Verfügbarkeit: Diffusion mass transfer in fluid systems

Diffusion mass transfer in fluid systems:

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Bibliographische Detailangaben
1. Verfasser:	Cussler, E. L. 1940- (VerfasserIn)
Format:	Buch
Sprache:	English
Veröffentlicht:	Cambridge [u.a.] Cambridge Univ. Press 2009
Ausgabe:	3. ed.
Schlagworte:	Diffusion Mass transfer Fluids Diffusion (Physique) Fluides Transfert de masse Flüssigkeit Stoffübertragung Patentschrift
Online-Zugang:	Contributor biographical information Publisher description Inhaltsverzeichnis Inhaltsverzeichnis
Beschreibung:	XXII, 631 S. graph. Darst.
ISBN:	9780521871211

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adam_text	Contents List of Symbols xiii Preface to Third Edition xix Preface to Second Edition xxi / Models for Diffusion 1 1.1 The Two Basic Models 2 1.2 Choosing Between the Two Models 3 1.3 Examples 7 1.4 Conclusions 9 Questions for Discussion 10 PART I Fundamentals of Diffusion 2 Diffusion in Dilute Solutions 13 2.1 Pioneers in Diffusion 13 2.2 Steady Diffusion Across a Thin Film 17 2.3 Unsteady Diffusion in a Semi-infinite Slab 26 2.4 Three Other Examples 33 2.5 Convection and Dilute Diffusion 41 2.6 A Final Perspective 49 Questions for Discussion 50 Problems 51 Further Reading 55 3 Diffusion in Concentrated Solutions 56 3.1 Diffusion With Convection 56 3.2 Different Forms of the Diffusion Equation 59 3.3 Parallel Diffusion and Convection 67 3.4 Generalized Mass Balances 75 3.5 A Guide to Previous Work 84 3.6 Conclusions 90 Questions for Discussion 90 Problems 91 Further Reading 94 4 Dispersion 95 4.1 Dispersion From a Stack 95 4.2 Dispersion Coefficients 97 vn viii Contents 4.3 Dispersion in Turbulent Flow 101 4.4 Dispersion in Laminar Flow: Taylor Dispersion 104 4.5 Conclusions ПО Questions for Discussion 110 Problems 111 Further Reading 113 PART II Diffusion Coefficients 5 Values of Diffusion Coefficients 117 5.1 Diffusion Coefficients in Gases 117 5.2 Diffusion Coefficients in Liquids 126 5.3 Diffusion in Solids 134 5.4 Diffusion in Polymers 135 5.5 Brownian Motion 139 5.6 Measurement of Diffusion Coefficients 142 5.7 A Final Perspective 156 Questions for Discussion 157 Problems 157 Further Reading 159 6 Diffusion of Interacting Species 161 6.1 Strong Electrolytes 161 6.2 Associating Solutes 172 6.3 Solute-Solvent Interactions 183 6.4 Solute-Boundary Interactions 190 6.5 A Final Perspective 205 Questions for Discussion 206 Problems 206 Further Reading 209 7 Multicomponent Diffusion 211 7.1 Flux Equations for Multicomponent Diffusion 211 7.2 Irreversible Thermodynamics 214 7.3 Solving the Multicomponent Flux Equations 218 7.4 Ternary Diffusion Coefficients 224 7.5 Tracer Diffusion 225 7.6 Conclusions 231 Questions for Discussion 232 Problems 232 Further Reading 234 PART III Mass Transfer 8 Fundamentals of Mass Transfer 237 8.1 A Definition of a Mass Transfer Coefficient 237 8.2 Other Definitions of Mass Transfer Coefficients 243 Contents ix 8.3 Correlations of Mass Transfer Coefficients 249 8.4 Dimensional Analysis: The Route to Correlations 257 8.5 Mass Transfer Across Interfaces 261 8.6 Conclusions 269 Questions for Discussion 270 Problems 270 Further Reading 273 9 Theories of Mass Transfer 274 9.1 The Film Theory 275 9.2 Penetration and Surface-Renewal Theories 277 9.3 Why Theories Fail 281 9.4 Theories for Solid-Fluid Interfaces 284 9.5 Theories for Concentrated Solutions 294 9.6 Conclusions 298 Questions for Discussion 300 Problems 300 Further Reading 303 10 Absorption 304 10.1 The Basic Problem 305 10.2 Absorption Equipment 307 10.3 Absorption of a Dilute Vapor 314 10.4 Absorption of a Concentrated Vapor 321 10.5 Conclusions 326 Questions for Discussion 326 Problems 327 Further Reading 331 11 Mass Transfer in Biology and Medicine 332 11.1 Mass Transfer Coefficients 333 11.2 Artificial Lungs and Artificial Kidneys 339 11.3 Pharmocokinetics 347 11.4 Conclusions 350 Questions for Discussion 351 Problems 351 Further Reading 352 12 Differential Distillation 353 12.1 Overview of Distillation 353 12.2 Very Pure Products 356 12.3 The Column s Feed and its Location 362 12.4 Concentrated Differential Distillation 366 12.5 Conclusions 371 Questions for Discussion 371 Problems 372 Further Reading 374 Contents 13 Staged Distillation 375 13.1 Staged Distillation Equipment 376 13.2 Staged Distillation of Nearly Pure Products 379 13.3 Concentrated Staged Distillation 385 13.4 Stage Efficiencies 393 13.5 Conclusions 400 Questions for Discussion 400 Problems 401 Further Reading 403 14 Extraction 404 14.1 The Basic Problem 404 14.2 Extraction Equipment 407 14.3 Differential Extraction 409 14.4 Staged Extraction 413 14.5 Leaching 416 14.6 Conclusions 420 Questions for Discussion 420 Problems 421 Further Reading 423 /5 Adsorption 424 15.1 Where Adsorption is Important 425 15.2 Adsorbents and Adsorption Isotherms 427 15.3 Breakthrough Curves 431 15.4 Mass Transfer Effects 439 15.5 Other Characteristics of Adsorption 443 15.6 Conclusions 450 Questions for Discussion 450 Problems 450 Further Reading 452 PART IV Diffusion Coupled With Other Processes 16 General Questions and Heterogeneous Chemical Reactions 455 16.1 Is the Reaction Heterogeneous or Homogeneous? 456 16.2 What is a Diffusion-Controlled Reaction? 457 16.3 Diffusion and First-Order Heterogeneous Reactions 459 16.4 Finding the Mechanism of Irreversible Heterogeneous Reactions 465 16.5 Heterogeneous Reactions of Unusual Stoichiometries 469 16.6 Conclusions 473 Questions for Discussion 473 Problems 474 Further Reading 477 Contents xi 17 Homogeneous Chemical Reactions 478 17.1 Mass Transfer with First-Order Chemical Reactions 479 17.2 Mass Transfer with Second-Order Chemical Reactions 488 17.3 Industrial Gas Treating 492 17.4 Diffusion-Controlled Fast Reactions 500 17.5 Dispersion-Controlled Fast Reactions 504 17.6 Conclusions 507 Questions f or Discussion 508 Problems 508 Further Reading 512 18 Membranes 513 18.1 Physical Factors in Membranes 514 18.2 Gas Separations 520 18.3 Reverse Osmosis and Ultrafiltration 526 18.4 Pervaporation 534 18.5 Facilitated Diffusion 539 18.5 Conclusions 545 Questions for Discussion 545 Problems 546 Further Reading 548 19 Controlled Release and Related Phenomena 549 19.1 Controlled Release by Solute Diffusion 551 19.2 Controlled Release by Solvent Diffusion 555 19.3 Barriers 558 19.4 Diffusion and Phase Equilibrium 562 19.5 Conclusions 565 Questions for Discussion 565 Problems 566 Further Reading 566 20 Heat Transfer 568 20.1 Fundamentals of Heat Conduction 568 20.2 General Energy Balances 575 20.3 Heat Transfer Coefficients 579 20.4 Rate Constants for Heat Transfer 585 20.5 Conclusions 591 Questions for Discussion 591 Problems 591 Further Reading 593 21 Simultaneous Heat and Mass Transfer 594 21.1 Mathematical Analogies Among Mass, Heat, and Momentum Transfer 594 21.2 Physical Equalities Among Mass, Heat, and Momentum Transfer 600 xii Contents 21.3 Drying 604 21.4 Design of Cooling Towers 609 21.5 Thermal Diffusion and Effusion 615 21.6 Conclusions 621 Questions for Discussion 621 Problems 622 Further Reading 624 Index 626
adam_txt	Contents List of Symbols xiii Preface to Third Edition xix Preface to Second Edition xxi / Models for Diffusion 1 1.1 The Two Basic Models 2 1.2 Choosing Between the Two Models 3 1.3 Examples 7 1.4 Conclusions 9 Questions for Discussion 10 PART I Fundamentals of Diffusion 2 Diffusion in Dilute Solutions 13 2.1 Pioneers in Diffusion 13 2.2 Steady Diffusion Across a Thin Film 17 2.3 Unsteady Diffusion in a Semi-infinite Slab 26 2.4 Three Other Examples 33 2.5 Convection and Dilute Diffusion 41 2.6 A Final Perspective 49 Questions for Discussion 50 Problems 51 Further Reading 55 3 Diffusion in Concentrated Solutions 56 3.1 Diffusion With Convection 56 3.2 Different Forms of the Diffusion Equation 59 3.3 Parallel Diffusion and Convection 67 3.4 Generalized Mass Balances 75 3.5 A Guide to Previous Work 84 3.6 Conclusions 90 Questions for Discussion 90 Problems 91 Further Reading 94 4 Dispersion 95 4.1 Dispersion From a Stack 95 4.2 Dispersion Coefficients 97 vn viii Contents 4.3 Dispersion in Turbulent Flow 101 4.4 Dispersion in Laminar Flow: Taylor Dispersion 104 4.5 Conclusions ПО Questions for Discussion 110 Problems 111 Further Reading 113 PART II Diffusion Coefficients 5 Values of Diffusion Coefficients 117 5.1 Diffusion Coefficients in Gases 117 5.2 Diffusion Coefficients in Liquids 126 5.3 Diffusion in Solids 134 5.4 Diffusion in Polymers 135 5.5 Brownian Motion 139 5.6 Measurement of Diffusion Coefficients 142 5.7 A Final Perspective 156 Questions for Discussion 157 Problems 157 Further Reading 159 6 Diffusion of Interacting Species 161 6.1 Strong Electrolytes 161 6.2 Associating Solutes 172 6.3 Solute-Solvent Interactions 183 6.4 Solute-Boundary Interactions 190 6.5 A Final Perspective 205 Questions for Discussion 206 Problems 206 Further Reading 209 7 Multicomponent Diffusion 211 7.1 Flux Equations for Multicomponent Diffusion 211 7.2 Irreversible Thermodynamics 214 7.3 Solving the Multicomponent Flux Equations 218 7.4 Ternary Diffusion Coefficients 224 7.5 Tracer Diffusion 225 7.6 Conclusions 231 Questions for Discussion 232 Problems 232 Further Reading 234 PART III Mass Transfer 8 Fundamentals of Mass Transfer 237 8.1 A Definition of a Mass Transfer Coefficient 237 8.2 Other Definitions of Mass Transfer Coefficients 243 Contents ix 8.3 Correlations of Mass Transfer Coefficients 249 8.4 Dimensional Analysis: The Route to Correlations 257 8.5 Mass Transfer Across Interfaces 261 8.6 Conclusions 269 Questions for Discussion 270 Problems 270 Further Reading 273 9 Theories of Mass Transfer 274 9.1 The Film Theory 275 9.2 Penetration and Surface-Renewal Theories 277 9.3 Why Theories Fail 281 9.4 Theories for Solid-Fluid Interfaces 284 9.5 Theories for Concentrated Solutions 294 9.6 Conclusions 298 Questions for Discussion 300 Problems 300 Further Reading 303 10 Absorption 304 10.1 The Basic Problem 305 10.2 Absorption Equipment 307 10.3 Absorption of a Dilute Vapor 314 10.4 Absorption of a Concentrated Vapor 321 10.5 Conclusions 326 Questions for Discussion 326 Problems 327 Further Reading 331 11 Mass Transfer in Biology and Medicine 332 11.1 Mass Transfer Coefficients 333 11.2 Artificial Lungs and Artificial Kidneys 339 11.3 Pharmocokinetics 347 11.4 Conclusions 350 Questions for Discussion 351 Problems 351 Further Reading 352 12 Differential Distillation 353 12.1 Overview of Distillation 353 12.2 Very Pure Products 356 12.3 The Column's Feed and its Location 362 12.4 Concentrated Differential Distillation 366 12.5 Conclusions 371 Questions for Discussion 371 Problems 372 Further Reading 374 Contents 13 Staged Distillation 375 13.1 Staged Distillation Equipment 376 13.2 Staged Distillation of Nearly Pure Products 379 13.3 Concentrated Staged Distillation 385 13.4 Stage Efficiencies 393 13.5 Conclusions 400 Questions for Discussion 400 Problems 401 Further Reading 403 14 Extraction 404 14.1 The Basic Problem 404 14.2 Extraction Equipment 407 14.3 Differential Extraction 409 14.4 Staged Extraction 413 14.5 Leaching 416 14.6 Conclusions 420 Questions for Discussion 420 Problems 421 Further Reading 423 /5 Adsorption 424 15.1 Where Adsorption is Important 425 15.2 Adsorbents and Adsorption Isotherms 427 15.3 Breakthrough Curves 431 15.4 Mass Transfer Effects 439 15.5 Other Characteristics of Adsorption 443 15.6 Conclusions 450 Questions for Discussion 450 Problems 450 Further Reading 452 PART IV Diffusion Coupled With Other Processes 16 General Questions and Heterogeneous Chemical Reactions 455 16.1 Is the Reaction Heterogeneous or Homogeneous? 456 16.2 What is a Diffusion-Controlled Reaction? 457 16.3 Diffusion and First-Order Heterogeneous Reactions 459 16.4 Finding the Mechanism of Irreversible Heterogeneous Reactions 465 16.5 Heterogeneous Reactions of Unusual Stoichiometries 469 16.6 Conclusions 473 Questions for Discussion 473 Problems 474 Further Reading 477 Contents xi 17 Homogeneous Chemical Reactions 478 17.1 Mass Transfer with First-Order Chemical Reactions 479 17.2 Mass Transfer with Second-Order Chemical Reactions 488 17.3 Industrial Gas Treating 492 17.4 Diffusion-Controlled Fast Reactions 500 17.5 Dispersion-Controlled Fast Reactions 504 17.6 Conclusions 507 Questions f or Discussion 508 Problems 508 Further Reading 512 18 Membranes 513 18.1 Physical Factors in Membranes 514 18.2 Gas Separations 520 18.3 Reverse Osmosis and Ultrafiltration 526 18.4 Pervaporation 534 18.5 Facilitated Diffusion 539 18.5 Conclusions 545 Questions for Discussion 545 Problems 546 Further Reading 548 19 Controlled Release and Related Phenomena 549 19.1 Controlled Release by Solute Diffusion 551 19.2 Controlled Release by Solvent Diffusion 555 19.3 Barriers 558 19.4 Diffusion and Phase Equilibrium 562 19.5 Conclusions 565 Questions for Discussion 565 Problems 566 Further Reading 566 20 Heat Transfer 568 20.1 Fundamentals of Heat Conduction 568 20.2 General Energy Balances 575 20.3 Heat Transfer Coefficients 579 20.4 Rate Constants for Heat Transfer 585 20.5 Conclusions 591 Questions for Discussion 591 Problems 591 Further Reading 593 21 Simultaneous Heat and Mass Transfer 594 21.1 Mathematical Analogies Among Mass, Heat, and Momentum Transfer 594 21.2 Physical Equalities Among Mass, Heat, and Momentum Transfer 600 xii Contents 21.3 Drying 604 21.4 Design of Cooling Towers 609 21.5 Thermal Diffusion and Effusion 615 21.6 Conclusions 621 Questions for Discussion 621 Problems 622 Further Reading 624 Index 626
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spelling	Cussler, E. L. 1940- Verfasser (DE-588)131662139 aut Diffusion mass transfer in fluid systems E. L. Cussler Diffusion 3. ed. Cambridge [u.a.] Cambridge Univ. Press 2009 XXII, 631 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Mass transfer Fluids Diffusion (Physique) Fluides Transfert de masse Flüssigkeit (DE-588)4017621-6 gnd rswk-swf Diffusion (DE-588)4012277-3 gnd rswk-swf Stoffübertragung (DE-588)4057696-6 gnd rswk-swf (DE-588)4173536-5 Patentschrift gnd-content Flüssigkeit (DE-588)4017621-6 s Stoffübertragung (DE-588)4057696-6 s DE-604 Diffusion (DE-588)4012277-3 s http://www.loc.gov/catdir/enhancements/fy0834/2008018927-b.html Contributor biographical information lizenzfrei http://www.loc.gov/catdir/enhancements/fy0834/2008018927-d.html Publisher description lizenzfrei http://www.loc.gov/catdir/enhancements/fy0834/2008018927-t.html lizenzfrei Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016489552&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Cussler, E. L. 1940- Diffusion mass transfer in fluid systems Diffusion Mass transfer Fluids Diffusion (Physique) Fluides Transfert de masse Flüssigkeit (DE-588)4017621-6 gnd Diffusion (DE-588)4012277-3 gnd Stoffübertragung (DE-588)4057696-6 gnd
subject_GND	(DE-588)4017621-6 (DE-588)4012277-3 (DE-588)4057696-6 (DE-588)4173536-5
title	Diffusion mass transfer in fluid systems
title_alt	Diffusion
title_auth	Diffusion mass transfer in fluid systems
title_exact_search	Diffusion mass transfer in fluid systems
title_exact_search_txtP	Diffusion mass transfer in fluid systems
title_full	Diffusion mass transfer in fluid systems E. L. Cussler
title_fullStr	Diffusion mass transfer in fluid systems E. L. Cussler
title_full_unstemmed	Diffusion mass transfer in fluid systems E. L. Cussler
title_short	Diffusion mass transfer in fluid systems
title_sort	diffusion mass transfer in fluid systems
topic	Diffusion Mass transfer Fluids Diffusion (Physique) Fluides Transfert de masse Flüssigkeit (DE-588)4017621-6 gnd Diffusion (DE-588)4012277-3 gnd Stoffübertragung (DE-588)4057696-6 gnd
topic_facet	Diffusion Mass transfer Fluids Diffusion (Physique) Fluides Transfert de masse Flüssigkeit Stoffübertragung Patentschrift
url	http://www.loc.gov/catdir/enhancements/fy0834/2008018927-b.html http://www.loc.gov/catdir/enhancements/fy0834/2008018927-d.html http://www.loc.gov/catdir/enhancements/fy0834/2008018927-t.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016489552&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA
work_keys_str_mv	AT cusslerel diffusionmasstransferinfluidsystems AT cusslerel diffusion

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