Six-membered transition states in organic synthesis:
Gespeichert in:
1. Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Hoboken, N.J.
Wiley-Interscience
2008
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | Includes bibliographical references and indexes [3,3]-Sigmatropic rearrangements. Claisen rearrangement ; Johnson-Claisen rearrangement ; Ireland-Claisen rearrangement ; Cope rearrangement ; Anionic oxy-Cope rearrangement ; Aza-Cope-Mannich reaction -- Aldol reactions. Asymmetric syn-Aldol reaction ; Asymmetric anti-Aldol reaction ; Proline-catalyzed asymmetric Aldol reaction -- Metal allylation reactions. Boron allylation reaction ; Silicon allylation reaction -- Stereoselective reductions. Diastereoselective syn-reduction of [beta]-hydroxy ketones ; Diastereoselective anti-reduction of [beta]-hydroxy ketones ; Asymmetric reduction |
Beschreibung: | X, 210 S. Ill. 25 cm |
Internformat
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245 | 1 | 0 | |a Six-membered transition states in organic synthesis |c Jaemoon Yang |
264 | 1 | |a Hoboken, N.J. |b Wiley-Interscience |c 2008 | |
300 | |a X, 210 S. |b Ill. |c 25 cm | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
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500 | |a Includes bibliographical references and indexes | ||
500 | |a [3,3]-Sigmatropic rearrangements. Claisen rearrangement ; Johnson-Claisen rearrangement ; Ireland-Claisen rearrangement ; Cope rearrangement ; Anionic oxy-Cope rearrangement ; Aza-Cope-Mannich reaction -- Aldol reactions. Asymmetric syn-Aldol reaction ; Asymmetric anti-Aldol reaction ; Proline-catalyzed asymmetric Aldol reaction -- Metal allylation reactions. Boron allylation reaction ; Silicon allylation reaction -- Stereoselective reductions. Diastereoselective syn-reduction of [beta]-hydroxy ketones ; Diastereoselective anti-reduction of [beta]-hydroxy ketones ; Asymmetric reduction | ||
650 | 4 | |a Reaction mechanisms (Chemistry) | |
650 | 4 | |a Stereochemistry | |
650 | 4 | |a Organic compounds / Synthesis | |
650 | 4 | |a Organic compounds |x Synthesis | |
650 | 4 | |a Reaction mechanisms (Chemistry) | |
650 | 4 | |a Stereochemistry | |
650 | 0 | 7 | |a Übergangszustand |0 (DE-588)4186592-3 |2 gnd |9 rswk-swf |
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Datensatz im Suchindex
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adam_text | CONTENTS
Preface ix
Introduction 1
1 [3,3]-Sigmatropic Rearrangements 5
General Considerations, 5
Reactions, 13
1.1 Claisen Rearrangement, 13
1.2 Johnson-Claisen Rearrangement, 20
1.3 Ireland-Claisen Rearrangement, 27
1.4 Cope Rearrangement, 32
1.5 Anionic Oxy-Cope Rearrangement, 36
1.6 Aza-Cope-Mannich Reaction, 43
2 Aldol Reactions 49
General Considerations, 49
Reactions, 57
2.1 Asymmetrie Syn-AMol Reaction, 57
2.2 Asymmetrie Anti-Mdcl Reaction, 78
2.3 Proline-Catalyzed Asymmetrie Aldol
Reaction, 91
3 Metal ADylatkm Reactioas 97
General Considerations, 97
Reactions, 102
3.1 Boron Allylation Reaction, 102
3.2 Silicon Allylation Reaction, 127
4 Stereoselecti ve Redwtions 147
General Considerations, 147
Reactions, 151
4.1 Diastereoselective 5 n-Reduction of ß-Hydroxy
151
vlii CONTENTS
4.2 Diastereoselective Anfi-Reduction of ß-Hydroxy
Ketones, 161
4.3 Asymmetrie Reduction, 173
List of Copyrighted Materials 197
Abbreviations 199
Subject Index 201
Scheine Index of Natural Products 209
|
adam_txt |
CONTENTS
Preface ix
Introduction 1
1 [3,3]-Sigmatropic Rearrangements 5
General Considerations, 5
Reactions, 13
1.1 Claisen Rearrangement, 13
1.2 Johnson-Claisen Rearrangement, 20
1.3 Ireland-Claisen Rearrangement, 27
1.4 Cope Rearrangement, 32
1.5 Anionic Oxy-Cope Rearrangement, 36
1.6 Aza-Cope-Mannich Reaction, 43
2 Aldol Reactions 49
General Considerations, 49
Reactions, 57
2.1 Asymmetrie Syn-AMol Reaction, 57
2.2 Asymmetrie Anti-Mdcl Reaction, 78
2.3 Proline-Catalyzed Asymmetrie Aldol
Reaction, 91
3 Metal ADylatkm Reactioas 97
General Considerations, 97
Reactions, 102
3.1 Boron Allylation Reaction, 102
3.2 Silicon Allylation Reaction, 127
4 Stereoselecti ve Redwtions 147
General Considerations, 147
Reactions, 151
4.1 Diastereoselective 5 n-Reduction of ß-Hydroxy
151
vlii CONTENTS
4.2 Diastereoselective Anfi-Reduction of ß-Hydroxy
Ketones, 161
4.3 Asymmetrie Reduction, 173
List of Copyrighted Materials 197
Abbreviations 199
Subject Index 201
Scheine Index of Natural Products 209 |
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author | Yang, Jaemoon |
author_facet | Yang, Jaemoon |
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ctrlnum | (OCoLC)126230993 (DE-599)BVBBV023307645 |
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dewey-ones | 547 - Organic chemistry |
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dewey-sort | 3547 12 |
dewey-tens | 540 - Chemistry and allied sciences |
discipline | Chemie / Pharmazie Chemie |
discipline_str_mv | Chemie / Pharmazie Chemie |
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id | DE-604.BV023307645 |
illustrated | Illustrated |
index_date | 2024-07-02T20:49:08Z |
indexdate | 2024-07-09T21:15:30Z |
institution | BVB |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016491984 |
oclc_num | 126230993 |
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owner_facet | DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-11 |
physical | X, 210 S. Ill. 25 cm |
publishDate | 2008 |
publishDateSearch | 2008 |
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publisher | Wiley-Interscience |
record_format | marc |
spelling | Yang, Jaemoon Verfasser aut Six-membered transition states in organic synthesis Jaemoon Yang Hoboken, N.J. Wiley-Interscience 2008 X, 210 S. Ill. 25 cm txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and indexes [3,3]-Sigmatropic rearrangements. Claisen rearrangement ; Johnson-Claisen rearrangement ; Ireland-Claisen rearrangement ; Cope rearrangement ; Anionic oxy-Cope rearrangement ; Aza-Cope-Mannich reaction -- Aldol reactions. Asymmetric syn-Aldol reaction ; Asymmetric anti-Aldol reaction ; Proline-catalyzed asymmetric Aldol reaction -- Metal allylation reactions. Boron allylation reaction ; Silicon allylation reaction -- Stereoselective reductions. Diastereoselective syn-reduction of [beta]-hydroxy ketones ; Diastereoselective anti-reduction of [beta]-hydroxy ketones ; Asymmetric reduction Reaction mechanisms (Chemistry) Stereochemistry Organic compounds / Synthesis Organic compounds Synthesis Übergangszustand (DE-588)4186592-3 gnd rswk-swf Stereoselektive Synthese (DE-588)4135601-9 gnd rswk-swf Stereoselektive Synthese (DE-588)4135601-9 s Übergangszustand (DE-588)4186592-3 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016491984&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Yang, Jaemoon Six-membered transition states in organic synthesis Reaction mechanisms (Chemistry) Stereochemistry Organic compounds / Synthesis Organic compounds Synthesis Übergangszustand (DE-588)4186592-3 gnd Stereoselektive Synthese (DE-588)4135601-9 gnd |
subject_GND | (DE-588)4186592-3 (DE-588)4135601-9 |
title | Six-membered transition states in organic synthesis |
title_auth | Six-membered transition states in organic synthesis |
title_exact_search | Six-membered transition states in organic synthesis |
title_exact_search_txtP | Six-membered transition states in organic synthesis |
title_full | Six-membered transition states in organic synthesis Jaemoon Yang |
title_fullStr | Six-membered transition states in organic synthesis Jaemoon Yang |
title_full_unstemmed | Six-membered transition states in organic synthesis Jaemoon Yang |
title_short | Six-membered transition states in organic synthesis |
title_sort | six membered transition states in organic synthesis |
topic | Reaction mechanisms (Chemistry) Stereochemistry Organic compounds / Synthesis Organic compounds Synthesis Übergangszustand (DE-588)4186592-3 gnd Stereoselektive Synthese (DE-588)4135601-9 gnd |
topic_facet | Reaction mechanisms (Chemistry) Stereochemistry Organic compounds / Synthesis Organic compounds Synthesis Übergangszustand Stereoselektive Synthese |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016491984&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT yangjaemoon sixmemberedtransitionstatesinorganicsynthesis |