Nanotechnology: 2 Environmental aspects
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2008
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XV, 317 S. Ill., graph. Darst. 25 cm |
| ISBN: | 9783527317356 |
Internformat
MARC
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| 245 | 1 | 0 | |a Nanotechnology |n 2 |p Environmental aspects |c G. Schmid ... (eds.) |
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Datensatz im Suchindex
| _version_ | 1804137533118873600 |
|---|---|
| adam_text | Contents
Preface
XI
List of Contributors
ХШ
Ί
Pollution Prevention and Treatment Using Nanotechnology
1
Bernd Nowack
1.1
Introduction
1
1.2
More Efficient Resource and Energy Consumption
3
1.3
Pollution Detection and Sensing
4
1.4
Water Treatment
4
1.4.1
Adsorption of Pollutants
4
1.4.2
Magnetic Nanopartid.es
6
1.4.3
Nanofiltration
6
1.4.4
Degradation of Pollutants
б
1.4.5
Zerovalent Iron
7
1.5
Soil and Groundwater Remediation
9
1.6
Environmental Risks
10
1.6.1
Behavior in the Environment
10
1.6.2
Ecotoxicology
11
1.7
Conclusions
11
References
12
2
Photocatalytic Surfaces:
Antipollution
and Antimicrobial Effects
17
Norman S. Allen,
Michele
Edge, Joanne
Venan,
John Stratton,
julie Maltby,
and Claire Bygott
2.1
Introduction to Photocatalysis: Titanium Dioxide Chemistry
and Structure—Activity
17
2.2
Applications
26
2.3
Photocatalytic Chemistry
26
2.4
Photoactivity Tests for 2-Propanol Oxidation and Hydroxyl
Content
31
Contents
2.5
Self-Cleaning Effects: Paints/Cementitious Materials
33
2.5.1
Antibacterial Effect
38
2.5.2
Depollution: NO^/VOC Removal
42
2.6
Conclusions
48
References
49
3
Nanosized Photocatalysts in Environmental Remediation
51
Jess P. Wilcoxon and
Billie
L
Abrams
3.1
Introduction
51
3.1.1
Global Issues
51
3.1.2
Scope
53
3.2
General Field of Environmental Remediation
54
3.3
Photocatalysis
57
3.3.1
History and Background
57
3.3.2
Definitions
58
3.3.3
Well-Known Example
-
Water Splitting Reaction
59
3.4
Design Issues for Environmental Remediation Photocatalysts
60
3.4.1
Introduction
60
3.4.2
Charge Separation
61
3.4.3
pH
of Solution
62
ЗЛА
Charge Transfer
62
3.4.5
Presence of Simple and Complex Salts
62
3.4.6
Effect of Surfactants
64
3.4.7
Effect of Solvent and Dissolved Oxygen
65
3.4.8
Light Intensity
66
3.5
Potential for Nanomaterials in Environmental Remediation
66
3.5.1
Introduction
66
3.5.2
Nanomaterials and Advantages in Photocatalysis
68
3.5.2.1
Semiconductor Nanoclusters
68
3.5.2.2
Quantum Confinement
68
3.5.2.3
Surface Chemistry
71
3.5.2.4
Other Unique Materials Properties
71
3.5.2.5
Importance of Nanocluster Photostability
72
3.6
Nanoparticle Synthesis and Characterization
73
3.6.1
Introduction
73
3.6.2
Characterization
74
3.6.3
Detailed Examples of Nanocluster Synthesis and Photocatalysis
77
3.6.3.1
Semiconductor Nanoclusters
77
3.6.3.2
TiO2
78
3.6.3.3
Alternative Photocatalytic Materials
83
3.6.3.4
MoS2 and Other Metal Dichakogenides
86
3.7
Current and Future Technological Applications of Photocatalysts for
Environmental Remediation
122
3.7.1
Indoor Air Purification
213
3.7.2
Outdoor Air Purification
115
Contents
VII
3.8
Conclusion
117
References
119
4
Pollution
Treatment, Remediation and Sensing
125
Abhilash Sugunan andJoydeep Dutta
4.1
Introduction
125
4.2
Treatment Technologies to Remove Environmental Pollutants
127
4.3
Remediation Technologies to Clean Up Environmental Pollutants
Effectively
131
4.4
Sensors
133
4.4.1
Biosensors
134
4.4.2
Electrochemical Sensors
134
4.4.3
Mass Sensors
135
4.4.4
Optical Sensors
137
4.4.5
Gas Sensors
138
4.4.6
Novel Sensing Technologies and Devices for Pollutant and Microbial
Detection
140
4.4.6.1
Real-Time Chemical Composition Measurements of Fine and
Ultrarme
Airborne Particles
140
4.4.6.2
Ultrasensitive Detection of Pathogens in Water
240
4.4.6.3
Detection of Heavy Metals in Water
141
4.5
Conclusions
143
References
143
5
Benefits in Energy Budget
147
lan ¡var Suni
5.1
Introduction
147
5.2
Nanomaterials in Fuel Cells
148
5.2.1
Low-Temperature Fuel Cell Technology
148
5.2.2
Nanoparticle Catalysts in Low-Temperature Fuel Cells
150
5.2.3
Fuel Cell Catalyst Support Materials
151
5.2.4
Carbon Nanotubes: Science and Technology
152
5.2.5
Carbon Nanotubes within Operating PEMFCs
153
5.3
Hydrogen Storage
157
5.3.1
Hydrogen Storage Using Carbon Nanomaterials
358
5.4
Solar Cells
159
5.4.1
Solar Energy Basics, Including Quantum Confinement
159
5.4.2
Nanocrystalline Dye-Sensitized Solar Cells
161
5.4.3
Nanomaterials in Solar Cell Counter Electrodes
364
5.5
Lithium Ion Battery Anode Materials
165
5.5.1
lithium Ion Batteries
365
5.5.2
Nanomaterials for Lithium Ion Storage: Sn Nanoparticles
166
5.5.3
Nanomaterials for Lithium Ion Storage: Si Nanocomposites
369
5.5.4
Nanomaterials for Lithium Ion Storage: Carbon Nanotubes and Carbon
Nanotube-Based Composites
370
Vili
Contents
5.5.5 Lithium Ion
Storage: Further Considerations
171
References
172
6
An Industrial Ecology Perspective
277
Shannon M. Lloyd, Deanna
N.
Lekas,
and Ketra
A
Schmitt
6.1
Introduction
177
6.1.1
Industrial Ecology
277
6.1.2
Applying Industrial Ecology to Nanotechnology
178
6.2
Life Cycle Assessment
179
6.2.1
Background on Life Cycle Assessment
179
6.2.2
Life Cycle Implications for Nanotechnology ISO
6.2.3
Life Cycle Studies Conducted to Date
282
6.3
Substance Flow Analysis
284
6.3.1
Background on Substance Flow Analysis
284
6.3.2
Substance Flow Analysis Implications for Nanotechnology
185
6.3.3
Summary of Substance Flow Analysis Work Conducted to Date
285
6.4
Corporate Social Responsibility
186
6.4.1
Background on Corporate Social Responsibility
286
6.4.2
Corporate Social Responsibility Implications for Nanotechnology
287
6.4.3
Summary of Work Conducted to Understand Nanofirm
EHS
Concerns
and Actions
288
6.5
Conclusions
289
References
290
7
Composition, Transformation and Effects of Nanoparticles
in the Atmosphere
295
Ulrich
Paschi
7.1
Introduction
295
7.2
Composition
299
7.2.1
Carbonaceous Components
299
7.2.2
Primary and Secondary Organic Components
202
7.3
Transformation
205
7.3.1
Chemical Transformation of Carbonaceous Aerosol
Components
208
7.3.2
Restructuring, Phase Transitions, Hygroscopic Growth and CCN/IN
Activation of Aerosol Particles upon Interaction with Water Vapor
212
7.4
Climate and Health Effects
226
7.5
Summary and Outlook
229
References
221
8
Measurement and Detection of Nanoparticles Within
the Environment
229
Thomas AJ.
Kuhlbusch,
Heinz
Fissa«,
and
Christof Asbach
8.1
Introduction
229
8.2
Occurrence of Nanoparticles in Environmental Media
233
Contents
IX
8.2.1
Ambient
Environment 233
8.2.1.1
Water and Soils
233
8.2.1.2
Air
234
8.2.2
Workplace Environment
234
8.3
Nanoparticle Detection and Measurement Techniques
235
8.3.1
Soil
235
8.3.2
Water and Liquids
235
8.3.2.1
Coulter Counter
235
8.3.2.2
Light Scattering
236
8.3.3
Air
238
8.3.3.1
Basics
238
8.3.3.2
Online Physical Characterization
243
8.3.3.3
Online Physical-Chemical Characterization
256
8.3.3.4
Offline Physical Characterization
258
8.4
Nanoparticle Detection and Measurement Strategies
259
References
262
9
Epidemiological Studies on Participate Air Pollution
267
Irene
Brüske-Hohlfeld
and Annette Peters
9.1
Introduction
267
9.1.1
Outline of the Chapter
267
9.1.2
A Short Definition of Particle Sizes
268
9.1.3
A Brief Comment on Epidemiological Study Design
269
9.2
Potential Entry Routes for Nanoparticles into the Human Body
270
9.2.1
Inhalation and Metabolism of Airborne Particles
270
9.3
Studies of Environmental Air Pollution in the USA and Europe
271
9.3.1
PM10 and PM2.5
271
9.3.1.1
Short-Term Studies
272
9.3.1.2
Long-Term
Studies
272
9.3.2
Ultrafine
Particles
(UFP) 273
9.4
Cardiovascular Disease
275
9.5
Respiratory Disease
276
9.5.1
Deterioration of Lung Function and Respiratory Symptoms
276
9.5.2
Asthma and Allergies
277
9.5.3
Lung Cancer
278
9.6
Diseases of the Central Nervous System
279
9.7
Paniculate Air Pollution at the Workplace
281
References
286
10
Impact of Nanotechnological Developments on the Environment
291
Harald F. Krug
and
Petra Klug
10.1 Problem 291
10.2
Risk
Management 292
10.3
Sources of
Nanoparticles: New Products 294
10.4
Production and Use of Nanomaterials
296
Contents
10.5
Workplace and the Environment: Effects and Aspects of
Nanomaterials
297
10.6
Distribution of Nanoparticles in Ambient Air
298
10.7
Distribution of Nanoparticles in Water
299
10.8
Conclusions
302
References
303
Index
307
|
| adam_txt |
Contents
Preface
XI
List of Contributors
ХШ
Ί
Pollution Prevention and Treatment Using Nanotechnology
1
Bernd Nowack
1.1
Introduction
1
1.2
More Efficient Resource and Energy Consumption
3
1.3
Pollution Detection and Sensing
4
1.4
Water Treatment
4
1.4.1
Adsorption of Pollutants
4
1.4.2
Magnetic Nanopartid.es
6
1.4.3
Nanofiltration
6
1.4.4
Degradation of Pollutants
б
1.4.5
Zerovalent Iron
7
1.5
Soil and Groundwater Remediation
9
1.6
Environmental Risks
10
1.6.1
Behavior in the Environment
10
1.6.2
Ecotoxicology
11
1.7
Conclusions
11
References
12
2
Photocatalytic Surfaces:
Antipollution
and Antimicrobial Effects
17
Norman S. Allen,
Michele
Edge, Joanne
Venan,
John Stratton,
julie Maltby,
and Claire Bygott
2.1
Introduction to Photocatalysis: Titanium Dioxide Chemistry
and Structure—Activity
17
2.2
Applications
26
2.3
Photocatalytic Chemistry
26
2.4
Photoactivity Tests for 2-Propanol Oxidation and Hydroxyl
Content
31
Contents
2.5
Self-Cleaning Effects: Paints/Cementitious Materials
33
2.5.1
Antibacterial Effect
38
2.5.2
Depollution: NO^/VOC Removal
42
2.6
Conclusions
48
References
49
3
Nanosized Photocatalysts in Environmental Remediation
51
Jess P. Wilcoxon and
Billie
L
Abrams
3.1
Introduction
51
3.1.1
Global Issues
51
3.1.2
Scope
53
3.2
General Field of Environmental Remediation
54
3.3
Photocatalysis
57
3.3.1
History and Background
57
3.3.2
Definitions
58
3.3.3
Well-Known Example
-
Water Splitting Reaction
59
3.4
Design Issues for Environmental Remediation Photocatalysts
60
3.4.1
Introduction
60
3.4.2
Charge Separation
61
3.4.3
pH
of Solution
62
ЗЛА
Charge Transfer
62
3.4.5
Presence of Simple and Complex Salts
62
3.4.6
Effect of Surfactants
64
3.4.7
Effect of Solvent and Dissolved Oxygen
65
3.4.8
Light Intensity
66
3.5
Potential for Nanomaterials in Environmental Remediation
66
3.5.1
Introduction
66
3.5.2
Nanomaterials and Advantages in Photocatalysis
68
3.5.2.1
Semiconductor Nanoclusters
68
3.5.2.2
Quantum Confinement
68
3.5.2.3
Surface Chemistry
71
3.5.2.4
Other Unique Materials Properties
71
3.5.2.5
Importance of Nanocluster Photostability
72
3.6
Nanoparticle Synthesis and Characterization
73
3.6.1
Introduction
73
3.6.2
Characterization
74
3.6.3
Detailed Examples of Nanocluster Synthesis and Photocatalysis
77
3.6.3.1
Semiconductor Nanoclusters
77
3.6.3.2
TiO2
78
3.6.3.3
Alternative Photocatalytic Materials
83
3.6.3.4
MoS2 and Other Metal Dichakogenides
86
3.7
Current and Future Technological Applications of Photocatalysts for
Environmental Remediation
122
3.7.1
Indoor Air Purification
213
3.7.2
Outdoor Air Purification
115
Contents
VII
3.8
Conclusion
117
References
119
4
Pollution
Treatment, Remediation and Sensing
125
Abhilash Sugunan andJoydeep Dutta
4.1
Introduction
125
4.2
Treatment Technologies to Remove Environmental Pollutants
127
4.3
Remediation Technologies to Clean Up Environmental Pollutants
Effectively
131
4.4
Sensors
133
4.4.1
Biosensors
134
4.4.2
Electrochemical Sensors
134
4.4.3
Mass Sensors
135
4.4.4
Optical Sensors
137
4.4.5
Gas Sensors
138
4.4.6
Novel Sensing Technologies and Devices for Pollutant and Microbial
Detection
140
4.4.6.1
Real-Time Chemical Composition Measurements of Fine and
Ultrarme
Airborne Particles
140
4.4.6.2
Ultrasensitive Detection of Pathogens in Water
240
4.4.6.3
Detection of Heavy Metals in Water
141
4.5
Conclusions
143
References
143
5
Benefits in Energy Budget
147
lan ¡var Suni
5.1
Introduction
147
5.2
Nanomaterials in Fuel Cells
148
5.2.1
Low-Temperature Fuel Cell Technology
148
5.2.2
Nanoparticle Catalysts in Low-Temperature Fuel Cells
150
5.2.3
Fuel Cell Catalyst Support Materials
151
5.2.4
Carbon Nanotubes: Science and Technology
152
5.2.5
Carbon Nanotubes within Operating PEMFCs
153
5.3
Hydrogen Storage
157
5.3.1
Hydrogen Storage Using Carbon Nanomaterials
358
5.4
Solar Cells
159
5.4.1
Solar Energy Basics, Including Quantum Confinement
159
5.4.2
Nanocrystalline Dye-Sensitized Solar Cells
161
5.4.3
Nanomaterials in Solar Cell Counter Electrodes
364
5.5
Lithium Ion Battery Anode Materials
165
5.5.1
lithium Ion Batteries
365
5.5.2
Nanomaterials for Lithium Ion Storage: Sn Nanoparticles
166
5.5.3
Nanomaterials for Lithium Ion Storage: Si Nanocomposites
369
5.5.4
Nanomaterials for Lithium Ion Storage: Carbon Nanotubes and Carbon
Nanotube-Based Composites
370
Vili
Contents
5.5.5 Lithium Ion
Storage: Further Considerations
171
References
172
6
An Industrial Ecology Perspective
277
Shannon M. Lloyd, Deanna
N.
Lekas,
and Ketra
A
Schmitt
6.1
Introduction
177
6.1.1
Industrial Ecology
277
6.1.2
Applying Industrial Ecology to Nanotechnology
178
6.2
Life Cycle Assessment
179
6.2.1
Background on Life Cycle Assessment
179
6.2.2
Life Cycle Implications for Nanotechnology ISO
6.2.3
Life Cycle Studies Conducted to Date
282
6.3
Substance Flow Analysis
284
6.3.1
Background on Substance Flow Analysis
284
6.3.2
Substance Flow Analysis Implications for Nanotechnology
185
6.3.3
Summary of Substance Flow Analysis Work Conducted to Date
285
6.4
Corporate Social Responsibility
186
6.4.1
Background on Corporate Social Responsibility
286
6.4.2
Corporate Social Responsibility Implications for Nanotechnology
287
6.4.3
Summary of Work Conducted to Understand Nanofirm
EHS
Concerns
and Actions
288
6.5
Conclusions
289
References
290
7
Composition, Transformation and Effects of Nanoparticles
in the Atmosphere
295
Ulrich
Paschi
7.1
Introduction
295
7.2
Composition
299
7.2.1
Carbonaceous Components
299
7.2.2
Primary and Secondary Organic Components
202
7.3
Transformation
205
7.3.1
Chemical Transformation of Carbonaceous Aerosol
Components
208
7.3.2
Restructuring, Phase Transitions, Hygroscopic Growth and CCN/IN
Activation of Aerosol Particles upon Interaction with Water Vapor
212
7.4
Climate and Health Effects
226
7.5
Summary and Outlook
229
References
221
8
Measurement and Detection of Nanoparticles Within
the Environment
229
Thomas AJ.
Kuhlbusch,
Heinz
Fissa«,
and
Christof Asbach
8.1
Introduction
229
8.2
Occurrence of Nanoparticles in Environmental Media
233
Contents
IX
8.2.1
Ambient
Environment 233
8.2.1.1
Water and Soils
233
8.2.1.2
Air
234
8.2.2
Workplace Environment
234
8.3
Nanoparticle Detection and Measurement Techniques
235
8.3.1
Soil
235
8.3.2
Water and Liquids
235
8.3.2.1
Coulter Counter
235
8.3.2.2
Light Scattering
236
8.3.3
Air
238
8.3.3.1
Basics
238
8.3.3.2
Online Physical Characterization
243
8.3.3.3
Online Physical-Chemical Characterization
256
8.3.3.4
Offline Physical Characterization
258
8.4
Nanoparticle Detection and Measurement Strategies
259
References
262
9
Epidemiological Studies on Participate Air Pollution
267
Irene
Brüske-Hohlfeld
and Annette Peters
9.1
Introduction
267
9.1.1
Outline of the Chapter
267
9.1.2
A Short Definition of Particle Sizes
268
9.1.3
A Brief Comment on Epidemiological Study Design
269
9.2
Potential Entry Routes for Nanoparticles into the Human Body
270
9.2.1
Inhalation and Metabolism of Airborne Particles
270
9.3
Studies of Environmental Air Pollution in the USA and Europe
271
9.3.1
PM10 and PM2.5
271
9.3.1.1
Short-Term Studies
272
9.3.1.2
Long-Term
Studies
272
9.3.2
Ultrafine
Particles
(UFP) 273
9.4
Cardiovascular Disease
275
9.5
Respiratory Disease
276
9.5.1
Deterioration of Lung Function and Respiratory Symptoms
276
9.5.2
Asthma and Allergies
277
9.5.3
Lung Cancer
278
9.6
Diseases of the Central Nervous System
279
9.7
Paniculate Air Pollution at the Workplace
281
References
286
10
Impact of Nanotechnological Developments on the Environment
291
Harald F. Krug
and
Petra Klug
10.1 Problem 291
10.2
Risk
Management 292
10.3
Sources of
Nanoparticles: New Products 294
10.4
Production and Use of Nanomaterials
296
Contents
10.5
Workplace and the Environment: Effects and Aspects of
Nanomaterials
297
10.6
Distribution of Nanoparticles in Ambient Air
298
10.7
Distribution of Nanoparticles in Water
299
10.8
Conclusions
302
References
303
Index
307 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author_GND | (DE-588)13573097X |
| building | Verbundindex |
| bvnumber | BV023237342 |
| classification_rvk | ZN 3460 ZN 3700 |
| ctrlnum | (OCoLC)635249993 (DE-599)BVBBV023237342 |
| discipline | Elektrotechnik / Elektronik / Nachrichtentechnik |
| discipline_str_mv | Elektrotechnik / Elektronik / Nachrichtentechnik |
| format | Book |
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| id | DE-604.BV023237342 |
| illustrated | Illustrated |
| index_date | 2024-07-02T20:22:37Z |
| indexdate | 2024-07-09T21:13:48Z |
| institution | BVB |
| isbn | 9783527317356 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016422940 |
| oclc_num | 635249993 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-20 DE-29T DE-1102 DE-703 DE-210 DE-92 DE-83 DE-91S DE-BY-TUM DE-11 |
| owner_facet | DE-355 DE-BY-UBR DE-20 DE-29T DE-1102 DE-703 DE-210 DE-92 DE-83 DE-91S DE-BY-TUM DE-11 |
| physical | XV, 317 S. Ill., graph. Darst. 25 cm |
| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Nanotechnology 2 Environmental aspects G. Schmid ... (eds.) Weinheim Wiley-VCH 2008 XV, 317 S. Ill., graph. Darst. 25 cm txt rdacontent n rdamedia nc rdacarrier Umwelt (DE-588)4061616-2 gnd rswk-swf Nanotechnologie (DE-588)4327470-5 gnd rswk-swf Nanotechnologie (DE-588)4327470-5 s Umwelt (DE-588)4061616-2 s DE-604 Krug, Harald Sonstige oth Schmid, Günter 1937- Sonstige (DE-588)13573097X oth (DE-604)BV023237305 2 Digitalisierung UB Regensburg application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016422940&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Nanotechnology Umwelt (DE-588)4061616-2 gnd Nanotechnologie (DE-588)4327470-5 gnd |
| subject_GND | (DE-588)4061616-2 (DE-588)4327470-5 |
| title | Nanotechnology |
| title_auth | Nanotechnology |
| title_exact_search | Nanotechnology |
| title_exact_search_txtP | Nanotechnology |
| title_full | Nanotechnology 2 Environmental aspects G. Schmid ... (eds.) |
| title_fullStr | Nanotechnology 2 Environmental aspects G. Schmid ... (eds.) |
| title_full_unstemmed | Nanotechnology 2 Environmental aspects G. Schmid ... (eds.) |
| title_short | Nanotechnology |
| title_sort | nanotechnology environmental aspects |
| topic | Umwelt (DE-588)4061616-2 gnd Nanotechnologie (DE-588)4327470-5 gnd |
| topic_facet | Umwelt Nanotechnologie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016422940&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV023237305 |
| work_keys_str_mv | AT krugharald nanotechnology2 AT schmidgunter nanotechnology2 |