Colloid stability and application in pharmacy
title_full	Colloid stability and application in pharmacy ed. by Tharwat F. Tadros
title_fullStr	Colloid stability and application in pharmacy ed. by Tharwat F. Tadros
title_full_unstemmed	Colloid stability and application in pharmacy ed. by Tharwat F. Tadros
title_short	Colloid stability and application in pharmacy
title_sort	colloid stability and application in pharmacy
topic	Colloids Colloids in medicine Colloids Stability Pharmaceutical chemistry Kolloidchemie (DE-588)4134420-0 gnd
topic_facet	Colloids Colloids in medicine Colloids Stability Pharmaceutical chemistry Kolloidchemie
url	http://deposit.dnb.de/cgi-bin/dokserv?id=2878101&prov=M&dok_var=1&dok_ext=htm http://www.gbv.de/dms/bs/toc/522156681.pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016496915&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
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work_keys_str_mv	AT tadrostharwatf colloidstabilityandapplicationinpharmacy

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