Electron paramagnetic resonance: elementary theory and practical applications
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, N.J.
Wiley-Interscience
2007
|
| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Table of contents only Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references |
| Beschreibung: | XXIII, 664 S. graph. Darst. |
| ISBN: | 047175496X 9780471754961 |
Internformat
MARC
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| 020 | |a 9780471754961 |9 978-0-471-75496-1 | ||
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| 100 | 1 | |a Weil, John A. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Electron paramagnetic resonance |b elementary theory and practical applications |c John A. Weil ; James R. Bolton |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Hoboken, N.J. |b Wiley-Interscience |c 2007 | |
| 300 | |a XXIII, 664 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references | ||
| 650 | 4 | |a Spectroscopie de résonance paramagnétique électronique | |
| 650 | 4 | |a Electron paramagnetic resonance spectroscopy | |
| 650 | 0 | 7 | |a Theorie |0 (DE-588)4059787-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Anwendung |0 (DE-588)4196864-5 |2 gnd |9 rswk-swf |
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| 700 | 1 | |a Bolton, James R. |d 1937- |e Verfasser |0 (DE-588)143601547 |4 aut | |
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Datensatz im Suchindex
| _version_ | 1804136667851784193 |
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* * * * * * * * * * * * * * * * * * * * ***** * * * * * * * * * * * * *
* * * * * 1.2* H I S T O R I C A L P E R S P E C T I V E / 3 *
1.3* A S I M P L E E P R S P E C T R O M E T E R / 4 *
1.4* S C O P E O F T H E E P R T E C H N I Q U E /
7 * 1.5* E N E R G Y F L O W IN P A R A M A G N E T I C S Y
S T E M S / I I * 1.6* Q U A N T I Z A T I O N O F A N G
U L A R M O M E N T A / 13* 1.7* R E L A T I O N B E T W E E
N M A G N E T I C M O M E N T S A N D * A N G U L A R M O
M E N T A / 14* 1.8* M A G N E T I C F I E L D Q U A N T I T
I E S A N D U N I T S / 15* 1.9* B U L K M A G N E T I C
P R O P E R T I E S / 18* 1 . 1 0 * M A G N E T I C E N E
R G I E S A N D S T A T E S / 2 0 * 1.11* I N T E R A C T
I O N O F M A G N E T I C D I P O L E S W I T H E L E C T
R O M A G N E T I C * R A D I A T I O N / 21* 1.12* C H A R A C
T E R I S T I C S O F T H E S P I N S Y S T E M S /
23* 1.12.1 T H E G F A C T O R / 23* 1 . 1 2 . 2 C H A R A C
T E R I S T I C S O F D I P O L A R I N T E R A C T I O N S
/ 27 1.13* P A R A L 1 E L - F I E L D E P R / 28* VII
VIII* CONTENTS 1.14 TIME-RESOLVED EPR / 29* 1.15 COMPUTERO1OGY / 29*
1.16 EPR IMAGING / 30* REFERENEES / 30* NOTES / 32* FURTHER READING /
34* PROBLEMS / 35* 2 M A G N E T I C I N T E R A C T I O N
BETWEEN P A R T I C L E S 3 6 * 2.1* INTRODUETION / 36* 2.2*
THEORETIEAL CONSIDERATIONS 01 THE HYPERFINE INTERAETION / 38* 2.3*
ANGULAR-MOMENTUM AND ENERGY OPERATORS / 40* 2.3.1* SPIN OPERATORS AND
HAMILTONIANS / 41* 2.3.2* E1EETRONIE AND NUELEAR ZEEMAN INTERAETIONS /
43* 2.3.3* SPIN HAMILTONIAN INCLUDING ISOTROPIE* HYPERFINE INTERAETION /
46* 2.4* ENERGY LEVELS 01 A SYSTEM WITH ONE UNPAIRED ELEETRON* AND ONE
NUCLEUS WITH 1=1 / 47* 2.5* ENERGY LEVELS 01 A SYSTEM WITH S = 1 AND 1=
1 / 50* 2.6* SIGNS 01 ISOTROPIE HYPERFINE COUPLING CONSTANTS / 53* 2.7
DIPOLAR INTERAETIONS BETWEEN ELEETRONS / 54* REFERENEES / 54* NOTES /
55* FURTHER READING / 56* PROBLEMS / 56* 3 I S O T R O P I C H Y P E
R F I N E E F F E C T S IN EPR S P E C T R A 5 8 * 3.1*
INTRODUETION / 58* 3.2* HYPERFINE SPLITTING FROM PROTONS / 59* 3.2.1*
SINGLE SET 01 EQUIVALENT PROTONS / 59* 3.2.2* MULTIPLE SETS 01
EQUIVALENT PROTONS / 62* 3.3* HYPERFINE SPLITTINGS FROM OTHER NUCLEI
WITH 1=1 / 68* 3.4* HYPERFINE SPLITTINGS FROM NUELEI WITH I 1/ 69*
3.5* USEFUL RULES FOR THE INTERPRETATION 01 EPR SPEETRA / 74* 3.6*
HIGHER-ORDER CONTRIBUTIONS TO HYPERFINE SPLITTINGS / 75* 3.7* DEVIATIONS
FROM THE SIMPLE MULTINOMIA1 SEHEME / 77* 3.8* OTHER PROBLEMS ENEOUNTERED
IN EPR SPEETRA 01 * FREE RADIEALS / 77* 3.9* SOME INTERESTING 1T-TYPE
FREE RADIEALS / 78* IX CONTENTS REFERENEES / 79* NOTES / 79* FURTHER
READING / 80* PROBLEMS / 80* 4 ZEEMAN ENERGY (G) ANISOTROPY* 85* 4.1*
INTRODUETION / 85* 4.2* SYSTEMS WITH HIGH LOEAL SYMMETRY / 88* 4.3*
SYSTEMS WITH RHOMBIE LOEAL SYMMETRY / 90* 4.4* CONSTRUETION OF THE G
MATRIX / 92* 4.5* SYMMETRY-RELATED SITES / 96* 4.6* EPR LINE INTENSITIES
/ 97* 4.7* STATISTIEALLY RANDOMLY ORIENTED SOLIDS / 99* 4.8* SPIN-ORBIT
COUPLING AND QUANTUM-MEEHANIEAL* MODELING OF R / 105* 4.9 COMPARATIVE
OVERVIEW / 110* REFERENEES / II I* NOTES / 112* FURTHER READING / I 14*
PROBLEMS / I 14* 5 HYPERFINE (A) ANISOTROPY* 118* 5.1* INTRODUETION /
118* 5.2* ORIGIN OF THE ANISOTROPIE PART OF THE* HYPERFINE LNTERAETION /
120* 5.3* DETERMINATION AND INTERPRETATION OF THE* HYPERFINE MATRIX /
122* 5.3.1 THE ANISOTROPIE BREIT-RABI CASE / 122* 5.3.2 THE CASE OF
DOMINANT ELEETRON ZEEMAN ENERGY / 124* 5.3.2.1 GENERALCASE /126 5.3.2.2
THE CASE OF B ;::::; BHF / 128* 5.3.2.3 THE CASE OF B »BHF / 141* 5.4*
COMBINED G AND HYPERFINE ANISOTROPY / 143* 5.5* MULTIPLE HYPERFINE
MATRIEES / 144* 5.6* SYSTEMS WITH J ~ / 144* 5.7 HYPERFINE POWDER
LINESHAPES / 145* REFERENEES / 150* NOTES / 151* FURTHER READING / 152*
X CONTENTS* PROBLEMS / 152* 6 SYSTEMS WITH MORE THAN ONE UNPAIRED
ELECTRON 158* 6.1 INTRODUETION / 158* 6.2 SPIN HAMILTONIAN FOR TWO
INTERAETING ELEETRONS / 159* 6.2.1 ELEETRON-EXEHANGE INTERAETION / 160*
6.2.2 ELEETRON-ELEETRON DIPOLE INTERAETION / 162* 6.3 SYSTEMS WITH S = I
(TRIPLET STATES) / 164* 6.3.1 SPIN ENERGIES AND EIGENFUNETIONS / 165*
6.3.2 T::.M S = 2 TRANSITIONS / 172* 6.3.3 RANDOMLY ORIENTED TRIPLET
SYSTEMS / 173* 6.3.4 PHOTO-EXEITED TRIPLET-STATE ENTITIES / 177* 6.3.5
THERMALLY AEEESSIBLE TRIPLET ENTITIES / 182* 6.3.6 GROUND-STATE TRIPLET
ENTITIES / 185* 6.3.6.1* CARBENES AND NITRENES / 185* 6.3.6.2* DIANIONS
OF SYMMETRIE AROMATIE* HYDROEARBONS / 187* 6.3.6.3* INORGANIE TRIPLET
SPEEIES / 188* 6.4 INTERAETING RADIEAL PAIRS / 189* 6.5 BIRADIEALS /
190* 6.6 SYSTEMS WITH S I / 195* 6.7 HIGH-SPIN AND HIGH-FIELD ENERGY
TERMS / 196* 6.8 THE SPIN HAMILTONIAN: A SUMMING UP / 197* 6.9 MODELING
THE SPIN-HAMILTONIAN PARAMETERS / 199* REFERENEES / 200* NOTES / 203*
FURTHER READING / 204* PROBLEMS / 205* 7 PARAMAGNETIC SPECIES IN THE GAS
PHASE 208* 7.1 INTRODUETION / 208* 7.2 MONATOMIE GAS-PHASE SPEEIES /
209* 7.3 DIATOMIE GAS-PHASE SPEEIES / 211* 7.4 TRIATOMIE AND POLYATOMIE
GAS-PHASE MOLECULES / 217* 7.5 LASER ELEETRON PARAMAGNETIE RESONANEE /
219* 7.6 OTHER TEEHNIQUES / 219* 7.7 REAETION KINETIES / 220* 7.8
ASTRO-EPR / 220* XI CONTENTS REFERENCES / 221* NOTES / 222* FURTHER
READING / 222* PROBLEMS / 223* 8 TRANSITION-GROUP IONS* 225* 8.1*
INTRODUCTION / 225* 8.2* THE ELECTRONIC GROUND STATES OF D-ELECTRON*
SPECIES / 227* 8.3* THE EPR PARAMETERS OF D-ELECTRON SPECIES / 232* 8.4*
TANABE-SUGANO DIAGRAMS AND ENERGY-LEVEL* CROSSINGS / 240* 8.5* COVALENCY
EFFECTS / 243* 8.6* A FERROELECTRIC SYSTEM / 244* 8.7 SOME F-ELECTRON
SYSTEMS / 245* REFERENCES / 246* NOTES / 248* FURTHER READING / 249*
PROBLEMS / 249* 9 THE INTERPRETATION OF EPR PARAMETERS* 253* 9.1*
INTRODUCTION / 253* 9.2* 1T-TYPE ORGANIC RADICALS / 254* 9.2.1* ANIONS
AND CATIONS OF BENZENE* AND SOME OF ITS DERIVATIVES / 259* 9.2.2* ANIONS
AND CATIONS OF POLYACENES / 262* 9.2.3* G FACTORS OF 1T RADICAIS / 262*
9.2.4* ORIGIN OF PROTON HYPERFINE SPLITTINGS / 263* 9.2.5* SIGN OF THE
PROTON HYPERFINE SPLITTING CONSTANT / 265* 9.2.6* METHYL PROTON
HYPERFINE SPLITTINGS* AND HYPERCONJUGATION / 268* 9.2.7* HYPERFINE
SPLITTING FROM NUCLEI OTHER* THAN PROTONS / 270* 9.2.8* ONE-DIMENSIONAL
CHAIN PARAMAGNETS / 272* 9.3* A-TYPE ORGANIC RADICALS / 274* 9.4*
TRIPLET STATES AND BIRADICALS / 275* 9.5* INORGANIC RADICALS / 276* 9.6*
ELECTRICALLY CONDUCTING SYSTEMS / 281* 9.6.1* METALS / 281* XII*
CONTENTS 9.6.2* METALS DISSOLVED IN AMMONIA AND* AMINE SOLUTIONS / 282*
9.6.3* SEMICONDUCTORS / 283* 9.6.4* GRAPHITIC COMPOUNDS / 285* 9.7*
TECHNIQUES FOR STRUCTURAL ESTIMATES FROM EPR DATA / 285* 9.7.1* THE
NEWMAN SUPERPOSITION MODEL / 285* 9.7.2* THE PSEUDO-CUBE METHOD / 286*
9.7.3* DISTANCES FROM PARAMETER D / 286* 9.7.4* EATONS
INTERSPIN-DISTANCE FORMULA / 287* 9.7.5 SUMMARY / 287* REFERENCES / 287*
NOTES / 291* FURTHER READING / 291* PROBLEMS / 292* APPENDIX 9A HUECKEL
MOLECULAR-ORBITAL CALCULATIONS / 294* HMO REFERENCES / 298* HMO PROBLEMS
/ 299* 10* RELAXATION TIMES, L1NEWIDTHS AND SPIN KINETIC* PHENOMENA 301*
10.1 INTRODUCTION / 30 I* 10.2 SPIN RELAXATION: GENERAL ASPECTS / 302*
10.2.1 SPIN TEMPERATURE AND BOLTZMANN DISTRIBUTION / 302* 10.2.2 SPIN
DYNAMICS / 303* 10.2.3 MECHANISMS FOR TI / 305* 10.3 SPIN RELAXATION:
BLOCH MODEL / 308* 10.3.1 MAGNETIZATION IN A STATIC MAGNETIC FIELD /
309* 10.3.2 ADDITION OF AN OSCILLATING MAGNETIC FIELD / 310* 10.3.3
ROTATING FRAME / 311* 10.3.4 STEADY-STATE SOLUTIONS 01 BLOCH EQUATIONS
/ 312* 10.4 LINEWIDTHS / 316* 10.4.1 HOMOGENEOUS BROADENING / 316*
10.4.2 INHOMOGENEOUS BROADENING / 316* 10.5 DYNAMIC LINESHAPE EFFECTS /
317* 10.5.1 GENERALIZED BLOCH EQUATIONS / 318* 10.5.2 OTHER THEORETICAL
MODELS / 322* 10.5.3 EXAMPLES OF LINE-BROADENING MECHANISMS / 322*
10.5.3.1 ELECTRON-SPIN EXCHANGE / 323* )0.5.3.2 ELECTRON TRANSFER / 324*
CONTENTS XIII* 10.5.3.3 PROTON TRANSFER / 326* 10.5.3.4 FLUXIONAL MOTION
/ 326* 10.5.4* LINEWIDTH VARIATION: DYNAMIC HYPERFINE* CONTRIBUTIONS /
327* 10.5.4.1 SINGLE NUCLEUS / 328* 10.5.4.2 MULTIPLE NUCLEI / 329*
10.5.5* MOLECULAR TUMBLING EFFECTS / 333* 10.5.5.1 DIPOLAR EFFECTS /
335* 10.5.5.2 SPIN-ROTATION INTERACTION / 339* 10.5.6* GENERAL EXAMPLE /
340* 10.6 LONGITUDINAL DETECTION / 342* 10.7 SATURATION- TRANSFER EPR /
343* 10.8 TIME DEPENDENCE OF THE EPR SIGNAL AMPLITUDE / 343* 10.8.1*
CONCENTRATION CHANGES / 343* 10.8.2* CHEMICALLY INDUCED DYNAMIC
ELECTRON* POLARIZATION / 345* 10.9 DYNAMIC NUCLEAR POLARIZATION / 347*
10.10* BIO-OXYGEN / 347* 10.11 SUMMARY / 347* REFERENCES / 348* NOTES /
351* FURTHER READING / 352* PROBLEMS / 353* 11 NONCONTINUOUS EXCITATION
OF SPINS* 357* 11.1 INTRODUCTION / 357* 11.2 THE IDEALIZED BI SWITCH-ON
/ 359* 11.3 THE SINGLE BI PULSE / 362* 11.4 FOURIER-TRANSFORM EPR AND
FID ANALYSIS / 364* 11.5 MULTIPLE PULSES / 368* 11.6 ELECTRON SPIN-ECHO
ENVELOPE MODULATION / 369* 11.7 ADVANCED TECHNIQUES / 375* I 1.8 SPIN
COHERENCE AND CORRELATION / 375* REFERENCES / 378* NOTES / 380* FURTHER
READING / 381* PROBLEMS / 382* XIV* CONTENTS 12 DOUBLE-RESONANCE
TECHNIQUES* 385* 12.1* INTRODUETION / 385* 12.2* A CONTINUOUS-WAVE ENDOR
EXPERIMENT / 386* 12.3* ENERGY LEVELS AND ENDOR TRANSITIONS / 388* 12.4*
RELAXATION PROEESSES IN STEADY-STATE ENDOR 5 / 392* 12.5* CW ENDOR:
SINGLE-CRYSTAL EXAMPLES / 397* 12.5.1* THE F CENTERS IN THE ALKALI
HALIDES / 397* 12.5.2* METAL-ION TETRAPHENYLPORPHYRINS / 401* 12.6* CW
ENDOR IN POWDERS AND* NON-CRYSTALLINE SOLIDS / 401* 12.7* CW ENDOR IN
LIQUID SOLUTIONS / 402* 12.8* PULSE DOUBLE-RESONANEE EXPERIMENTS / 404*
12.9* ELEETRON-ELEETRON DOUBLE RESONANEE (ELDOR) / 404* 12.10* OPTIEALLY
DETEETED MAGNETIE RESONANEE / 406* 12.11 FLUORESEENEE-DETEETED MAGNETIE
RESONANEE / 407* REFERENEES / 408* NOTES / 410* FURTHER READING / 411*
PROBLEMS / 411* 13 OTHER TOPICS* 414* 13.1* APOLOGIA / 414* 13.2*
BIOLOGIEAL SYSTEMS / 414* 13.3* CLUSTERS / 415* 13.4* CHAREOAL, COAL,
GRAPHITE AND SOOT / 415* 13.5* COLLOIDS / 415* 13.6* ELEETROEHEMIEAL EPR
/ 415* 13.7* EPR IMAGING / 416* 13.8* FERROMAGNETS, ANTIFERROMAGNETS
AND* SUPERPARAMAGNETS / 416* 13.9* GLASSES / 417* 13.10*
GEOLOGIE/MINERALOGIE SYSTEMS* AND SELEETED GEMS / 417* 13.10.1 AMETHYST
/ 417* 13.10.2 BERYL AND CHRYSOBERYL / 417* 13.10.3 DIAMOND / 417*
13.10.4 EMERALD / 418* 13.10.5 OPAL / 418* CONTENTS XV 13.10.6 ROCK
CRYSTAL (A-QUARTZ) / 418* 13.[0.7 RUBY / 418* 13.10.8 SAPPHIRE / 418*
13.10.9 TOPAZ / 418* 13.10.10 TOURMALINE / 419* 13.10.11 TURQUOISE /
419* 13.10.12 ZIRCON / 419* 13.11 LIQUID CRYSTALS / 419* 13.12 POINT
DEFECTS / 419* 13.12.1 INSU1ATORS / 419* 13.12.1.1 ALKALI HALIDES / 419*
13.12.1.2 OXIDES / 419* 13.12.2 SEMICONDUCTORS / 420* 13.13 POLYMERS /
420* 13.14 RADIATION DOSAGE AND DATING / 420* 13.15 SPIN LABELS / 421*
13.16 SPIN TRAPS / 421* 13.17 TRAPPED ATOMS AND MOLECULES / 421*
APPENDIX A MATHEMATICAL OPERATIONS* 422* AI* COMPLEX NUMBERS / 422* A.2*
OPERATOR ALGEBRA / 423* A.2.1 PROPERTIES OF OPERATORS / 423* A2.2
EIGENVALUES AND EIGENFUNCTIONS / 426* A3 DETERMINANTS / 428* AA VECTORS:
SCALAR, VECTOR, AND OUTER PRODUCTS / 430* A.5* MATRICES / 432* A5.1
ADDITION AND SUBTRACTION OF MATRICES / 434* A5.2 MULTIPLICATION OF
MATRICES / 434* A.5.3 SPECIAL MATRICES AND MATRIX PROPERTIES / 438* A.5A
DIRAC NOTATION FOR EIGENFUNCTIONS AND* MATRIX ELEMENTS / 438* A.5.5
DIAGONALIZATION OF MATRICES / 440* A5.6 MATRIX INVARIANTS / 446* A.6*
PERTURBATION THEORY / 446* A.7 DIRAC DELTA FUNCTION / 449* A8 GROUP
THEORY / 450* REFERENCES / 450* XVI* CONTENTS NOTES / 451* FURTHER
READING / 451* PROBLEMS / 451* APPENDIX B* QUANTUM MECHANICS OF ANGULAR*
MOMENTUM 455* B.I* [NTRODUCTION / 455* B.2* ANGULAR-MOMENTUM OPERATORS /
457* B.3* COMMUTATION RELATIONS 1 AR GENERAL* ANGULAR-MOMENTUM OPERATORS
/ 458* BA EIGENVALUES 01 J 2 AND J Z / 459* B.5* SUPERPOSITION 01
STATES / 464* B.6* ANGULAR-MOMENTUM MATRICES / 464* B.7* ADDITION 01
ANGULAR MOMENTA / 466* B.8* NOTATION 1 AR ATOMIC AND MOLECULAR STATES /
472* B.9* ANGULAR MOMENTUM AND DEGENERACY OF STATES / 473* 8.10* TIME
DEPENDENCE / 475* B.II* PRECESSION / 475* B.12* MAGNETIC FLUX
QUANTIZATION / 477* B.13 SUMMARY / 478* REFERENCES / 479* NOTES / 480*
FURTHER READING / 480* PROBLEMS / 481* NOTES FOR PROBLEM B.12 / 483*
APPENDIX C* THE HYDROGEN ATOM AND SELECTED* RADICALS RH 484* CL*
HYDROGEN ATOM / 484* CL.] SPIN HAMILTONIAN / 484* CI.2 THE SPIN
EIGENKETS AND ENERGY MATRIX / 485* CL .3 EXACT SOLUTION FOR THE ENERGY
EIGENVALUES / 487* CI A ENERGY EIGENSTATES AND ALLOWED TRANSITIONS /
489* CI.5* RESONANT FREQUENCIES IN CONSTANT MAGNETIC FIELD / 493* CI.6*
RESONANT MAGNETIC FIELDS AT CONSTANT* EXCITATION FREQUENCY / 493* CI.7*
CALCULATION OF SPIN ENERGY LEVELS BY* PERTURBATION THEORY / 495*
CONTENTS XVII* C2 RH RADICALS / 497* C3 RH: RADICALS / 498* C3. I SPIN
HAMILTONIAN AND ENERGY LEVELS / 499* C.3.2 EPR TRANSITIONS / 499*
REFERENCES / 50 I* NOTES / 501* FURTHER READING / 502* PROBLEMS / 502*
APPENDIX D* PHOTONS 505* D.I* INTRODUCTION / 505* 0.2* THE PHYSICAL
ASPECTS OF PHOTONS / 505* 0.3 MAGNETIC-RESONANCE ASPECTS / 508*
REFERENCES / 510* NOTES / 510* APPENDIX E* INSTRUMENTATION AND
TECHNICAL* PERFORMANCE 512* E.L* INSTRUMENTAL: BACKGROUND / 512* E.2* CW
EPR SPECTROMETERS / 515* E.2.1 MAGNET SYSTEM / 516* E.2.2 RADIATION
SOURCE / 517* E.2.3 MICROWAVE TRANSMISSION / 518* E.2A COUPLI NG OF THE
SOURCE TO THE RESONATOR / 519* E.2.5 RESONATOR SYSTEM / 520* E.2.6
FIELD-MODULATION SYSTEM / 525* E.2.7 COUPLING OF THE RESONATOR TO THE
DETECTOR / 525* E.2.8 DETECTION SYSTEM / 526* E.3 PULSED EPR
SPECTROMETERS / 529* EA COMPUTER INTERFACING WITH EPR SPECTROMETERS /
530* E.5* TECHNIQUES FOR TEMPERATURE VARIATION* AND CONTROL / 531* E.6
TECHNIQUES TOR PRESSURE VARIATION / 532* REFERENCES / 533* NOTES / 535*
FURTHER READING / 535* PROBLEMS / 536* XVIII CONTENTS APPENDIX
FEXPERIMENTAL CONSIDERATIONS* 537* F.I TECHNIQUES FOR GENERATION OF
PARAMAGNETIC SPECIES / 537* F.2 LINESHAPES AND INTENSITIES / 539* F.2.1
LINESHAPES / 539* F.2.2 SIGNAL INTENSITIES AND SPIN-CONCENTRATION
STANDARDS / 545* F.3 SENSITIVITY AND RESOLUTION / 548* F.3.1 OPTIMUM
SENSITIVITY / 548* F.3.2 SAMPIE TEMPERATURE / 550* F.3.3 MICROWAVE
FREQUENCY / 550* F.3 A Q FACTOR OF THE RESONATOR / 551* F.3.5 MICROWAVE
POWER LEVEL AND MEASUREMENTS OF BI / 553* F.3.6 MODULATION AMPLITUDE /
554* F.3.7 MODULATION FREQUENCY / 557* FA MEASUREMENTS / 557* FA.I G
FACTORS AND HYPERFINE SPLITTINGS / 557* FA.2 RELAXATION TIME / 559* FA.3
SPIN-NUMBER DETERMINATIONS / 561* REFERENCES / 561* NOTES / 564* FURTHER
READING / 565* PROBLEMS / 565* APPENDIX G* EPR-RELATED BOOKS AND*
SELECTED CHAPTERS 567* APPENDIX H* FUNDAMENTAL CONSTANTS, CONVERSION*
FACTORS, AND KEY DATA 577* APPENDIX I MISCELLANEOUS GUIDELINES* 588* 1.1
NOTATION FOR SYMBOLS / 588* 1.2 GIOSSARY OF SYMBOLS / 590* 1.3
ABBREVIATIONS / 600* IA EXPONENT NOMENCLATURE / 602* 1.5 JOURNAL
REFERENCE STYLE / 602* AUTHOR INDEX* 603* SUBJECT INDEX* 624*
|
| adam_txt |
* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *
* * * * * * * * * * * * * ****** * * * * * * * * * * * * * * * * * * * *
* * * * * * * * * * * * * * * * * * * * ***** * * * * * * * * * * * * *
* * * * * 1.2* H I S T O R I C A L P E R S P E C T I V E / 3 *
1.3* A S I M P L E E P R S P E C T R O M E T E R / 4 *
1.4* S C O P E O F T H E E P R T E C H N I Q U E /
7 * 1.5* E N E R G Y F L O W IN P A R A M A G N E T I C S Y
S T E M S / I I * 1.6* Q U A N T I Z A T I O N O F A N G
U L A R M O M E N T A / 13* 1.7* R E L A T I O N B E T W E E
N M A G N E T I C M O M E N T S A N D * A N G U L A R M O
M E N T A / 14* 1.8* M A G N E T I C F I E L D Q U A N T I T
I E S A N D U N I T S / 15* 1.9* B U L K M A G N E T I C
P R O P E R T I E S / 18* 1 . 1 0 * M A G N E T I C E N E
R G I E S A N D S T A T E S / 2 0 * 1.11* I N T E R A C T
I O N O F M A G N E T I C D I P O L E S W I T H E L E C T
R O M A G N E T I C * R A D I A T I O N / 21* 1.12* C H A R A C
T E R I S T I C S O F T H E S P I N S Y S T E M S /
23* 1.12.1 T H E G F A C T O R / 23* 1 . 1 2 . 2 C H A R A C
T E R I S T I C S O F D I P O L A R I N T E R A C T I O N S
/ '27 1.13* P A R A L 1 E L - F I E L D E P R / 28* VII
VIII* CONTENTS 1.14 TIME-RESOLVED EPR / 29* 1.15 COMPUTERO1OGY / 29*
1.16 EPR IMAGING / 30* REFERENEES / 30* NOTES / 32* FURTHER READING /
34* PROBLEMS / 35* 2 M A G N E T I C I N T E R A C T I O N
BETWEEN P A R T I C L E S 3 6 * 2.1* INTRODUETION / 36* 2.2*
THEORETIEAL CONSIDERATIONS 01' THE HYPERFINE INTERAETION / 38* 2.3*
ANGULAR-MOMENTUM AND ENERGY OPERATORS / 40* 2.3.1* SPIN OPERATORS AND
HAMILTONIANS / 41* 2.3.2* E1EETRONIE AND NUELEAR ZEEMAN INTERAETIONS /
43* 2.3.3* SPIN HAMILTONIAN INCLUDING ISOTROPIE* HYPERFINE INTERAETION /
46* 2.4* ENERGY LEVELS 01' A SYSTEM WITH ONE UNPAIRED ELEETRON* AND ONE
NUCLEUS WITH 1=1 / 47* 2.5* ENERGY LEVELS 01' A SYSTEM WITH S = 1 AND 1=
1 / 50* 2.6* SIGNS 01' ISOTROPIE HYPERFINE COUPLING CONSTANTS / 53* 2.7
DIPOLAR INTERAETIONS BETWEEN ELEETRONS / 54* REFERENEES / 54* NOTES /
55* FURTHER READING / 56* PROBLEMS / 56* 3 I S O T R O P I C H Y P E
R F I N E E F F E C T S IN EPR S P E C T R A 5 8 * 3.1*
INTRODUETION / 58* 3.2* HYPERFINE SPLITTING FROM PROTONS / 59* 3.2.1*
SINGLE SET 01' EQUIVALENT PROTONS / 59* 3.2.2* MULTIPLE SETS 01'
EQUIVALENT PROTONS / 62* 3.3* HYPERFINE SPLITTINGS FROM OTHER NUCLEI
WITH 1=1 / 68* 3.4* HYPERFINE SPLITTINGS FROM NUELEI WITH I 1/ 69*
3.5* USEFUL RULES FOR THE INTERPRETATION 01' EPR SPEETRA / 74* 3.6*
HIGHER-ORDER CONTRIBUTIONS TO HYPERFINE SPLITTINGS / 75* 3.7* DEVIATIONS
FROM THE SIMPLE MULTINOMIA1 SEHEME / 77* 3.8* OTHER PROBLEMS ENEOUNTERED
IN EPR SPEETRA 01'* FREE RADIEALS / 77* 3.9* SOME INTERESTING 1T-TYPE
FREE RADIEALS / 78* IX CONTENTS REFERENEES / 79* NOTES / 79* FURTHER
READING / 80* PROBLEMS / 80* 4 ZEEMAN ENERGY (G) ANISOTROPY* 85* 4.1*
INTRODUETION / 85* 4.2* SYSTEMS WITH HIGH LOEAL SYMMETRY / 88* 4.3*
SYSTEMS WITH RHOMBIE LOEAL SYMMETRY / 90* 4.4* CONSTRUETION OF THE G
MATRIX / 92* 4.5* SYMMETRY-RELATED SITES / 96* 4.6* EPR LINE INTENSITIES
/ 97* 4.7* STATISTIEALLY RANDOMLY ORIENTED SOLIDS / 99* 4.8* SPIN-ORBIT
COUPLING AND QUANTUM-MEEHANIEAL* MODELING OF R / 105* 4.9 COMPARATIVE
OVERVIEW / 110* REFERENEES / II I* NOTES / 112* FURTHER READING / I 14*
PROBLEMS / I 14* 5 HYPERFINE (A) ANISOTROPY* 118* 5.1* INTRODUETION /
118* 5.2* ORIGIN OF THE ANISOTROPIE PART OF THE* HYPERFINE LNTERAETION /
120* 5.3* DETERMINATION AND INTERPRETATION OF THE* HYPERFINE MATRIX /
122* 5.3.1 THE ANISOTROPIE BREIT-RABI CASE / 122* 5.3.2 THE CASE OF
DOMINANT ELEETRON ZEEMAN ENERGY / 124* 5.3.2.1 GENERALCASE /126 5.3.2.2
THE CASE OF B ;::::; BHF / 128* 5.3.2.3 THE CASE OF B »BHF / 141* 5.4*
COMBINED G AND HYPERFINE ANISOTROPY / 143* 5.5* MULTIPLE HYPERFINE
MATRIEES / 144* 5.6* SYSTEMS WITH J ~ / 144* 5.7 HYPERFINE POWDER
LINESHAPES / 145* REFERENEES / 150* NOTES / 151* FURTHER READING / 152*
X CONTENTS* PROBLEMS / 152* 6 SYSTEMS WITH MORE THAN ONE UNPAIRED
ELECTRON 158* 6.1 INTRODUETION / 158* 6.2 SPIN HAMILTONIAN FOR TWO
INTERAETING ELEETRONS / 159* 6.2.1 ELEETRON-EXEHANGE INTERAETION / 160*
6.2.2 ELEETRON-ELEETRON DIPOLE INTERAETION / 162* 6.3 SYSTEMS WITH S = I
(TRIPLET STATES) / 164* 6.3.1 SPIN ENERGIES AND EIGENFUNETIONS / 165*
6.3.2 'T::.M S = 2' TRANSITIONS / 172* 6.3.3 RANDOMLY ORIENTED TRIPLET
SYSTEMS / 173* 6.3.4 PHOTO-EXEITED TRIPLET-STATE ENTITIES / 177* 6.3.5
THERMALLY AEEESSIBLE TRIPLET ENTITIES / 182* 6.3.6 GROUND-STATE TRIPLET
ENTITIES / 185* 6.3.6.1* CARBENES AND NITRENES / 185* 6.3.6.2* DIANIONS
OF SYMMETRIE AROMATIE* HYDROEARBONS / 187* 6.3.6.3* INORGANIE TRIPLET
SPEEIES / 188* 6.4 INTERAETING RADIEAL PAIRS / 189* 6.5 BIRADIEALS /
190* 6.6 SYSTEMS WITH S I / 195* 6.7 HIGH-SPIN AND HIGH-FIELD ENERGY
TERMS / 196* 6.8 THE SPIN HAMILTONIAN: A SUMMING UP / 197* 6.9 MODELING
THE SPIN-HAMILTONIAN PARAMETERS / 199* REFERENEES / 200* NOTES / 203*
FURTHER READING / 204* PROBLEMS / 205* 7 PARAMAGNETIC SPECIES IN THE GAS
PHASE 208* 7.1 INTRODUETION / 208* 7.2 MONATOMIE GAS-PHASE SPEEIES /
209* 7.3 DIATOMIE GAS-PHASE SPEEIES / 211* 7.4 TRIATOMIE AND POLYATOMIE
GAS-PHASE MOLECULES / 217* 7.5 LASER ELEETRON PARAMAGNETIE RESONANEE /
219* 7.6 OTHER TEEHNIQUES / 219* 7.7 REAETION KINETIES / 220* 7.8
ASTRO-EPR / 220* XI CONTENTS REFERENCES / 221* NOTES / 222* FURTHER
READING / 222* PROBLEMS / 223* 8 TRANSITION-GROUP IONS* 225* 8.1*
INTRODUCTION / 225* 8.2* THE ELECTRONIC GROUND STATES OF D-ELECTRON*
SPECIES / 227* 8.3* THE EPR PARAMETERS OF D-ELECTRON SPECIES / 232* 8.4*
TANABE-SUGANO DIAGRAMS AND ENERGY-LEVEL* CROSSINGS / 240* 8.5* COVALENCY
EFFECTS / 243* 8.6* A FERROELECTRIC SYSTEM / 244* 8.7 SOME F-ELECTRON
SYSTEMS / 245* REFERENCES / 246* NOTES / 248* FURTHER READING / 249*
PROBLEMS / 249* 9 THE INTERPRETATION OF EPR PARAMETERS* 253* 9.1*
INTRODUCTION / 253* 9.2* 1T-TYPE ORGANIC RADICALS / 254* 9.2.1* ANIONS
AND CATIONS OF BENZENE* AND SOME OF ITS DERIVATIVES / 259* 9.2.2* ANIONS
AND CATIONS OF POLYACENES / 262* 9.2.3* G FACTORS OF 1T RADICAIS / 262*
9.2.4* ORIGIN OF PROTON HYPERFINE SPLITTINGS / 263* 9.2.5* SIGN OF THE
PROTON HYPERFINE SPLITTING CONSTANT / 265* 9.2.6* METHYL PROTON
HYPERFINE SPLITTINGS* AND HYPERCONJUGATION / 268* 9.2.7* HYPERFINE
SPLITTING FROM NUCLEI OTHER* THAN PROTONS / 270* 9.2.8* ONE-DIMENSIONAL
CHAIN PARAMAGNETS / 272* 9.3* A-TYPE ORGANIC RADICALS / 274* 9.4*
TRIPLET STATES AND BIRADICALS / 275* 9.5* INORGANIC RADICALS / 276* 9.6*
ELECTRICALLY CONDUCTING SYSTEMS / 281* 9.6.1* METALS / 281* XII*
CONTENTS 9.6.2* METALS DISSOLVED IN AMMONIA AND* AMINE SOLUTIONS / 282*
9.6.3* SEMICONDUCTORS / 283* 9.6.4* GRAPHITIC COMPOUNDS / 285* 9.7*
TECHNIQUES FOR STRUCTURAL ESTIMATES FROM EPR DATA / 285* 9.7.1* THE
NEWMAN SUPERPOSITION MODEL / 285* 9.7.2* THE PSEUDO-CUBE METHOD / 286*
9.7.3* DISTANCES FROM PARAMETER D / 286* 9.7.4* EATONS'
INTERSPIN-DISTANCE FORMULA / 287* 9.7.5 SUMMARY / 287* REFERENCES / 287*
NOTES / 291* FURTHER READING / 291* PROBLEMS / 292* APPENDIX 9A HUECKEL
MOLECULAR-ORBITAL CALCULATIONS / 294* HMO REFERENCES / 298* HMO PROBLEMS
/ 299* 10* RELAXATION TIMES, L1NEWIDTHS AND SPIN KINETIC* PHENOMENA 301*
10.1 INTRODUCTION / 30 I* 10.2 SPIN RELAXATION: GENERAL ASPECTS / 302*
10.2.1 SPIN TEMPERATURE AND BOLTZMANN DISTRIBUTION / 302* 10.2.2 SPIN
DYNAMICS / 303* 10.2.3 MECHANISMS FOR TI / 305* 10.3 SPIN RELAXATION:
BLOCH MODEL / 308* 10.3.1 MAGNETIZATION IN A STATIC MAGNETIC FIELD /
309* 10.3.2 ADDITION OF AN OSCILLATING MAGNETIC FIELD / 310* 10.3.3
ROTATING FRAME / 311* 10.3.4 STEADY-STATE SOLUTIONS 01' BLOCH EQUATIONS
/ 312* 10.4 LINEWIDTHS / 316* 10.4.1 HOMOGENEOUS BROADENING / 316*
10.4.2 INHOMOGENEOUS BROADENING / 316* 10.5 DYNAMIC LINESHAPE EFFECTS /
317* 10.5.1 GENERALIZED BLOCH EQUATIONS / 318* 10.5.2 OTHER THEORETICAL
MODELS / 322* 10.5.3 EXAMPLES OF LINE-BROADENING MECHANISMS / 322*
10.5.3.1 ELECTRON-SPIN EXCHANGE / 323* )0.5.3.2 ELECTRON TRANSFER / 324*
CONTENTS XIII* 10.5.3.3 PROTON TRANSFER / 326* 10.5.3.4 FLUXIONAL MOTION
/ 326* 10.5.4* LINEWIDTH VARIATION: DYNAMIC HYPERFINE* CONTRIBUTIONS /
327* 10.5.4.1 SINGLE NUCLEUS / 328* 10.5.4.2 MULTIPLE NUCLEI / 329*
10.5.5* MOLECULAR TUMBLING EFFECTS / 333* 10.5.5.1 DIPOLAR EFFECTS /
335* 10.5.5.2 SPIN-ROTATION INTERACTION / 339* 10.5.6* GENERAL EXAMPLE /
340* 10.6 LONGITUDINAL DETECTION / 342* 10.7 SATURATION- TRANSFER EPR /
343* 10.8 TIME DEPENDENCE OF THE EPR SIGNAL AMPLITUDE / 343* 10.8.1*
CONCENTRATION CHANGES / 343* 10.8.2* CHEMICALLY INDUCED DYNAMIC
ELECTRON* POLARIZATION / 345* 10.9 DYNAMIC NUCLEAR POLARIZATION / 347*
10.10* BIO-OXYGEN / 347* 10.11 SUMMARY / 347* REFERENCES / 348* NOTES /
351* FURTHER READING / 352* PROBLEMS / 353* 11 NONCONTINUOUS EXCITATION
OF SPINS* 357* 11.1 INTRODUCTION / 357* 11.2 THE IDEALIZED BI SWITCH-ON
/ 359* 11.3 THE SINGLE BI PULSE / 362* 11.4 FOURIER-TRANSFORM EPR AND
FID ANALYSIS / 364* 11.5 MULTIPLE PULSES / 368* 11.6 ELECTRON SPIN-ECHO
ENVELOPE MODULATION / 369* 11.7 ADVANCED TECHNIQUES / 375* I 1.8 SPIN
COHERENCE AND CORRELATION / 375* REFERENCES / 378* NOTES / 380* FURTHER
READING / 381* PROBLEMS / 382* XIV* CONTENTS 12 DOUBLE-RESONANCE
TECHNIQUES* 385* 12.1* INTRODUETION / 385* 12.2* A CONTINUOUS-WAVE ENDOR
EXPERIMENT / 386* 12.3* ENERGY LEVELS AND ENDOR TRANSITIONS / 388* 12.4*
RELAXATION PROEESSES IN STEADY-STATE ENDOR 5 / 392* 12.5* CW ENDOR:
SINGLE-CRYSTAL EXAMPLES / 397* 12.5.1* THE F CENTERS IN THE ALKALI
HALIDES / 397* 12.5.2* METAL-ION TETRAPHENYLPORPHYRINS / 401* 12.6* CW
ENDOR IN POWDERS AND* NON-CRYSTALLINE SOLIDS / 401* 12.7* CW ENDOR IN
LIQUID SOLUTIONS / 402* 12.8* PULSE DOUBLE-RESONANEE EXPERIMENTS / 404*
12.9* ELEETRON-ELEETRON DOUBLE RESONANEE (ELDOR) / 404* 12.10* OPTIEALLY
DETEETED MAGNETIE RESONANEE / 406* 12.11 FLUORESEENEE-DETEETED MAGNETIE
RESONANEE / 407* REFERENEES / 408* NOTES / 410* FURTHER READING / 411*
PROBLEMS / 411* 13 OTHER TOPICS* 414* 13.1* APOLOGIA / 414* 13.2*
BIOLOGIEAL SYSTEMS / 414* 13.3* CLUSTERS / 415* 13.4* CHAREOAL, COAL,
GRAPHITE AND SOOT / 415* 13.5* COLLOIDS / 415* 13.6* ELEETROEHEMIEAL EPR
/ 415* 13.7* EPR IMAGING / 416* 13.8* FERROMAGNETS, ANTIFERROMAGNETS
AND* SUPERPARAMAGNETS / 416* 13.9* GLASSES / 417* 13.10*
GEOLOGIE/MINERALOGIE SYSTEMS* AND SELEETED GEMS / 417* 13.10.1 AMETHYST
/ 417* 13.10.2 BERYL AND CHRYSOBERYL / 417* 13.10.3 DIAMOND / 417*
13.10.4 EMERALD / 418* 13.10.5 OPAL / 418* CONTENTS XV 13.10.6 ROCK
CRYSTAL (A-QUARTZ) / 418* 13.[0.7 RUBY / 418* 13.10.8 SAPPHIRE / 418*
13.10.9 TOPAZ / 418* 13.10.10 TOURMALINE / 419* 13.10.11 TURQUOISE /
419* 13.10.12 ZIRCON / 419* 13.11 LIQUID CRYSTALS / 419* 13.12 "POINT"
DEFECTS / 419* 13.12.1 INSU1ATORS / 419* 13.12.1.1 ALKALI HALIDES / 419*
13.12.1.2 OXIDES / 419* 13.12.2 SEMICONDUCTORS / 420* 13.13 POLYMERS /
420* 13.14 RADIATION DOSAGE AND DATING / 420* 13.15 SPIN LABELS / 421*
13.16 SPIN TRAPS / 421* 13.17 TRAPPED ATOMS AND MOLECULES / 421*
APPENDIX A MATHEMATICAL OPERATIONS* 422* AI* COMPLEX NUMBERS / 422* A.2*
OPERATOR ALGEBRA / 423* A.2.1 PROPERTIES OF OPERATORS / 423* A2.2
EIGENVALUES AND EIGENFUNCTIONS / 426* A3 DETERMINANTS / 428* AA VECTORS:
SCALAR, VECTOR, AND OUTER PRODUCTS / 430* A.5* MATRICES / 432* A5.1
ADDITION AND SUBTRACTION OF MATRICES / 434* A5.2 MULTIPLICATION OF
MATRICES / 434* A.5.3 SPECIAL MATRICES AND MATRIX PROPERTIES / 438* A.5A
DIRAC NOTATION FOR EIGENFUNCTIONS AND* MATRIX ELEMENTS / 438* A.5.5
DIAGONALIZATION OF MATRICES / 440* A5.6 MATRIX INVARIANTS / 446* A.6*
PERTURBATION THEORY / 446* A.7 DIRAC DELTA FUNCTION / 449* A8 GROUP
THEORY / 450* REFERENCES / 450* XVI* CONTENTS NOTES / 451* FURTHER
READING / 451* PROBLEMS / 451* APPENDIX B* QUANTUM MECHANICS OF ANGULAR*
MOMENTUM 455* B.I* [NTRODUCTION / 455* B.2* ANGULAR-MOMENTUM OPERATORS /
457* B.3* COMMUTATION RELATIONS 1'AR GENERAL* ANGULAR-MOMENTUM OPERATORS
/ 458* BA EIGENVALUES 01' J '2 AND J ' Z / 459* B.5* SUPERPOSITION 01'
STATES / 464* B.6* ANGULAR-MOMENTUM MATRICES / 464* B.7* ADDITION 01'
ANGULAR MOMENTA / 466* B.8* NOTATION 1'AR ATOMIC AND MOLECULAR STATES /
472* B.9* ANGULAR MOMENTUM AND DEGENERACY OF STATES / 473* 8.10* TIME
DEPENDENCE / 475* B.II* PRECESSION / 475* B.12* MAGNETIC FLUX
QUANTIZATION / 477* B.13 SUMMARY / 478* REFERENCES / 479* NOTES / 480*
FURTHER READING / 480* PROBLEMS / 481* NOTES FOR PROBLEM B.12 / 483*
APPENDIX C* THE HYDROGEN ATOM AND SELECTED* RADICALS RH" 484* CL*
HYDROGEN ATOM / 484* CL.] SPIN HAMILTONIAN / 484* CI.2 THE SPIN
EIGENKETS AND ENERGY MATRIX / 485* CL .3 EXACT SOLUTION FOR THE ENERGY
EIGENVALUES / 487* CI A ENERGY EIGENSTATES AND ALLOWED TRANSITIONS /
489* CI.5* RESONANT FREQUENCIES IN CONSTANT MAGNETIC FIELD / 493* CI.6*
RESONANT MAGNETIC FIELDS AT CONSTANT* EXCITATION FREQUENCY / 493* CI.7*
CALCULATION OF SPIN ENERGY LEVELS BY* PERTURBATION THEORY / 495*
CONTENTS XVII* C2 RH RADICALS / 497* C3 RH: RADICALS / 498* C3. I SPIN
HAMILTONIAN AND ENERGY LEVELS / 499* C.3.2 EPR TRANSITIONS / 499*
REFERENCES / 50 I* NOTES / 501* FURTHER READING / 502* PROBLEMS / 502*
APPENDIX D* PHOTONS 505* D.I* INTRODUCTION / 505* 0.2* THE PHYSICAL
ASPECTS OF PHOTONS / 505* 0.3 MAGNETIC-RESONANCE ASPECTS / 508*
REFERENCES / 510* NOTES / 510* APPENDIX E* INSTRUMENTATION AND
TECHNICAL* PERFORMANCE 512* E.L* INSTRUMENTAL: BACKGROUND / 512* E.2* CW
EPR SPECTROMETERS / 515* E.2.1 MAGNET SYSTEM / 516* E.2.2 RADIATION
SOURCE / 517* E.2.3 MICROWAVE TRANSMISSION / 518* E.2A COUPLI NG OF THE
SOURCE TO THE RESONATOR / 519* E.2.5 RESONATOR SYSTEM / 520* E.2.6
FIELD-MODULATION SYSTEM / 525* E.2.7 COUPLING OF THE RESONATOR TO THE
DETECTOR / 525* E.2.8 DETECTION SYSTEM / 526* E.3 PULSED EPR
SPECTROMETERS / 529* EA COMPUTER INTERFACING WITH EPR SPECTROMETERS /
530* E.5* TECHNIQUES FOR TEMPERATURE VARIATION* AND CONTROL / 531* E.6
TECHNIQUES TOR PRESSURE VARIATION / 532* REFERENCES / 533* NOTES / 535*
FURTHER READING / 535* PROBLEMS / 536* XVIII CONTENTS APPENDIX
FEXPERIMENTAL CONSIDERATIONS* 537* F.I TECHNIQUES FOR GENERATION OF
PARAMAGNETIC SPECIES / 537* F.2 LINESHAPES AND INTENSITIES / 539* F.2.1
LINESHAPES / 539* F.2.2 SIGNAL INTENSITIES AND SPIN-CONCENTRATION
STANDARDS / 545* F.3 SENSITIVITY AND RESOLUTION / 548* F.3.1 OPTIMUM
SENSITIVITY / 548* F.3.2 SAMPIE TEMPERATURE / 550* F.3.3 MICROWAVE
FREQUENCY / 550* F.3 A Q FACTOR OF THE RESONATOR / 551* F.3.5 MICROWAVE
POWER LEVEL AND MEASUREMENTS OF BI / 553* F.3.6 MODULATION AMPLITUDE /
554* F.3.7 MODULATION FREQUENCY / 557* FA MEASUREMENTS / 557* FA.I G
FACTORS AND HYPERFINE SPLITTINGS / 557* FA.2 RELAXATION TIME / 559* FA.3
SPIN-NUMBER DETERMINATIONS / 561* REFERENCES / 561* NOTES / 564* FURTHER
READING / 565* PROBLEMS / 565* APPENDIX G* EPR-RELATED BOOKS AND*
SELECTED CHAPTERS 567* APPENDIX H* FUNDAMENTAL CONSTANTS, CONVERSION*
FACTORS, AND KEY DATA 577* APPENDIX I MISCELLANEOUS GUIDELINES* 588* 1.1
NOTATION FOR SYMBOLS / 588* 1.2 GIOSSARY OF SYMBOLS / 590* 1.3
ABBREVIATIONS / 600* IA EXPONENT NOMENCLATURE / 602* 1.5 JOURNAL
REFERENCE STYLE / 602* AUTHOR INDEX* 603* SUBJECT INDEX* 624* |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Weil, John A. Bolton, James R. 1937- |
| author_GND | (DE-588)143601547 |
| author_facet | Weil, John A. Bolton, James R. 1937- |
| author_role | aut aut |
| author_sort | Weil, John A. |
| author_variant | j a w ja jaw j r b jr jrb |
| building | Verbundindex |
| bvnumber | BV022550352 |
| callnumber-first | Q - Science |
| callnumber-label | QC763 |
| callnumber-raw | QC763 |
| callnumber-search | QC763 |
| callnumber-sort | QC 3763 |
| callnumber-subject | QC - Physics |
| classification_rvk | UP 9340 UP 9400 VG 9700 |
| ctrlnum | (OCoLC)69020990 (DE-599)BVBBV022550352 |
| dewey-full | 543/.67 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 543 - Analytical chemistry |
| dewey-raw | 543/.67 |
| dewey-search | 543/.67 |
| dewey-sort | 3543 267 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| discipline_str_mv | Chemie / Pharmazie Physik |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV022550352 |
| illustrated | Illustrated |
| index_date | 2024-07-02T18:13:18Z |
| indexdate | 2024-07-09T21:00:03Z |
| institution | BVB |
| isbn | 047175496X 9780471754961 |
| language | English |
| lccn | 2006016130 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-015756679 |
| oclc_num | 69020990 |
| open_access_boolean | |
| owner | DE-703 DE-19 DE-BY-UBM DE-11 DE-188 DE-355 DE-BY-UBR DE-20 DE-29T |
| owner_facet | DE-703 DE-19 DE-BY-UBM DE-11 DE-188 DE-355 DE-BY-UBR DE-20 DE-29T |
| physical | XXIII, 664 S. graph. Darst. |
| publishDate | 2007 |
| publishDateSearch | 2007 |
| publishDateSort | 2007 |
| publisher | Wiley-Interscience |
| record_format | marc |
| spelling | Weil, John A. Verfasser aut Electron paramagnetic resonance elementary theory and practical applications John A. Weil ; James R. Bolton 2. ed. Hoboken, N.J. Wiley-Interscience 2007 XXIII, 664 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references Spectroscopie de résonance paramagnétique électronique Electron paramagnetic resonance spectroscopy Theorie (DE-588)4059787-8 gnd rswk-swf Anwendung (DE-588)4196864-5 gnd rswk-swf Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd rswk-swf Elektronenspinresonanz (DE-588)4132116-9 gnd rswk-swf Elektronenspinresonanzspektroskopie (DE-588)4151888-3 s DE-604 Theorie (DE-588)4059787-8 s 1\p DE-604 Anwendung (DE-588)4196864-5 s 2\p DE-604 Elektronenspinresonanz (DE-588)4132116-9 s 3\p DE-604 Bolton, James R. 1937- Verfasser (DE-588)143601547 aut http://www.loc.gov/catdir/toc/ecip0613/2006016130.html Table of contents only OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015756679&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Weil, John A. Bolton, James R. 1937- Electron paramagnetic resonance elementary theory and practical applications Spectroscopie de résonance paramagnétique électronique Electron paramagnetic resonance spectroscopy Theorie (DE-588)4059787-8 gnd Anwendung (DE-588)4196864-5 gnd Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd Elektronenspinresonanz (DE-588)4132116-9 gnd |
| subject_GND | (DE-588)4059787-8 (DE-588)4196864-5 (DE-588)4151888-3 (DE-588)4132116-9 |
| title | Electron paramagnetic resonance elementary theory and practical applications |
| title_auth | Electron paramagnetic resonance elementary theory and practical applications |
| title_exact_search | Electron paramagnetic resonance elementary theory and practical applications |
| title_exact_search_txtP | Electron paramagnetic resonance elementary theory and practical applications |
| title_full | Electron paramagnetic resonance elementary theory and practical applications John A. Weil ; James R. Bolton |
| title_fullStr | Electron paramagnetic resonance elementary theory and practical applications John A. Weil ; James R. Bolton |
| title_full_unstemmed | Electron paramagnetic resonance elementary theory and practical applications John A. Weil ; James R. Bolton |
| title_short | Electron paramagnetic resonance |
| title_sort | electron paramagnetic resonance elementary theory and practical applications |
| title_sub | elementary theory and practical applications |
| topic | Spectroscopie de résonance paramagnétique électronique Electron paramagnetic resonance spectroscopy Theorie (DE-588)4059787-8 gnd Anwendung (DE-588)4196864-5 gnd Elektronenspinresonanzspektroskopie (DE-588)4151888-3 gnd Elektronenspinresonanz (DE-588)4132116-9 gnd |
| topic_facet | Spectroscopie de résonance paramagnétique électronique Electron paramagnetic resonance spectroscopy Theorie Anwendung Elektronenspinresonanzspektroskopie Elektronenspinresonanz |
| url | http://www.loc.gov/catdir/toc/ecip0613/2006016130.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015756679&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT weiljohna electronparamagneticresonanceelementarytheoryandpracticalapplications AT boltonjamesr electronparamagneticresonanceelementarytheoryandpracticalapplications |