Rheology for chemists: an introduction
Gespeichert in:
Hauptverfasser: | , |
---|---|
Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Cambridge, UK
RSC Publ.
2008
|
Ausgabe: | 2. ed. |
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XI, 264 S. graph. Darst. |
ISBN: | 9780854048397 |
Internformat
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020 | |a 9780854048397 |c (hardcover) |9 978-0-85404-839-7 | ||
035 | |a (OCoLC)195753079 | ||
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100 | 1 | |a Goodwin, James W. |e Verfasser |0 (DE-588)124334164 |4 aut | |
245 | 1 | 0 | |a Rheology for chemists |b an introduction |c Jim W Goodwin ; Roy W Hughes |
250 | |a 2. ed. | ||
264 | 1 | |a Cambridge, UK |b RSC Publ. |c 2008 | |
300 | |a XI, 264 S. |b graph. Darst. | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
650 | 7 | |a Rhéologie |2 ram | |
650 | 4 | |a Rheology | |
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700 | 1 | |a Hughes, Roy W. |e Verfasser |4 aut | |
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Datensatz im Suchindex
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adam_text |
Contents
Chapter
1
Introduction
1.1
Definitions
2
1.1.1
Stress and Strain
2
1.1.2
Rate of Strain and Flow
4
1.2
Simple Constitutive Equations
5
1.2.1
Linear and Nonlinear Behaviour
5
1.2.2
Using Constitutive Equations
6
1.3
Dimensionless Groups
6
1.3.1
The Deborah Number
7
1.3.2
The
Péclet
Number
8
1.3.3
The Reduced Stress
9
1.3.4
The Taylor Number
10
1.3.5
The Reynolds Number
11
1.4
Macromolecular and Colloidal Systems
12
References
13
Chapter
2
Elasticity: High Deborah Number Measurements
2.1
Introduction
14
2.2
The Liquid-Solid Transition
16
2.2.1
Bulk Elasticity
18
2.2.2
Wave Propagation
19
2.3
Crystalline Solids at Large Strains
22
2.3.1
Lattice Defects
23
2.4
Macromolecular Solids
25
2.4.1
Polymers
-
An Introduction
26
2.4.2
Chain Conformation
26
2.4.3
Polymer Crystallinity
31
2.4.4
Crosslinked Elastomers
34
2.4.5
Self-associating Polymers
36
2.4.6
Noninteractive Fillers
40
Contents ix
2.4.7 Interactive
Fillers
42
2.4.8
Summary of Polymeric Systems
44
2.5
Colloidal Gels
44
2.5.1
Interactions Between Colloidal Particles
44
2.5.2
London-van
der Waals'
Interactions
45
2.5.3
Depletion Interactions
46
2.5.4
Electrostatic Repulsion
47
2.5.5
Steric Repulsion
48
2.5.6
Electrosteric Interactions
50
References
52
Chapter
3
Viscosity: Low Deborah Number Measurements
3.1
Initial Considerations
55
3.2
Viscometric Measurement
58
3.2.1
The Cone and Plate
59
3.2.2
The
Couette
or Concentric Cylinder
60
3.3
The Molecular Origins of Viscosity
63
3.3.1
Flow of Gases
63
3.3.2
The Flow of Liquids
64
3.3.3
Density and Phase Changes
65
3.3.4
Free-volume Model of Liquid Flow
67
3.3.5
Activation-energy Models
70
3.4
Superfluids
71
3.5
Macromolecular Fluids
72
3.5.1
Colloidal Dispersions
72
3.5.2
Dilute Dispersions of Spheres
72
3.5.3
Concentrated Dispersions of Spheres
75
3.5.4
Shear-thickening Behaviour in Dense
Suspensions
80
3.5.5
Charge-stabilised Dispersions
81
3.5.6
Dilute Polymer Solutions
87
3.5.7
Surfactant Solutions
89
Reft
îrences
90
Chapter
4
Linear Viscoelasticity I: Phenomenological Approach
4.1
Viscoelasticity
92
4.2
Length and Timescales
93
4.3
Mechanical Spectroscopy
94
4.4
Linear Viscoelasticity
95
4.4.1
Mechanical Analogues
96
4.4.2
Relaxation Derived as an Analogue
to lst-order Chemical Kinetics
98
Contents
4.4.3
Oscillation
Response
100
4.4.4
Multiple
Processes
104
4.4.5
A Spectral
Approach to Linear Viscoelastic
Theory
108
4.5
Linear Viscoelastic Experiments 111
4.5.1
Relaxation
113
4.5.2
Stress Growth
115
4.5.3
Antithixotropic Response
116
4.5.4
Creep and Recovery
117
4.5.5
Strain Oscillation
119
4.5.6
Stress Oscillation
121
4.6
Interrelationships Between the Measurements
and the Spectra
122
4.6.1
The Relationship Between Compliance
and Modulus
123
4.6.2
Retardation and Relaxation Spectrum
125
4.6.3
The Relaxation Function and the Storage
and Loss Modulus
126
4.6.4
Creep and Relaxation Interrelations
126
4.7
Applications to the Models
127
4.8
Microstructural
Influences on the Kernel
130
4.8.1
The Extended Exponential
130
4.8.2
Power Law or the Gel Equation
131
4.8.3
Exact Inversions from the Relaxation
or Retardation Spectrum
132
4.9
Nonshearing Fields and Extension
132
References
134
Chapter
5
Linear Viscoelasticity II:
Microstructural
Approach
5.1
Intermediate Deborah Numbers De
« 1 135
5.2
Hard Spheres and Atomic Fluids
136
5.3
Quasihard-sphere Dispersions
137
5.3.1
Quasihard-sphere Phase Diagrams
138
5.3.2
Quasihard-sphere Viscoelasticity
and Viscosity
142
5.4
Weakly Attractive Systems
147
5.5
Charge-repulsion Systems
155
5.6
Simple Homopolymer Systems
165
5.6.1
Phase Behaviour and the Chain Overlap
in Good Solvents
165
5.6.2
Dilute Solution Polymers
172
5.6.3
Undiluted and Concentrated Nonentangled
Polymers
175
Contents xi
5.6.4
Entanglement Coupling
176
5.6.5
Reptation
and Linear Viscoelasticity
178
5.7
Polymer Network Structures
184
5.7.1
The Formation of Gels
184
5.7.2
Chemical Networks
186
5.7.3
Physical Networks
187
References
192
Chapter
6
Nonlinear Responses
6.1
Introduction
194
6.2
The Phenomenological Approach
195
6.2.1
Flow Curves: Definitions and Equations
195
6.2.2
Time Dependence in Flow and the Boltzmann
Superposition Principle
198
6.2.3
Yield Stress Sedimentation, and Linearity
204
6.3
The
Microstructural
Approach
-
Particles
208
6.3.1
Flow in Hard-sphere Systems
208
6.3.2
The Addition of a Surface Layer
211
6.3.3
Aggregation and Dispersion in Shear
212
6.3.4
Weakly Flocculated Dispersions
215
6.3.5
Strongly Aggregated and Coagulated Systems
221
6.3.6
Long-range Repulsive Systems
226
6.3.7
Rod-like Particles
230
6.4
The
Microstructural
Approach
-
Polymers
235
6.4.1
The Role of Entanglements in Nonlinear
Viscoelasticity
235
6.4.2
Entanglement of Solution Homopolymers
238
6.4.3
The
Reptation
Approach
239
6.5
Novel Applications
245
6.5.1
Extension and Complex Flows
245
6.5.2
Uniaxial
Compression Modulus
249
6.5.3
Deformabile
Particles
252
References
256
Subject Index
258 |
adam_txt |
Contents
Chapter
1
Introduction
1.1
Definitions
2
1.1.1
Stress and Strain
2
1.1.2
Rate of Strain and Flow
4
1.2
Simple Constitutive Equations
5
1.2.1
Linear and Nonlinear Behaviour
5
1.2.2
Using Constitutive Equations
6
1.3
Dimensionless Groups
6
1.3.1
The Deborah Number
7
1.3.2
The
Péclet
Number
8
1.3.3
The Reduced Stress
9
1.3.4
The Taylor Number
10
1.3.5
The Reynolds Number
11
1.4
Macromolecular and Colloidal Systems
12
References
13
Chapter
2
Elasticity: High Deborah Number Measurements
2.1
Introduction
14
2.2
The Liquid-Solid Transition
16
2.2.1
Bulk Elasticity
18
2.2.2
Wave Propagation
19
2.3
Crystalline Solids at Large Strains
22
2.3.1
Lattice Defects
23
2.4
Macromolecular Solids
25
2.4.1
Polymers
-
An Introduction
26
2.4.2
Chain Conformation
26
2.4.3
Polymer Crystallinity
31
2.4.4
Crosslinked Elastomers
34
2.4.5
Self-associating Polymers
36
2.4.6
Noninteractive Fillers
40
Contents ix
2.4.7 Interactive
Fillers
42
2.4.8
Summary of Polymeric Systems
44
2.5
Colloidal Gels
44
2.5.1
Interactions Between Colloidal Particles
44
2.5.2
London-van
der Waals'
Interactions
45
2.5.3
Depletion Interactions
46
2.5.4
Electrostatic Repulsion
47
2.5.5
Steric Repulsion
48
2.5.6
Electrosteric Interactions
50
References
52
Chapter
3
Viscosity: Low Deborah Number Measurements
3.1
Initial Considerations
55
3.2
Viscometric Measurement
58
3.2.1
The Cone and Plate
59
3.2.2
The
Couette
or Concentric Cylinder
60
3.3
The Molecular Origins of Viscosity
63
3.3.1
Flow of Gases
63
3.3.2
The Flow of Liquids
64
3.3.3
Density and Phase Changes
65
3.3.4
Free-volume Model of Liquid Flow
67
3.3.5
Activation-energy Models
70
3.4
Superfluids
71
3.5
Macromolecular Fluids
72
3.5.1
Colloidal Dispersions
72
3.5.2
Dilute Dispersions of Spheres
72
3.5.3
Concentrated Dispersions of Spheres
75
3.5.4
Shear-thickening Behaviour in Dense
Suspensions
80
3.5.5
Charge-stabilised Dispersions
81
3.5.6
Dilute Polymer Solutions
87
3.5.7
Surfactant Solutions
89
Reft
îrences
90
Chapter
4
Linear Viscoelasticity I: Phenomenological Approach
4.1
Viscoelasticity
92
4.2
Length and Timescales
93
4.3
Mechanical Spectroscopy
94
4.4
Linear Viscoelasticity
95
4.4.1
Mechanical Analogues
96
4.4.2
Relaxation Derived as an Analogue
to lst-order Chemical Kinetics
98
Contents
4.4.3
Oscillation
Response
100
4.4.4
Multiple
Processes
104
4.4.5
A Spectral
Approach to Linear Viscoelastic
Theory
108
4.5
Linear Viscoelastic Experiments 111
4.5.1
Relaxation
113
4.5.2
Stress Growth
115
4.5.3
Antithixotropic Response
116
4.5.4
Creep and Recovery
117
4.5.5
Strain Oscillation
119
4.5.6
Stress Oscillation
121
4.6
Interrelationships Between the Measurements
and the Spectra
122
4.6.1
The Relationship Between Compliance
and Modulus
123
4.6.2
Retardation and Relaxation Spectrum
125
4.6.3
The Relaxation Function and the Storage
and Loss Modulus
126
4.6.4
Creep and Relaxation Interrelations
126
4.7
Applications to the Models
127
4.8
Microstructural
Influences on the Kernel
130
4.8.1
The Extended Exponential
130
4.8.2
Power Law or the Gel Equation
131
4.8.3
Exact Inversions from the Relaxation
or Retardation Spectrum
132
4.9
Nonshearing Fields and Extension
132
References
134
Chapter
5
Linear Viscoelasticity II:
Microstructural
Approach
5.1
Intermediate Deborah Numbers De
« 1 135
5.2
Hard Spheres and Atomic Fluids
136
5.3
Quasihard-sphere Dispersions
137
5.3.1
Quasihard-sphere Phase Diagrams
138
5.3.2
Quasihard-sphere Viscoelasticity
and Viscosity
142
5.4
Weakly Attractive Systems
147
5.5
Charge-repulsion Systems
155
5.6
Simple Homopolymer Systems
165
5.6.1
Phase Behaviour and the Chain Overlap
in Good Solvents
165
5.6.2
Dilute Solution Polymers
172
5.6.3
Undiluted and Concentrated Nonentangled
Polymers
175
Contents xi
5.6.4
Entanglement Coupling
176
5.6.5
Reptation
and Linear Viscoelasticity
178
5.7
Polymer Network Structures
184
5.7.1
The Formation of Gels
184
5.7.2
Chemical Networks
186
5.7.3
Physical Networks
187
References
192
Chapter
6
Nonlinear Responses
6.1
Introduction
194
6.2
The Phenomenological Approach
195
6.2.1
Flow Curves: Definitions and Equations
195
6.2.2
Time Dependence in Flow and the Boltzmann
Superposition Principle
198
6.2.3
Yield Stress Sedimentation, and Linearity
204
6.3
The
Microstructural
Approach
-
Particles
208
6.3.1
Flow in Hard-sphere Systems
208
6.3.2
The Addition of a Surface Layer
211
6.3.3
Aggregation and Dispersion in Shear
212
6.3.4
Weakly Flocculated Dispersions
215
6.3.5
Strongly Aggregated and Coagulated Systems
221
6.3.6
Long-range Repulsive Systems
226
6.3.7
Rod-like Particles
230
6.4
The
Microstructural
Approach
-
Polymers
235
6.4.1
The Role of Entanglements in Nonlinear
Viscoelasticity
235
6.4.2
Entanglement of Solution Homopolymers
238
6.4.3
The
Reptation
Approach
239
6.5
Novel Applications
245
6.5.1
Extension and Complex Flows
245
6.5.2
Uniaxial
Compression Modulus
249
6.5.3
Deformabile
Particles
252
References
256
Subject Index
258 |
any_adam_object | 1 |
any_adam_object_boolean | 1 |
author | Goodwin, James W. Hughes, Roy W. |
author_GND | (DE-588)124334164 |
author_facet | Goodwin, James W. Hughes, Roy W. |
author_role | aut aut |
author_sort | Goodwin, James W. |
author_variant | j w g jw jwg r w h rw rwh |
building | Verbundindex |
bvnumber | BV023280179 |
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callnumber-search | QC189.5 TP156.R45 |
callnumber-sort | QC 3189.5 |
callnumber-subject | QC - Physics |
classification_rvk | UF 3500 VE 5900 VE 5901 |
classification_tum | CHE 180f CHE 712f CHE 216f CHE 710f |
ctrlnum | (OCoLC)195753079 (DE-599)GBV556494091 |
dewey-full | 531/.1134 |
dewey-hundreds | 500 - Natural sciences and mathematics |
dewey-ones | 531 - Classical mechanics |
dewey-raw | 531/.1134 |
dewey-search | 531/.1134 |
dewey-sort | 3531 41134 |
dewey-tens | 530 - Physics |
discipline | Chemie / Pharmazie Physik Chemie |
discipline_str_mv | Chemie / Pharmazie Physik Chemie |
edition | 2. ed. |
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id | DE-604.BV023280179 |
illustrated | Illustrated |
index_date | 2024-07-02T20:39:29Z |
indexdate | 2024-12-11T13:03:13Z |
institution | BVB |
isbn | 9780854048397 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016464996 |
oclc_num | 195753079 |
open_access_boolean | |
owner | DE-703 DE-29T DE-91G DE-BY-TUM DE-11 DE-92 |
owner_facet | DE-703 DE-29T DE-91G DE-BY-TUM DE-11 DE-92 |
physical | XI, 264 S. graph. Darst. |
publishDate | 2008 |
publishDateSearch | 2008 |
publishDateSort | 2008 |
publisher | RSC Publ. |
record_format | marc |
spelling | Goodwin, James W. Verfasser (DE-588)124334164 aut Rheology for chemists an introduction Jim W Goodwin ; Roy W Hughes 2. ed. Cambridge, UK RSC Publ. 2008 XI, 264 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Rhéologie ram Rheology Rheologie (DE-588)4049828-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Kolloid (DE-588)4164695-2 gnd rswk-swf Rheologie (DE-588)4049828-1 s Polymere (DE-588)4046699-1 s DE-604 Kolloid (DE-588)4164695-2 s Hughes, Roy W. Verfasser aut Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016464996&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Goodwin, James W. Hughes, Roy W. Rheology for chemists an introduction Rhéologie ram Rheology Rheologie (DE-588)4049828-1 gnd Polymere (DE-588)4046699-1 gnd Kolloid (DE-588)4164695-2 gnd |
subject_GND | (DE-588)4049828-1 (DE-588)4046699-1 (DE-588)4164695-2 |
title | Rheology for chemists an introduction |
title_auth | Rheology for chemists an introduction |
title_exact_search | Rheology for chemists an introduction |
title_exact_search_txtP | Rheology for chemists an introduction |
title_full | Rheology for chemists an introduction Jim W Goodwin ; Roy W Hughes |
title_fullStr | Rheology for chemists an introduction Jim W Goodwin ; Roy W Hughes |
title_full_unstemmed | Rheology for chemists an introduction Jim W Goodwin ; Roy W Hughes |
title_short | Rheology for chemists |
title_sort | rheology for chemists an introduction |
title_sub | an introduction |
topic | Rhéologie ram Rheology Rheologie (DE-588)4049828-1 gnd Polymere (DE-588)4046699-1 gnd Kolloid (DE-588)4164695-2 gnd |
topic_facet | Rhéologie Rheology Rheologie Polymere Kolloid |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016464996&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT goodwinjamesw rheologyforchemistsanintroduction AT hughesroyw rheologyforchemistsanintroduction |