Mass transfer and separation processes: principles and applications
Gespeichert in:
| Vorheriger Titel: | Basmadjian, Diran Mass transfer |
|---|---|
| 1. Verfasser: | |
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Boca Raton [u.a.]
CRC Press
2007
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| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Publisher description Inhaltsverzeichnis Inhaltsverzeichnis |
| Beschreibung: | 487 S. Ill., graph. Darst. |
| ISBN: | 9781420051599 1420051598 |
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| 245 | 1 | 0 | |a Mass transfer and separation processes |b principles and applications |c Diran Basmadjian |
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Datensatz im Suchindex
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| adam_text | Titel: Mass transfer and separation processes
Autor: Basmadjian, Diran
Jahr: 2007
Table of Contents
1 Some Basic Notions: Rates of Mass Transfer..............................1
1.1 Gradient-Driven and Forced Transport.....................................................2
1.1.1 The Rate Laws...................................................................................2
1.1.2 The Transport Diffusivities..............................................................5
1.1.3 The Gradient......................................................................................7
1.1.4 Simple Integrations of Fick s Law................................................14
1.2 Transport Driven by a Potential Difference (Constant Gradient):
The Film Concept and the Mass Transfer Coefficient...........................21
1.2.1 Units of the Potential and of the Mass Transfer Coefficient.... 24
1.2.2 Equimolar Diffusion and Diffusion through a Stagnant Film:
The Log-Mean Concentration Difference....................................26
1.2.2.1 Equimolar Counterdiffusion...........................................27
1.2.2.2 Diffusion through a Stagnant Film................................27
1.3 The Two-Film Theory.................................................................................33
1.3.1 Overall Driving Forces and Mass Transfer Coefficients...........36
1.3.1.1 Comments..........................................................................38
Practice Problems..................................................................................................42
2 Modeling Mass Transport: The Mass Balances.........................51
2.1 The Compartment or Stirred Tank and the One-Dimensional Pipe ....51
2.2 The Classification of Mass Balances.........................................................62
2.2.1 The Role of Balance Space.............................................................62
2.2.2 The Role of Time.............................................................................63
2.2.2.1 Unsteady Integral Balances.............................................63
2.2.2.2 Cumulative (Integral) Balances......................................63
2.2.2.3 Unsteady Differential Balances.......................................64
2.2.3 Dependent and Independent Variables.......................................64
2.3 Information Obtained from Model Solutions.........................................76
2.4 Setting Up Partial Differential Equations................................................78
2.5 The General Conservation Equations......................................................90
Practice Problems..................................................................................................99
3 Diffusion through Gases, Liquids, and Solids.......................107
3.1 Diffusion Coefficients................................................................................107
3.1.1 Diffusion in Gases.........................................................................107
3.1.2 Diffusion in Liquids......................................................................Ill
3.1.3 Diffusion in Solids.........................................................................118
3.1.3.1 Diffusion of Gases through Polymers and Metals.... 118
3.1.3.2 Diffusion of Gases through Porous Solids.................126
3.1.3.3 Diffusion of Solids in Solids.........................................134
Practice Problems.......................?.....................................................................137
4 More about Diffusion: Transient Diffusion and
Diffusion with Reaction............................................................143
4.1 Transient Diffusion....................................................................................143
4.1.1 Source Problems............................................................................145
4.1.2 Nonsource Problems.....................................................................157
4.1.2.1 Diffusion into a Semi-Infinite Medium.......................157
4.1.2.2 Diffusion in Finite Geometries:
The Plane Sheet, the Cylinder, and the Sphere.........161
4.1.2.3 Diffusion in Finite Geometries:
The Short-Time and Long-Time Solutions.........166
4.2 Diffusion and Reaction.............................................................................170
4.2.1 Reaction and Diffusion in a Catalyst Particle..........................171
4.2.2 Gas-Solid Reactions Accompanied by Diffusion:
Moving-Boundary Problems.......................................................171
4.2.3 Gas-Liquid Systems: Reaction and Diffusion in the
Liquid Film.....................................................................................172
Practice Problems................................................................................................186
5 More about Mass Transfer Coefficients...................................195
5.1 Dimensionless Groups..............................................................................196
5.2 Mass Transfer Coefficients in Laminar Flow: Extraction from the
PDE Model..................................................................................................200
5.2.1 Mass Transfer Coefficients in Laminar Tubular Flow.............201
5.2.2 Mass Transfer Coefficients in Laminar Flow around
Simple Geometries........................................................................203
5.3 Mass Transfer in Turbulent Flow: Dimensional Analysis and the
Buckingham % Theorem...........................................................................206
5.3.1 Dimensional Analysis...................................................................206
5.3.2 The Buckingham k Theorem.......................................................207
5.4 Mass Transfer Coefficients for Tower Packings....................................216
5.5 Mass Transfer Coefficients in Agitated Vessels....................................222
5.6 Mass Transfer Coefficients in the Environment:
Uptake and Clearance of Toxic Substances in Animals ?
The Bioconcentration Factor....................................................................226
Practice Problems................................................................................................231
6 Phase Equilibria.......................................................................... 239
6.1 Single-Component Systems: Vapor Pressure........................................240
6.2 Multicomponent Systems: Distribution of a Single Component.......246
6.2.1 Gas-Liquid Equilibria...................................................................246
6.2.2 Liquid and Solid Solubilities.......................................................251
6.2.3 Fluid-Solid Equilibria: The Langmuir Isotherm......................253
6.2.4 Liquid-Liquid Equilibria: The Triangular Phase Diagram ....264
6.2.5 Equilibria Involving a Supercritical Fluid................................270
6.2.6 Equilibria in Biology and the Environment:
Partitioning of a Solute between Compartments.....................274
6.3 Multicomponent Equilibria: Distribution of Several Components.....276
6.3.1 The Phase Rule..............................................................................276
6.3.2 Binary Vapor-Liquid Equilibria..................................................277
6.3.2.1 Phase Diagrams...............................................................277
6.3.2.2 Ideal Solutions and Raoult s Law:
Deviation from Ideality.................................................280
6.3.2.3 Activity Coefficients.......................................................282
6.3.3 The Separation Factor oc: Azeotropes.........................................284
Practice Problems................................................................................................293
7 Staged Operations: The Equilibrium Stage.............................299
7.1 Equilibrium Stages....................................................................................301
7.1.1 Single-Stage Processes..................................................................301
7.1.2 Single-Stage Differential Operation...........................................307
7.2 Staged Cascades.........................................................................................313
7.2.1 Crosscurrent Cascades..................................................................313
7.2.2 Countercurrent Cascades.............................................................320
7.2.3 Countercurrent Cascades: The Linear Case and the
Kremser Equation..........................................................................323
7.3 The Equilibrium Stage in the Real World.............................................330
7.3.1 The Mixer-Settler Configuration................................................330
7.3.2 Gas-Liquid Systems: The Tray Tower.......................................331
7.3.3 Staged Liquid Extraction Again: The Karr Column................332
7.3.4 Staged Leaching: Oil Extraction from Seeds............................333
7.3.5 Staged Washing of Solids (CCD)................................................335
7.4 Multistage Distillation..............................................................................336
7.4.1 Continuous Fractional Distillation.............................................337
7.4.2 Mass and Energy Balances: Equimolar Overflow and
Vaporization...................................................................................339
7.4.3 The McCabe-Thiele Diagram......................................................341
7.4.4 Minimum Reflux Ratio and Number of Plates........................346
7.4.4.1 Comments........................................................................348
7.4.5 Column and Tray Parameters.....................................................356
7.4.6 Limiting Flow Rates: Column Diameter...................................358
7.4.6.1 Gas or Vapor Flow Rates...............................................359
7.4.6.2 Liquid Velocities..............................................................360
7.4.6.3 Lower Limits...................................................................360
7.4.6.4 Comments........................................................................360
7.4.7 Batch Fractional Distillation: Model Equations and
Some Simple Algebraic Calculations.........................................360
7.4.7.1 Distillation at Constant xn, Variable R........................362
7.4.7.2 Distillation at Constant R, Variable xD........................364
7.4.7.3 Multicomponent Batch Distillation
(Forget McCabe-Thiele, Part 2)....................................366
7.5 Percolation Processes.............................................................-..................367
7.6 Stage Efficiencies........................................................................................370
7.6.1 Distillation and Absorption.........................................................370
7.6.2 Extraction........................................................................................372
7.6.3 Adsorption and Leaching............................................................372
7.6.4 Percolation Processes....................................................................373
Practice Problems................................................................................................376
8 Continuous-Contact Operations................................................385
8.1 Packed-Column Operation.......................................................................386
8.1.1 The Countercurrent Gas Scrubber Revisited............................387
8.1.1.1 Comments........................................................................390
8.1.2 The Countercurrent Gas Scrubber Again: Analysis of the
Linear Case.....................................................................................391
8.1.2.1 Comments........................................................................394
8.1.3 Packed Column Characteristics..................................................395
8.1.3.1 Main Features..................................................................395
8.1.3.2 Relation between HTU and HETP...............................396
8.1.3.3 Operational Parameters.................................................396
8.1.3.4 Comparison of Packed and Tray Columns................398
8.1.4 Liquid-Liquid Extraction in a Packed Column.......................403
8.2 Membrane Processes.................................................................................411
8.2.1 Membrane Structure, Configuration, and Applications.........413
8.2.2 Process Considerations and Calculations.................................418
Practice Problems................................................................................................433
9 Simultaneous Heat and Mass Transfer....................................439
9.1 The Air-Water System: Humidification and Dehumidification,
Evaporative Cooling..................................................................................440
9.1.1 The Wet-Bulb Temperature..........................................................440
9.1.2 The Adiabatic Saturation Temperature and the
Psychrometric Ratio......................................................................441
9.1.3 Model for Countercurrent Air-Water Contact:
The Water Cooling Tower.............................................................448
9.1.3.1 Water Balance Over Gas Phase (kg H20/mls)..........448
9.1.3.2 Water Balance Over Water Phase.................................449
9.1.3.3 Gas-Phase Energv Balance (kj/m2s)............................450
9.1.3.4 Liquid-Phase Energy Balance (k!/m%).......................450
9.2 Drying Operations.....................................................................................455
9.3 Heat Effects in a Catalyst Pellet: The Nonisothermal
Effectiveness Factor...................................................................................462
9.3.1 Comments.......................................................................................465
Practice Problems................................................................................................467
Selected References__..___...__.....................__...............?...........?......... 469
Appendix Al: The D-Qperatar Method...................__..................?...?.475
Appendix A2: Hyperbolic Functions and OBEs.....................__....__...?477
|
| adam_txt |
Titel: Mass transfer and separation processes
Autor: Basmadjian, Diran
Jahr: 2007
Table of Contents
1 Some Basic Notions: Rates of Mass Transfer.1
1.1 Gradient-Driven and Forced Transport.2
1.1.1 The Rate Laws.2
1.1.2 The Transport Diffusivities.5
1.1.3 The Gradient.7
1.1.4 Simple Integrations of Fick's Law.14
1.2 Transport Driven by a Potential Difference (Constant Gradient):
The Film Concept and the Mass Transfer Coefficient.21
1.2.1 Units of the Potential and of the Mass Transfer Coefficient. 24
1.2.2 Equimolar Diffusion and Diffusion through a Stagnant Film:
The Log-Mean Concentration Difference.26
1.2.2.1 Equimolar Counterdiffusion.27
1.2.2.2 Diffusion through a Stagnant Film.27
1.3 The Two-Film Theory.33
1.3.1 Overall Driving Forces and Mass Transfer Coefficients.36
1.3.1.1 Comments.38
Practice Problems.42
2 Modeling Mass Transport: The Mass Balances.51
2.1 The Compartment or Stirred Tank and the One-Dimensional Pipe .51
2.2 The Classification of Mass Balances.62
2.2.1 The Role of Balance Space.62
2.2.2 The Role of Time.63
2.2.2.1 Unsteady Integral Balances.63
2.2.2.2 Cumulative (Integral) Balances.63
2.2.2.3 Unsteady Differential Balances.64
2.2.3 Dependent and Independent Variables.64
2.3 Information Obtained from Model Solutions.76
2.4 Setting Up Partial Differential Equations.78
2.5 The General Conservation Equations.90
Practice Problems.99
3 Diffusion through Gases, Liquids, and Solids.107
3.1 Diffusion Coefficients.107
3.1.1 Diffusion in Gases.107
3.1.2 Diffusion in Liquids.Ill
3.1.3 Diffusion in Solids.118
3.1.3.1 Diffusion of Gases through Polymers and Metals. 118
3.1.3.2 Diffusion of Gases through Porous Solids.126
3.1.3.3 Diffusion of Solids in Solids.134
Practice Problems.?.137
4 More about Diffusion: Transient Diffusion and
Diffusion with Reaction.143
4.1 Transient Diffusion.143
4.1.1 Source Problems.145
4.1.2 Nonsource Problems.157
4.1.2.1 Diffusion into a Semi-Infinite Medium.157
4.1.2.2 Diffusion in Finite Geometries:
The Plane Sheet, the Cylinder, and the Sphere.161
4.1.2.3 Diffusion in Finite Geometries:
The ''Short-Time" and "Long-Time" Solutions.166
4.2 Diffusion and Reaction.170
4.2.1 Reaction and Diffusion in a Catalyst Particle.171
4.2.2 Gas-Solid Reactions Accompanied by Diffusion:
Moving-Boundary Problems.171
4.2.3 Gas-Liquid Systems: Reaction and Diffusion in the
Liquid Film.172
Practice Problems.186
5 More about Mass Transfer Coefficients.195
5.1 Dimensionless Groups.196
5.2 Mass Transfer Coefficients in Laminar Flow: Extraction from the
PDE Model.200
5.2.1 Mass Transfer Coefficients in Laminar Tubular Flow.201
5.2.2 Mass Transfer Coefficients in Laminar Flow around
Simple Geometries.203
5.3 Mass Transfer in Turbulent Flow: Dimensional Analysis and the
Buckingham % Theorem.206
5.3.1 Dimensional Analysis.206
5.3.2 The Buckingham k Theorem.207
5.4 Mass Transfer Coefficients for Tower Packings.216
5.5 Mass Transfer Coefficients in Agitated Vessels.222
5.6 Mass Transfer Coefficients in the Environment:
Uptake and Clearance of Toxic Substances in Animals ?
The Bioconcentration Factor.226
Practice Problems.231
6 Phase Equilibria. 239
6.1 Single-Component Systems: Vapor Pressure.240
6.2 Multicomponent Systems: Distribution of a Single Component.246
6.2.1 Gas-Liquid Equilibria.246
6.2.2 Liquid and Solid Solubilities.251
6.2.3 Fluid-Solid Equilibria: The Langmuir Isotherm.253
6.2.4 Liquid-Liquid Equilibria: The Triangular Phase Diagram .264
6.2.5 Equilibria Involving a Supercritical Fluid.270
6.2.6 Equilibria in Biology and the Environment:
Partitioning of a Solute between Compartments.274
6.3 Multicomponent Equilibria: Distribution of Several Components.276
6.3.1 The Phase Rule.276
6.3.2 Binary Vapor-Liquid Equilibria.277
6.3.2.1 Phase Diagrams.277
6.3.2.2 Ideal Solutions and Raoult's Law:
Deviation from Ideality.280
6.3.2.3 Activity Coefficients.282
6.3.3 The Separation Factor oc: Azeotropes.284
Practice Problems.293
7 Staged Operations: The Equilibrium Stage.299
7.1 Equilibrium Stages.301
7.1.1 Single-Stage Processes.301
7.1.2 Single-Stage Differential Operation.307
7.2 Staged Cascades.313
7.2.1 Crosscurrent Cascades.313
7.2.2 Countercurrent Cascades.320
7.2.3 Countercurrent Cascades: The Linear Case and the
Kremser Equation.323
7.3 The Equilibrium Stage in the Real World.330
7.3.1 The Mixer-Settler Configuration.330
7.3.2 Gas-Liquid Systems: The Tray Tower.331
7.3.3 Staged Liquid Extraction Again: The Karr Column.332
7.3.4 Staged Leaching: Oil Extraction from Seeds.333
7.3.5 Staged Washing of Solids (CCD).335
7.4 Multistage Distillation.336
7.4.1 Continuous Fractional Distillation.337
7.4.2 Mass and Energy Balances: Equimolar Overflow and
Vaporization.339
7.4.3 The McCabe-Thiele Diagram.341
7.4.4 Minimum Reflux Ratio and Number of Plates.346
7.4.4.1 Comments.348
7.4.5 Column and Tray Parameters.356
7.4.6 Limiting Flow Rates: Column Diameter.358
7.4.6.1 Gas or Vapor Flow Rates.359
7.4.6.2 Liquid Velocities.360
7.4.6.3 Lower Limits.360
7.4.6.4 Comments.360
7.4.7 Batch Fractional Distillation: Model Equations and
Some Simple Algebraic Calculations.360
7.4.7.1 Distillation at Constant xn, Variable R.362
7.4.7.2 Distillation at Constant R, Variable xD.364
7.4.7.3 Multicomponent Batch Distillation
(Forget McCabe-Thiele, Part 2).366
7.5 Percolation Processes.-.367
7.6 Stage Efficiencies.370
7.6.1 Distillation and Absorption.370
7.6.2 Extraction.372
7.6.3 Adsorption and Leaching.372
7.6.4 Percolation Processes.373
Practice Problems.376
8 Continuous-Contact Operations.385
8.1 Packed-Column Operation.386
8.1.1 The Countercurrent Gas Scrubber Revisited.387
8.1.1.1 Comments.390
8.1.2 The Countercurrent Gas Scrubber Again: Analysis of the
Linear Case.391
8.1.2.1 Comments.394
8.1.3 Packed Column Characteristics.395
8.1.3.1 Main Features.395
8.1.3.2 Relation between HTU and HETP.396
8.1.3.3 Operational Parameters.396
8.1.3.4 Comparison of Packed and Tray Columns.398
8.1.4 Liquid-Liquid Extraction in a Packed Column.403
8.2 Membrane Processes.411
8.2.1 Membrane Structure, Configuration, and Applications.413
8.2.2 Process Considerations and Calculations.418
Practice Problems.433
9 Simultaneous Heat and Mass Transfer.439
9.1 The Air-Water System: Humidification and Dehumidification,
Evaporative Cooling.440
9.1.1 The Wet-Bulb Temperature.440
9.1.2 The Adiabatic Saturation Temperature and the
Psychrometric Ratio.441
9.1.3 Model for Countercurrent Air-Water Contact:
The Water Cooling Tower.448
9.1.3.1 Water Balance Over Gas Phase (kg H20/mls).448
9.1.3.2 Water Balance Over Water Phase.449
9.1.3.3 Gas-Phase Energv Balance (kj/m2s).450
9.1.3.4 Liquid-Phase Energy Balance (k!/m%).450
9.2 Drying Operations.455
9.3 Heat Effects in a Catalyst Pellet: The Nonisothermal
Effectiveness Factor.462
9.3.1 Comments.465
Practice Problems.467
Selected References_._._._.?.?. 469
Appendix Al: The D-Qperatar Method._.?.?.475
Appendix A2: Hyperbolic Functions and OBEs._._.?477 |
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| author | Basmadjian, Diran |
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| dewey-ones | 660 - Chemical engineering |
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| dewey-sort | 3660.28423 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Physik |
| discipline_str_mv | Chemie / Pharmazie Physik |
| edition | 2. ed. |
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| id | DE-604.BV022494962 |
| illustrated | Illustrated |
| index_date | 2024-07-02T17:53:11Z |
| indexdate | 2024-07-09T20:58:50Z |
| institution | BVB |
| isbn | 9781420051599 1420051598 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-015702113 |
| oclc_num | 255831191 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-703 DE-83 DE-634 |
| owner_facet | DE-91G DE-BY-TUM DE-703 DE-83 DE-634 |
| physical | 487 S. Ill., graph. Darst. |
| publishDate | 2007 |
| publishDateSearch | 2007 |
| publishDateSort | 2007 |
| publisher | CRC Press |
| record_format | marc |
| spelling | Basmadjian, Diran Verfasser aut Mass transfer and separation processes principles and applications Diran Basmadjian 2. ed. Boca Raton [u.a.] CRC Press 2007 487 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Mass transfer Textbooks Separation (Technology) Textbooks Stoffübertragung (DE-588)4057696-6 gnd rswk-swf Stoffübertragung (DE-588)4057696-6 s DE-604 1. Auflage Basmadjian, Diran Mass transfer http://www.loc.gov/catdir/enhancements/fy0708/2007008242-d.html Publisher description lizenzfrei http://www.loc.gov/catdir/toc/ecip0712/2007008242.html lizenzfrei Inhaltsverzeichnis HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015702113&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Basmadjian, Diran Mass transfer and separation processes principles and applications Mass transfer Textbooks Separation (Technology) Textbooks Stoffübertragung (DE-588)4057696-6 gnd |
| subject_GND | (DE-588)4057696-6 |
| title | Mass transfer and separation processes principles and applications |
| title_auth | Mass transfer and separation processes principles and applications |
| title_exact_search | Mass transfer and separation processes principles and applications |
| title_exact_search_txtP | Mass transfer and separation processes principles and applications |
| title_full | Mass transfer and separation processes principles and applications Diran Basmadjian |
| title_fullStr | Mass transfer and separation processes principles and applications Diran Basmadjian |
| title_full_unstemmed | Mass transfer and separation processes principles and applications Diran Basmadjian |
| title_old | Basmadjian, Diran Mass transfer |
| title_short | Mass transfer and separation processes |
| title_sort | mass transfer and separation processes principles and applications |
| title_sub | principles and applications |
| topic | Mass transfer Textbooks Separation (Technology) Textbooks Stoffübertragung (DE-588)4057696-6 gnd |
| topic_facet | Mass transfer Textbooks Separation (Technology) Textbooks Stoffübertragung |
| url | http://www.loc.gov/catdir/enhancements/fy0708/2007008242-d.html http://www.loc.gov/catdir/toc/ecip0712/2007008242.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015702113&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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Inhaltsverzeichnis