Amino group chemistry: from synthesis to the life sciences
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| Sprache: | English |
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WILEY-VCH
2008
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| Beschreibung: | XIV, 394 S. graph. Darst. 240 mm x 170 mm |
| ISBN: | 9783527317417 3527317414 |
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MARC
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| 245 | 1 | 0 | |a Amino group chemistry |b from synthesis to the life sciences |c ed. by Alfredo Ricci |
| 264 | 1 | |a Weinheim |b WILEY-VCH |c 2008 | |
| 300 | |a XIV, 394 S. |b graph. Darst. |c 240 mm x 170 mm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 7 | |a Aminoglycosiden |2 gtt | |
| 650 | 7 | |a Aminogroepen |2 gtt | |
| 650 | 7 | |a Aminosuikers |2 gtt | |
| 650 | 7 | |a Aminozuren |2 gtt | |
| 650 | 7 | |a Biomoleculen |2 gtt | |
| 650 | 7 | |a Katalyse |2 gtt | |
| 650 | 7 | |a Nitroverbindingen |2 gtt | |
| 650 | 7 | |a Symmetrie |2 gtt | |
| 650 | 4 | |a Amino acids | |
| 650 | 0 | 7 | |a Aminogruppe |0 (DE-588)4326843-2 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Aminogruppe |0 (DE-588)4326843-2 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Ricci, Alfredo |e Sonstige |4 oth | |
| 856 | 4 | 2 | |q text/html |u http://deposit.dnb.de/cgi-bin/dokserv?id=2930742&prov=M&dok_var=1&dok_ext=htm |3 Inhaltstext |
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| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-016262375 | |
Datensatz im Suchindex
| _version_ | 1805089765804998656 |
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| adam_text |
CONTENTS PREFACE XI* LIST OF CONTRIBUTORS XII I* SIMPLE MOLECULES,
HIGHLY EFFICIENT AMINATION SHUNSUKE CHIBA AND KOICHI NARASAKA 1.1*
INTRODUCTION 1* 1.2* HYDROXYLAMINE DERIVATIVES 1* 1.2.1*
O-SULFONYLHYDROXYLAMINE 1* 1.2.2* 0-PHOSPHINYLHYDROXYLAMINE 4* 1.2.3*
O-ACYLHYDROXYLAMINE 5* 1.2.4* O-TRIMETHYLSILYLHYDROXYLAMINE 6* 1.2.5*
EXPERIMENTAL PROCEDURES 7* 1.3* OXIME DERIVATIVES 9* 1.3.1* SYNTHESIS OF
PRIMARY AMINES BY ELECTROPHILIC AMINATION OF* CARBANIONS 9* 1.3.2*
EXPERIMENTAL PROCEDURES 13* 1.4* AZO COMPOUNDS 15* 1.4.1*
AZODICARBOXYLATES 15* 1.4.1.1* ALLYLIC AMINATION THROUGH ENE-TYPE
REACTIONS 15* 1.4.1.2* HYDROHYDRAZINATION OF ALKENES 16* 1.4.2* ARYLAZO
SULFONES 19* 1.4.3* EXPERIMENTAL PROCEDURES 20* 1.5* OXAZIRIDINE
DERIVATIVES 23* 1.5.1* ELECTROPHILIC AMINATION OF CARBON NUCLEOPHILES
23* 1.5.2* AMINATION OF ALLYLIC AND PROPARGYLIC SULFIDES BY USE OF A*
KETOMALONATE-DERIVED OXAZIRIDINE 23* 1.5.3* EXPERIMENTAL PROCEDURES 25*
1.6* CHLORAMINE-T 26* 1.6.1* AMINOCHALCOGENATION OF ALKENES 26* 1.6.2*
AMINOHYDROXYLATION OF ALKENES 26* 1.6.3* AZIRIDINATION OF ALKENES 27*
1.6.4* OTHER APPLICATIONS 32* 1.6.5* EXPERIMENTAL PROCEDURES 34* AMINO
GROUP CHEMISTRY. FROM SYNTHESIS TO THE LIFT SEIENEES. EDITED BY ALFREDO
RIECI COPYRIGHT WILEY-VCH VERLAG GMBH & CO. KGAA. WEINHEIM ISBN:
978-3-527-31741-7 VI I CONTENTS 1.7 1.7.1 1.7.2 1.8 1.8.1 1.8.2 1.9
1.9.1 1.9.2 1.9.3 1.9.4 1.10 1.10.1 1.10.2 1.11 2* 2.1 2.2 2.3 2.3.1
2.3.1.1 2.3.1.2 2.3.1.3 2.3.2 2.3.2.1 2.3.2.2 2.4 2.4.1 2.4.2 2.4.3 2.5
2.6 2.6.1 2.6.2 2.6.3 2.7 3* 3.1 3.2 N-SULFONYLIMINOPHENYLIODINANE 35*
TRANSITION METAL-CATALYZED AMINATION OF ALKENES 36* EXPERIMENTAL
PROCEDURES 37* TRANSITION METAL-NITRIDE COMPLEXES 38* NITROGEN ATOM
TRANSFER MEDIATED BY TRANSITION METAL/NITRIDE COMPLEXES 38* EXPERIMENTAL
PROCEDURES 39* AZIDO DERIVATIVES 41* ELECTROPHILIC AMINATION OF
ORGANOMETALLIC REAGENTS WITH ORGANIC AZIDES 42* RADICAL-MEDIATED
AMINATION WITH SULFONYL AZIDES 43* HYDROAZIDATION OF ALKENES WITH
SULFONYL AZIDES 43* EXPERIMENTAL PROCEDURES 44* GABRIEL-TYPE REAGENTS
46* NUCLEOPHILIC AMINATION REACTIONS 46* EXPERIMENTAL PROCEDURE 49*
CONCLUSION 50* CATALYTIC C-H AMINATION WITH NITRENES 55* PHILIPPE DAUBAN
AND ROBERT H. DODD INTRODUCTION 55* HISTORICAL OVERVIEW 56* HYPERVALENT
IODINE-MEDIATED C-H AMINATION 60* INTRAMOLECULAR C-H AMINATION 60* FROM
NHZ CARBAMATES 60* FROM NHZ SULFAMATES 62* FROM OTHER NITROGEN
FUNCTIONALITIES 65* INTERMOLECULAR C-H AMINATION 67* GENERAL SCOPE AND
LIMITATIONS 67* RECENT MAJOR IMPROVEMENTS 70* OTHER NITRENE PRECURSORS
FOR C-H AMINATION 73* AZIDES 73* HALOAMINES 74* CARBAMATE DERIVATIVES
76* AMINATION OF AROMATIC C-H BONDS 77* APPLICATIONS IN TOTAL SYNTHESIS
80* APPLICATION OF INTRAMOLECULAR C-H AMINATION WITH* CARBAMATES 80*
APPLICATION OF INTRAMOLECULAR C-H AMINATION WITH SULFAMATES 83*
APPLICATION OF INTERMOLECULAR C-H AMINATION 87* CONCLUSIONS 88*
NITROALKENES AS AMINATION 100LS 93* ROBERTO BALLINI, ENRICO MARCANTONI,
AND MARINO PETRINI INTRODUCTION 93* GENERAL STRATEGIES FOR THE SYNTHESIS
OF NITROALKENES 93* 3.3 3.3.1 3.3.2 3.3.3 3.3.4 3.4 3.4.1 3.4.2 3.5 3.6
3.7 3.7.1 3.7.2 3.7.3 3.8 3.9 4* 4.1 4.2 4.2.1 4.2.2 4.3 4.4 4.5 4.6 5*
5.1 5.2 5.3 5.4 6* 6.1 6.2 6.2.1 6.2.2 6.2.2.1 6.2.2.2 6.2.2.3 SYNTHESIS
OF ALKYLAMINES 95* PYRROLIZIDINES AND RELATED DERIVATIVES* ARENE-FUSED
NITROGEN HETEROCYCLES* MONOAMINES 95* AMINO ACID DERIVATIVES 98* AMINO
ALCOHOLS 103* DIAMINO DERIVATIVES 106* PYRROLIDINE DERIVATIVES 112*
PYRROLIDINONES 112* PYRROLIDINES 115* PIPERIDINES AND PIPERAZINES 124*
PYRROLOINDOLE DERIVATIVES 132* CONTENTS IVII* 126 132 CARBOLINES AND
THEIR TRYPTAMINE PRECURSORS 132* ARENE-FUSED PIPERIDINE COMPOUNDS 135*
OTHER POLYCYCLIC DERIVATIVES 140* CONCLUSION 144* ISOCYANIDE-BASED
MULTIEOMPONENT REACTIONS (IMCRS) AS A VALUABLE TOOL* WITH WHICH TO
SYNTHESIZE NITROGEN-CONTAINING COMPOUNDS 149* A/EXANDER DOEM/ING
INTRODUCTION 149* THE UGI REACTION 152* INTRAMOLECULAR UGI REACTIONS
INVOLVING TWO FUNCTIONAL GROUPS 158* THE UGI REACTION AND SECONDARY
TRANSFORMATIONS 166* PASSERINI REACTION 171* VAN LEUSEN REACTION 175*
OTHER IMCRS 177* OUTLOOK 180* DIRECT CATALYTIE ASYMMETRIE MANNIEH
REACTIONS AND SURROUNDINGS 185* ARMANDO C6RDOLLA AND RAMON RIAS
INTRODUCTION 185* ORGANOMETALLIC CATALYSTS 186* METAL-FREE
ORGANOCATALYSIS 191* CONCLUSIONS 201* AMINO-BASED BUILDING BLOCKS FOR
THE CONSTRUCTION OF BIOMOLECULES 207* ANDRE MANN* INTRODUCTION 207*
PROPARGYLAMINES (PLAS) 208* SYNTHESIS OF PLAS 209* PLAS IN SYNTHESIS
211* PLAS IN THE SYNTHESIS OF HETEROCYCLES 211* PLAS IN PD(O)-CATALYZED
PROCESSES 211* PLAS IN PERICYCLIC REACTIONS 213* VIII I CONTENTS 6.2.2.4
PLAS IN MULTICOMPONENT REACTIONS (MCRS) 215* 6.2.2.5 PLA IN RADICAL
REACTIONS 217* 6.3 TRANS-4-HYDROXY-(S)-PROLINE (HYP) 217* 6.3.1
STRUCTURAL TRANSFORMATIONS OFHYP 218* 6.3.1.1 C-4 ALKYLATION OF HYP 218*
6.3.1.2 C-4 FLUORINATION AND FLUOROALKYLATION OF HYP 218* 6.3.1.3 C-3
FUNCTIONALIZATION OF HYP 221* 6.3.2 HYP IN THE SYNTHESIS OF BIOMOLECULES
221* 6.3.2.1 HYP IN THE SYNTHESIS OF ALKALOIDS 221* 6.3.2.2 HYP IN THE
SYNTHESIS OF KAINIC ACID DERIVATIVES 222* 6.3.2.3 HYP IN THE SYNTHESIS
OF AMINO SUGARS 222* 6.3.2.4 HEPATITISC INHIBITORS 224* 6.4 L-SERINE
(SER) 224* 6.4.1 SER AND SER DERIVATIVES IN THE SYNTHESIS OF
BIOMOLECULES 225* 6.4.1.1 SER IN THE SYNTHESIS OF CARBOLINES 225*
6.4.1.2 SER IN THE SYNTHESIS OFFURANOMYCIN 226* 6.4.1. 3 SER IN THE
SYNTHESIS OF DIKETOPIPERAZINE ALKALOIDS 226* 6.4.1.4 SER IN THE
SYNTHESIS OFCLEOMYCIN 226* 6.4.1.5 SER IN THE SYNTHESIS OF PIPERIDINE
ALKALOIDS 228* 6.4.1.6 SER IN THE SYNTHESIS OF NONPROTEINOGENIC AMINO
ACIDS 228* 6.4.1.7 SER IN THE SYNTHESIS OFA,A'-DIAMINOACIDS 229* 6.4.1.8
SER IN THE SYNTHESIS OFRIGIDIFIED GLUTAMIC ACID 230* 6.5
4-METHOXYPYRIDINE (MOP) 230* 6.5.1 MOP IN THE SYNTHESIS OF BIOMOLECULES
231* 6.5.1.1 MOP IN THE SYNTHESIS OF ALKALOIDS 231* 6.5.1.2 MOP IN THE
SYNTHESIS OF PLUMERININE 232* 6.5.1.3 MOP IN THE SYNTHESIS
OF2,4-DISUBSTITUTED PIPERIDINES 234* 6.5.1.4 MOP IN THE SYNTHESIS
OFTOXINS 234* 6.5.1.5 MOP IN THE SYNTHESIS OFTROPANES 235* 6.6
AZIRIDINES (AZIS) 236* 6.6.1 AZIS IN THE SYNTHESIS OF BIOMOLECULES 236*
6.6.1.1 AZIS IN THE SYNTHESIS OF 1,2-DIAMINES 236* 6.6.1.2 AZIS IN THE
SYNTHESIS OF A-AMINO ACIDS 237* 6.6.1.3 AZI IN THE SYNTHESIS OF
FERRUGININE, AN ACETYLCHOLINE RECEPTOR 238* 6.6.1.4 AZIS IN THE
SYNTHESIS OFTRYPTOPHAN DERIVATIVES 238* 6.6.1.5 AZIS IN THE SYNTHESIS OF
FUNCTIONALIZED PIPERIDINES 239* 6.6.1.6 AN AZI IN THE SYNTHESIS OF THE
ALKALOID PUMILIOTOXIN 240* 6.6.1.7 AN AZI IN THE SYNTHESIS OF
PHENYLKAINIC ACID 240* 6.6.1.8 AZIS IN THE SYNTHESIS OF PSEUDODISTOMIN
ALKALOIDS 241* 6.7 HOMOALLYLAMINE (HAM) 242* 6.7.1 SYNTHESIS OF HAMS
242* 6.7.2 HAMS IN THE SYNTHESIS OF BIOMOLECULES 243* 6.7.2.1 HAM IN THE
SYNTHESIS OF IMIDAZOAZEPINES 243* 6.7.2.2 HAMS IN THE SYNTHESIS OF
ALKALOIDS 244* 6.7.2.3 HAMS IN THE SYNTHESIS OF PIPERIDINE DERIVATIVES
246* CONTENTS IIX* 6.7.2.4 6.8 6.8.1 6.8.2 6.9 7* 7.1 7.1.1 7.1.2 7.1.3
7.1.4 7.1.5 7.1.6 7.1.7 7.1.8 7.2 7.2.1 7.2.1.1 7.2.1.2 7.2.2 7.2.2.1
7.2.2.2 7.2.2.3 7.2.3 7.2.4 7.3 7.3.1 7.3.1.1 7.3.1.2 7.3.1.3 7.3.2
7.3.3 7.4 8* 8.1 8.2 8.3 8.4 8.4.1 HAMS IN THE SYNTHESIS OF CHIRAL
HETEROCYCLES 247* INDOLE (IND) 247* SYNTHESIS OF INDOLES 248* INDS IN
THE SYNTHESIS OF BIOMOLECULES 251* CONCLUSION 252* AMINATED SUGARS,
SYNTHESIS, AND BIOLOGICAL ACTIVITY 257* FRANCESCO NICOTRA, BARBARA LA
FERLA, AND CRISTINA AIROLDI BIOLOGICAL RELEVANCE OF AMINATED SUGARS 257*
N-ACETYLNEURAMINIC ACID 257* SIALYL LEWIS X 258* TUMOR-ASSOCIATED
ANTIGENS 259* CHITIN AND CHITOSAN 260* BACTERIAL POLYSACCHARIDES 260*
GLYCOSAMINOGLYCANS 261* IMINOSUGARS 262* SUGAR AMINO ACIDS 264*
SYNTHESIS OF AMINATED SUGARS 266* AMINATION AT THE ANOMERIC CENTER 266*
AMINATION EXPLOITING CARBONYL REACTIVITY 267* AMINATION EXPLOITING
OXONIUM ION REACTIVITY 270* AMINATION IN THE SUGAR CHAIN 273* AMINO
SUGARS BY NUCLEOPHILIC DISPLACEMENT 273* AMINO SUGARS THROUGH
INTRAMOLECULAR DISPLACEMENTS 279* AMINO SUGARS BY REDUCTIVE AMINATION
279* AMINATION OF GLYCALS 283* AMINATION THROUGH RING-OPENING OF
EPOXIDES 287* SYNTHESIS OF IMINOSUGARS 288* AMINATION AT THE ANOMERIC
CENTER WITH SUBSEQUENT CYCLIZATION 290* EXPLOITATION OF THE REACTIVITY
OF THE CARBONYL FUNCTION 290* EXPLOITATION OF THE REACTIVITY OF LACTONES
291* INSERTION OF A NEW ELECTROPHILE 292* AMINATION AT THE CARBOHYDRATE
CHAIN AND SUBSEQUENT CYCLIZATION 293* CONCOMITANT INSERTION OF NITROGEN
AT BOTH CARBON ATOMS 297* CONCLUSIONS 300* SELECTIVE N-DERIVATIZATION OF
AMINOGLYCOSIDES EN ROUTE TO NEW* ANTIBIOTICS AND ANTIVIRALS 305* FLORIS
LOUIS VAN DELFT* AMINOGLYCOSIDE ANTIBIOTICS REGIOSELECTIVE
N-MODIFICATION OF NATURALLY OCCURRING* 305* RNA TARGETING BY
AMINOGLYCOSIDES 308* THE ROLE OF AMINO FUNCTIONS IN RNA BINDING 310*
DEVELOPMENT OF RNA-TARGETING DMGS 312* AMINOGLYCOSIDES 313* X I CONTENTS
8.4.2 8.5 9* 9.1 9.2 9.2.1 9.2.1.1 9.2.1.2 9.2.1.3 9.2.2 9.2.2.1 9.2.2.2
9.2.2.3 9.2.2.4 9.2.2.5 9.2.2.6 9.2.2.7 9.2.2.8 9.3 9.3.1 9.3.2 9.3.3
9.4 9~1 9.4.2 9.5 9.5.1 9.5.2 9.5.3 9.6 9.7 NEAMINE-BASED RNA LIGANDS
321* CONCLUDING REMARKS 327* EVOLUTION OFTRANSITION METAL*CATALYZED
AMINATION REACTIONS: THE* INDUSTRIAL APPROACH 333* ULRICH SCHOLZ
INTRODUCTION: FIRST STEPS IN THE FIELD OF CATALYTIC AROMATIC AMINATION
333* ALTERNATIVES TO TRANSITION METAL-CATALYZED ARYLAMINATION 335*
REDUCTION OF NITROARENES 335* TRANSFER HYDROGENATION 335* DIRECT
HYDROGENATION 336* OTHER METHODS FOR NITRO REDUCTIONS 336* TRANSITION
METAL-FREE ALTERNATIVES FOR AMINE-HALOGEN EXCHANGE 337* METAL-FREE
REPLACEMENT OF HALOGENS WITH AMINES 337* THE CHICHIBABIN REACTION 338*
THE NUCLEOPHILIC AROMATIC SUBSTITUTION OF HYDROGEN (NASH* REACTION) 339*
AROMATIC AMINATION BY USE OF AZIDES 339* THE MINISCI REACTION 340* THE
BUCHERER REACTION 340* METAL-FREE REPLACEMENT OFNITRO GROUPS BY AMINES
341* METAL-FREE REPLACEMENT OF SULFONIC ACID ESTERS BY AMINES 341* THE
QUEST FOR INDUSTRIAL APPLICATIONS OFTRANSITION METAL-CATALYZED
ARYLAMINATION 341* INDUSTRIAL-SCALE HALOGEN-AMINE EXCHANGES 342*
TRANSITION METAL-CATALYZED DIRECT AMINATION OF AROMATIC* COMPOUNDS 345*
INDUSTRIAL-SCALE AMINOLYSIS OF PHENOLS 345* COPPER-CATALYZED PROCESSES -
MORE RECENT DEVELOPMENTS 346* ALTERNATIVE ARYLATING AGENTS 346* CATALYST
TUNING 347* PALLADIUM-CATALYZED PROCESSES 353* EARLY DEVELOPMENTS 353*
LIGAND DEVELOPMENTS 355* OTHER COMPONENTS OFTHE REACTION 361*
NICKEL-CATALYZED PROCESSES 361* SUMMARY 363* INDEX 377* |
| adam_txt |
CONTENTS PREFACE XI* LIST OF CONTRIBUTORS XII I* SIMPLE MOLECULES,
HIGHLY EFFICIENT AMINATION SHUNSUKE CHIBA AND KOICHI NARASAKA 1.1*
INTRODUCTION 1* 1.2* HYDROXYLAMINE DERIVATIVES 1* 1.2.1*
O-SULFONYLHYDROXYLAMINE 1* 1.2.2* 0-PHOSPHINYLHYDROXYLAMINE 4* 1.2.3*
O-ACYLHYDROXYLAMINE 5* 1.2.4* O-TRIMETHYLSILYLHYDROXYLAMINE 6* 1.2.5*
EXPERIMENTAL PROCEDURES 7* 1.3* OXIME DERIVATIVES 9* 1.3.1* SYNTHESIS OF
PRIMARY AMINES BY ELECTROPHILIC AMINATION OF* CARBANIONS 9* 1.3.2*
EXPERIMENTAL PROCEDURES 13* 1.4* AZO COMPOUNDS 15* 1.4.1*
AZODICARBOXYLATES 15* 1.4.1.1* ALLYLIC AMINATION THROUGH ENE-TYPE
REACTIONS 15* 1.4.1.2* HYDROHYDRAZINATION OF ALKENES 16* 1.4.2* ARYLAZO
SULFONES 19* 1.4.3* EXPERIMENTAL PROCEDURES 20* 1.5* OXAZIRIDINE
DERIVATIVES 23* 1.5.1* ELECTROPHILIC AMINATION OF CARBON NUCLEOPHILES
23* 1.5.2* AMINATION OF ALLYLIC AND PROPARGYLIC SULFIDES BY USE OF A*
KETOMALONATE-DERIVED OXAZIRIDINE 23* 1.5.3* EXPERIMENTAL PROCEDURES 25*
1.6* CHLORAMINE-T 26* 1.6.1* AMINOCHALCOGENATION OF ALKENES 26* 1.6.2*
AMINOHYDROXYLATION OF ALKENES 26* 1.6.3* AZIRIDINATION OF ALKENES 27*
1.6.4* OTHER APPLICATIONS 32* 1.6.5* EXPERIMENTAL PROCEDURES 34* AMINO
GROUP CHEMISTRY. FROM SYNTHESIS TO THE LIFT SEIENEES. EDITED BY ALFREDO
RIECI COPYRIGHT WILEY-VCH VERLAG GMBH & CO. KGAA. WEINHEIM ISBN:
978-3-527-31741-7 VI I CONTENTS 1.7 1.7.1 1.7.2 1.8 1.8.1 1.8.2 1.9
1.9.1 1.9.2 1.9.3 1.9.4 1.10 1.10.1 1.10.2 1.11 2* 2.1 2.2 2.3 2.3.1
2.3.1.1 2.3.1.2 2.3.1.3 2.3.2 2.3.2.1 2.3.2.2 2.4 2.4.1 2.4.2 2.4.3 2.5
2.6 2.6.1 2.6.2 2.6.3 2.7 3* 3.1 3.2 N-SULFONYLIMINOPHENYLIODINANE 35*
TRANSITION METAL-CATALYZED AMINATION OF ALKENES 36* EXPERIMENTAL
PROCEDURES 37* TRANSITION METAL-NITRIDE COMPLEXES 38* NITROGEN ATOM
TRANSFER MEDIATED BY TRANSITION METAL/NITRIDE COMPLEXES 38* EXPERIMENTAL
PROCEDURES 39* AZIDO DERIVATIVES 41* ELECTROPHILIC AMINATION OF
ORGANOMETALLIC REAGENTS WITH ORGANIC AZIDES 42* RADICAL-MEDIATED
AMINATION WITH SULFONYL AZIDES 43* HYDROAZIDATION OF ALKENES WITH
SULFONYL AZIDES 43* EXPERIMENTAL PROCEDURES 44* GABRIEL-TYPE REAGENTS
46* NUCLEOPHILIC AMINATION REACTIONS 46* EXPERIMENTAL PROCEDURE 49*
CONCLUSION 50* CATALYTIC C-H AMINATION WITH NITRENES 55* PHILIPPE DAUBAN
AND ROBERT H. DODD INTRODUCTION 55* HISTORICAL OVERVIEW 56* HYPERVALENT
IODINE-MEDIATED C-H AMINATION 60* INTRAMOLECULAR C-H AMINATION 60* FROM
NHZ CARBAMATES 60* FROM NHZ SULFAMATES 62* FROM OTHER NITROGEN
FUNCTIONALITIES 65* INTERMOLECULAR C-H AMINATION 67* GENERAL SCOPE AND
LIMITATIONS 67* RECENT MAJOR IMPROVEMENTS 70* OTHER NITRENE PRECURSORS
FOR C-H AMINATION 73* AZIDES 73* HALOAMINES 74* CARBAMATE DERIVATIVES
76* AMINATION OF AROMATIC C-H BONDS 77* APPLICATIONS IN TOTAL SYNTHESIS
80* APPLICATION OF INTRAMOLECULAR C-H AMINATION WITH* CARBAMATES 80*
APPLICATION OF INTRAMOLECULAR C-H AMINATION WITH SULFAMATES 83*
APPLICATION OF INTERMOLECULAR C-H AMINATION 87* CONCLUSIONS 88*
NITROALKENES AS AMINATION 100LS 93* ROBERTO BALLINI, ENRICO MARCANTONI,
AND MARINO PETRINI INTRODUCTION 93* GENERAL STRATEGIES FOR THE SYNTHESIS
OF NITROALKENES 93* 3.3 3.3.1 3.3.2 3.3.3 3.3.4 3.4 3.4.1 3.4.2 3.5 3.6
3.7 3.7.1 3.7.2 3.7.3 3.8 3.9 4* 4.1 4.2 4.2.1 4.2.2 4.3 4.4 4.5 4.6 5*
5.1 5.2 5.3 5.4 6* 6.1 6.2 6.2.1 6.2.2 6.2.2.1 6.2.2.2 6.2.2.3 SYNTHESIS
OF ALKYLAMINES 95* PYRROLIZIDINES AND RELATED DERIVATIVES* ARENE-FUSED
NITROGEN HETEROCYCLES* MONOAMINES 95* AMINO ACID DERIVATIVES 98* AMINO
ALCOHOLS 103* DIAMINO DERIVATIVES 106* PYRROLIDINE DERIVATIVES 112*
PYRROLIDINONES 112* PYRROLIDINES 115* PIPERIDINES AND PIPERAZINES 124*
PYRROLOINDOLE DERIVATIVES 132* CONTENTS IVII* 126 132 CARBOLINES AND
THEIR TRYPTAMINE PRECURSORS 132* ARENE-FUSED PIPERIDINE COMPOUNDS 135*
OTHER POLYCYCLIC DERIVATIVES 140* CONCLUSION 144* ISOCYANIDE-BASED
MULTIEOMPONENT REACTIONS (IMCRS) AS A VALUABLE TOOL* WITH WHICH TO
SYNTHESIZE NITROGEN-CONTAINING COMPOUNDS 149* A/EXANDER DOEM/ING
INTRODUCTION 149* THE UGI REACTION 152* INTRAMOLECULAR UGI REACTIONS
INVOLVING TWO FUNCTIONAL GROUPS 158* THE UGI REACTION AND SECONDARY
TRANSFORMATIONS 166* PASSERINI REACTION 171* VAN LEUSEN REACTION 175*
OTHER IMCRS 177* OUTLOOK 180* DIRECT CATALYTIE ASYMMETRIE MANNIEH
REACTIONS AND SURROUNDINGS 185* ARMANDO C6RDOLLA AND RAMON RIAS
INTRODUCTION 185* ORGANOMETALLIC CATALYSTS 186* METAL-FREE
ORGANOCATALYSIS 191* CONCLUSIONS 201* AMINO-BASED BUILDING BLOCKS FOR
THE CONSTRUCTION OF BIOMOLECULES 207* ANDRE MANN* INTRODUCTION 207*
PROPARGYLAMINES (PLAS) 208* SYNTHESIS OF PLAS 209* PLAS IN SYNTHESIS
211* PLAS IN THE SYNTHESIS OF HETEROCYCLES 211* PLAS IN PD(O)-CATALYZED
PROCESSES 211* PLAS IN PERICYCLIC REACTIONS 213* VIII I CONTENTS 6.2.2.4
PLAS IN MULTICOMPONENT REACTIONS (MCRS) 215* 6.2.2.5 PLA IN RADICAL
REACTIONS 217* 6.3 TRANS-4-HYDROXY-(S)-PROLINE (HYP) 217* 6.3.1
STRUCTURAL TRANSFORMATIONS OFHYP 218* 6.3.1.1 C-4 ALKYLATION OF HYP 218*
6.3.1.2 C-4 FLUORINATION AND FLUOROALKYLATION OF HYP 218* 6.3.1.3 C-3
FUNCTIONALIZATION OF HYP 221* 6.3.2 HYP IN THE SYNTHESIS OF BIOMOLECULES
221* 6.3.2.1 HYP IN THE SYNTHESIS OF ALKALOIDS 221* 6.3.2.2 HYP IN THE
SYNTHESIS OF KAINIC ACID DERIVATIVES 222* 6.3.2.3 HYP IN THE SYNTHESIS
OF AMINO SUGARS 222* 6.3.2.4 HEPATITISC INHIBITORS 224* 6.4 L-SERINE
(SER) 224* 6.4.1 SER AND SER DERIVATIVES IN THE SYNTHESIS OF
BIOMOLECULES 225* 6.4.1.1 SER IN THE SYNTHESIS OF CARBOLINES 225*
6.4.1.2 SER IN THE SYNTHESIS OFFURANOMYCIN 226* 6.4.1. 3 SER IN THE
SYNTHESIS OF DIKETOPIPERAZINE ALKALOIDS 226* 6.4.1.4 SER IN THE
SYNTHESIS OFCLEOMYCIN 226* 6.4.1.5 SER IN THE SYNTHESIS OF PIPERIDINE
ALKALOIDS 228* 6.4.1.6 SER IN THE SYNTHESIS OF NONPROTEINOGENIC AMINO
ACIDS 228* 6.4.1.7 SER IN THE SYNTHESIS OFA,A'-DIAMINOACIDS 229* 6.4.1.8
SER IN THE SYNTHESIS OFRIGIDIFIED GLUTAMIC ACID 230* 6.5
4-METHOXYPYRIDINE (MOP) 230* 6.5.1 MOP IN THE SYNTHESIS OF BIOMOLECULES
231* 6.5.1.1 MOP IN THE SYNTHESIS OF ALKALOIDS 231* 6.5.1.2 MOP IN THE
SYNTHESIS OF PLUMERININE 232* 6.5.1.3 MOP IN THE SYNTHESIS
OF2,4-DISUBSTITUTED PIPERIDINES 234* 6.5.1.4 MOP IN THE SYNTHESIS
OFTOXINS 234* 6.5.1.5 MOP IN THE SYNTHESIS OFTROPANES 235* 6.6
AZIRIDINES (AZIS) 236* 6.6.1 AZIS IN THE SYNTHESIS OF BIOMOLECULES 236*
6.6.1.1 AZIS IN THE SYNTHESIS OF 1,2-DIAMINES 236* 6.6.1.2 AZIS IN THE
SYNTHESIS OF A-AMINO ACIDS 237* 6.6.1.3 AZI IN THE SYNTHESIS OF
FERRUGININE, AN ACETYLCHOLINE RECEPTOR 238* 6.6.1.4 AZIS IN THE
SYNTHESIS OFTRYPTOPHAN DERIVATIVES 238* 6.6.1.5 AZIS IN THE SYNTHESIS OF
FUNCTIONALIZED PIPERIDINES 239* 6.6.1.6 AN AZI IN THE SYNTHESIS OF THE
ALKALOID PUMILIOTOXIN 240* 6.6.1.7 AN AZI IN THE SYNTHESIS OF
PHENYLKAINIC ACID 240* 6.6.1.8 AZIS IN THE SYNTHESIS OF PSEUDODISTOMIN
ALKALOIDS 241* 6.7 HOMOALLYLAMINE (HAM) 242* 6.7.1 SYNTHESIS OF HAMS
242* 6.7.2 HAMS IN THE SYNTHESIS OF BIOMOLECULES 243* 6.7.2.1 HAM IN THE
SYNTHESIS OF IMIDAZOAZEPINES 243* 6.7.2.2 HAMS IN THE SYNTHESIS OF
ALKALOIDS 244* 6.7.2.3 HAMS IN THE SYNTHESIS OF PIPERIDINE DERIVATIVES
246* CONTENTS IIX* 6.7.2.4 6.8 6.8.1 6.8.2 6.9 7* 7.1 7.1.1 7.1.2 7.1.3
7.1.4 7.1.5 7.1.6 7.1.7 7.1.8 7.2 7.2.1 7.2.1.1 7.2.1.2 7.2.2 7.2.2.1
7.2.2.2 7.2.2.3 7.2.3 7.2.4 7.3 7.3.1 7.3.1.1 7.3.1.2 7.3.1.3 7.3.2
7.3.3 7.4 8* 8.1 8.2 8.3 8.4 8.4.1 HAMS IN THE SYNTHESIS OF CHIRAL
HETEROCYCLES 247* INDOLE (IND) 247* SYNTHESIS OF INDOLES 248* INDS IN
THE SYNTHESIS OF BIOMOLECULES 251* CONCLUSION 252* AMINATED SUGARS,
SYNTHESIS, AND BIOLOGICAL ACTIVITY 257* FRANCESCO NICOTRA, BARBARA LA
FERLA, AND CRISTINA AIROLDI BIOLOGICAL RELEVANCE OF AMINATED SUGARS 257*
N-ACETYLNEURAMINIC ACID 257* SIALYL LEWIS X 258* TUMOR-ASSOCIATED
ANTIGENS 259* CHITIN AND CHITOSAN 260* BACTERIAL POLYSACCHARIDES 260*
GLYCOSAMINOGLYCANS 261* IMINOSUGARS 262* SUGAR AMINO ACIDS 264*
SYNTHESIS OF AMINATED SUGARS 266* AMINATION AT THE ANOMERIC CENTER 266*
AMINATION EXPLOITING CARBONYL REACTIVITY 267* AMINATION EXPLOITING
OXONIUM ION REACTIVITY 270* AMINATION IN THE SUGAR CHAIN 273* AMINO
SUGARS BY NUCLEOPHILIC DISPLACEMENT 273* AMINO SUGARS THROUGH
INTRAMOLECULAR DISPLACEMENTS 279* AMINO SUGARS BY REDUCTIVE AMINATION
279* AMINATION OF GLYCALS 283* AMINATION THROUGH RING-OPENING OF
EPOXIDES 287* SYNTHESIS OF IMINOSUGARS 288* AMINATION AT THE ANOMERIC
CENTER WITH SUBSEQUENT CYCLIZATION 290* EXPLOITATION OF THE REACTIVITY
OF THE CARBONYL FUNCTION 290* EXPLOITATION OF THE REACTIVITY OF LACTONES
291* INSERTION OF A NEW ELECTROPHILE 292* AMINATION AT THE CARBOHYDRATE
CHAIN AND SUBSEQUENT CYCLIZATION 293* CONCOMITANT INSERTION OF NITROGEN
AT BOTH CARBON ATOMS 297* CONCLUSIONS 300* SELECTIVE N-DERIVATIZATION OF
AMINOGLYCOSIDES EN ROUTE TO NEW* ANTIBIOTICS AND ANTIVIRALS 305* FLORIS
LOUIS VAN DELFT* AMINOGLYCOSIDE ANTIBIOTICS REGIOSELECTIVE
N-MODIFICATION OF NATURALLY OCCURRING* 305* RNA TARGETING BY
AMINOGLYCOSIDES 308* THE ROLE OF AMINO FUNCTIONS IN RNA BINDING 310*
DEVELOPMENT OF RNA-TARGETING DMGS 312* AMINOGLYCOSIDES 313* X I CONTENTS
8.4.2 8.5 9* 9.1 9.2 9.2.1 9.2.1.1 9.2.1.2 9.2.1.3 9.2.2 9.2.2.1 9.2.2.2
9.2.2.3 9.2.2.4 9.2.2.5 9.2.2.6 9.2.2.7 9.2.2.8 9.3 9.3.1 9.3.2 9.3.3
9.4 9~1 9.4.2 9.5 9.5.1 9.5.2 9.5.3 9.6 9.7 NEAMINE-BASED RNA LIGANDS
321* CONCLUDING REMARKS 327* EVOLUTION OFTRANSITION METAL*CATALYZED
AMINATION REACTIONS: THE* INDUSTRIAL APPROACH 333* ULRICH SCHOLZ
INTRODUCTION: FIRST STEPS IN THE FIELD OF CATALYTIC AROMATIC AMINATION
333* ALTERNATIVES TO TRANSITION METAL-CATALYZED ARYLAMINATION 335*
REDUCTION OF NITROARENES 335* TRANSFER HYDROGENATION 335* DIRECT
HYDROGENATION 336* OTHER METHODS FOR NITRO REDUCTIONS 336* TRANSITION
METAL-FREE ALTERNATIVES FOR AMINE-HALOGEN EXCHANGE 337* METAL-FREE
REPLACEMENT OF HALOGENS WITH AMINES 337* THE CHICHIBABIN REACTION 338*
THE NUCLEOPHILIC AROMATIC SUBSTITUTION OF HYDROGEN (NASH* REACTION) 339*
AROMATIC AMINATION BY USE OF AZIDES 339* THE MINISCI REACTION 340* THE
BUCHERER REACTION 340* METAL-FREE REPLACEMENT OFNITRO GROUPS BY AMINES
341* METAL-FREE REPLACEMENT OF SULFONIC ACID ESTERS BY AMINES 341* THE
QUEST FOR INDUSTRIAL APPLICATIONS OFTRANSITION METAL-CATALYZED
ARYLAMINATION 341* INDUSTRIAL-SCALE HALOGEN-AMINE EXCHANGES 342*
TRANSITION METAL-CATALYZED DIRECT AMINATION OF AROMATIC* COMPOUNDS 345*
INDUSTRIAL-SCALE AMINOLYSIS OF PHENOLS 345* COPPER-CATALYZED PROCESSES -
MORE RECENT DEVELOPMENTS 346* ALTERNATIVE ARYLATING AGENTS 346* CATALYST
TUNING 347* PALLADIUM-CATALYZED PROCESSES 353* EARLY DEVELOPMENTS 353*
LIGAND DEVELOPMENTS 355* OTHER COMPONENTS OFTHE REACTION 361*
NICKEL-CATALYZED PROCESSES 361* SUMMARY 363* INDEX 377* |
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| bvnumber | BV023059116 |
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| callnumber-search | QD431 |
| callnumber-sort | QD 3431 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VK 7400 VK 8560 |
| classification_tum | CHE 649f |
| ctrlnum | (OCoLC)191223138 (DE-599)DNB983499144 |
| dewey-full | 572/.65 |
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| dewey-search | 572/.65 |
| dewey-sort | 3572 265 |
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| discipline | Chemie / Pharmazie Biologie Chemie |
| discipline_str_mv | Chemie / Pharmazie Biologie Chemie |
| format | Book |
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| id | DE-604.BV023059116 |
| illustrated | Illustrated |
| index_date | 2024-07-02T19:28:03Z |
| indexdate | 2024-07-20T09:29:07Z |
| institution | BVB |
| isbn | 9783527317417 3527317414 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016262375 |
| oclc_num | 191223138 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-703 DE-19 DE-BY-UBM DE-11 |
| owner_facet | DE-91G DE-BY-TUM DE-703 DE-19 DE-BY-UBM DE-11 |
| physical | XIV, 394 S. graph. Darst. 240 mm x 170 mm |
| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | WILEY-VCH |
| record_format | marc |
| spelling | Amino group chemistry from synthesis to the life sciences ed. by Alfredo Ricci Weinheim WILEY-VCH 2008 XIV, 394 S. graph. Darst. 240 mm x 170 mm txt rdacontent n rdamedia nc rdacarrier Aminoglycosiden gtt Aminogroepen gtt Aminosuikers gtt Aminozuren gtt Biomoleculen gtt Katalyse gtt Nitroverbindingen gtt Symmetrie gtt Amino acids Aminogruppe (DE-588)4326843-2 gnd rswk-swf Aminogruppe (DE-588)4326843-2 s DE-604 Ricci, Alfredo Sonstige oth text/html http://deposit.dnb.de/cgi-bin/dokserv?id=2930742&prov=M&dok_var=1&dok_ext=htm Inhaltstext OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016262375&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Amino group chemistry from synthesis to the life sciences Aminoglycosiden gtt Aminogroepen gtt Aminosuikers gtt Aminozuren gtt Biomoleculen gtt Katalyse gtt Nitroverbindingen gtt Symmetrie gtt Amino acids Aminogruppe (DE-588)4326843-2 gnd |
| subject_GND | (DE-588)4326843-2 |
| title | Amino group chemistry from synthesis to the life sciences |
| title_auth | Amino group chemistry from synthesis to the life sciences |
| title_exact_search | Amino group chemistry from synthesis to the life sciences |
| title_exact_search_txtP | Amino group chemistry from synthesis to the life sciences |
| title_full | Amino group chemistry from synthesis to the life sciences ed. by Alfredo Ricci |
| title_fullStr | Amino group chemistry from synthesis to the life sciences ed. by Alfredo Ricci |
| title_full_unstemmed | Amino group chemistry from synthesis to the life sciences ed. by Alfredo Ricci |
| title_short | Amino group chemistry |
| title_sort | amino group chemistry from synthesis to the life sciences |
| title_sub | from synthesis to the life sciences |
| topic | Aminoglycosiden gtt Aminogroepen gtt Aminosuikers gtt Aminozuren gtt Biomoleculen gtt Katalyse gtt Nitroverbindingen gtt Symmetrie gtt Amino acids Aminogruppe (DE-588)4326843-2 gnd |
| topic_facet | Aminoglycosiden Aminogroepen Aminosuikers Aminozuren Biomoleculen Katalyse Nitroverbindingen Symmetrie Amino acids Aminogruppe |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=2930742&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016262375&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT riccialfredo aminogroupchemistryfromsynthesistothelifesciences |