Polymer dynamics and relaxation:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cambridge [u.a.]
Cambridge Univ. Press
2007
|
| Ausgabe: | 1. publ. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 255 S. Ill., graph. Darst. |
| ISBN: | 9780521814195 |
Internformat
MARC
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| 100 | 1 | |a Boyd, Richard H. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Polymer dynamics and relaxation |c Richard H. Boyd ; Grant D. Smith |
| 250 | |a 1. publ. | ||
| 264 | 1 | |a Cambridge [u.a.] |b Cambridge Univ. Press |c 2007 | |
| 300 | |a X, 255 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Molecular dynamics | |
| 650 | 4 | |a Polymers | |
| 650 | 4 | |a Polymers |x Structure | |
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Datensatz im Suchindex
| _version_ | 1804137239798611968 |
|---|---|
| adam_text | Contents
Preface
page
ix
Part I Methodology
1
1
Mechanical relaxation
3
1.1
Regimes of behavior
3
1.2
Superposition principle
5
1.3
Relaxation modulus
5
1.4
Simple stress relaxation
6
1.5
Dynamic modulus
7
1.6
Interconversion
of stress relaxation and dynamic modulus
9
1.7
Representation of the relaxation function: single relaxation
time (SRT)
11
1.8
Relaxations in polymeric materials tend to be broad
13
1.9
Distribution of relaxation times
14
1.10
Relaxation spectrum from
Er
(í)
15
1.11
Creep compliance
18
1.12
Dynamic compliance
19
1.13
Representation of the retardation function
21
1.14
Summary of the data transformations illustrated
22
Appendix
Al A
brief summary of elasticity
23
References
26
2
Dielectric relaxation
27
2.1
Dielectric permittivity
27
2.2
Measurement of dielectric permittivity
30
2.3
Time dependence of polarization:
reorientation
of permanent dipoles
31
2.4
Polarization and permittivity in time dependent electric fields
33
2.5
Empirical representations of the dielectric permittivity
35
References
43
vi
Contents
3 NMR spectroscopy 44
3.1 NMR
basics
45
3.2
The pulsed NMR method
47
3.3
NMR relaxation measurements
49
3.4
NMR exchange spectroscopy
54
References
56
4
Dynamic neutron scattering
57
4.1
Neutron scattering basics
57
4.2
Time-of-flight
(TOF)
and backscattering QENS
63
4.3
Neutron spin echo (NSE) spectroscopy
66
References
69
5
Molecular dynamics (MD) simulations of amorphous polymers
70
5.1
A brief history of atomistic MD simulations
of amorphous polymers
70
5.2
The mechanics of MD simulations
71
5.3
Studying relaxation processes using atomistic MD simulations
75
5.4
Classical atomistic force fields
76
References
79
Partii
Amorphous polymers
81
6
The primary transition region
83
6.1
Mechanical relaxation
83
6.2
Dielectric relaxation
90
6.3
Mechanical vs. dielectric relaxation
96
6.4
NMR relaxation
104
6.5
Neutron scattering
110
References
118
7
Secondary (subglass) relaxations
120
7.1
Occurrence of mechanical and dielectric secondary processes
120
7.2
Complexity and multiplicity of secondary processes
121
7.3
Flexible side group motion as a source of secondary relaxation
129
7.4
NMR spectroscopy studies of flexible side group motion
138
References
140
8
The transition from melt to glass and its molecular basis
142
8.1
Experimental description
142
8.2
Molecular basis
157
References
194
Partili
Complex systems
197
9
Semi-crystalline polymers
199
9.1
Phase assignment
200
Contents
vii
9.2
Effect of crystal phase presence on amorphous
fraction relaxation
209
9.3
Relaxations in semi-crystalline polymers with a crystal
phase relaxation
214
9.4
NMR insights
223
References
226
10
Miscible
polymer blends
227
10.1
Poly(isoprene)/poly(vinyl
ethylene) (PI/PVE)
blends
228
10.2
Models for
miscible
blend dynamics
229
10.3
MD simulations of model
miscible
blends
233
10.4
PI/PVE blends revisited
239
References
243
Appendix
AI
The Rouse model
244
AI.
1
Formulation and normal modes
244
AI.2 Establishment of Rouse parameters for a real polymer
245
AI.3 The viscoelastic response of a Rouse chain
245
AI.4 Bead displacements and the coherent single-chain
structure factor
246
References
247
Appendix All Site models for localized relaxation
248
All.
1
Dipolar relaxation in terms of site models
248
AII.2 Mechanical relaxation in terms of site models
251
References
252
Index
253
|
| adam_txt |
Contents
Preface
page
ix
Part I Methodology
1
1
Mechanical relaxation
3
1.1
Regimes of behavior
3
1.2
Superposition principle
5
1.3
Relaxation modulus
5
1.4
Simple stress relaxation
6
1.5
Dynamic modulus
7
1.6
Interconversion
of stress relaxation and dynamic modulus
9
1.7
Representation of the relaxation function: single relaxation
time (SRT)
11
1.8
Relaxations in polymeric materials tend to be "broad"
13
1.9
Distribution of relaxation times
14
1.10
Relaxation spectrum from
Er
(í)
15
1.11
Creep compliance
18
1.12
Dynamic compliance
19
1.13
Representation of the retardation function
21
1.14
Summary of the data transformations illustrated
22
Appendix
Al A
brief summary of elasticity
23
References
26
2
Dielectric relaxation
27
2.1
Dielectric permittivity
27
2.2
Measurement of dielectric permittivity
30
2.3
Time dependence of polarization:
reorientation
of permanent dipoles
31
2.4
Polarization and permittivity in time dependent electric fields
33
2.5
Empirical representations of the dielectric permittivity
35
References
43
vi
Contents
3 NMR spectroscopy 44
3.1 NMR
basics
45
3.2
The pulsed NMR method
47
3.3
NMR relaxation measurements
49
3.4
NMR exchange spectroscopy
54
References
56
4
Dynamic neutron scattering
57
4.1
Neutron scattering basics
57
4.2
Time-of-flight
(TOF)
and backscattering QENS
63
4.3
Neutron spin echo (NSE) spectroscopy
66
References
69
5
Molecular dynamics (MD) simulations of amorphous polymers
70
5.1
A brief history of atomistic MD simulations
of amorphous polymers
70
5.2
The mechanics of MD simulations
71
5.3
Studying relaxation processes using atomistic MD simulations
75
5.4
Classical atomistic force fields
76
References
79
Partii
Amorphous polymers
81
6
The primary transition region
83
6.1
Mechanical relaxation
83
6.2
Dielectric relaxation
90
6.3
Mechanical vs. dielectric relaxation
96
6.4
NMR relaxation
104
6.5
Neutron scattering
110
References
118
7
Secondary (subglass) relaxations
120
7.1
Occurrence of mechanical and dielectric secondary processes
120
7.2
Complexity and multiplicity of secondary processes
121
7.3
Flexible side group motion as a source of secondary relaxation
129
7.4
NMR spectroscopy studies of flexible side group motion
138
References
140
8
The transition from melt to glass and its molecular basis
142
8.1
Experimental description
142
8.2
Molecular basis
157
References
194
Partili
Complex systems
197
9
Semi-crystalline polymers
199
9.1
Phase assignment
200
Contents
vii
9.2
Effect of crystal phase presence on amorphous
fraction relaxation
209
9.3
Relaxations in semi-crystalline polymers with a crystal
phase relaxation
214
9.4
NMR insights
223
References
226
10
Miscible
polymer blends
227
10.1
Poly(isoprene)/poly(vinyl
ethylene) (PI/PVE)
blends
228
10.2
Models for
miscible
blend dynamics
229
10.3
MD simulations of model
miscible
blends
233
10.4
PI/PVE blends revisited
239
References
243
Appendix
AI
The Rouse model
244
AI.
1
Formulation and normal modes
244
AI.2 Establishment of Rouse parameters for a real polymer
245
AI.3 The viscoelastic response of a Rouse chain
245
AI.4 Bead displacements and the coherent single-chain
structure factor
246
References
247
Appendix All Site models for localized relaxation
248
All.
1
Dipolar relaxation in terms of site models
248
AII.2 Mechanical relaxation in terms of site models
251
References
252
Index
253 |
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| id | DE-604.BV023020346 |
| illustrated | Illustrated |
| index_date | 2024-07-02T19:12:52Z |
| indexdate | 2024-07-09T21:09:08Z |
| institution | BVB |
| isbn | 9780521814195 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016224426 |
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| physical | X, 255 S. Ill., graph. Darst. |
| publishDate | 2007 |
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| publisher | Cambridge Univ. Press |
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| spelling | Boyd, Richard H. Verfasser aut Polymer dynamics and relaxation Richard H. Boyd ; Grant D. Smith 1. publ. Cambridge [u.a.] Cambridge Univ. Press 2007 X, 255 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Molecular dynamics Polymers Polymers Structure Relaxation (DE-588)4049365-9 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf (DE-588)4173536-5 Patentschrift gnd-content Polymere (DE-588)4046699-1 s Relaxation (DE-588)4049365-9 s DE-604 Smith, Grant D. Verfasser aut Digitalisierung UB Regensburg application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016224426&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Boyd, Richard H. Smith, Grant D. Polymer dynamics and relaxation Molecular dynamics Polymers Polymers Structure Relaxation (DE-588)4049365-9 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4049365-9 (DE-588)4046699-1 (DE-588)4173536-5 |
| title | Polymer dynamics and relaxation |
| title_auth | Polymer dynamics and relaxation |
| title_exact_search | Polymer dynamics and relaxation |
| title_exact_search_txtP | Polymer dynamics and relaxation |
| title_full | Polymer dynamics and relaxation Richard H. Boyd ; Grant D. Smith |
| title_fullStr | Polymer dynamics and relaxation Richard H. Boyd ; Grant D. Smith |
| title_full_unstemmed | Polymer dynamics and relaxation Richard H. Boyd ; Grant D. Smith |
| title_short | Polymer dynamics and relaxation |
| title_sort | polymer dynamics and relaxation |
| topic | Molecular dynamics Polymers Polymers Structure Relaxation (DE-588)4049365-9 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Molecular dynamics Polymers Polymers Structure Relaxation Polymere Patentschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016224426&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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