Nanoparticles and catalysis:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Weinheim
WILEY-VCH
2008
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XXIII, 640 S. Ill., graph. Darst. |
| ISBN: | 9783527315727 3527315721 |
Internformat
MARC
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| 020 | |a 3527315721 |c Gb. : ca. EUR 299.00 (freier Pr.), ca. sfr 472.00 (freier Pr.) |9 3-527-31572-1 | ||
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| 084 | |a CHE 167f |2 stub | ||
| 245 | 1 | 0 | |a Nanoparticles and catalysis |c ed. by Didier Astruc |
| 264 | 1 | |a Weinheim |b WILEY-VCH |c 2008 | |
| 300 | |a XXIII, 640 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Catalysis | |
| 650 | 4 | |a Nanoparticles | |
| 650 | 0 | 7 | |a Katalyse |0 (DE-588)4029921-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Nanopartikel |0 (DE-588)4333369-2 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Nanopartikel |0 (DE-588)4333369-2 |D s |
| 689 | 0 | 1 | |a Katalyse |0 (DE-588)4029921-1 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Astruc, Didier |e Sonstige |0 (DE-588)112945058 |4 oth | |
| 856 | 4 | 2 | |q text/html |u http://deposit.dnb.de/cgi-bin/dokserv?id=2930862&prov=M&dok_var=1&dok_ext=htm |3 Inhaltstext |
| 856 | 4 | 2 | |m OEBV Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016163080&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-016163080 | |
Datensatz im Suchindex
| _version_ | 1805089613299056640 |
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* * * * * * * * * ******** ****** LIST O F C O N T R I B U T O R S X
I X * 1 * T R A N S I T I O N - M E T A L N A N O P A R T I C L
E S IN C A T A L Y S I S : F R O M H I S T O R I C A L *
BACKGROUND T O T H E S T A T E - O F - T H E A R T 1 *
DIDIER ASTRUC 1.1* I N T R O D U C T I O N 1 * 1.2* HISTORICAL B A
C K G R O U N D 4 * 1.3* POLYMERS AS NP S T A B I L I Z E R S 7
* 1.4* D E N D R I M E R S AS NP S T A B I L I Z E R S 11* 1.5*
LIGAND S T A B I L I Z A T I O N O F N P S 16* 1.6*
"LIGAND-FREE" H E C K R E A C T I O N S U S I N G LOW
PD-LOADING 18* 1.7* T H E ROLES O F MICELLES, M I C R O E M U L S
I O N S , S U R F A C T A N T S A N D A E R O G E L S 20*
1.8* L O N K LIQUID MEDIA FOR C A T A L Y S I S BY NPS 22* 1.9*
OXIDE S U P P O R T S FOR NP C A T A L Y S T S 24* 1.10* CARBON S
U P P O R T S FOR NP C A T A L Y S T S 28* 1.11* NPS O F NOBLE
M E T A L S (RU, RH, P D , P T A N D T H E I R OXIDES) I
N * CATALYSIS 3 0 * 1.12* GOLD N A N O P A R T I C I E - B A S E D
C A T A L Y S T S 3 0 * 1.13* E N V I R O N M E N T A L P R
O B L E M S : NOX P O L L U T I O N A N D H O W TO R E M O V
E NOX* USING N P CATALYSIS 34* 1.14* H Y D R O C A R B O N R E
F O R M I N G : A C T I V A T I O N O F H Y D R O C A R B O N S
BY NP* CATALYSTS 34* 1.15* SURFACE O R G A N O M E T A L L I C C H
E M I S T R Y O N M E T A L NPS 36* 1.16* APPLICATION A N D
P E R S P E C T I V E S I N O R G A N I C C H E M I S T R Y
36* 1.17* C O N C L U S I O N 3 7 * NANOPARTIELES AND CATAYSIS.
E D I T E D BY D I D I E R A S T R U C C O P Y R I G H T
2008 WILEY*VCH V E R L A G G M B H & C O . KGAA, W E I
N H E I M ISBN: 9 7 8 * 3 * 5 2 7 * 3 1 5 7 2 - 7 VI I CONTENTS 2
* 2.1 2.2 2.3 2.3.1 2.3.1.1 2 . 3 . 1 . 2 2.3.2 2.3.2.1 2.3.2.2
2.3.2.3 2.3.3 2.4 2.4.1 2.4.2 2.4.2.1 2 . 4 . 3 2.4.3.1 2.4.3.2 2.5 3
* 3.1 3.2 3.2.1 3.2.1.1 3.2.1.1.1 3.2.1.1.2 3.2.1.2 3.2.1.3 3.2.2 3.3
4 * 4.1 4.1.1 4.1.2 4.1.3 C O L L O I D A L N A N O P A R T I C L
E S STABILIZED BY SURFACTANTS OR* O R G A N O - A L U M I N U M
DERIVATIVES : PREPARATION AND USE AS CATALYST* PRECURSORS 4 9 *
HELMUT BOENNEMANN, KYATANAHALLI 5. NAGABHUSHANA, AND* RYAN M. RICHARDS* B
A C K G R O U N D 4 9 * G E N E R A L I N T R O D U C T I O N
5 0 * S Y N T H E T I C M E T H O D O L O G I E S 55* S T A
B I L I Z A T I O N V I A S U R F A C T A N T S 55* O R G A N O
S O L S 55* H Y D R O S O L S 5 8 * " R E D U C T I V E S T
A B I L I Z A T I O N " W I T H A L U M I N U M ALKYLS 5 9 *
O R G A N O S O L S 5 9 * H Y D R O S O L S 6 0 * F O R M A
T I O N O F N A N O P A R T I D E N E T W O R K S 63* S H A
P E - S E L E C T I V E P A R T I C L E S Y N T H E S I S 65* A
P P L I C A T I O N S I N C A T A L Y S I S 66* Q U A S I - H O
M O G E N E O U S C A T A L Y S T S 67* H E T E R O G E N E O U S
C A T A L Y S T S 67* T H E " P R E C U R S O R C O N C E P
T " 68* A P P L I C A T I O N S 71* F I N E C H E M I C A L S
71* E L E C T R O C A T A L Y S I S 73* M I S C E L L A N E O U S
A P P L I C A T I O N S A N D F U T U R E O U T L O O K
83* N A N O P A R T I C U L A T E CATALYSTS BASED ON NANOSTRUCTURED
POLYMERS 93* LYUDMILA M. BRONSTEIN, VALENTINA G. MATVEELLA, AND ESTHER
M. SULMAN* N A N O P A R T I C U L A T E C A T A L Y S T S F O R M
E D I N H I G H L Y - F U N C T I O N A L I Z E D P O L Y M E R
* I N T R O D U C T I O N 93* C A T A L Y T I C N A N O P A R T
I C 1 E S I N A N A N O S T R U C T U R E D E N V I R O N M
E N T 96* H Y D R O G E N A T I O N W I T H C A T A L Y T I C
N A N O P A R T I C L E S 96* BLOCK C O P O L Y M E R - B A S E D
C A T A L Y S T S 96* P S - B - P 4 V P - B A S E D C A T A L Y
S T S 96* P E O * B - P 4 V P - B A S E D C A T A L Y S T S
104* N A N O P A R T I C U L A T E C A T A L Y S T S F O R M E D
VIA M I C R O G E L T E M P L A T I N G 1 1 0 * C O L L O I
D S 112* O X I D A T I O N W I T H C A T A L Y T I C N A N O
P A R T I C L E S 115* C O N C L U S I O N S A N D O U T L O O
K 123* P A M A M D E N D R I M E R T E M P L A T E D N A N O
P A R T I C L E CATALYSTS 1 2 9 * BERT D. CHANDLER AND JOHN D.
GILBERTSON* I N T R O D U C T I O N A N D B A C K G R O U N D
129* T R A D I T I O N A L R O U T E S T O H E T E R O G E N E
O U S C A T A L Y S T S 1 2 9 * M O L E C U L A R C L U S T
E R A N D C O L L O I D R O U T E S 1 3 0 * P A M A M
D E N D R I M E R S 131* CONTENTS IVII* 4.2* SYNTHESIS AND
CHARACTERIZATION OF DENDRIMER ENCAPSULATED* NANOPARTICLES 132* 4.2.1*
SYNTHETIC SCHEMES AND NOMENCLATURE 132* 4.2.2* BIMETALLIC NANOPARTICLES
133* 4.2.3* CORE-SHELL NANOPARTICLES 135* 4.2.4* CHARACTERIZATION 136*
4.3* HOMOGENEOUS CATALYSIS 139* 4.3.1* MONOMETALLIC CATALYSTS 139*
4.3.2* BIMETALLIC CATALYSTS 140* 4.4* SUPPORTED DENDRIMER TEMPLATED
NANOPARTICLES 142* 4.4.1* IMMOBILIZED INTACT DENS 143* 4.4.1.1*
ELECTROCATALYSIS BY IMMOBILIZED INTACT DENS 143* 4.4.1.2* CONSTRUCTION
OF DENS ON OXIDE SURFACES 144* 4.4.1.3* DEN DEPOSITION ONTO OXIDE
SUPPORTS 145* 4.4.2* HIGH TEMPERATURE DENDRIMER REMOVAL 145* 4.4.2.1*
MODELS FOR DENDRIMER REMOVAL 148* 4.4.2.2* LOW TEMPERATURE DENDRIMER
REMOVAL 149* 4.4.3* MONOMETALLIC DENDRIMER TEMPLATED NANOPARTICLE
CATALYSTS 151* 4.4.4* SUPPORTED BIMETALLIC DENDRIMER TEMPLATED
NANOPARTICLES 152* 4.4.4.1* INFRARED SPECTROSCOPY OF SUPPORTED
BIMETALLIC DENDRIMER TEMPLATED* NANOPARTICLES 152* 4.4.4.2* CATALYSIS BY
SUPPORTED BIMETALLIC DENDRIMER TEMPLATED* NANOPARTICLES 153* 4.5*
SUMMARY, OUTLOOK, AND LINKS BETWEEN HOMOGENEOUS AND* HETEROGENEOUS
CATALYSIS 156* 5* AEROGEL SUPPORTED NANOPARTICLES IN CATALYSIS 161*
ADELINA VA/LRIBERA AND FLIES MOLINS 5.1* INTRODUCTION 161* 5.2* AEROGEL
NANOCOMPOSITES AS CATALYSTS OF IMPORTANT REACTIONS IN* GASEOUS MEDIA
166* 5.2.1* FISCHER-TROPSCH SYNTHESIS 166* 5.2.2 STEAM REFORMING 166*
5.2.3 OXIDATION PROCESSES 167* . 5.2.3.1* OXIDATION OF CARBON MONOXIDE
167* 5.2.3.2* METHANOLOXIDATION 168* 5.2.3.3* N-BUTANE OXIDATION 168*
5.2.3.4* VOLATILE ORGANIC COMPOUNDS OXIDATION 169* 5.2.4*
DEHYDROCHLORINATION OF CHLORINATED VOLATILE ORGANIC* COMPOUNDS 170*
5.2.5* OXYGEN REDUCTION REACTION 170* 5.2.6* CYCLOHEXENE HYDROGENATION
172* 5.2.7* ISOMERIZATION OF 1-BUTENE 173* 5.3* AEROGEL NANOCOMPOSITES
AS CATALYSTS OF IMPORTANT REACTIONS IN* LIQUID MEDIA 173* VIII I
CONTENTS 5.3.1* OXIDATION OF OLEFINS 173* 5.3.1.1* DIHYDROXYLATION OF
OLEFINS 173* 5.3.1.2* EPOXIDATION OF OLEFINS 176* 5.3.2* CLAISEN-SCHMIDT
CONDENSATION 179* 5.3.3* MIZOROKI-HECK C-C COUPLING REACTIONS 179*
5.3.4* HYDROCARBONYLATION OF ARYL HALIDES 185* 5.3.5* MICHAEL ADDITIONS
187* 5.3.6* SYNTHESIS OF CARBON NANOTUBES 190* 6* TRANSITION-METAL
NANOPARTICLE CATALYSIS IN IMIDAZOLIUM LONK* LIQUIDS 195* JAIRTON DUPONT
AND DAGOBERTO DE OLIVEIRA SI/VA 6.1* INTRODUCTION 195* 6.2* LONIC
LIQUIDS: STRUCTURAL ASPECTS 196* 6.3* FORMATION OF NANOPARTICLES IN
LMIDAZOLIUM LONIC LIQUIDS 198* 6.4* STABILIZATION OF THE METAL
NANOPARTIDES IN IMIDAZOLIUM IONIC* LIQUIDS 202* 6.4.1* ANALYSIS OF THE
ISOLATED NANOPARTIC1ES (XRD AND XPS) 203* 6.4.2 ANALYSIS OF THE MNPS
DISPERSED IN LONIC LIQUIDS 204* 6,4.3 H{D AND D{H LABELING EXPERIMENTS
207* 6,4,4 MNPS IN LONIC LIQUID{ADDITIVE LIGANDS OR POLYMERIE
STABILIZERS 207* 6.5* CATALYTIC PROPERTIES OFTRANSITION-METAL
NANOPARTICLES IN LONIC* LIQUIDS 208* 6.5.1* HYDROGENATION OF ALKENES AND
KETONES 209* 6.5.2* HYDROGENATION OF KETONES 211* 6.5.3* HYDROGENATIONS
OF ARENES 211* 6.5.4* MISCELLANEOUS REACTIONS 213* 6.6* CONCLUSIONS AND
PERSPECTIVES 213* 7* CARBON AND SILICON CARBIDE NANOTUBES CONTAINING
CATALYSTS 219* CUONG PHAM-HUU, OVIDIU ERSEN, AND MARC-JACQUES LEDOUX
7.1* INTRODUCTION 219* 7.2* CARBON AND SIC NANOTUBES/NANOFIBERS 221*
7.2.1* CARBON NANOTUBES AND NANOFIBERS 221* 7.2.2* DIRECT MACROSCOPIC
SHAPING OF CARBON NANOTUBES 226* 7.2.2.1* SELF.SUPPORTED CARBON
NANOTUBES THROUGH CONSTRAINT* SYNTHESIS 226* 7.2.2.2* PARALLEL AND
PATTERNED CARBON NANOTUBES BY PYROLYSIS OF ORGANIC* COMPOUNDS 228*
7.2.2.3* CARBON NANOTUBES GROWTH ON PERIODICALLY PATTEMED* STRUCTURE
230* 7.2.3* STRUCTURAL ORDERING ASSISTED BY THERMAL TREATMENT 232*
7.2.4* SIC NANOTUBES AND NANOFIBERS 234* 7.3* ONE-DIMENSIONAL CONDUCTIVE
MATERIALS FOR CATALYSIS 235* 7.3.1* CARBON NANOTUBES CONTAINING
NANOPARTICLE CATALYSTS 236* 7.3.1.1 7.3.1.2 7.3.1.3 7.3.1.4 7.3.2
7.3.2.1 7.4 7.5 8* 8.1 8.1.1 8.2 8.3 8.4 9* 9.1 9.2 9.2.1 9.2.2 9.2.3
9.2.4 9.3 9.3.1 9.3.2 9.3.2.1 9.3.2.2 9.3.3 9.3.3.1 9.3.3.2 9.3.3.3
CORLTENTS IIX* PD/CNTS CATALYST CHARACTERISTICS 236* SELECTIVE
HYDROGENATION OF NITROBENZENE TO ANILINE IN THE LIQUID* SELECTIVE
OXIDATIVE DEHYDROGENATION (ODH) OF DIHYDROANTHRACENE TO* HYDROGENATION
OF THE C=C BOND IN THE LIQUID PHASE 241* PHASE 242* ANTHRACENE 243* SIC
NANOTUBES CONTAINING NANOPARTICLES CATALYSTS 246* SELECTIVE OXIDATION OF
H 2 S TO ELEMENTAL SULFUR IN A TRICKLE-BED 246* CONCLUSION 247* OUTLOOK
249* SIZE-SELECTIVE SYNTHESIS OF NANOSTRUCTURED METAL AND METAL OXIDE*
COLLOIDS AND THEIR USE AS CATALYSTS 253* MANFRED T. REETZ INTRODUCTION
253* GENERAL COMMENTS ON CATALYSIS USING TRANSITION METAL* SIZE- AND
SHAPE-SELECTIVE PREPARATION OF METAL NANOPARTICLES IN THE* NANOPARTICLES
253* ZEROVALENT FORM 254* PREPARATION AND APPLICATION OF AQUEOUS
COLLOIDS OF METAL OXIDE AND* MULTIMETAL OXIDE NANOPARTICLES 264*
CONCLUSION 272* MULTIMETALLIC NANOPARTICLES PREPARED BY REDOX PROCESSES
APPLIED IN* CATALYSIS 279* F/ORENCE EPRON, CATHERINE ESPECE/, GWENDO/INE
LAFAYE, AND PATRICE MARECOT INTRODUCTION 279* GENERAL ASPECTS 279*
PREPARATION OF BIMETALLIC CATALYSTS BY DIRECT REDOX* REDOX REACTIONS OF
ADSORBED SPECIES IN THE PREPARATION OF BIMETALLIC* REACTION 280*
CATALYSTS 281* CATALYTIC REDUCTION IN THE PREPARATION OF BIMETALLIC
CATALYSTS 282* UNDERPOTENTIAL DEPOSITION 282* PRACTICAL ASPECTS 283*
STABILITY OF SUPPORTED CATALYSTS IN THE AQUEOUS PHASE 283* STUDY OF THE
DEPOSITION REACTION 285* ON BULK CATALYSTS 285* ON SUPPORTED CATALYSTS
286* CHARACTERIZATION OF THE METAL-METAL INTERACTION 288* MODEL
REACTIONS 288* ADSORPTION OF PROBE MOLECULES 288* PHYSICAL TECHNIQUES
289* XI CONTENTS 9.3.4 9.4 9.4.1 9.4.1.1 9.4.1.2 9.4.2 9.5 9.6 9.6.1
9.6.2 9.7 10* 10.1 10.2 10.2.1 10.2.2 10.3 10.3.1 10.3.2 10.4 10.5
10.5.1 10.5.2 10.5.2.1 10.5.2.2 10.5.3 10.5.3.1 10.5.3.2 10.5.3.3 10.5.4
10.5.5 10.5.5.1 10.6 INFTUENCE OF THE GASEOUS ENVIRONMENT ON THE
NANOPARTICLE STABILITY 291* APPLICATIONS IN THE SYNTHESIS OF ORGANIC
CHEMICALS 292* SELECTIVE HYDROGENATION 292* COMPETITION BETWEEN C=C AND
C=O BONDS 293* COMPETITION BETWEEN C=C BONDS 295* SELECTIVE
HYDROGENOLYSIS 295* APPLICATIONS IN ENVIRONMENTAL CATALYSIS 296*
APPLICATIONS IN CATALYSIS FOR ENERGY 297* NAPHTHA REFORMING 297* FUEL
CELLS 299* CONC1USION 300* THE ROLE OF PALLADIUM NANOPARTICLES AS
CATALYSTS FAR CARBON-CARBON* COUPLING REACTIONS 303* LAURENT DJAKOVITCH,
KLAUS KOEHLER, ANDJOHANNES G. DE VRIES* LIGAND-FREE PALLADIUM AS CATALYST
IN OTHER C-C BOND FORMING* PALLADACYCLES, PINCERS AND OTHER PALLADIUM
COMPLEXES AS PRECURSORS* PALLADIUM SUPPORTED ON SOLIDS AS CATALYSTS FOR
CARBON-CARBON* HECK COUPLING BY SUPPORTED (SOLID) PD CATALYSTS -
GENERAL* PROGRESS IN HECK REACTIONS CATALYZED BY PALLADIUM* SUPPORTED ON
SOLIDS - ACTIVATION OF BROMOBENZENE AND ARYL* MECHANISTIC ASPECTS OF
HECK (AND RELATED) REACTIONS BY* (SUPPORTED) NANOPARTICLES: HOMOGENEOUS
OR HETEROGENEOUS* INTRODUCTION 303* STABLE PALLADIUM COLLOIDS AND
NANOPARTICLES 303* PALLADIUM COLLOIDS IN THE HECK REACTION 305*
PALLADIUM COLLOIDS IN OTHER C-C COUPLING REACTIONS 314* LIGAND.FREE
PALLADIUM CATALYSTS 316* THE LIGAND-FREE HECK REACTION 316* REACTIONS
321* OF PALLADIUM NANOCLUSTERS 323* COUPLING REACTIONS 327* MOTIVATION
328* CHLORIDES 329* HECK REACTIONS OF NON*ACTIVATED ARYL BROMIDES 330*
REACTIONS OF ARYL CBLORIDES 332* CONC1USIONS FROM THE LITERATURE REPORTS
334* PROPERTIES OF THE CATALYST 334* IMPORTANCE OF REACTION CONDITIONS
334* POTENTIAL FOR PRACTICAL APPLICATIONS 335* SUPPORTED PALLADIUM
CATALYSTS IN OTHER COUPLING REACTIONS 335* CATALYSIS? 336* MECHANISTIC
CYDE 340* CONCLUSIONS 342* CONTENTS IXI* 11 11.1 11.2 11.3 11.3.1
11.3.1.1 11.3.1.1.1 11.3.1.1.2 11.3.1.1.3 11.3.1.2 11.3.1.2.1 11.3.1.2.2
11.3.1.3 11.3.1.4 11.3.1.4.1 11.3.1.4.2 11.3.1.5 11.3.1.5.1 11.3.1.5.2
11.3.1.6 11.3.1.6.1 11.3.1.6.2 11.3.2 11.3.3 11.4 11.4.1 11.4.2 11.4.3
11.4.4 11.5 11.5.1 11.5.2 11.5.3 11.6 12* 12.1 12.2 12.2.1 12.2.2 12.2.3
RHODIUM AND RUTHENIUM NANOPARTICLES IN CATALYSIS 349* ALAIN ROUCOUX,
AUDREY NOWICKI, AND KARINE PHILIPPOT LNTRODUCTION 349* GENERALITIES ON
THE SYNTHESIS AND THE STABILIZATION MODES OF* RH AND RU NANOPARTICLES AS
CATALYSTS IN HYDROGENATION* NANOPARTICLES 350* REACTIONS 351*
HYDROGENATION OF UNSATURATED HYDROCARBONS 352* POLYMER STABILIZED RH AND
RU NANOPARTICLES 352* HYDROGENATION OF COMPOUNDS WITH C=C BONDS 352*
HYDROGENATION OF COMPOUNDS WITH C=C BONDS 353* HYDROGENATION OF AROMATIC
COMPOUNDS 354* SURFACTANT-STABILIZED RH AND RU NANOPARTICLES 354*
HYDROGENATION OF COMPOUNDS WITH C=C BONDS 354* HYDROGENATION OF AROMATIC
COMPOUNDS 356* LIGAND-STABILIZED RH AND RU NANOPARTICLES 363*
POLYOXOANION-STABILIZED RH AND RU NANOPARTICLES 365* HYDROGENATION OF
COMPOUNDS WITH C=C BONDS 366* HYDROGENATION OF AROMATIC COMPOUNDS 366*
LONIC LIQUIDS-STABILIZED RH AND RU NANOPARTICLES 366* HYDROGENATION OF
COMPOUNDS WITH C=C BONDS 366* HYDROGENATION OF AROMATIC COMPOUNDS 367*
DENDRIMER- OR CYCLODEXTRIN-STABILIZED RH AND RU NANOPARTICLES 368*
DENDRIMER-STABILIZED RH AND RU NANOPARTICLES 368*
CYCLODEXTRIN-STABILIZED RH AND RU NANOPARTICLES 369* HYDROGENATION OF
COMPOUNDS WITH C=O BONDS 371* HYDROGENATION OF AROMATIC NITRO COMPOUNDS
376* CATALYTIC FORMATION OF C-C BONDS 377* HYDROFORMYLATION OF OLEFINS
378* METHANOL CARBONYLATION 379* COUPLING REACTIONS 380*
PAUSON-KHANDREACTION 381* OTHER REACTIONS 382* HYDROCARBON OXIDATION
382* DEHYDROCOUPLING OF AMINE-BORANE ADDUCTS 382* HYDROSILYLATION 384*
CONCLUSION 384* SUPPORTED GOLD NANOPARTICLES AS OXIDATION CATALYSTS 389*
ALLELINO CORMA AND HERMENEGILDO GARCIA LNTRODUCTION 389* NANOPARTICLES
AND THEIR PROPERTIES 390* SURFACE CHEMISTRY AND NANOPARTICLES 390*
PROPERTIES OF NANOPARTICLES 392* STABILIZED GOLD NANOPARTICLES 397* XII
I CONTENTS 12.3* INFLUENCE OF THE SUPPORT ON THE CATALYTIC ACTIVITY OF
SUPPORTED GOLD* NANOPARTICLES 401* 12.4* SUSTAINABILITY AND GREEN
CHEMISTRY 404* 12.5* ALCOHOL OXIDATION IN ORGANIC CHEMISTRY 406* 12.6*
RELATED PRECEDENTS TO THE USE OF GOLD CATALYSTS FOR THE AEROBIC*
OXIDATION OF ALCOHOLS 408* 12.7* GOLD NANOPARTICLES SUPPORTED ON CERIA
NANOPARTICLES 409* 12.8* GOLD VS. PALLADIUM CATALYSTS FOR THE AEROBIC
OXIDATION OF* ALCOHOLS 412* 12.9* REACTION MECHANISM OF GOLD*CATALYZED
ALCOHOL OXIDATIONS 415* 12.10* INFLUENCE OF THE SOLVENT ON AEROBIC
OXIDATION 419* 12.11* CONCLUSIONS AND FUTURE PROSPECTS 421* 13* GOLD
NANOPARTICLES-CATALYZED OXIDATIONS IN ORGANIC CHEMISTRY 427* CRISTINA
DELLA PINA, ERMELINDA FA/LETTA, AND MICHEIE ROSSI 13.1* INTRODUCTION
427* 13.2* CATALYST PREPARATION 427* 13.3* SIZE-DEPENDENT PROPERTIES OF
GOLD 428* 13.3.1* SUPPORTED PARTICLES 429* 13.3.2* UNSUPPORTED PARTICLES
430* 13.4* OXIDATION MECHANISM 435* 13.4.1* METAL-SUPPORT INTERACTION
436* 13.4.2* KINETIC DATA AND MOLECULAR MECHANISM 436* 13.5* GOLD
CATALYSIS FOR SELECTIVE OXIDATION 438* 13.6* LIQUID PHASE OXIDATION OF
THE ALCOHOLIC GROUP 440* 13.6.1* OXIDATION OF DIOLS 441* 13.6.2*
OXIDATION OF OTHER POLYOLS 444* 13.6.2.1* GLYCEROL 444* 13.6.2.2*
SORBITOL 445* 13.6.2.3* OXIDATION OF OTHER ALCOHOLS 446* 13.6.2.4*
OXIDATION OF AMINOALCOHOLS 446* 13.7* OXIDATION OF ALDEHYDES 447* 13.8*
OXIDATION OF GLUCOSE 448* 13.8.1* OXIDATION TO SODIUM GLUCONATE 449*
13.8.2* OXIDATION TO FREE GLUCONIC ACID 450* 13.9* PERSPECTIVE FOR GOLD
CATALYSIS IN LIQUID PHASE OXIDATION 452* 13.10* CONCLUSIONS 453* AU
NP-CATALYSED PROPENE EPOXIDATION BY DIOXYGEN AND* DIHYDROGEN 457* JUN
KAWAHARA AND MASATAKE HARUTA 14.1* INTRODUCTION 457* 14.2* CATALYST
PREPARATION AND CATALYTIC TESTS 459* 14.3* AU/TI0 2 462* 14.3.1* EFFECT
OFTHE CRYSTAL STRUCTURE OFTIO Z 462* 14 CONTENTS I XIII* 14.3.2* CONTACT
STRUCTURE OFAU NANOPARTICLES WITH THE TI02 SUPPORTS 463* 14.3.3* SIZE
EFFECT OF AU PARTICLES 464* 14.3.4* REACTION PATHWAYS FOR PROPENE
EPOXIDATION OVER AU/TI02 465* 14.4* AU/TI-SI02 466* 14.4.1* EFFECT OF
PORE STRUCTURE AND PORE SIZE OF TITANIUM SILICATE* SUPPORT 466* 14.4.2*
EFFECT OF REACTANT CONCENTRATIONS 467* 14.4.3* SURFACE TREATMENTS AND
PROMOTERS 467* 14.4.4* REACTION PATHWAYS FOR PROPENE EPOXIDATION OVER
PROMOTED* AU/TI-SI0 2 469* 14.5* CONC1USIONS 471* 15* GOLD
NANOPARTICLES: RECENT ADVANCES IN CO OXIDATION 475* CATHERINE LOUIS
15.1* INTRODUCTION 475* 15.2* PREPARATION OF SUPPORTED GOLD CATALYSTS
478* 15.3* MAIN PARAMETERS INFLUENCING THE CATALYTIC BEHAVIOR OF GOLD*
SUPPORTED ON METAL OXIDES IN CO OXIDATION 479* 15.3.1* PRELIMINARY
REMARKS 479* 15.3.2* GOLD PARTICLE SIZE 480* 15.3.3* NATURE OF THE
SUPPORT 480* 15.3.4* WATER IN THE GAS FEED OR IN THE CATALYST 481*
15.3.5* CONDITIONS OF ACTIVATION OF GOLD CATALYSTS AND STATE OF GOLD IN
ACTIVE* CATALYSTS 482* 15.4* PROPERTIES OF GOLD NANOPARTICLES (FREE OR
SUPPORTED) 483* 15.4.1* ELECTRONIC PROPERTIES 483* 15.4.2* METAL-SUPPORT
INTERACTIONS 484* 15.4.2.1* PARTIC1E MORPHOLOGY 484* 15.4.2.2* INFLUENCE
OF THE OXIDE SUPPORT ON THE ELECTRONIC PROPERTIES OF GOLD* PARTICLES
485* 15.4.2.3* INFLUENCE OF THE GOLD PARTICLES ON THE OXIDE SUPPORT
PROPERTIES 486* 15.4.3* CO AND O2 CHEMISORPTION 486* 15.5* OVERVIEW OF
THE MECHANISMS OF CARBON MONOXIDE OXIDATION 487* 15.5.1* MECHANISMS
INVOLVING THE OXIDE SUPPORT 487* 15.5.1.1* HARUTA'S MECHANISM: META!
GOLD PARTICLES 487* 15.5.1.2* BOND AND THOMPSON'S MECHANISM: UNREDUCED
GOLD AT THE* INTERFACE 488* 15.5.2* MECHANISMS INVOLVING "GOLD PARTICLES
ONLY" 489* 15.5.2.1* GOODMAN'S MECHANISM 489* 15.5.2.2* KUNG'S MECHANISM
490* 15.5.3* CATIONIC GOLD FOR CO OXIDATION 490* 15.6* CONTRIBUTION OF
QUANTUM CHEMICAL CALCULATION AND SURFACE SCIENCE* TO THE UNDERSTANDING
OF CO OXIDATION 491* 15.6.1* GOLD SUPPORTED ON MGO OR ON NON-REDUCIBLE
SUPPORTS 491* 15.6.2* GOLD SUPPORTED ON TI0 2 OR ON REDUCIBLE SUPPORTS
493* XIV I CONTENTS 15.6.3 15.6.4 15.7 16* 16.1 16.2 16.3 16.3.1 16.3.2
16.4 16.4.1 16.4.2 16.4.3 16.4.4 16.5 16.5.1 16.5.2 16.5.3 16.5.3.1
16.5.3.2 16.5.3.3 16.6 16.6.1 16.6.2 16.7 17* 17.1 17.1.1 17.1.2 17.1.3
17.1.4 17.1.5 17.1.5.1 17.1.5.2 INTLUENCE OF WATER ON THE ADSORPTION OF
O2 ON GOLD CLUSTERS 494* HOW TO GO FURTHER IN UNDERSTANDING THE
MECHANISM(S) OF CO* OXIDATION THANKS TO MODEL CATALYSTS 495* CONCLUDING
REMARKS: ATTEMPT TO RATIONALISE THE RESULTS ON CO* OXIDATION 497* NO
HETEROGENEOUS CATALYSIS VIEWED FROM THE ANGLE OF* NANOPARTICLES 505*
FREDUEIC THIBAULT-STARZYK, MARCO DATURI, PHILIPPE BAZIN,* FORMATION OF
SPECIFIC METAL COMPLEXES IN NANOMETRIC ZEOHTE* AND OLIVIER MARIE*
INTRODUCTION 505* THE CHEMISTRY OF DENOX CATALYSIS 507* THE METAL CENTER
509* SIZE OF NANOPARTICLES 509* MORPHOLOGY OF METAL PARTICLES 510*
METALS IN ZEOLITES 510* CERIUM FOR CONTROLLING METAL PARTICLE SIZE 511*
PORES 512* INFLUENCE OF THE ZEOHTE SI/AL RATIO AND PORE STRUCTURE 513*
NON-THERMAL ASSISTED PLASMA REACTION 513* THREE-WAY CATALYSIS 514*
GENERAL POINTS 514* THE METALLIC PHASE 515* THE ROLE OF CERIA 517*
PARTIC1E SIZE, STABILITY 517* ROLE OF ZR02 ADDITIVE: THE CERIA-ZIRCONIA
SOLID SOLUTION 518* METAL-SUPPORT INTERACTION 521* NEW NANOCATALYTIC
MATERIALS 523* NANO-GAZ 523* NANOTUBES 524* CONCLUSION 525* HYDROCARBON
CATALYTIC REACTIVITY OF SUPPORTED NANOMETALLIC* PARTICLES 529* FRAN~OIS
GARIN AND PIERRE LEGARE CATALYTIC ALKANE REFORMING ON NANOMETALLIC
PARTICLES 529* INTRODUCTION 529* INTLUENCE OF THE MEAN METALLIC PARTIC1E
SIZES IN CATALYTIC* REACTIONS 530* REACTION INTERMEDIATES 535* INTLUENCE
OF THE GAS ATRNOSPHERE AROUND THE NANOPARTICLES 538* REACTION
INTERMEDIATES DETERMINED FROM KINETIC DATA 538* KINETIC MODELS 538*
INTERRNEDIATE SPECIES 541* CONTENTS I XV 17.1.6 17.2 17.3 18* 18.1 18.2
18.2.1 18.2.1.1 18.2.1.2 18.2.2 18.2.2.1 18.2.2.2 18.2.3 18.2.3.1
18.2.3.2 18.2.3.2.1 18.2.3.2.2 18.2.3.3 18.2.4 18.2.4.1 18.2.4.2 18.3
18.3.1 18.3.2 18.3.3 18.3.4 18.3.5 18.3.6 18.4 18.4.1 18.4.2 18.4.2.1
GOLD NANOPARTICLES 541* ELECTRONIC STRUCTURE OF METAL NANOPARTICLES 542*
GENERAL DISCUSSION 548* SURFACE ORGANOMETALLIC CHEMISTRY ON METAL:
SYNTHESIS,* CHARAETERIZATION AND APPLICATION IN CATALYSIS 553* KATRIN
PELZER, JEAN-PIERRE CANDY, GREGORY GODARD, AND JEAN-MARIE BASSET
INTRODUCTION 553* SUPPORTED BIMETALLIC NANOPARTICLES 557* REACTION OF
GROUP XIV ORGANOMETALLIC COMPOUNDS WITH "HOST"* PREPARATION AND
CHARACTERIZATION OF RU NANOPARTICLES STABILIZED BY* SOME APPLICATIONS OF
SUPPORTED NANOPARTICLES MODIFIED BY* GROUP A: EVIDENCE FOR A SELECTIVE
EFFECT IN CATALYSIS OF THE GRAFTED* COMPETITIVE HYDROGENATION OF
HEX-2-EN-L-01 AND HEX-S-EN-L-OL* SUPPORTS 557* METHODOLOGY AND TOOLS
557* CHARACTERISATION OF METALLIC SURFACES AND METAL NANOPARTICLES 561*
SUPPORTED HOST METAL 562* HOST METAL DEPOSITION ON THE SUPPORTS 562*
CHARACTERIZATION OF THE HOST MONOMETALLIC CATALYSTS 562* METALS 564*
GENERAL CONSIDERATIONS 564* REACTION OF SNBU4 UNDER HYDROGEN IN SOLUTION
566* GENERAL CONSIDERATIONS 566* WATER-SOLUBLE ORGANO-TIN COMPLEXES 569*
REACTION OF SNBU4 UNDER HYDROGEN IN THE ABSENCE OF A SOLVENT:*
CHARACTERIZATION OF THE BIMETALLIC CATALYSTS 569* REACTIVITY OF ARSENIC
AND MERCURY ORGANOMETALLIC COMPOUNDS WITH* "NANOPARTICLES" OF NICKEL
COVERED WITH HYDROGEN 574* TRIPHENYLARSINE 575* DIPHENYLMERCURY 576*
UNSUPPORTED BIMETALLIC PARTICLES 577* INTRODUCTION 577* SYNTHESIS OF
UNSUPPORTED NANOPARTICLES 578* STABILIZATION OF UNSUPPORTED
NANOPARTICLES 579* HEXADECYLAMINE 581* PREPARATION AND CHARACTERIZATION
OF RU NANOPARTICLES STABILIZED BY* GRAFTED ORGANOMETALLIC FRAGMENTS 585*
PREPARATION AND CHARACTERIZATION OF PT NANOPARTICLES STABILIZED BY*
GRAFTED ORGANOSILYL FRAGMENTS 587* ORGANOMETALLICS 590* INTRODUCTION
590* "ORGANOMETALLIC LIGAND" 592* UNSATURATED ALCOHOLS 592* XVI I
CONTENTS 18.4.2.2 18.4.3 18.4.3.1 18.4.3.2 18.4.3.3 18.4.4 18.4.4.1
18.4.4.2 18.5 18.5.1 18.5.1.1 18.5.1.2 18.5.1.3 18.5.1.4 18.5.1.5
18.5.1.6 18.5.2 18.5.2.1 18.5.2.2 18.5.2.3 18.6 HYDROGENATION OF
A,SS-UNSATURATED ALDEHYDES 593* SELECTIVE HYDROGENOLYSIS OF ESTERS AND
ACIDS TO ALDEHYDES AND* TYPICAL RAM II (REMOVAL OF ARSENIC AND MERCURY)
PROCESS* APPLICATION IN "HEAVY" META! ION REMOVAL FROM AQUEOUS* GROUP B:
THE ROLE OF "ADATOMS" IN SELECTIVITY 596* ISOMERIZATION OF 3-CARENE INTO
2-CARENE 596* DEHYDROGENATION OF BUTAN-2-01 TO METHYL ETHYL KETONE 596*
SELECTIVE HYDROGENATION OF ACETOPHENONE TO PHENYL ETHANOL 597* GROUP C:
"SITE ISOLATION" PHENOMENON 597* DEHYDROGENATION OF ISOBUTANE TO
ISOBUTENE 598* ALCOHOLS 599* APPLICATION OF SURFACE ORGANOMETALLIC
CHEMISTRY ON METALS TO THE* REMOVAL OF "HEAVY" METAL FROM CONTAMINATED
FEEDS 603* APPLICATION IN "HEAVY" METAL ELIMINATION FROM CRUDE OIL 603*
INTRODUCTION 603* NATURAL GAS CONDENSATES AS STEAM-CRACKER FEEDSTOCKS
604* MERCURY REMOVAL METHODS 605* DESCRIPTION 605* CHEMICAL REACTIONS
606* CONCLUSION 608* EFFLUENTS 608* CD 2 + REMOVAL 608* N E+ AND C0 2 +
REMOVAL 611* CR VI REMOVAL 613* CONCLUSION 613* INDEX 621* |
| adam_txt |
* * * * * * * * * ******** ****** LIST O F C O N T R I B U T O R S X
I X * 1 * T R A N S I T I O N - M E T A L N A N O P A R T I C L
E S IN C A T A L Y S I S : F R O M H I S T O R I C A L *
BACKGROUND T O T H E S T A T E - O F - T H E A R T 1 *
DIDIER ASTRUC 1.1* I N T R O D U C T I O N 1 * 1.2* HISTORICAL B A
C K G R O U N D 4 * 1.3* POLYMERS AS NP S T A B I L I Z E R S 7
* 1.4* D E N D R I M E R S AS NP S T A B I L I Z E R S 11* 1.5*
LIGAND S T A B I L I Z A T I O N O F N P S 16* 1.6*
"LIGAND-FREE" H E C K R E A C T I O N S U S I N G LOW
PD-LOADING 18* 1.7* T H E ROLES O F MICELLES, M I C R O E M U L S
I O N S , S U R F A C T A N T S A N D A E R O G E L S 20*
1.8* L O N K LIQUID MEDIA FOR C A T A L Y S I S BY NPS 22* 1.9*
OXIDE S U P P O R T S FOR NP C A T A L Y S T S 24* 1.10* CARBON S
U P P O R T S FOR NP C A T A L Y S T S 28* 1.11* NPS O F NOBLE
M E T A L S (RU, RH, P D , P T A N D T H E I R OXIDES) I
N * CATALYSIS 3 0 * 1.12* GOLD N A N O P A R T I C I E - B A S E D
C A T A L Y S T S 3 0 * 1.13* E N V I R O N M E N T A L P R
O B L E M S : NOX P O L L U T I O N A N D H O W TO R E M O V
E NOX* USING N P CATALYSIS 34* 1.14* H Y D R O C A R B O N R E
F O R M I N G : A C T I V A T I O N O F H Y D R O C A R B O N S
BY NP* CATALYSTS 34* 1.15* SURFACE O R G A N O M E T A L L I C C H
E M I S T R Y O N M E T A L NPS 36* 1.16* APPLICATION A N D
P E R S P E C T I V E S I N O R G A N I C C H E M I S T R Y
36* 1.17* C O N C L U S I O N 3 7 * NANOPARTIELES AND CATAYSIS.
E D I T E D BY D I D I E R A S T R U C C O P Y R I G H T
2008 WILEY*VCH V E R L A G G M B H & C O . KGAA, W E I
N H E I M ISBN: 9 7 8 * 3 * 5 2 7 * 3 1 5 7 2 - 7 VI I CONTENTS 2
* 2.1 2.2 2.3 2.3.1 2.3.1.1 2 . 3 . 1 . 2 2.3.2 2.3.2.1 2.3.2.2
2.3.2.3 2.3.3 2.4 2.4.1 2.4.2 2.4.2.1 2 . 4 . 3 2.4.3.1 2.4.3.2 2.5 3
* 3.1 3.2 3.2.1 3.2.1.1 3.2.1.1.1 3.2.1.1.2 3.2.1.2 3.2.1.3 3.2.2 3.3
4 * 4.1 4.1.1 4.1.2 4.1.3 C O L L O I D A L N A N O P A R T I C L
E S STABILIZED BY SURFACTANTS OR* O R G A N O - A L U M I N U M
DERIVATIVES : PREPARATION AND USE AS CATALYST* PRECURSORS 4 9 *
HELMUT BOENNEMANN, KYATANAHALLI 5. NAGABHUSHANA, AND* RYAN M. RICHARDS* B
A C K G R O U N D 4 9 * G E N E R A L I N T R O D U C T I O N
5 0 * S Y N T H E T I C M E T H O D O L O G I E S 55* S T A
B I L I Z A T I O N V I A S U R F A C T A N T S 55* O R G A N O
S O L S 55* H Y D R O S O L S 5 8 * " R E D U C T I V E S T
A B I L I Z A T I O N " W I T H A L U M I N U M ALKYLS 5 9 *
O R G A N O S O L S 5 9 * H Y D R O S O L S 6 0 * F O R M A
T I O N O F N A N O P A R T I D E N E T W O R K S 63* S H A
P E - S E L E C T I V E P A R T I C L E S Y N T H E S I S 65* A
P P L I C A T I O N S I N C A T A L Y S I S 66* Q U A S I - H O
M O G E N E O U S C A T A L Y S T S 67* H E T E R O G E N E O U S
C A T A L Y S T S 67* T H E " P R E C U R S O R C O N C E P
T " 68* A P P L I C A T I O N S 71* F I N E C H E M I C A L S
71* E L E C T R O C A T A L Y S I S 73* M I S C E L L A N E O U S
A P P L I C A T I O N S A N D F U T U R E O U T L O O K
83* N A N O P A R T I C U L A T E CATALYSTS BASED ON NANOSTRUCTURED
POLYMERS 93* LYUDMILA M. BRONSTEIN, VALENTINA G. MATVEELLA, AND ESTHER
M. SULMAN* N A N O P A R T I C U L A T E C A T A L Y S T S F O R M
E D I N H I G H L Y - F U N C T I O N A L I Z E D P O L Y M E R
* I N T R O D U C T I O N 93* C A T A L Y T I C N A N O P A R T
I C 1 E S I N A N A N O S T R U C T U R E D E N V I R O N M
E N T 96* H Y D R O G E N A T I O N W I T H C A T A L Y T I C
N A N O P A R T I C L E S 96* BLOCK C O P O L Y M E R - B A S E D
C A T A L Y S T S 96* P S - B - P 4 V P - B A S E D C A T A L Y
S T S 96* P E O * B - P 4 V P - B A S E D C A T A L Y S T S
104* N A N O P A R T I C U L A T E C A T A L Y S T S F O R M E D
VIA M I C R O G E L T E M P L A T I N G 1 1 0 * C O L L O I
D S 112* O X I D A T I O N W I T H C A T A L Y T I C N A N O
P A R T I C L E S 115* C O N C L U S I O N S A N D O U T L O O
K 123* P A M A M D E N D R I M E R T E M P L A T E D N A N O
P A R T I C L E CATALYSTS 1 2 9 * BERT D. CHANDLER AND JOHN D.
GILBERTSON* I N T R O D U C T I O N A N D B A C K G R O U N D
129* T R A D I T I O N A L R O U T E S T O H E T E R O G E N E
O U S C A T A L Y S T S 1 2 9 * M O L E C U L A R C L U S T
E R A N D C O L L O I D R O U T E S 1 3 0 * P A M A M
D E N D R I M E R S 131* CONTENTS IVII* 4.2* SYNTHESIS AND
CHARACTERIZATION OF DENDRIMER ENCAPSULATED* NANOPARTICLES 132* 4.2.1*
SYNTHETIC SCHEMES AND NOMENCLATURE 132* 4.2.2* BIMETALLIC NANOPARTICLES
133* 4.2.3* CORE-SHELL NANOPARTICLES 135* 4.2.4* CHARACTERIZATION 136*
4.3* HOMOGENEOUS CATALYSIS 139* 4.3.1* MONOMETALLIC CATALYSTS 139*
4.3.2* BIMETALLIC CATALYSTS 140* 4.4* SUPPORTED DENDRIMER TEMPLATED
NANOPARTICLES 142* 4.4.1* IMMOBILIZED INTACT DENS 143* 4.4.1.1*
ELECTROCATALYSIS BY IMMOBILIZED INTACT DENS 143* 4.4.1.2* CONSTRUCTION
OF DENS ON OXIDE SURFACES 144* 4.4.1.3* DEN DEPOSITION ONTO OXIDE
SUPPORTS 145* 4.4.2* HIGH TEMPERATURE DENDRIMER REMOVAL 145* 4.4.2.1*
MODELS FOR DENDRIMER REMOVAL 148* 4.4.2.2* LOW TEMPERATURE DENDRIMER
REMOVAL 149* 4.4.3* MONOMETALLIC DENDRIMER TEMPLATED NANOPARTICLE
CATALYSTS 151* 4.4.4* SUPPORTED BIMETALLIC DENDRIMER TEMPLATED
NANOPARTICLES 152* 4.4.4.1* INFRARED SPECTROSCOPY OF SUPPORTED
BIMETALLIC DENDRIMER TEMPLATED* NANOPARTICLES 152* 4.4.4.2* CATALYSIS BY
SUPPORTED BIMETALLIC DENDRIMER TEMPLATED* NANOPARTICLES 153* 4.5*
SUMMARY, OUTLOOK, AND LINKS BETWEEN HOMOGENEOUS AND* HETEROGENEOUS
CATALYSIS 156* 5* AEROGEL SUPPORTED NANOPARTICLES IN CATALYSIS 161*
ADELINA VA/LRIBERA AND FLIES MOLINS 5.1* INTRODUCTION 161* 5.2* AEROGEL
NANOCOMPOSITES AS CATALYSTS OF IMPORTANT REACTIONS IN* GASEOUS MEDIA
166* 5.2.1* FISCHER-TROPSCH SYNTHESIS 166* 5.2.2 STEAM REFORMING 166*
5.2.3 OXIDATION PROCESSES 167* . 5.2.3.1* OXIDATION OF CARBON MONOXIDE
167* 5.2.3.2* METHANOLOXIDATION 168* 5.2.3.3* N-BUTANE OXIDATION 168*
5.2.3.4* VOLATILE ORGANIC COMPOUNDS OXIDATION 169* 5.2.4*
DEHYDROCHLORINATION OF CHLORINATED VOLATILE ORGANIC* COMPOUNDS 170*
5.2.5* OXYGEN REDUCTION REACTION 170* 5.2.6* CYCLOHEXENE HYDROGENATION
172* 5.2.7* ISOMERIZATION OF 1-BUTENE 173* 5.3* AEROGEL NANOCOMPOSITES
AS CATALYSTS OF IMPORTANT REACTIONS IN* LIQUID MEDIA 173* VIII I
CONTENTS 5.3.1* OXIDATION OF OLEFINS 173* 5.3.1.1* DIHYDROXYLATION OF
OLEFINS 173* 5.3.1.2* EPOXIDATION OF OLEFINS 176* 5.3.2* CLAISEN-SCHMIDT
CONDENSATION 179* 5.3.3* MIZOROKI-HECK C-C COUPLING REACTIONS 179*
5.3.4* HYDROCARBONYLATION OF ARYL HALIDES 185* 5.3.5* MICHAEL ADDITIONS
187* 5.3.6* SYNTHESIS OF CARBON NANOTUBES 190* 6* TRANSITION-METAL
NANOPARTICLE CATALYSIS IN IMIDAZOLIUM LONK* LIQUIDS 195* JAIRTON DUPONT
AND DAGOBERTO DE OLIVEIRA SI/VA 6.1* INTRODUCTION 195* 6.2* LONIC
LIQUIDS: STRUCTURAL ASPECTS 196* 6.3* FORMATION OF NANOPARTICLES IN
LMIDAZOLIUM LONIC LIQUIDS 198* 6.4* STABILIZATION OF THE METAL
NANOPARTIDES IN IMIDAZOLIUM IONIC* LIQUIDS 202* 6.4.1* ANALYSIS OF THE
ISOLATED NANOPARTIC1ES (XRD AND XPS) 203* 6.4.2 ANALYSIS OF THE MNPS
DISPERSED IN LONIC LIQUIDS 204* 6,4.3 H{D AND D{H LABELING EXPERIMENTS
207* 6,4,4 MNPS IN LONIC LIQUID{ADDITIVE LIGANDS OR POLYMERIE
STABILIZERS 207* 6.5* CATALYTIC PROPERTIES OFTRANSITION-METAL
NANOPARTICLES IN LONIC* LIQUIDS 208* 6.5.1* HYDROGENATION OF ALKENES AND
KETONES 209* 6.5.2* HYDROGENATION OF KETONES 211* 6.5.3* HYDROGENATIONS
OF ARENES 211* 6.5.4* MISCELLANEOUS REACTIONS 213* 6.6* CONCLUSIONS AND
PERSPECTIVES 213* 7* CARBON AND SILICON CARBIDE NANOTUBES CONTAINING
CATALYSTS 219* CUONG PHAM-HUU, OVIDIU ERSEN, AND MARC-JACQUES LEDOUX
7.1* INTRODUCTION 219* 7.2* CARBON AND SIC NANOTUBES/NANOFIBERS 221*
7.2.1* CARBON NANOTUBES AND NANOFIBERS 221* 7.2.2* DIRECT MACROSCOPIC
SHAPING OF CARBON NANOTUBES 226* 7.2.2.1* SELF.SUPPORTED CARBON
NANOTUBES THROUGH CONSTRAINT* SYNTHESIS 226* 7.2.2.2* PARALLEL AND
PATTERNED CARBON NANOTUBES BY PYROLYSIS OF ORGANIC* COMPOUNDS 228*
7.2.2.3* CARBON NANOTUBES GROWTH ON PERIODICALLY PATTEMED* STRUCTURE
230* 7.2.3* STRUCTURAL ORDERING ASSISTED BY THERMAL TREATMENT 232*
7.2.4* SIC NANOTUBES AND NANOFIBERS 234* 7.3* ONE-DIMENSIONAL CONDUCTIVE
MATERIALS FOR CATALYSIS 235* 7.3.1* CARBON NANOTUBES CONTAINING
NANOPARTICLE CATALYSTS 236* 7.3.1.1 7.3.1.2 7.3.1.3 7.3.1.4 7.3.2
7.3.2.1 7.4 7.5 8* 8.1 8.1.1 8.2 8.3 8.4 9* 9.1 9.2 9.2.1 9.2.2 9.2.3
9.2.4 9.3 9.3.1 9.3.2 9.3.2.1 9.3.2.2 9.3.3 9.3.3.1 9.3.3.2 9.3.3.3
CORLTENTS IIX* PD/CNTS CATALYST CHARACTERISTICS 236* SELECTIVE
HYDROGENATION OF NITROBENZENE TO ANILINE IN THE LIQUID* SELECTIVE
OXIDATIVE DEHYDROGENATION (ODH) OF DIHYDROANTHRACENE TO* HYDROGENATION
OF THE C=C BOND IN THE LIQUID PHASE 241* PHASE 242* ANTHRACENE 243* SIC
NANOTUBES CONTAINING NANOPARTICLES CATALYSTS 246* SELECTIVE OXIDATION OF
H 2 S TO ELEMENTAL SULFUR IN A TRICKLE-BED 246* CONCLUSION 247* OUTLOOK
249* SIZE-SELECTIVE SYNTHESIS OF NANOSTRUCTURED METAL AND METAL OXIDE*
COLLOIDS AND THEIR USE AS CATALYSTS 253* MANFRED T. REETZ INTRODUCTION
253* GENERAL COMMENTS ON CATALYSIS USING TRANSITION METAL* SIZE- AND
SHAPE-SELECTIVE PREPARATION OF METAL NANOPARTICLES IN THE* NANOPARTICLES
253* ZEROVALENT FORM 254* PREPARATION AND APPLICATION OF AQUEOUS
COLLOIDS OF METAL OXIDE AND* MULTIMETAL OXIDE NANOPARTICLES 264*
CONCLUSION 272* MULTIMETALLIC NANOPARTICLES PREPARED BY REDOX PROCESSES
APPLIED IN* CATALYSIS 279* F/ORENCE EPRON, CATHERINE ESPECE/, GWENDO/INE
LAFAYE, AND PATRICE MARECOT INTRODUCTION 279* GENERAL ASPECTS 279*
PREPARATION OF BIMETALLIC CATALYSTS BY DIRECT REDOX* REDOX REACTIONS OF
ADSORBED SPECIES IN THE PREPARATION OF BIMETALLIC* REACTION 280*
CATALYSTS 281* CATALYTIC REDUCTION IN THE PREPARATION OF BIMETALLIC
CATALYSTS 282* UNDERPOTENTIAL DEPOSITION 282* PRACTICAL ASPECTS 283*
STABILITY OF SUPPORTED CATALYSTS IN THE AQUEOUS PHASE 283* STUDY OF THE
DEPOSITION REACTION 285* ON BULK CATALYSTS 285* ON SUPPORTED CATALYSTS
286* CHARACTERIZATION OF THE METAL-METAL INTERACTION 288* MODEL
REACTIONS 288* ADSORPTION OF PROBE MOLECULES 288* PHYSICAL TECHNIQUES
289* XI CONTENTS 9.3.4 9.4 9.4.1 9.4.1.1 9.4.1.2 9.4.2 9.5 9.6 9.6.1
9.6.2 9.7 10* 10.1 10.2 10.2.1 10.2.2 10.3 10.3.1 10.3.2 10.4 10.5
10.5.1 10.5.2 10.5.2.1 10.5.2.2 10.5.3 10.5.3.1 10.5.3.2 10.5.3.3 10.5.4
10.5.5 10.5.5.1 10.6 INFTUENCE OF THE GASEOUS ENVIRONMENT ON THE
NANOPARTICLE STABILITY 291* APPLICATIONS IN THE SYNTHESIS OF ORGANIC
CHEMICALS 292* SELECTIVE HYDROGENATION 292* COMPETITION BETWEEN C=C AND
C=O BONDS 293* COMPETITION BETWEEN C=C BONDS 295* SELECTIVE
HYDROGENOLYSIS 295* APPLICATIONS IN ENVIRONMENTAL CATALYSIS 296*
APPLICATIONS IN CATALYSIS FOR ENERGY 297* NAPHTHA REFORMING 297* FUEL
CELLS 299* CONC1USION 300* THE ROLE OF PALLADIUM NANOPARTICLES AS
CATALYSTS FAR CARBON-CARBON* COUPLING REACTIONS 303* LAURENT DJAKOVITCH,
KLAUS KOEHLER, ANDJOHANNES G. DE VRIES* LIGAND-FREE PALLADIUM AS CATALYST
IN OTHER C-C BOND FORMING* PALLADACYCLES, PINCERS AND OTHER PALLADIUM
COMPLEXES AS PRECURSORS* PALLADIUM SUPPORTED ON SOLIDS AS CATALYSTS FOR
CARBON-CARBON* HECK COUPLING BY SUPPORTED (SOLID) PD CATALYSTS -
GENERAL* PROGRESS IN HECK REACTIONS CATALYZED BY PALLADIUM* SUPPORTED ON
SOLIDS - ACTIVATION OF BROMOBENZENE AND ARYL* MECHANISTIC ASPECTS OF
HECK (AND RELATED) REACTIONS BY* (SUPPORTED) NANOPARTICLES: HOMOGENEOUS
OR HETEROGENEOUS* INTRODUCTION 303* STABLE PALLADIUM COLLOIDS AND
NANOPARTICLES 303* PALLADIUM COLLOIDS IN THE HECK REACTION 305*
PALLADIUM COLLOIDS IN OTHER C-C COUPLING REACTIONS 314* LIGAND.FREE
PALLADIUM CATALYSTS 316* THE LIGAND-FREE HECK REACTION 316* REACTIONS
321* OF PALLADIUM NANOCLUSTERS 323* COUPLING REACTIONS 327* MOTIVATION
328* CHLORIDES 329* HECK REACTIONS OF NON*ACTIVATED ARYL BROMIDES 330*
REACTIONS OF ARYL CBLORIDES 332* CONC1USIONS FROM THE LITERATURE REPORTS
334* PROPERTIES OF THE CATALYST 334* IMPORTANCE OF REACTION CONDITIONS
334* POTENTIAL FOR PRACTICAL APPLICATIONS 335* SUPPORTED PALLADIUM
CATALYSTS IN OTHER COUPLING REACTIONS 335* CATALYSIS? 336* MECHANISTIC
CYDE 340* CONCLUSIONS 342* CONTENTS IXI* 11 11.1 11.2 11.3 11.3.1
11.3.1.1 11.3.1.1.1 11.3.1.1.2 11.3.1.1.3 11.3.1.2 11.3.1.2.1 11.3.1.2.2
11.3.1.3 11.3.1.4 11.3.1.4.1 11.3.1.4.2 11.3.1.5 11.3.1.5.1 11.3.1.5.2
11.3.1.6 11.3.1.6.1 11.3.1.6.2 11.3.2 11.3.3 11.4 11.4.1 11.4.2 11.4.3
11.4.4 11.5 11.5.1 11.5.2 11.5.3 11.6 12* 12.1 12.2 12.2.1 12.2.2 12.2.3
RHODIUM AND RUTHENIUM NANOPARTICLES IN CATALYSIS 349* ALAIN ROUCOUX,
AUDREY NOWICKI, AND KARINE PHILIPPOT LNTRODUCTION 349* GENERALITIES ON
THE SYNTHESIS AND THE STABILIZATION MODES OF* RH AND RU NANOPARTICLES AS
CATALYSTS IN HYDROGENATION* NANOPARTICLES 350* REACTIONS 351*
HYDROGENATION OF UNSATURATED HYDROCARBONS 352* POLYMER STABILIZED RH AND
RU NANOPARTICLES 352* HYDROGENATION OF COMPOUNDS WITH C=C BONDS 352*
HYDROGENATION OF COMPOUNDS WITH C=C BONDS 353* HYDROGENATION OF AROMATIC
COMPOUNDS 354* SURFACTANT-STABILIZED RH AND RU NANOPARTICLES 354*
HYDROGENATION OF COMPOUNDS WITH C=C BONDS 354* HYDROGENATION OF AROMATIC
COMPOUNDS 356* LIGAND-STABILIZED RH AND RU NANOPARTICLES 363*
POLYOXOANION-STABILIZED RH AND RU NANOPARTICLES 365* HYDROGENATION OF
COMPOUNDS WITH C=C BONDS 366* HYDROGENATION OF AROMATIC COMPOUNDS 366*
LONIC LIQUIDS-STABILIZED RH AND RU NANOPARTICLES 366* HYDROGENATION OF
COMPOUNDS WITH C=C BONDS 366* HYDROGENATION OF AROMATIC COMPOUNDS 367*
DENDRIMER- OR CYCLODEXTRIN-STABILIZED RH AND RU NANOPARTICLES 368*
DENDRIMER-STABILIZED RH AND RU NANOPARTICLES 368*
CYCLODEXTRIN-STABILIZED RH AND RU NANOPARTICLES 369* HYDROGENATION OF
COMPOUNDS WITH C=O BONDS 371* HYDROGENATION OF AROMATIC NITRO COMPOUNDS
376* CATALYTIC FORMATION OF C-C BONDS 377* HYDROFORMYLATION OF OLEFINS
378* METHANOL CARBONYLATION 379* COUPLING REACTIONS 380*
PAUSON-KHANDREACTION 381* OTHER REACTIONS 382* HYDROCARBON OXIDATION
382* DEHYDROCOUPLING OF AMINE-BORANE ADDUCTS 382* HYDROSILYLATION 384*
CONCLUSION 384* SUPPORTED GOLD NANOPARTICLES AS OXIDATION CATALYSTS 389*
ALLELINO CORMA AND HERMENEGILDO GARCIA LNTRODUCTION 389* NANOPARTICLES
AND THEIR PROPERTIES 390* SURFACE CHEMISTRY AND NANOPARTICLES 390*
PROPERTIES OF NANOPARTICLES 392* STABILIZED GOLD NANOPARTICLES 397* XII
I CONTENTS 12.3* INFLUENCE OF THE SUPPORT ON THE CATALYTIC ACTIVITY OF
SUPPORTED GOLD* NANOPARTICLES 401* 12.4* SUSTAINABILITY AND GREEN
CHEMISTRY 404* 12.5* ALCOHOL OXIDATION IN ORGANIC CHEMISTRY 406* 12.6*
RELATED PRECEDENTS TO THE USE OF GOLD CATALYSTS FOR THE AEROBIC*
OXIDATION OF ALCOHOLS 408* 12.7* GOLD NANOPARTICLES SUPPORTED ON CERIA
NANOPARTICLES 409* 12.8* GOLD VS. PALLADIUM CATALYSTS FOR THE AEROBIC
OXIDATION OF* ALCOHOLS 412* 12.9* REACTION MECHANISM OF GOLD*CATALYZED
ALCOHOL OXIDATIONS 415* 12.10* INFLUENCE OF THE SOLVENT ON AEROBIC
OXIDATION 419* 12.11* CONCLUSIONS AND FUTURE PROSPECTS 421* 13* GOLD
NANOPARTICLES-CATALYZED OXIDATIONS IN ORGANIC CHEMISTRY 427* CRISTINA
DELLA PINA, ERMELINDA FA/LETTA, AND MICHEIE ROSSI 13.1* INTRODUCTION
427* 13.2* CATALYST PREPARATION 427* 13.3* SIZE-DEPENDENT PROPERTIES OF
GOLD 428* 13.3.1* SUPPORTED PARTICLES 429* 13.3.2* UNSUPPORTED PARTICLES
430* 13.4* OXIDATION MECHANISM 435* 13.4.1* METAL-SUPPORT INTERACTION
436* 13.4.2* KINETIC DATA AND MOLECULAR MECHANISM 436* 13.5* GOLD
CATALYSIS FOR SELECTIVE OXIDATION 438* 13.6* LIQUID PHASE OXIDATION OF
THE ALCOHOLIC GROUP 440* 13.6.1* OXIDATION OF DIOLS 441* 13.6.2*
OXIDATION OF OTHER POLYOLS 444* 13.6.2.1* GLYCEROL 444* 13.6.2.2*
SORBITOL 445* 13.6.2.3* OXIDATION OF OTHER ALCOHOLS 446* 13.6.2.4*
OXIDATION OF AMINOALCOHOLS 446* 13.7* OXIDATION OF ALDEHYDES 447* 13.8*
OXIDATION OF GLUCOSE 448* 13.8.1* OXIDATION TO SODIUM GLUCONATE 449*
13.8.2* OXIDATION TO FREE GLUCONIC ACID 450* 13.9* PERSPECTIVE FOR GOLD
CATALYSIS IN LIQUID PHASE OXIDATION 452* 13.10* CONCLUSIONS 453* AU
NP-CATALYSED PROPENE EPOXIDATION BY DIOXYGEN AND* DIHYDROGEN 457* JUN
KAWAHARA AND MASATAKE HARUTA 14.1* INTRODUCTION 457* 14.2* CATALYST
PREPARATION AND CATALYTIC TESTS 459* 14.3* AU/TI0 2 462* 14.3.1* EFFECT
OFTHE CRYSTAL STRUCTURE OFTIO Z 462* 14 CONTENTS I XIII* 14.3.2* CONTACT
STRUCTURE OFAU NANOPARTICLES WITH THE TI02 SUPPORTS 463* 14.3.3* SIZE
EFFECT OF AU PARTICLES 464* 14.3.4* REACTION PATHWAYS FOR PROPENE
EPOXIDATION OVER AU/TI02 465* 14.4* AU/TI-SI02 466* 14.4.1* EFFECT OF
PORE STRUCTURE AND PORE SIZE OF TITANIUM SILICATE* SUPPORT 466* 14.4.2*
EFFECT OF REACTANT CONCENTRATIONS 467* 14.4.3* SURFACE TREATMENTS AND
PROMOTERS 467* 14.4.4* REACTION PATHWAYS FOR PROPENE EPOXIDATION OVER
PROMOTED* AU/TI-SI0 2 469* 14.5* CONC1USIONS 471* 15* GOLD
NANOPARTICLES: RECENT ADVANCES IN CO OXIDATION 475* CATHERINE LOUIS
15.1* INTRODUCTION 475* 15.2* PREPARATION OF SUPPORTED GOLD CATALYSTS
478* 15.3* MAIN PARAMETERS INFLUENCING THE CATALYTIC BEHAVIOR OF GOLD*
SUPPORTED ON METAL OXIDES IN CO OXIDATION 479* 15.3.1* PRELIMINARY
REMARKS 479* 15.3.2* GOLD PARTICLE SIZE 480* 15.3.3* NATURE OF THE
SUPPORT 480* 15.3.4* WATER IN THE GAS FEED OR IN THE CATALYST 481*
15.3.5* CONDITIONS OF ACTIVATION OF GOLD CATALYSTS AND STATE OF GOLD IN
ACTIVE* CATALYSTS 482* 15.4* PROPERTIES OF GOLD NANOPARTICLES (FREE OR
SUPPORTED) 483* 15.4.1* ELECTRONIC PROPERTIES 483* 15.4.2* METAL-SUPPORT
INTERACTIONS 484* 15.4.2.1* PARTIC1E MORPHOLOGY 484* 15.4.2.2* INFLUENCE
OF THE OXIDE SUPPORT ON THE ELECTRONIC PROPERTIES OF GOLD* PARTICLES
485* 15.4.2.3* INFLUENCE OF THE GOLD PARTICLES ON THE OXIDE SUPPORT
PROPERTIES 486* 15.4.3* CO AND O2 CHEMISORPTION 486* 15.5* OVERVIEW OF
THE MECHANISMS OF CARBON MONOXIDE OXIDATION 487* 15.5.1* MECHANISMS
INVOLVING THE OXIDE SUPPORT 487* 15.5.1.1* HARUTA'S MECHANISM: META!
GOLD PARTICLES 487* 15.5.1.2* BOND AND THOMPSON'S MECHANISM: UNREDUCED
GOLD AT THE* INTERFACE 488* 15.5.2* MECHANISMS INVOLVING "GOLD PARTICLES
ONLY" 489* 15.5.2.1* GOODMAN'S MECHANISM 489* 15.5.2.2* KUNG'S MECHANISM
490* 15.5.3* CATIONIC GOLD FOR CO OXIDATION 490* 15.6* CONTRIBUTION OF
QUANTUM CHEMICAL CALCULATION AND SURFACE SCIENCE* TO THE UNDERSTANDING
OF CO OXIDATION 491* 15.6.1* GOLD SUPPORTED ON MGO OR ON NON-REDUCIBLE
SUPPORTS 491* 15.6.2* GOLD SUPPORTED ON TI0 2 OR ON REDUCIBLE SUPPORTS
493* XIV I CONTENTS 15.6.3 15.6.4 15.7 16* 16.1 16.2 16.3 16.3.1 16.3.2
16.4 16.4.1 16.4.2 16.4.3 16.4.4 16.5 16.5.1 16.5.2 16.5.3 16.5.3.1
16.5.3.2 16.5.3.3 16.6 16.6.1 16.6.2 16.7 17* 17.1 17.1.1 17.1.2 17.1.3
17.1.4 17.1.5 17.1.5.1 17.1.5.2 INTLUENCE OF WATER ON THE ADSORPTION OF
O2 ON GOLD CLUSTERS 494* HOW TO GO FURTHER IN UNDERSTANDING THE
MECHANISM(S) OF CO* OXIDATION THANKS TO MODEL CATALYSTS 495* CONCLUDING
REMARKS: ATTEMPT TO RATIONALISE THE RESULTS ON CO* OXIDATION 497* NO
HETEROGENEOUS CATALYSIS VIEWED FROM THE ANGLE OF* NANOPARTICLES 505*
FREDUEIC THIBAULT-STARZYK, MARCO DATURI, PHILIPPE BAZIN,* FORMATION OF
SPECIFIC METAL COMPLEXES IN NANOMETRIC ZEOHTE* AND OLIVIER MARIE*
INTRODUCTION 505* THE CHEMISTRY OF DENOX CATALYSIS 507* THE METAL CENTER
509* SIZE OF NANOPARTICLES 509* MORPHOLOGY OF METAL PARTICLES 510*
METALS IN ZEOLITES 510* CERIUM FOR CONTROLLING METAL PARTICLE SIZE 511*
PORES 512* INFLUENCE OF THE ZEOHTE SI/AL RATIO AND PORE STRUCTURE 513*
NON-THERMAL ASSISTED PLASMA REACTION 513* THREE-WAY CATALYSIS 514*
GENERAL POINTS 514* THE METALLIC PHASE 515* THE ROLE OF CERIA 517*
PARTIC1E SIZE, STABILITY 517* ROLE OF ZR02 ADDITIVE: THE CERIA-ZIRCONIA
SOLID SOLUTION 518* METAL-SUPPORT INTERACTION 521* NEW NANOCATALYTIC
MATERIALS 523* NANO-GAZ 523* NANOTUBES 524* CONCLUSION 525* HYDROCARBON
CATALYTIC REACTIVITY OF SUPPORTED NANOMETALLIC* PARTICLES 529* FRAN~OIS
GARIN AND PIERRE LEGARE CATALYTIC ALKANE REFORMING ON NANOMETALLIC
PARTICLES 529* INTRODUCTION 529* INTLUENCE OF THE MEAN METALLIC PARTIC1E
SIZES IN CATALYTIC* REACTIONS 530* REACTION INTERMEDIATES 535* INTLUENCE
OF THE GAS ATRNOSPHERE AROUND THE NANOPARTICLES 538* REACTION
INTERMEDIATES DETERMINED FROM KINETIC DATA 538* KINETIC MODELS 538*
INTERRNEDIATE SPECIES 541* CONTENTS I XV 17.1.6 17.2 17.3 18* 18.1 18.2
18.2.1 18.2.1.1 18.2.1.2 18.2.2 18.2.2.1 18.2.2.2 18.2.3 18.2.3.1
18.2.3.2 18.2.3.2.1 18.2.3.2.2 18.2.3.3 18.2.4 18.2.4.1 18.2.4.2 18.3
18.3.1 18.3.2 18.3.3 18.3.4 18.3.5 18.3.6 18.4 18.4.1 18.4.2 18.4.2.1
GOLD NANOPARTICLES 541* ELECTRONIC STRUCTURE OF METAL NANOPARTICLES 542*
GENERAL DISCUSSION 548* SURFACE ORGANOMETALLIC CHEMISTRY ON METAL:
SYNTHESIS,* CHARAETERIZATION AND APPLICATION IN CATALYSIS 553* KATRIN
PELZER, JEAN-PIERRE CANDY, GREGORY GODARD, AND JEAN-MARIE BASSET
INTRODUCTION 553* SUPPORTED BIMETALLIC NANOPARTICLES 557* REACTION OF
GROUP XIV ORGANOMETALLIC COMPOUNDS WITH "HOST"* PREPARATION AND
CHARACTERIZATION OF RU NANOPARTICLES STABILIZED BY* SOME APPLICATIONS OF
SUPPORTED NANOPARTICLES MODIFIED BY* GROUP A: EVIDENCE FOR A SELECTIVE
EFFECT IN CATALYSIS OF THE GRAFTED* COMPETITIVE HYDROGENATION OF
HEX-2-EN-L-01 AND HEX-S-EN-L-OL* SUPPORTS 557* METHODOLOGY AND TOOLS
557* CHARACTERISATION OF METALLIC SURFACES AND METAL NANOPARTICLES 561*
SUPPORTED HOST METAL 562* HOST METAL DEPOSITION ON THE SUPPORTS 562*
CHARACTERIZATION OF THE HOST MONOMETALLIC CATALYSTS 562* METALS 564*
GENERAL CONSIDERATIONS 564* REACTION OF SNBU4 UNDER HYDROGEN IN SOLUTION
566* GENERAL CONSIDERATIONS 566* WATER-SOLUBLE ORGANO-TIN COMPLEXES 569*
REACTION OF SNBU4 UNDER HYDROGEN IN THE ABSENCE OF A SOLVENT:*
CHARACTERIZATION OF THE BIMETALLIC CATALYSTS 569* REACTIVITY OF ARSENIC
AND MERCURY ORGANOMETALLIC COMPOUNDS WITH* "NANOPARTICLES" OF NICKEL
COVERED WITH HYDROGEN 574* TRIPHENYLARSINE 575* DIPHENYLMERCURY 576*
UNSUPPORTED BIMETALLIC PARTICLES 577* INTRODUCTION 577* SYNTHESIS OF
UNSUPPORTED NANOPARTICLES 578* STABILIZATION OF UNSUPPORTED
NANOPARTICLES 579* HEXADECYLAMINE 581* PREPARATION AND CHARACTERIZATION
OF RU NANOPARTICLES STABILIZED BY* GRAFTED ORGANOMETALLIC FRAGMENTS 585*
PREPARATION AND CHARACTERIZATION OF PT NANOPARTICLES STABILIZED BY*
GRAFTED ORGANOSILYL FRAGMENTS 587* ORGANOMETALLICS 590* INTRODUCTION
590* "ORGANOMETALLIC LIGAND" 592* UNSATURATED ALCOHOLS 592* XVI I
CONTENTS 18.4.2.2 18.4.3 18.4.3.1 18.4.3.2 18.4.3.3 18.4.4 18.4.4.1
18.4.4.2 18.5 18.5.1 18.5.1.1 18.5.1.2 18.5.1.3 18.5.1.4 18.5.1.5
18.5.1.6 18.5.2 18.5.2.1 18.5.2.2 18.5.2.3 18.6 HYDROGENATION OF
A,SS-UNSATURATED ALDEHYDES 593* SELECTIVE HYDROGENOLYSIS OF ESTERS AND
ACIDS TO ALDEHYDES AND* TYPICAL RAM II (REMOVAL OF ARSENIC AND MERCURY)
PROCESS* APPLICATION IN "HEAVY" META! ION REMOVAL FROM AQUEOUS* GROUP B:
THE ROLE OF "ADATOMS" IN SELECTIVITY 596* ISOMERIZATION OF 3-CARENE INTO
2-CARENE 596* DEHYDROGENATION OF BUTAN-2-01 TO METHYL ETHYL KETONE 596*
SELECTIVE HYDROGENATION OF ACETOPHENONE TO PHENYL ETHANOL 597* GROUP C:
"SITE ISOLATION" PHENOMENON 597* DEHYDROGENATION OF ISOBUTANE TO
ISOBUTENE 598* ALCOHOLS 599* APPLICATION OF SURFACE ORGANOMETALLIC
CHEMISTRY ON METALS TO THE* REMOVAL OF "HEAVY" METAL FROM CONTAMINATED
FEEDS 603* APPLICATION IN "HEAVY" METAL ELIMINATION FROM CRUDE OIL 603*
INTRODUCTION 603* NATURAL GAS CONDENSATES AS STEAM-CRACKER FEEDSTOCKS
604* MERCURY REMOVAL METHODS 605* DESCRIPTION 605* CHEMICAL REACTIONS
606* CONCLUSION 608* EFFLUENTS 608* CD 2 + REMOVAL 608* N E+ AND C0 2 +
REMOVAL 611* CR VI REMOVAL 613* CONCLUSION 613* INDEX 621* |
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| callnumber-subject | QD - Chemistry |
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| classification_tum | CHE 315f CHE 167f |
| ctrlnum | (OCoLC)181925634 (DE-599)DNB98350010X |
| dewey-full | 620.5 |
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| discipline | Chemie / Pharmazie Physik Chemie |
| discipline_str_mv | Chemie / Pharmazie Physik Chemie |
| format | Book |
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| id | DE-604.BV022958688 |
| illustrated | Illustrated |
| index_date | 2024-07-02T19:03:48Z |
| indexdate | 2024-07-20T09:26:42Z |
| institution | BVB |
| isbn | 9783527315727 3527315721 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-016163080 |
| oclc_num | 181925634 |
| open_access_boolean | |
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| owner_facet | DE-29T DE-91G DE-BY-TUM DE-19 DE-BY-UBM DE-703 DE-526 DE-634 DE-83 |
| physical | XXIII, 640 S. Ill., graph. Darst. |
| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | WILEY-VCH |
| record_format | marc |
| spelling | Nanoparticles and catalysis ed. by Didier Astruc Weinheim WILEY-VCH 2008 XXIII, 640 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Catalysis Nanoparticles Katalyse (DE-588)4029921-1 gnd rswk-swf Nanopartikel (DE-588)4333369-2 gnd rswk-swf Nanopartikel (DE-588)4333369-2 s Katalyse (DE-588)4029921-1 s DE-604 Astruc, Didier Sonstige (DE-588)112945058 oth text/html http://deposit.dnb.de/cgi-bin/dokserv?id=2930862&prov=M&dok_var=1&dok_ext=htm Inhaltstext OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=016163080&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Nanoparticles and catalysis Catalysis Nanoparticles Katalyse (DE-588)4029921-1 gnd Nanopartikel (DE-588)4333369-2 gnd |
| subject_GND | (DE-588)4029921-1 (DE-588)4333369-2 |
| title | Nanoparticles and catalysis |
| title_auth | Nanoparticles and catalysis |
| title_exact_search | Nanoparticles and catalysis |
| title_exact_search_txtP | Nanoparticles and catalysis |
| title_full | Nanoparticles and catalysis ed. by Didier Astruc |
| title_fullStr | Nanoparticles and catalysis ed. by Didier Astruc |
| title_full_unstemmed | Nanoparticles and catalysis ed. by Didier Astruc |
| title_short | Nanoparticles and catalysis |
| title_sort | nanoparticles and catalysis |
| topic | Catalysis Nanoparticles Katalyse (DE-588)4029921-1 gnd Nanopartikel (DE-588)4333369-2 gnd |
| topic_facet | Catalysis Nanoparticles Katalyse Nanopartikel |
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