Thermodynamics of substances inherent in the living matter:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
[Erlangen]
[Druck und Digital]
[2007]
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Bildet Forts. von: Buhler, Peter: Nanothermodynamics |
| Beschreibung: | 203 S. Ill., graph. Darst. |
| ISBN: | 9783932763045 |
Internformat
MARC
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| 008 | 071116s2007 ad|| |||| 00||| eng d | ||
| 020 | |a 9783932763045 |9 978-3-932763-04-5 | ||
| 035 | |a (OCoLC)244292068 | ||
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| 100 | 1 | |a Buhler, Peter |d 1935-2007 |e Verfasser |0 (DE-588)124192831 |4 aut | |
| 245 | 1 | 0 | |a Thermodynamics of substances inherent in the living matter |c Peter Buhler |
| 264 | 1 | |a [Erlangen] |b [Druck und Digital] |c [2007] | |
| 300 | |a 203 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Bildet Forts. von: Buhler, Peter: Nanothermodynamics | ||
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Datensatz im Suchindex
| _version_ | 1804137219763470336 |
|---|---|
| adam_text | Introduction. Formulation
of the problem
7
Part I Thermodynamic introduction
9
Chapter
1
Substance and the laws of thermodynamics
10
1.1.
Definition of substance and the substance composition
10
1.2.
Internal energy is the property of a substance
1
1
1.3.
Internal energy of a substance. First Law of Thermodynamics
11
1.4.
Free energy and entropy of a substance. Second Law of Thermodynamics
12
1.5.
Thermodynamic properties of a substance depend on temperature^ pressure and
surface area
15
1.6.
Changes in the thermodynamic properties of a substance when passing into a
solution. Activity coefficient of a substance
18
1.7.
Transformation of a substance in the course of a chemical reaction
20
1.7.1.
Equilibrium constant of a chemical reaction
21
1.7.2.
Standard energy, standard free energy and standard entropy of a chemical
reaction
22
1.7.3.
Connection of the equilibrium constant to the standard thermodynamic
characteristics of a chemical reaction
22
1.7.4.
Dependence of the equilibrium constant of a chemical reaction on
temperature and the surface areas of the reaction participants
26
Chapter
2
Thermodynamic properties of substance molecules and their
functions
28
2.1.
Principle structure-function of molecules in biochemistry and thermodynamics
28
2.2.
Thermodynamic properties of isomers of organic substances and their phase
transformations
30
2.3.
Thermodynamic properties of a substance and the chemical transformation
36
2.4.
Information system of the nonliving matter
38
Partii
Starting substances of the living matter
42
Chapter
3
Water and aqueous solutions
43
3.1.
Water in living organisms
43
3.2.
Physicochemical properties of water
44
3.3.
Thermodynamic properties of water
45
3.4.
Aqueous solutions
47
3.4.1.
Compositions of aqueous solutions in living organisms
47
3.4.2.
Energy change when dissolving a substance in water
47
3.4.3.
Freezing and boiling temperatures of aqueous solutions
50
3.4.4.
Osmotic pressure
51
3.5.
Surface energy of water and aqueous solutions.
Interphase
energy
52
3.5
Л
.
Surface energy
52
3.5.2.
Interphase
energy
55
3.6.
Water as a nanophase at the surface of a solid
56
3.7.
On the conventional thermodynamics of water and aqueous solutions
57
Chapter
4
Starting substances of biomolecules
61
4.1.
Stages of biochemical evolution
61
4.2.
Chemical elements of the living matter entered initially into the composition of
the nonliving matter
61
4.3.
Specific strategy used by matter when forming the starting substances of
biomolecules
62
4.4.
Thermodynamic analysis of formation reactions for the starting substances of
biomolecules
64
4.4.1.
Amino
acids
64
4.4.2.
Nucleotides
68
4.4.3.
Monosaccharides
74
4.4.4.
Fatty acids and other substances participating in the formation of lipids
76
Chapter
5
Energies of monomers in polymeric molecules
81
5.1.
Principle of monomer formation and the monomer energy
81
5.2.
Energies of
amino
acid monomers
83
5.3.
Energies of nucleotide monomers
84
5.4.
Energies of carbohydrate monomers
86
Part III Biomolecules and a cell
87
Chapter
6
Biomolecules and their energies
88
6.1.
Fraction of chemical elements inherent in the nonliving matter enters into the
composition of the living matter
88
6.2.
Proteins
89
6.2.1.
Energies of protein monomers
90
6.2.2.
Energies of protein molecules
90
6.3.
Nucleic acids
95
6.3.1.
Energies of nucleic acid monomers
97
6.3.2.
Energies of nucleic acid.molecules
99
6.4.
Carbohydrates
102
6.4.1.
Energies of carbohydrate monomers
103
6.4.2.
Energies of carbohydrate molecules
103
6.5.
Lipids and the energies of their molecules
105
Chapter
7
Cell of the living matter
111
7.1.
Living matter consists of cells 111
7.2.
Molecular composition of a cell
112
7.3.
Prerequisites for a transition from atomic and/or molecular form of matter to the
cellular one
113
7.4.
Thermodynamic conditions for the appearance of a membrane filled with aqueous
solution
114
7.5.
Role of porous materials in the evolution of
lipid
membranes
116
7.6.
Self-replication of
RNA
molecules as a start of cellular form of matter
116
Chapter
8
Thermodynamic characterization of a cell
119
8.1.
Comparison of energies of
biomolecule
monomers
119
8.2.
Energy
oraceli
120
8.3.
Energy of oxidation of biomolecules in a cell 1
21
8.4.
Energy of hydrolysis of biomolecules in a cell
125
Chapter
9
Role of energies of biomolecules in transferring the genetic
information
127
9.1.
Replication of
DNA 128
9.2.
Transcription of
RNA
129
9.3.
Translation of proteins
130
9.3.1.
Genetic code
130
9.3.2.
Analysis of energetics of protein translation
132
Part IV Bioenergetics and metabolism
134
Chapter
10
Thermodynamics and bioenergetics
135
10.1.
Energetics of chemical reactions and bioenergetics
135
10.2.
Role of the free energy of a reaction in bioenergetics
139
10.3.
Supply of living matter with energy from environment
141
10.3.1.
Reaction of glucose photosynthesis
141
10.3.2.
Oxidation reactions of inorganic substances
142
Chapter
11
Supplying a cell with energy
145
11.1.
Principle of energy transfer in a cell
145
11.2.
Oxidation of glucose
146
11.2.1.
Glycolysis
146
11.2.2.
Fermentation (anaerobic transformation of pyruvate)
150
11.2.3.
Aerobic oxidation of glycolysis products
150
11.3.
Pentose phosphate pathway
155
11.4.
Oxidation of lipids
158
11.5.
Oxidation of proteins
158
11.6.
Comparison of oxidation energies for glucose, fatty acids and
amino
acids
160
Chapter
12
Biosynthesis of starting substances of biomolecules
161
12.1.
Synthesis of nucleotides
161
12.1.1.
Synthesis of ribonucleotides
162
12.1.2.
Synthesis of deoxyribonueleotides
166
12.2.
Synthesis of
amino
acids
168
12.2.1.
Nitrogen fixation
168
12.2.2.
Thermodynamic analysis of synthesis reactions for
amino
acids
169
12.3.
Synthesis of monosaccharides
176
12.3.1.
Photosynthesis of glucose
176
12.3.2.
Gluconeogenesis
177
12.4.
Synthesis of starting substances of lipids
178
12.4.1.
Synthesis of glycerol-S-phosphate
178
12.4.2.
Synthesis of fatty acids
178
Chapter
13
Synthesis of biomolecules
183
13.1.
Biosynthesis of carbohydrates
183
13.1.1.
Sucrose synthesis
183
13.1.2.
Gly
cogen
synthesis
185
13.1.3.
Starch synthesis
185
13.2.
Biosynthesis of Hpids
186
13.2.1.
Synthesis of triacyIglycerols
186
13.2.2.
Synthesis of phospholipids
187
13.2.3.
Synthesis of sphingolipids
189
13.2.4.
Synthesis of cholesterol
189
13.3.
Biosynthesis of
DNA, RNA
and proteins
191
13.3.1.
Biosynthesis (replication) of
DNA 191
13.3.2.
Biosynthesis (transcription) of
RNA
192
13.3.3.
Biosynthesis (translation) of proteins
192
References
195
Appendices
197
A
1.
Biological oxidizers
197
Al
. 1.
NAD and H2NAD (NAD+ and NADH)
197
Al
2.
FAD and H2FAD (FAD and FADH2)
198
Al
.3.
NADP and H2NADP (NADP+ and NADPH)
198
A2. Coenzyme A (CoA) and acetyl-coenzyme A (acetyl-CoA)
199
A3.
Internal energies of complementary pairs of nucleic acid monomers under
transferring the genetic information
200
A4.
Folate
(F),
Dihydrofolate (DHF), Tetrahydrofolate
(THF)
and
THF
Derivatives
201
A5. Expenditure of energy introduced into the living matter with glucose
photosynthesis (in
kJ
per mole glucose)
202
|
| adam_txt |
Introduction. Formulation
of the problem
7
Part I Thermodynamic introduction
9
Chapter
1
Substance and the laws of thermodynamics
10
1.1.
Definition of substance and the substance composition
10
1.2.
Internal energy is the property of a substance
1
1
1.3.
Internal energy of a substance. First Law of Thermodynamics
11
1.4.
Free energy and entropy of a substance. Second Law of Thermodynamics
12
1.5.
Thermodynamic properties of a substance depend on temperature^ pressure and
surface area
15
1.6.
Changes in the thermodynamic properties of a substance when passing into a
solution. Activity coefficient of a substance
18
1.7.
Transformation of a substance in the course of a chemical reaction
20
1.7.1.
Equilibrium constant of a chemical reaction
21
1.7.2.
Standard energy, standard free energy and standard entropy of a chemical
reaction
22
1.7.3.
Connection of the equilibrium constant to the standard thermodynamic
characteristics of a chemical reaction
22
1.7.4.
Dependence of the equilibrium constant of a chemical reaction on
temperature and the surface areas of the reaction participants
26
Chapter
2
Thermodynamic properties of substance molecules and their
functions
28
2.1.
Principle structure-function of molecules in biochemistry and thermodynamics
28
2.2.
Thermodynamic properties of isomers of organic substances and their phase
transformations
30
2.3.
Thermodynamic properties of a substance and the chemical transformation
36
2.4.
Information system of the nonliving matter
38
Partii
Starting substances of the living matter
42
Chapter
3
Water and aqueous solutions
43
3.1.
Water in living organisms
43
3.2.
Physicochemical properties of water
44
3.3.
Thermodynamic properties of water
45
3.4.
Aqueous solutions
47
3.4.1.
Compositions of aqueous solutions in living organisms
47
3.4.2.
Energy change when dissolving a substance in water
47
3.4.3.
Freezing and boiling temperatures of aqueous solutions
50
3.4.4.
Osmotic pressure
51
3.5.
Surface energy of water and aqueous solutions.
Interphase
energy
52
3.5
Л
.
Surface energy
52
3.5.2.
Interphase
energy
55
3.6.
Water as a nanophase at the surface of a solid
56
3.7.
On the conventional thermodynamics of water and aqueous solutions
57
Chapter
4
Starting substances of biomolecules
61
4.1.
Stages of biochemical evolution
61
4.2.
Chemical elements of the living matter entered initially into the composition of
the nonliving matter
61
4.3.
Specific strategy used by matter when forming the starting substances of
biomolecules
62
4.4.
Thermodynamic analysis of formation reactions for the starting substances of
biomolecules
64
4.4.1.
Amino
acids
64
4.4.2.
Nucleotides
68
4.4.3.
Monosaccharides
74
4.4.4.
Fatty acids and other substances participating in the formation of lipids
76
Chapter
5
Energies of monomers in polymeric molecules
81
5.1.
Principle of monomer formation and the monomer energy
81
5.2.
Energies of
amino
acid monomers
83
5.3.
Energies of nucleotide monomers
84
5.4.
Energies of carbohydrate monomers
86
Part III Biomolecules and a cell
87
Chapter
6
Biomolecules and their energies
88
6.1.
Fraction of chemical elements inherent in the nonliving matter enters into the
composition of the living matter
88
6.2.
Proteins
89
6.2.1.
Energies of protein monomers
90
6.2.2.
Energies of protein molecules
90
6.3.
Nucleic acids
95
6.3.1.
Energies of nucleic acid monomers
97
6.3.2.
Energies of nucleic acid.molecules
99
6.4.
Carbohydrates
102
6.4.1.
Energies of carbohydrate monomers
103
6.4.2.
Energies of carbohydrate molecules
103
6.5.
Lipids and the energies of their molecules
105
Chapter
7
Cell of the living matter
111
7.1.
Living matter consists of cells 111
7.2.
Molecular composition of a cell
112
7.3.
Prerequisites for a transition from atomic and/or molecular form of matter to the
cellular one
113
7.4.
Thermodynamic conditions for the appearance of a membrane filled with aqueous
solution
114
7.5.
Role of porous materials in the evolution of
lipid
membranes
116
7.6.
Self-replication of
RNA
molecules as a start of cellular form of matter
116
Chapter
8
Thermodynamic characterization of a cell
119
8.1.
Comparison of energies of
biomolecule
monomers
119
8.2.
Energy
oraceli
120
8.3.
Energy of oxidation of biomolecules in a cell 1
21
8.4.
Energy of hydrolysis of biomolecules in a cell
125
Chapter
9
Role of energies of biomolecules in transferring the genetic
information
127
9.1.
Replication of
DNA 128
9.2.
Transcription of
RNA
129
9.3.
Translation of proteins
130
9.3.1.
Genetic code
130
9.3.2.
Analysis of energetics of protein translation
132
Part IV Bioenergetics and metabolism
134
Chapter
10
Thermodynamics and bioenergetics
135
10.1.
Energetics of chemical reactions and bioenergetics
135
10.2.
Role of the free energy of a reaction in bioenergetics
139
10.3.
Supply of living matter with energy from environment
141
10.3.1.
Reaction of glucose photosynthesis
141
10.3.2.
Oxidation reactions of inorganic substances
142
Chapter
11
Supplying a cell with energy
145
11.1.
Principle of energy transfer in a cell
145
11.2.
Oxidation of glucose
146
11.2.1.
Glycolysis
146
11.2.2.
Fermentation (anaerobic transformation of pyruvate)
150
11.2.3.
Aerobic oxidation of glycolysis products
150
11.3.
Pentose phosphate pathway
155
11.4.
Oxidation of lipids
158
11.5.
Oxidation of proteins
158
11.6.
Comparison of oxidation energies for glucose, fatty acids and
amino
acids
160
Chapter
12
Biosynthesis of starting substances of biomolecules
161
12.1.
Synthesis of nucleotides
161
12.1.1.
Synthesis of ribonucleotides
162
12.1.2.
Synthesis of deoxyribonueleotides
166
12.2.
Synthesis of
amino
acids
168
12.2.1.
Nitrogen fixation
168
12.2.2.
Thermodynamic analysis of synthesis reactions for
amino
acids
169
12.3.
Synthesis of monosaccharides
176
12.3.1.
Photosynthesis of glucose
176
12.3.2.
Gluconeogenesis
177
12.4.
Synthesis of starting substances of lipids
178
12.4.1.
Synthesis of glycerol-S-phosphate
178
12.4.2.
Synthesis of fatty acids
178
Chapter
13
Synthesis of biomolecules
183
13.1.
Biosynthesis of carbohydrates
183
13.1.1.
Sucrose synthesis
183
13.1.2.
Gly
cogen
synthesis
185
13.1.3.
Starch synthesis
185
13.2.
Biosynthesis of Hpids
186
13.2.1.
Synthesis of triacyIglycerols
186
13.2.2.
Synthesis of phospholipids
187
13.2.3.
Synthesis of sphingolipids
189
13.2.4.
Synthesis of cholesterol
189
13.3.
Biosynthesis of
DNA, RNA
and proteins
191
13.3.1.
Biosynthesis (replication) of
DNA 191
13.3.2.
Biosynthesis (transcription) of
RNA
192
13.3.3.
Biosynthesis (translation) of proteins
192
References
195
Appendices
197
A
1.
Biological oxidizers
197
Al
. 1.
NAD and H2NAD (NAD+ and NADH)
197
Al
2.
FAD and H2FAD (FAD and FADH2)
198
Al
.3.
NADP and H2NADP (NADP+ and NADPH)
198
A2. Coenzyme A (CoA) and acetyl-coenzyme A (acetyl-CoA)
199
A3.
Internal energies of complementary pairs of nucleic acid monomers under
transferring the genetic information
200
A4.
Folate
(F),
Dihydrofolate (DHF), Tetrahydrofolate
(THF)
and
THF
Derivatives
201
A5. Expenditure of energy introduced into the living matter with glucose
photosynthesis (in
kJ
per mole glucose)
202 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Buhler, Peter 1935-2007 |
| author_GND | (DE-588)124192831 |
| author_facet | Buhler, Peter 1935-2007 |
| author_role | aut |
| author_sort | Buhler, Peter 1935-2007 |
| author_variant | p b pb |
| building | Verbundindex |
| bvnumber | BV022969015 |
| classification_rvk | VE 6000 |
| classification_tum | PHY 822f CHE 170f PHY 051f |
| ctrlnum | (OCoLC)244292068 (DE-599)BVBBV022969015 |
| dewey-full | 572.436 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 572 - Biochemistry |
| dewey-raw | 572.436 |
| dewey-search | 572.436 |
| dewey-sort | 3572.436 |
| dewey-tens | 570 - Biology |
| discipline | Chemie / Pharmazie Physik Biologie Chemie |
| discipline_str_mv | Chemie / Pharmazie Physik Biologie Chemie |
| format | Book |
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| genre | (DE-588)4151278-9 Einführung gnd-content |
| genre_facet | Einführung |
| id | DE-604.BV022969015 |
| illustrated | Illustrated |
| index_date | 2024-07-02T19:07:47Z |
| indexdate | 2024-07-09T21:08:49Z |
| institution | BVB |
| isbn | 9783932763045 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016173295 |
| oclc_num | 244292068 |
| open_access_boolean | |
| owner | DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-12 DE-29 DE-188 |
| owner_facet | DE-355 DE-BY-UBR DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-12 DE-29 DE-188 |
| physical | 203 S. Ill., graph. Darst. |
| publishDate | 2007 |
| publishDateSearch | 2007 |
| publishDateSort | 2007 |
| publisher | [Druck und Digital] |
| record_format | marc |
| spelling | Buhler, Peter 1935-2007 Verfasser (DE-588)124192831 aut Thermodynamics of substances inherent in the living matter Peter Buhler [Erlangen] [Druck und Digital] [2007] 203 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Bildet Forts. von: Buhler, Peter: Nanothermodynamics Thermodynamik (DE-588)4059827-5 gnd rswk-swf Biomolekül (DE-588)4135124-1 gnd rswk-swf (DE-588)4151278-9 Einführung gnd-content Thermodynamik (DE-588)4059827-5 s DE-604 Biomolekül (DE-588)4135124-1 s b DE-604 Digitalisierung UB Regensburg application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016173295&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Buhler, Peter 1935-2007 Thermodynamics of substances inherent in the living matter Thermodynamik (DE-588)4059827-5 gnd Biomolekül (DE-588)4135124-1 gnd |
| subject_GND | (DE-588)4059827-5 (DE-588)4135124-1 (DE-588)4151278-9 |
| title | Thermodynamics of substances inherent in the living matter |
| title_auth | Thermodynamics of substances inherent in the living matter |
| title_exact_search | Thermodynamics of substances inherent in the living matter |
| title_exact_search_txtP | Thermodynamics of substances inherent in the living matter |
| title_full | Thermodynamics of substances inherent in the living matter Peter Buhler |
| title_fullStr | Thermodynamics of substances inherent in the living matter Peter Buhler |
| title_full_unstemmed | Thermodynamics of substances inherent in the living matter Peter Buhler |
| title_short | Thermodynamics of substances inherent in the living matter |
| title_sort | thermodynamics of substances inherent in the living matter |
| topic | Thermodynamik (DE-588)4059827-5 gnd Biomolekül (DE-588)4135124-1 gnd |
| topic_facet | Thermodynamik Biomolekül Einführung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016173295&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT buhlerpeter thermodynamicsofsubstancesinherentinthelivingmatter |