Contaminant geochemistry: interactions and transport in the subsurface environment
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer Berlin
2008
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Inhaltsverzeichnis |
| Beschreibung: | XIII, 412 S. Ill., graph. Darst. 235 mm x 155 mm |
| ISBN: | 9783540743811 |
Internformat
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| 100 | 1 | |a Berkowitz, Brian |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Contaminant geochemistry |b interactions and transport in the subsurface environment |c Brian Berkowitz ; Ishai Dror ; Bruno Yaron |
| 264 | 1 | |a Berlin [u.a.] |b Springer Berlin |c 2008 | |
| 300 | |a XIII, 412 S. |b Ill., graph. Darst. |c 235 mm x 155 mm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Geochemistry | |
| 650 | 4 | |a Groundwater flow | |
| 650 | 4 | |a Groundwater |x Pollution | |
| 650 | 4 | |a Hydrogeology | |
| 650 | 4 | |a Pollutants | |
| 650 | 4 | |a Water chemistry | |
| 650 | 0 | 7 | |a Umweltgeochemie |0 (DE-588)4404136-6 |2 gnd |9 rswk-swf |
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| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Dror, Ishai |e Verfasser |4 aut | |
| 700 | 1 | |a Yaron, Bruno |d 1929- |e Verfasser |0 (DE-588)107957523 |4 aut | |
| 856 | 4 | |u http://d-nb.info/987388878/04 |3 Inhaltsverzeichnis | |
| 856 | 4 | 2 | |m GBV Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016444126&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-016444126 | ||
Datensatz im Suchindex
| _version_ | 1804137566499241984 |
|---|---|
| adam_text | BRIAN BERKOWITZ * ISHAI DROR * BRUNO YARON CONTAMINANT GEOCHEMISTRY*
INTERACTIONS AND TRANSPORT IN THE SUBSURFACE ENVIRONMENT ~ SPRINGER*
CONTENTS* PART I CHAPTER 1 CHAPTER 2 GEOCHEMISTRY REVISITED: SELECTED
ASPECTS CHARACTERIZATION OF THE SUBSURFACE ENVIRONMENT. . . . . . . . .
. 3 1.1 SUBSURFACE SOLID PHASE. . . . . . . . . . . . . . . . . . . . .
. . . . . . . 4* 1.1.1* SILICA MINERALS . . . . . . . . .. . . . . . . .
. . . . . . . . . . . 4* 1.1.2* CJAY MINERALS. . . . . . . . . . . . . .
. . . . . . . . . . . . . . . 6* 1.1.3* MINERALS OTHER THAN SILICA AND
CLAY . . . . . . . . . .. 12 1.1.4* ORGANIC MATTER . . . . . . . . . . .
. . . . . . . . . . . . . . . .. 14* 1.1.5* ELECTRICALLY CHARGED
SURFACES. . . . . . . . . . . . . . . .. 17 1.2 SUBSURFACE LIQUID PHASE.
. . . . . . . . . . . . . . . . . . . . . . . . .. 18* 1.2.1* NEAR SOLID
PHASE WATER. . . . . . . . . . . . . . . . . . . . .. 19* 1.2.2*
SUBSURFACE AQUEOUS SOLUTIONS . . . . . . . . . . . . . . .. 21* 1.3
SUBSURFACE GASEOUS PHASE. . . . . . . . . . . . . . . . . . . . . . . ..
22* 1.4 AQUIFERS........................................ 23* 1.4.1*
AQUIFER STRUCTURE. . . . . . . . . . . . . . . . . . . . . . . . . ..
23* 1.4.2* GROUNDWATER COMPOSITION . . . . . . . . . . . . . . . . . ..
25* SELECTED GEOCHEMICAL PROCESSES . . . . . . . . . . . . . . . . . . .
. . . .. 27* 2.1 THERMODYNAMICS AND EQUILIBRIUM . . . . . . . . . . . .
. . . . . .. 27* 2.1.1* ENTHALPY, ENTROPY, AND THE LAWS OFTHERMODYNAMICS
. . . . . . . . . . . . . . . . . . . . . . .. 27 2.1.2*
EQUILIBRIUM............................... 29* 2.1.3* SOLUBILITY,
CHEMICAL POTENTIAL, AND ION ACTIVITIES . . . . . . . . . . . . . . . . .
. . . . . . . .. 30 2.1.4* KINETIC CONSIDERATIONS AND REACTION RATE LAWS
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 33 2.2
WEATHERING...................................... 37* 2.2.1* DISSOLUTION
AND PRECIPITATION . . . . . . . . . . . . . . . .. 38* 2.2.2* REDOX
PROCESSES . . . . . . . . . . . . . . . . . . . . . . . . . .. 40* X
CONTENTS 2.3 ADSORPTION...................................... 44* 2.3.1*
ADSORPTION OF CHARGED IONIC COMPOUNDS . . . . . .. 44* 2.3.2* ADSORPTION
OF NONIONIC COMPOUNDS . . . . . . . . . .. 46* 2.3.3* KINETIC
CONSIDERATIONS . . . . . . . . . . . . . . . . . . . . .. 47* PART 11*
PROPERTIES OF POTENTIAL CONTAMINANTS: ENVIRONMENTAL AND HEALTH HAZARDS
CHAPTER 3 INORGANIC AND ORGANOMETALLIC COMPOUNDS. . . . . . . . . . . .
. .. 51* 3.1 NITROGEN........................................ 51* 3.2
PHOSPHORUS..................................... 53* 3.3
SA1TS........................................... 55* 3.3.1* AGRICULTURAJ
IMPACTS........................ 55* 3.3.2* IMPACTS ON WATER USAGE. . . .
. . . . . . . . . . . . . . . .. 57* 3.3.3* IMPACTS ON INFRASTTUCTURE .
. . . . . . . . . . . . . . . . . .. 58* 3.3.4* IMPACTS ON BIODIVERSITY*
AND THE ENVIRONMENT. . . . . . . . . . . . . . . . . . . . . . .. 58*
3.4 RADIONUCLIDES..................... . . . . . . . . . . . . .. 59*
3.5 HEAVY METALS AND METALLOIDS. . . . . . . . . . . . . . . . . . . . .
.. 61* 3.5.1* ARSENIC 61* 3.5.2*
CADMIUM................................. 63* 3.5.3*
CHROMIUM................................ 64* 3.5.4*
LEAD..................................... 65* 3.5.5*
NICKEL................................... 66* 3.6 NANOMATERIALS . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 67* CHAPTER
4 ORGANIC COMPOUNDS . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . .. 71* 4.1 PESTICIDES.......................................
71* 4.1.1* ORGANOCHLORINE INSECTICIDES . . . . . . . . . . . . . . . .
.. 73* 4.1.2* ORGANOPHOSPHATES.......................... 75* 4.1.3*
N-METHYL CARBAMATE. . . . . . . . . . . . . . . . . . . . . . .. 75*
4.1.4* TRIAZINES................................. 76* 4.1.5* PARAQUAT
AND DIQUAT . . . . . . . . . . . . . . . . . . . . . . .. 77* 4.2
SYNTHETIC HALOGENATED ORGANIC SUBSTANCES . . . . . . . . . . .. 78*
4.2.1* CHLORINATED HYDROCARBONS . . . . . . . . . . . . . . . . . .. 78*
4.2.2* BROMINATED FLAME RETARDANTS. . . . . . . . . . . . . . . .. 81*
4.3 PETROLEUM HYDROCARBONS AND FUEL ADDITIVES. . . . . . . . . .. 83*
4.4 PHARMACEUTICALS AND PERSONAL CARE PRODUCTS . . . . . . . . . .. 86*
4.4.1* ANALGESICS AND ANTIINFLAMMATORY DRUGS . . . . . . .. 88* 4.4.2*
HORMONES................................ 88* 4.4.3* ANTIBACTERIAJ DRUGS.
. . . . . . . . . . . . . . . . . . . . . . .. 89* 4.4.4* ANTIEPILEPTIC
DRUGS. . . . . . . . . . . . . . . . . . . . . . . .. 90* 4.4.5*
BETA-BLOCKERS.......................... . .. 90* CONTENTS PART III*
CHAPTER 5* CHAPTER 6* CHAPTER 7* CHAPTER 8* XI CONTAMINANT PARTITIONING
IN THE SUBSURFACE SORPTION, RETENTION, AND RELEASE* OF CONTAMINANTS . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 93*
5.1 SURFACE PROPERTIES OF ADSORBENTS . . . . . . . . . . . . . . . . . .
.. 93* 5.2 QUANTIFYING ADSORPTION. . . . . . . . . . . . . . . . . . . .
. . . . . . .. 95* 5.2.1 ADSORPTION-DESORPTION COEFFICIENTS. . . . . . .
. . . .. 95* 5.2.2 ADSORPTION ISOTHENNS . . . . . . . . . . . . . . . .
. . . . . .. 95* 5.3 KINETICS OF ADSORPTION. . . . . . . . . . . . . . .
. . . . . . . . . . . .. 101* 5.4 ADSORPTION OF IONIC CONTAMINANTS . . .
. . . . . . . . . . . . . . .. 104* 5.5 ADSORPTION OF NONIONIC
CONTAMINANTS 109* 5.6 OTHER FACTORS AFFECTING ADSORPTION 112* 5.7
NONADSORPTIVE RETENTION OF CONTAMINANTS . . . . . . . . . . . .. 114*
5.7.1 CONTAMINANT PRECIPITATION. . . . . . . . . . . . . . . . . . ..
115* 5.7.2 LIQUID TRAPPING. . . . . . . . . . . . . . . . . . . . . . .
. . . .. 116* 5.7.3 PARTICLE DEPOSITION AND TRAPPING 118* 5.8 REVERSIBLE
AND IRREVERSIBLE RETENTION 120* 5.8.1 GENUINE HYSTERESIS. . . . . . . .
. . . . . . . . . . . . . . . .. 120* 5.8.2 APPARENT HYSTERESIS . . . .
. . . . . . . . . . . . . . . . . . .. 122* 5.8.3 BOUND RESIDUES 123*
CONTAMINANT PARTITIONING IN THE AQUEOUS PHASE . . . . . . . . .. 127*
6.1 SOLUBILITY EQUILIBRIUM. . . . . . . . . . . . . . . . . . . . . . .
. . . . .. 128* 6.2 AQUEOUS SOLUBILITY OF ORGANIC CONTAMINANTS. . . . .
. . . . .. 130* 6.3 LIGAND EFFECTS . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . .. 131* 6.4 COSOLVENTS AND SURFACTANT
EFFECTS 133* 6.5 SALTING-OUT EFFECT . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . .. 136* 6.6 APPARENT SOLUBILITY . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . .. 139* PARTITIONING OF
VOLATILE COMPOUNDS . . . . . . . . . . . . . . . . . . . .. 143* 7.1
GAS-LIQUID RELATIONSHIPS . . . . . . . . . . . . . . . . . . . . . . . .
.. 144* 7.2 VOLATILIZATION FROM SUBSURFACE AQUEOUS SOLUTIONS 145* 7.3
VAPOR PRESSURE-VOLATILIZATION RELATIONSHIP . . . . . . . . . . .. 148*
7.4 VOLATILIZATION OF MULTICOMPONENT CONTAMINANTS . . . . . . .. 149*
SELECTED RESEARCH FINDINGS:* CONTAMINANT PARTITIONING . . . . . . . . .
. . . . . . . . . . . . . . . . . . .. 151* 8.1 PARTITIONING AMONG
PHASES . . . . . . . . . . . . . . . . . . . . . . . .. 151* 8.2
CONTAMINANT VOLATILIZATION . . . . . . . . . . . . . . . . . . . . . . .
.. 153* 8.2.1 INORGANIC CONTAMINANTS . . . . . . . . . . . . . . . . . .
. .. 154* 8.2.2 ORGANIC CONTAMINANTS. . . . . . . . . . . . . . . . . .
. . . .. 156* 8.2.3 MIXTURES OF ORGANIE CONTAMINANTS. . . . . . . . . .
. .. 160* XII* CONTENTS 8.3 SOLUBILITY AND DISSOLUTION* 165 8.3.1*
ACIDITY AND ALKALINITY EFFECTS 165 8.3.2* REDOX PROCESSES . . . . . . .
. . . . . . . . . . . . . . . .. 167* 8.3.3* DISSOLUTION FROM MIXTURES
OF ORGANIC CONTAMINANTS. . . . . . . . . . . . . . . . .. 169 8.3.4*
APPARENT SOLUBILITY . . . . . . . . . . . . . . . . . . . . .. 169* 8.4*
CONTAMINANT RETENTION IN THE SUBSURFACE. . . . . . . . . . .. 178 8.4.1*
CONTAMINANT ADSORPTION. . . . . . . . . . . . . . . . .. 179* 8.4.2*
NONADSORPTIVE RETENTION. . . . . . . . . . . . . . . . .. 196* 8.5*
CONTAMINANT RELEASE 201 8.6* BOUND RESIDUES. . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . .. 206* PART IV CONTAMINANT TRANSPORT FROM
LAND SURFACE TO GROUNDWATER CHAPTER 9 WATER FLOW IN THE SUBSURFACE
ENVIRONMENT . . . . . . . . . . . .. 213 9.1* WATER FLOW IN SOILS AND
THE VADOSE ZONE 213 9.2* FLOW THROUGH THE CAPILLARY FRINGE 216 CHAPTER
10 TRANSPORT OF PASSIVE CONTAMINANTS* 219 10.1* ADVECTION, DISPERSION,
AND MOLECULAR DIFFUSION. . . . .. 220 10.2* PREFERENTIAL TRANSPORT . . .
. . . . . . . . . . . . . . . . . . . . . . .. 223* 10.3* NON-FICKIAN
TRANSPORT 225 CHAPTER 11 TRANSPORT OF REACTIVE CONTAMINANTS* 231 11.1*
CONTAMINANT SORPTION. . . . . . . . . . . . . . . . . . . . . . . . . ..
231* 11.2* COLLOIDS AND SORPTION ON COLLOIDS 233 11.3* DISSOLVING AND
PRECIPITATING CONTAMINANTS , 234 11.4* TRANSPORT OF IMMISCIBLE LIQUIDS
237 11.5* TRANSPORT OF CONTAMINANTS BY RUNOFF . . . . . . . . . . . . .
.. 242 CHAPTER 12 SELECTED RESEARCH FINDINGS: CONTAMINANT TRANSPORT . .
. .. 247 12.1* AQUEOUS TRANSPORT OF REACTIVE CONTAMINANTS: FIELD AND
LABORATORY STUDIES 247 12.1.1* FIELD EXPERIMENT RESULTS , 247 12.1.2*
MODELING FIELD EXPERIMENTS 252 12.1.3* LABORATORY AND OUTDOOR STUDIES .
. . . . . . . . . .. 256 12.1.4* PREFERENTIAL FLOW . . . . . . . . . . .
. . . . . . . . . . . .. 257* 12.2* TRANSPORT OF NONAQUEOUS PHASE
LIQUIDS. . . . . . . . . . . .. 260 12.2.1* INFILTRATION INTO THE
SUBSURFACE . . . . . . . . . . . .. 260 12.2.2* TRANSPORT OF SOLUBLE
NAPL FRACTIONS IN AQUIFERS. . . . . . . . . . . . . . . . . . . . . . .
. . . . .. 263 12.3* COLIOID-MEDIATED TRANSPORT OF CONTAMINANTS 264
12.3.1* SURFACE RUNOFF. . . . . . . . . . . . . . . . . . . . . . . . ..
265* 12.3.2* TRANSPORT IN THE SUBSURFACE. . . . . . . . . . . . . . ..
266* CONLENTS* XIII PART V TRANSFORMATIONS AND REACTIONS OF
CONTAMINANTS* IN THE SUBSURFACE* CHAPTER 13* CHAPTER 14* CHAPTER 15*
CHAPTER 16* ABIOTIC CONTAMINANT TRANSFORMATIONS* IN SUBSURFACE WATER . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 273* 13.1*
ABIOTIC CONTAMINANT TRANSFORMATIONS* IN NATURAL SUBSURFACE WATER . . . .
. . . . . . . . . . . . . . . . .. 273* 13.1.1* FACTORS AFFECTING
CONTAMINANT* TRANSFORMATIONS 273* 13.1.2* REACTIONS IN NATURAL WATERS
275* 13.2* SELECTED CONTARNINANT TRANSFORMATIONS* IN SEDIMENTS AND
GROUNDWATER . . . . . . . . . . . . . . . . . . .. 286* 13.2.1* PH AND
HYDROLYSIS REACTIONS 286* 13.2.2* REDOX STATE AND REACTIONS . . . . . .
. . . . . . . . .. 287* ABIOTIC TRANSFORMATION AT THE SOLID-LIQUID
INTERFACE . .... 295* 14.1*
CATALYSIS..................................... 295* 14.2*
SURFACE-INDUCED TRANSFORMATION* OF ORGANIC CONTARNINANTS. . . . . . . .
. . . . . . . . . . . . . . . .. 296* 14.3* SURFACE-INDUCED
INTERACTIONS* OF INORGANIC CONTAMINANTS . . . . . . . . . . . . . . . .
. . . . . .. 301* BIOLOGICALLY MEDIATED TRANSFORMATIONS. . . . . . . . .
. . . . . . .. 303* 15.1* SUBSURFACE MICROBIAL POPULATIONS 303* 15.2*
PROCESSES GOVEMING CONTARNINANT ATTENUATION 303* 15.3* BIOTRANSFORMATION
OF ORGANIC CONTAMINANTS .. . . . . . .. 305* 15.4* BIOTRANSFORMATION
OFINORGANIC CONTAMINANTS 311* SELECTED RESEARCH FINDINGS:*
TRANSFORMATIONS AND REACTIONS. . . . . . . . . . . . . . . . . . . . . .
.. 317* 16.1* ABIOTIC ALTERATION OF CONTARNINANTS . . . . . . . . . . .
. . . .. 317* 16.1.1* TRANSFORMATION IN SUBSURFACE WATER 317* 16.1.2*
SURFACE-INDUCED TRANSFONNATION ON CLAYS . . .. 332* 16.1.3*
PHOTOCHERNICAL REACTIONS 336* 16.1.4* LIGAND EFFECTS . . . . . . . . . .
. . . . . . . . . . . . . . .. 342* 16.1.5* MU1TIP1E-COMPONENT
CONTARNINANT* TRANSFORMATION . . . . . . . . . . . . . . . . . . . . . .
. .. 345* 16.2* BIOMEDIATED TRANSFORMATION OF CONTAMINANTS 357* 16.2.1*
PETROLEUM PRODUCTS . . . . . . . . . . . . . . . . . . . . .. 357*
16.2.2* PESTICIDES 361* REFERENCES. . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 373*
SUBJECT INDEX . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . .. 409*
|
| adam_txt |
BRIAN BERKOWITZ * ISHAI DROR * BRUNO YARON CONTAMINANT GEOCHEMISTRY*
INTERACTIONS AND TRANSPORT IN THE SUBSURFACE ENVIRONMENT ~ SPRINGER*
CONTENTS* PART I CHAPTER 1 CHAPTER 2 GEOCHEMISTRY REVISITED: SELECTED
ASPECTS CHARACTERIZATION OF THE SUBSURFACE ENVIRONMENT. . . . . . . . .
. 3 1.1 SUBSURFACE SOLID PHASE. . . . . . . . . . . . . . . . . . . . .
. . . . . . . 4* 1.1.1* SILICA MINERALS . . . . . . . . . . . . . . . .
. . . . . . . . . . . 4* 1.1.2* CJAY MINERALS. . . . . . . . . . . . . .
. . . . . . . . . . . . . . . 6* 1.1.3* MINERALS OTHER THAN SILICA AND
CLAY . . . . . . . . . . 12 1.1.4* ORGANIC MATTER . . . . . . . . . . .
. . . . . . . . . . . . . . . . 14* 1.1.5* ELECTRICALLY CHARGED
SURFACES. . . . . . . . . . . . . . . . 17 1.2 SUBSURFACE LIQUID PHASE.
. . . . . . . . . . . . . . . . . . . . . . . . . 18* 1.2.1* NEAR SOLID
PHASE WATER. . . . . . . . . . . . . . . . . . . . . 19* 1.2.2*
SUBSURFACE AQUEOUS SOLUTIONS . . . . . . . . . . . . . . . 21* 1.3
SUBSURFACE GASEOUS PHASE. . . . . . . . . . . . . . . . . . . . . . . .
22* 1.4 AQUIFERS. 23* 1.4.1*
AQUIFER STRUCTURE. . . . . . . . . . . . . . . . . . . . . . . . . .
23* 1.4.2* GROUNDWATER COMPOSITION . . . . . . . . . . . . . . . . . .
25* SELECTED GEOCHEMICAL PROCESSES . . . . . . . . . . . . . . . . . . .
. . . . 27* 2.1 THERMODYNAMICS AND EQUILIBRIUM . . . . . . . . . . . .
. . . . . . 27* 2.1.1* ENTHALPY, ENTROPY, AND THE LAWS OFTHERMODYNAMICS
. . . . . . . . . . . . . . . . . . . . . . . 27 2.1.2*
EQUILIBRIUM. 29* 2.1.3* SOLUBILITY,
CHEMICAL POTENTIAL, AND ION ACTIVITIES . . . . . . . . . . . . . . . . .
. . . . . . . . 30 2.1.4* KINETIC CONSIDERATIONS AND REACTION RATE LAWS
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 2.2
WEATHERING. 37* 2.2.1* DISSOLUTION
AND PRECIPITATION . . . . . . . . . . . . . . . . 38* 2.2.2* REDOX
PROCESSES . . . . . . . . . . . . . . . . . . . . . . . . . . 40* X
CONTENTS 2.3 ADSORPTION. 44* 2.3.1*
ADSORPTION OF CHARGED IONIC COMPOUNDS . . . . . . 44* 2.3.2* ADSORPTION
OF NONIONIC COMPOUNDS . . . . . . . . . . 46* 2.3.3* KINETIC
CONSIDERATIONS . . . . . . . . . . . . . . . . . . . . . 47* PART 11*
PROPERTIES OF POTENTIAL CONTAMINANTS: ENVIRONMENTAL AND HEALTH HAZARDS
CHAPTER 3 INORGANIC AND ORGANOMETALLIC COMPOUNDS. . . . . . . . . . . .
. . 51* 3.1 NITROGEN. 51* 3.2
PHOSPHORUS. 53* 3.3
SA1TS. 55* 3.3.1* AGRICULTURAJ
IMPACTS. 55* 3.3.2* IMPACTS ON WATER USAGE. . . .
. . . . . . . . . . . . . . . . 57* 3.3.3* IMPACTS ON INFRASTTUCTURE .
. . . . . . . . . . . . . . . . . . 58* 3.3.4* IMPACTS ON BIODIVERSITY*
AND THE ENVIRONMENT. . . . . . . . . . . . . . . . . . . . . . . 58*
3.4 RADIONUCLIDES. . . . . . . . . . . . . . 59*
3.5 HEAVY METALS AND METALLOIDS. . . . . . . . . . . . . . . . . . . . .
. 61* 3.5.1* ARSENIC 61* 3.5.2*
CADMIUM. 63* 3.5.3*
CHROMIUM. 64* 3.5.4*
LEAD. 65* 3.5.5*
NICKEL. 66* 3.6 NANOMATERIALS . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67* CHAPTER
4 ORGANIC COMPOUNDS . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . 71* 4.1 PESTICIDES.
71* 4.1.1* ORGANOCHLORINE INSECTICIDES . . . . . . . . . . . . . . . .
. 73* 4.1.2* ORGANOPHOSPHATES. 75* 4.1.3*
N-METHYL CARBAMATE. . . . . . . . . . . . . . . . . . . . . . . 75*
4.1.4* TRIAZINES. 76* 4.1.5* PARAQUAT
AND DIQUAT . . . . . . . . . . . . . . . . . . . . . . . 77* 4.2
SYNTHETIC HALOGENATED ORGANIC SUBSTANCES . . . . . . . . . . . 78*
4.2.1* CHLORINATED HYDROCARBONS . . . . . . . . . . . . . . . . . . 78*
4.2.2* BROMINATED FLAME RETARDANTS. . . . . . . . . . . . . . . . 81*
4.3 PETROLEUM HYDROCARBONS AND FUEL ADDITIVES. . . . . . . . . . 83*
4.4 PHARMACEUTICALS AND PERSONAL CARE PRODUCTS . . . . . . . . . . 86*
4.4.1* ANALGESICS AND ANTIINFLAMMATORY DRUGS . . . . . . . 88* 4.4.2*
HORMONES. 88* 4.4.3* ANTIBACTERIAJ DRUGS.
. . . . . . . . . . . . . . . . . . . . . . . 89* 4.4.4* ANTIEPILEPTIC
DRUGS. . . . . . . . . . . . . . . . . . . . . . . . 90* 4.4.5*
BETA-BLOCKERS. . . 90* CONTENTS PART III*
CHAPTER 5* CHAPTER 6* CHAPTER 7* CHAPTER 8* XI CONTAMINANT PARTITIONING
IN THE SUBSURFACE SORPTION, RETENTION, AND RELEASE* OF CONTAMINANTS . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93*
5.1 SURFACE PROPERTIES OF ADSORBENTS . . . . . . . . . . . . . . . . . .
. 93* 5.2 QUANTIFYING ADSORPTION. . . . . . . . . . . . . . . . . . . .
. . . . . . . 95* 5.2.1 ADSORPTION-DESORPTION COEFFICIENTS. . . . . . .
. . . . 95* 5.2.2 ADSORPTION ISOTHENNS . . . . . . . . . . . . . . . .
. . . . . . 95* 5.3 KINETICS OF ADSORPTION. . . . . . . . . . . . . . .
. . . . . . . . . . . . 101* 5.4 ADSORPTION OF IONIC CONTAMINANTS . . .
. . . . . . . . . . . . . . . 104* 5.5 ADSORPTION OF NONIONIC
CONTAMINANTS 109* 5.6 OTHER FACTORS AFFECTING ADSORPTION " 112* 5.7
NONADSORPTIVE RETENTION OF CONTAMINANTS . . . . . . . . . . . . 114*
5.7.1 CONTAMINANT PRECIPITATION. . . . . . . . . . . . . . . . . . .
115* 5.7.2 LIQUID TRAPPING. . . . . . . . . . . . . . . . . . . . . . .
. . . . 116* 5.7.3 PARTICLE DEPOSITION AND TRAPPING 118* 5.8 REVERSIBLE
AND IRREVERSIBLE RETENTION 120* 5.8.1 GENUINE HYSTERESIS. . . . . . . .
. . . . . . . . . . . . . . . . 120* 5.8.2 APPARENT HYSTERESIS . . . .
. . . . . . . . . . . . . . . . . . . 122* 5.8.3 BOUND RESIDUES 123*
CONTAMINANT PARTITIONING IN THE AQUEOUS PHASE . . . . . . . . . 127*
6.1 SOLUBILITY EQUILIBRIUM. . . . . . . . . . . . . . . . . . . . . . .
. . . . . 128* 6.2 AQUEOUS SOLUBILITY OF ORGANIC CONTAMINANTS. . . . .
. . . . . 130* 6.3 LIGAND EFFECTS . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . 131* 6.4 COSOLVENTS AND SURFACTANT
EFFECTS 133* 6.5 SALTING-OUT EFFECT . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . 136* 6.6 APPARENT SOLUBILITY . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . 139* PARTITIONING OF
VOLATILE COMPOUNDS . . . . . . . . . . . . . . . . . . . . 143* 7.1
GAS-LIQUID RELATIONSHIPS . . . . . . . . . . . . . . . . . . . . . . . .
. 144* 7.2 VOLATILIZATION FROM SUBSURFACE AQUEOUS SOLUTIONS 145* 7.3
VAPOR PRESSURE-VOLATILIZATION RELATIONSHIP . . . . . . . . . . . 148*
7.4 VOLATILIZATION OF MULTICOMPONENT CONTAMINANTS . . . . . . . 149*
SELECTED RESEARCH FINDINGS:* CONTAMINANT PARTITIONING . . . . . . . . .
. . . . . . . . . . . . . . . . . . . 151* 8.1 PARTITIONING AMONG
PHASES . . . . . . . . . . . . . . . . . . . . . . . . 151* 8.2
CONTAMINANT VOLATILIZATION . . . . . . . . . . . . . . . . . . . . . . .
. 153* 8.2.1 INORGANIC CONTAMINANTS . . . . . . . . . . . . . . . . . .
. . 154* 8.2.2 ORGANIC CONTAMINANTS. . . . . . . . . . . . . . . . . .
. . . . 156* 8.2.3 MIXTURES OF ORGANIE CONTAMINANTS. . . . . . . . . .
. . 160* XII* CONTENTS 8.3 SOLUBILITY AND DISSOLUTION* 165 8.3.1*
ACIDITY AND ALKALINITY EFFECTS 165 8.3.2* REDOX PROCESSES . . . . . . .
. . . . . . . . . . . . . . . . 167* 8.3.3* DISSOLUTION FROM MIXTURES
OF ORGANIC CONTAMINANTS. . . . . . . . . . . . . . . . . 169 8.3.4*
APPARENT SOLUBILITY . . . . . . . . . . . . . . . . . . . . . 169* 8.4*
CONTAMINANT RETENTION IN THE SUBSURFACE. . . . . . . . . . . 178 8.4.1*
CONTAMINANT ADSORPTION. . . . . . . . . . . . . . . . . 179* 8.4.2*
NONADSORPTIVE RETENTION. . . . . . . . . . . . . . . . . 196* 8.5*
CONTAMINANT RELEASE 201 8.6* BOUND RESIDUES. . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . 206* PART IV CONTAMINANT TRANSPORT FROM
LAND SURFACE TO GROUNDWATER CHAPTER 9 WATER FLOW IN THE SUBSURFACE
ENVIRONMENT . . . . . . . . . . . . 213 9.1* WATER FLOW IN SOILS AND
THE VADOSE ZONE " 213 9.2* FLOW THROUGH THE CAPILLARY FRINGE 216 CHAPTER
10 TRANSPORT OF PASSIVE CONTAMINANTS* 219 10.1* ADVECTION, DISPERSION,
AND MOLECULAR DIFFUSION. . . . . 220 10.2* PREFERENTIAL TRANSPORT . . .
. . . . . . . . . . . . . . . . . . . . . . . 223* 10.3* NON-FICKIAN
TRANSPORT 225 CHAPTER 11 TRANSPORT OF REACTIVE CONTAMINANTS* 231 11.1*
CONTAMINANT SORPTION. . . . . . . . . . . . . . . . . . . . . . . . . .
231* 11.2* COLLOIDS AND SORPTION ON COLLOIDS 233 11.3* DISSOLVING AND
PRECIPITATING CONTAMINANTS , 234 11.4* TRANSPORT OF IMMISCIBLE LIQUIDS
237 11.5* TRANSPORT OF CONTAMINANTS BY RUNOFF . . . . . . . . . . . . .
. 242 CHAPTER 12 SELECTED RESEARCH FINDINGS: CONTAMINANT TRANSPORT . .
. . 247 12.1* AQUEOUS TRANSPORT OF REACTIVE CONTAMINANTS: FIELD AND
LABORATORY STUDIES 247 12.1.1* FIELD EXPERIMENT RESULTS , 247 12.1.2*
MODELING FIELD EXPERIMENTS 252 12.1.3* LABORATORY AND OUTDOOR STUDIES .
. . . . . . . . . . 256 12.1.4* PREFERENTIAL FLOW . . . . . . . . . . .
. . . . . . . . . . . . 257* 12.2* TRANSPORT OF NONAQUEOUS PHASE
LIQUIDS. . . . . . . . . . . . 260 12.2.1* INFILTRATION INTO THE
SUBSURFACE . . . . . . . . . . . . 260 12.2.2* TRANSPORT OF SOLUBLE
NAPL FRACTIONS IN AQUIFERS. . . . . . . . . . . . . . . . . . . . . . .
. . . . . 263 12.3* COLIOID-MEDIATED TRANSPORT OF CONTAMINANTS 264
12.3.1* SURFACE RUNOFF. . . . . . . . . . . . . . . . . . . . . . . . .
265* 12.3.2* TRANSPORT IN THE SUBSURFACE. . . . . . . . . . . . . . .
266* CONLENTS* XIII PART V TRANSFORMATIONS AND REACTIONS OF
CONTAMINANTS* IN THE SUBSURFACE* CHAPTER 13* CHAPTER 14* CHAPTER 15*
CHAPTER 16* ABIOTIC CONTAMINANT TRANSFORMATIONS* IN SUBSURFACE WATER . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 273* 13.1*
ABIOTIC CONTAMINANT TRANSFORMATIONS* IN NATURAL SUBSURFACE WATER . . . .
. . . . . . . . . . . . . . . . . 273* 13.1.1* FACTORS AFFECTING
CONTAMINANT* TRANSFORMATIONS 273* 13.1.2* REACTIONS IN NATURAL WATERS
275* 13.2* SELECTED CONTARNINANT TRANSFORMATIONS* IN SEDIMENTS AND
GROUNDWATER . . . . . . . . . . . . . . . . . . . 286* 13.2.1* PH AND
HYDROLYSIS REACTIONS 286* 13.2.2* REDOX STATE AND REACTIONS . . . . . .
. . . . . . . . . 287* ABIOTIC TRANSFORMATION AT THE SOLID-LIQUID
INTERFACE . . 295* 14.1*
CATALYSIS. 295* 14.2*
SURFACE-INDUCED TRANSFORMATION* OF ORGANIC CONTARNINANTS. . . . . . . .
. . . . . . . . . . . . . . . . 296* 14.3* SURFACE-INDUCED
INTERACTIONS* OF INORGANIC CONTAMINANTS . . . . . . . . . . . . . . . .
. . . . . . 301* BIOLOGICALLY MEDIATED TRANSFORMATIONS. . . . . . . . .
. . . . . . . 303* 15.1* SUBSURFACE MICROBIAL POPULATIONS 303* 15.2*
PROCESSES GOVEMING CONTARNINANT ATTENUATION 303* 15.3* BIOTRANSFORMATION
OF ORGANIC CONTAMINANTS . . . . . . . 305* 15.4* BIOTRANSFORMATION
OFINORGANIC CONTAMINANTS 311* SELECTED RESEARCH FINDINGS:*
TRANSFORMATIONS AND REACTIONS. . . . . . . . . . . . . . . . . . . . . .
. 317* 16.1* ABIOTIC ALTERATION OF CONTARNINANTS . . . . . . . . . . .
. . . . 317* 16.1.1* TRANSFORMATION IN SUBSURFACE WATER 317* 16.1.2*
SURFACE-INDUCED TRANSFONNATION ON CLAYS . . . 332* 16.1.3*
PHOTOCHERNICAL REACTIONS 336* 16.1.4* LIGAND EFFECTS . . . . . . . . . .
. . . . . . . . . . . . . . . 342* 16.1.5* MU1TIP1E-COMPONENT
CONTARNINANT* TRANSFORMATION . . . . . . . . . . . . . . . . . . . . . .
. . 345* 16.2* BIOMEDIATED TRANSFORMATION OF CONTAMINANTS 357* 16.2.1*
PETROLEUM PRODUCTS . . . . . . . . . . . . . . . . . . . . . 357*
16.2.2* PESTICIDES 361* REFERENCES. . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 373*
SUBJECT INDEX . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . 409* |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Berkowitz, Brian Dror, Ishai Yaron, Bruno 1929- |
| author_GND | (DE-588)107957523 |
| author_facet | Berkowitz, Brian Dror, Ishai Yaron, Bruno 1929- |
| author_role | aut aut aut |
| author_sort | Berkowitz, Brian |
| author_variant | b b bb i d id b y by |
| building | Verbundindex |
| bvnumber | BV023258894 |
| callnumber-first | T - Technology |
| callnumber-label | TD426 |
| callnumber-raw | TD426 |
| callnumber-search | TD426 |
| callnumber-sort | TD 3426 |
| callnumber-subject | TD - Environmental Technology |
| classification_rvk | RB 10115 RB 10159 RB 10160 VE 9600 |
| ctrlnum | (OCoLC)255556160 (DE-599)DNB987388878 |
| dewey-full | 628.1/68 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 628 - Sanitary engineering |
| dewey-raw | 628.1/68 |
| dewey-search | 628.1/68 |
| dewey-sort | 3628.1 268 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Chemie / Pharmazie Geologie / Paläontologie Bauingenieurwesen Geographie |
| discipline_str_mv | Chemie / Pharmazie Geologie / Paläontologie Bauingenieurwesen Geographie |
| format | Book |
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| id | DE-604.BV023258894 |
| illustrated | Illustrated |
| index_date | 2024-07-02T20:31:07Z |
| indexdate | 2024-07-09T21:14:20Z |
| institution | BVB |
| isbn | 9783540743811 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016444126 |
| oclc_num | 255556160 |
| open_access_boolean | |
| owner | DE-29 DE-634 DE-11 |
| owner_facet | DE-29 DE-634 DE-11 |
| physical | XIII, 412 S. Ill., graph. Darst. 235 mm x 155 mm |
| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | Springer Berlin |
| record_format | marc |
| spelling | Berkowitz, Brian Verfasser aut Contaminant geochemistry interactions and transport in the subsurface environment Brian Berkowitz ; Ishai Dror ; Bruno Yaron Berlin [u.a.] Springer Berlin 2008 XIII, 412 S. Ill., graph. Darst. 235 mm x 155 mm txt rdacontent n rdamedia nc rdacarrier Geochemistry Groundwater flow Groundwater Pollution Hydrogeology Pollutants Water chemistry Umweltgeochemie (DE-588)4404136-6 gnd rswk-swf Umweltgift (DE-588)4186801-8 gnd rswk-swf Umweltgift (DE-588)4186801-8 s Umweltgeochemie (DE-588)4404136-6 s DE-604 Dror, Ishai Verfasser aut Yaron, Bruno 1929- Verfasser (DE-588)107957523 aut http://d-nb.info/987388878/04 Inhaltsverzeichnis GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016444126&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Berkowitz, Brian Dror, Ishai Yaron, Bruno 1929- Contaminant geochemistry interactions and transport in the subsurface environment Geochemistry Groundwater flow Groundwater Pollution Hydrogeology Pollutants Water chemistry Umweltgeochemie (DE-588)4404136-6 gnd Umweltgift (DE-588)4186801-8 gnd |
| subject_GND | (DE-588)4404136-6 (DE-588)4186801-8 |
| title | Contaminant geochemistry interactions and transport in the subsurface environment |
| title_auth | Contaminant geochemistry interactions and transport in the subsurface environment |
| title_exact_search | Contaminant geochemistry interactions and transport in the subsurface environment |
| title_exact_search_txtP | Contaminant geochemistry interactions and transport in the subsurface environment |
| title_full | Contaminant geochemistry interactions and transport in the subsurface environment Brian Berkowitz ; Ishai Dror ; Bruno Yaron |
| title_fullStr | Contaminant geochemistry interactions and transport in the subsurface environment Brian Berkowitz ; Ishai Dror ; Bruno Yaron |
| title_full_unstemmed | Contaminant geochemistry interactions and transport in the subsurface environment Brian Berkowitz ; Ishai Dror ; Bruno Yaron |
| title_short | Contaminant geochemistry |
| title_sort | contaminant geochemistry interactions and transport in the subsurface environment |
| title_sub | interactions and transport in the subsurface environment |
| topic | Geochemistry Groundwater flow Groundwater Pollution Hydrogeology Pollutants Water chemistry Umweltgeochemie (DE-588)4404136-6 gnd Umweltgift (DE-588)4186801-8 gnd |
| topic_facet | Geochemistry Groundwater flow Groundwater Pollution Hydrogeology Pollutants Water chemistry Umweltgeochemie Umweltgift |
| url | http://d-nb.info/987388878/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016444126&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT berkowitzbrian contaminantgeochemistryinteractionsandtransportinthesubsurfaceenvironment AT drorishai contaminantgeochemistryinteractionsandtransportinthesubsurfaceenvironment AT yaronbruno contaminantgeochemistryinteractionsandtransportinthesubsurfaceenvironment |
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