Interfacial forces in aqueous media:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Boca Raton, Fla. [u.a.]
Taylor & Francis
2006
|
| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Table of contents only Publisher description Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references (p. 407-430) and index |
| Beschreibung: | 438 S. Ill., graph. Darst. 24 cm |
| ISBN: | 9781574444827 1574444824 |
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| 100 | 1 | |a Van Oss, Carel J. |d 1923- |e Verfasser |0 (DE-588)172431549 |4 aut | |
| 245 | 1 | 0 | |a Interfacial forces in aqueous media |c Carel J. van Oss |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Boca Raton, Fla. [u.a.] |b Taylor & Francis |c 2006 | |
| 300 | |a 438 S. |b Ill., graph. Darst. |c 24 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references (p. 407-430) and index | ||
| 650 | 7 | |a Bioquímica |2 larpcal | |
| 650 | 7 | |a Físico-química |2 larpcal | |
| 650 | 7 | |a Química de superfície |2 larpcal | |
| 650 | 7 | |a Soluções (química) |2 larpcal | |
| 650 | 4 | |a Surface chemistry | |
| 650 | 4 | |a Solution (Chemistry) | |
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Datensatz im Suchindex
| _version_ | 1804136560685219840 |
|---|---|
| adam_text | Contents
Chapter I Introduction „... ]
Non-Covalenl Interactions „„„„„.„., „, .... ..,.., .... ... 1
van der Waals Forces..,. „,. .... „...„„ „ ]
Polar, or Lewis Acid-Base (AB) Interactknis ..„ ........2
Electrostatic (EL) Interactions .„. .„„„.,„..,. 3
Other Non-Covalent Forces .„. „.„....,.,.,. 4
Browman Movement (BR) Forces ..,. .4
Genera] B ibliography ....„ 4
PARTI Theory
Chapter n Lifshitz-van der Waals(LW) Interactions 9
van der Waals Forces,.,. , „.. 9
Macroscopic Approximation - 10
The Lifshkz Approach .r,. 12
Fnterfacial Lifshilz-van der Waals Interactions .— .r,. 16
Addirivity of the Three Elecbodynamk Contributions to the Surface Tension 17
Coda IS
Chapter III Relation Between the Hamaker Consent and the Apolar
Surface Tension Component 19
Proportionality Factor A/y^w 19
Significance of the Averaged €0 Value - - 20
Applicability of Eq. [III-l] to A,? A,2,, A,ä, .22
Coda ~ - 24
Chapter IV Polar or Lewis Acid-Base Interactions 25
Interfacial Lewis Acid Base Interactions - 25
The Young-Dupre Equation — - 2S
Atlraclive and Repulsive Polar Forces,™ - - —— 29
Relative Values of the Electron-Acceptor and Eleelron-Donor Parameters of Y 31
Monopolar Surfaces and Substances - - - 33
Different Modes of Intera^iion Between Two Polar Substances 36
The Surface Tension of Liquids and Solids™.. .„. 39
Inierfacial Tensions Between Polar Liquids,..-™- - - - —,.40
Earlier Approaches to Correlate Contact Angles and Surface Tensions
in Polar Systems. — -..-..— ¦- 41
Comparison Between Repulsive Lifsbia-van der Waals and Repulsive
Acid-Base Interactions...,-, --¦¦- ¦ - -¦¦-» -- -¦ ¦ - — 41
The Mechanisms Allowing AG : and AGm to Be Positive 45
Implications of AG^, 0 47
Implications of AG,32 0 47
Connection Between Hydrophobie and Hydrophilic Interactions 48
Coda 48
Chapter V Electrical Double Layer Interactions 51
Electrokinetic Potential and Ionic Double Layer 51
Free Energy of Electrostatic Interactions 53
Electrokinetic Phenomena 54
^-Potential, Ionic Strength and Electrokinetic Mobility 55
Influence of the Double Layer 56
Thick Double Layer 56
Thin Double Layer 58
Relaxation 60
Validity Ranges of the Equations 62
Confrontation of the Equations with Experimental Data 63
Small Ka 63
Large Ka 64
Transition 0.1 Ka 300 64
Calculation of ^-Potentials from Mobility Data 64
The Brooks Effect 67
Coda 68
Chapter VI Brownian Movement Forces—Osmotic Interactions
of Polymers 71
Brownian Movement Forces 71
Osmotic Interactions 72
Radius of Gyration 74
Polymer Concentration 75
Size and Shape of Polymer Molecules 75
Coda 78
Chapter VII Rate of Decay with Distance 79
Unretarded Lifshitz-van der Waals Forces 79
Retarded London-van der Waals Forces 80
Polar(AB) Interactions g|
Electrical Double Layer Interactions 84
Brownian Movement Interactions 84
Combined Interaction Forces Acting on Solids or on Suspended Particles
in Polymer Solutions 85
The Derjaguin Approximation 86
Energy-Balance Diagrams g6
Coda on
PART II Interfacial Properties and Structure
of Liquid Water
Chapter VIII Lifshitz-van der Waals and Lewis Acid-Base Properties
of Liquid Water—Physical and Physico-Chemical Effects 93
Dominance of the Lewis Acid-Base Properties of Water 93
Effect of Temperature on the y-Components of Water 94
The Surface Properties of Ice at 0°C 96
Cluster Formation in Liquid Water 97
Coda 99
Chapter IX Role of Water in Hydrophobie Attraction 101
The Hydrogen-Bonding (Lewis Acid-Base) Free Energy of Cohesion
of Water and the Hydrophobie Effect 101
Hydrophobie Hydration 102
Clathrate Formation 103
Action at a Distance 104
Modulation of the Hydrophobizing Capacity of Water 104
Decreasing IAG^ 1 104
Increasing IAG?^ 1 105
Coda 107
Chapter X Role of Water in Hydrophilic Repulsion 109
Water and Hydration Forces 109
Negative yiw Values and Hydrophilic Repulsion 110
Hydration Orientation and Action at a Distance 110
Hydrophilicity and Hydration Orientation 112
Hydration Orientation of Proteins 112
Modulation of the Hydrophilic Repulsion Through Temperature Changes 114
Raising AG^ 114
Lowering AGf^ 114
Coda 115
Chapter XI The Water-Air Interface 117
Hyper-Hydrophobicity of Air at the Water-Air Interface 117
Quantitative Expression of the Total Hydrophobie Attraction Energy
at the Water-Air Interface 119
Absence of Hydration of Air at the Water-Air Interface 120
Attraction of Partly Polar, or Amphiphilic Solutes to the Water-Air Interface.
Which decreases the Apparent Surface Tension of Water 121
Repulsion of Hydrophilic, or Near-Hydrophilic Solutes by the Air-Side of the
Water-Air Interface; the Increase of the Surface Tension of Aqueous Solutions
by the Admixture of Sugars and Salts 123
The ^-Potential of Air Bubbles in Water 124
Coda 126
PART III Experimental Measurement Methods
Chapter XII Contact Angle and Surface Tension Determination
and Preparation of Solid Surfaces 131
The Sessile Drop as a Force Balance 131
Spreading Pressure 131
Contact Angle Measurement in Air-Hysteresis 134
Contact Angles on Heterogeneous Surfaces—Cassie s Equation 135
Contact Angle Measurement in Liquids 137
Contact Angle Measurement by Wicking 139
Surface Tension of Liquids 141
Apolar and Polar Surface Tension Component of Liquids 142
Estimation of the Polar Surface Tension Parameters Yl and Yl of Liquids 143
Gel Method 143
Polar Solids Method 144
Purity of Contact Angle Liquids 148
Surface Tension and Surface Free Energy 149
Influence of Temperature on the Properties of Water as aContact Angle Liquid 149
Influence of the pH of Water as a Contact Angle Liquid on the
Surface Properties of Electrically Charged Solid Surfaces 150
Influence of the pH of Water on the Properties of Water Itself, in Connection
with Its Use as aContact Angle Liquid 151
Preparation of Solid Surfaces 152
Particles and Cells 152
Dried Solutes 153
Hydrated Solutes 153
Coda 155
Chapter XIII Interfacial Tension Determination—Influence
of Macroscopic- and Microscopic-Scale Interactions 157
Interfacial Tensions and Free Energies of Interfacial Interaction 157
Interfacial Tension Between Immiscible Liquids 158
Determination of Interfacial Tensions Between Condensed-Phase Materials
and Water 158
The Aqueous Solubility Approach for Determining Yow 160
Use of the cmc of Surfactant Molecules for Determining their YL 162
Contact Angle-Based Methods for Determining y w 164
Chapter XIV Different Approaches for Interpreting Contact Angles
and Determining the Surface Tension and Surface Tension
Components of Solids 165
The Concept of Surface Tension of a Solid 165
Critical Surface Tensions of Solids 166
Equation of State Approaches 166
f5^
The Concept of a Single Polar Surface Tension Component, yp .
in Conjunction with a Geometric Mean Combining Rule.....................................169
Comparison Between the yff and the y,p2 Approaches........................................170
Sedimentation of Particle Suspensions..................................................................173
Advancing Solidification Fronts............................................................................174
Adhesion Methods.................................................................................................176
Other Approaches..................................................................................................177
yLW and Hamaker Constants...........................................................................177
Phase Separation.............................................................................................178
Electrophoretic Mobility.................................................................................178
Coda.......................................................................................................................178
Chapter XV Electrokinetic Methods.............................................................179
Microelectrophoresis of Particles and Cells..........................................................179
Moving Boundary Electrophoresis........................................................................180
Zone Electrophoresis.............................................................................................180
Zone Electrophoresis of Particles and Cells..........................................................182
Descending Density Gradient Electrophoresis...............................................182
Ascending Electrophoresis.............................................................................183
Packed Column Cell Electrophoresis.............................................................183
Enhanced Electrophoretic Separation of Subclasses of Cells Through
Receptor-Tagging..................................................................................................184
Microgravity Electrophoresis.................................................................................184
Molecular Sieve Zone Electrophoresis..................................................................186
Starch Gel Electrophoresis.............................................................................186
Polyacrylamide Gel Electrophoresis...............................................................187
Sodium Dodecyl Sulfate Polyacrylamide Electrophoresis.............................187
Graded Porosity Gel Electrophoresis..............................................................188
Gel Electrophoresis of Nucleic Acids.............................................................188
Zone Electrophoresis of Adsorbed Proteins..........................................................189
Continuous Flow Electrophoresis..........................................................................190
Curtain Electrophoresis..................................................................................190
Free Flow Electrophoresis..............................................................................192
Endless Belt Electrophoresis..........................................................................192
Cylindrical Rotating Continuous Flow Electrophoresis.................................193
Stable Flow Electrophoresis...........................................................................193
Electrophoretic Field Flow Fractionation.......................................................193
Horizontal Rotating Cylinder Electrophoresis.......................................................194
Capillary Electrophoresis....................................................................................... 94
Isoelectric Focusing...............................................................................................195
Cell Isoelectric Focusing................................................................................ 97
Isotachophoresis.....................................................................................................197
Bidimensional Methods.........................................................................................198
Electroosmosis....................................................................................................... 98
Streaming Potential and Sedimentation Potential..................................................199
Electrophoresis in Non-Aqueous Media 200
Coda and Limitations 201
Chapter XVI Direct Measurement Methods, Treating the Force Balance
in Particular 203
Force Balance 203
Other Approaches 204
Interfacial Attraction Effects (Hydrophobie Interactions) in Water 206
Interfacial Repulsion Effects (Hydration Repulsion) in Water 207
Interactions Between Adsorbed Polymer Layers in Apolar Media 208
Interaction Between Adsorbed Biopolymers and Between Adsorbed
Phospholipids in Aqueous Media 208
Measurement of the Decay-Length of Water 209
Electrostatic Effects 209
Oscillatory Effects 210
Atomic Force Microscopy 210
Coda 210
PART IV Associated Phenomena and Applications
Chapter XVII Surface Tension Components and Parameters of Liquids
and Solids 213
Completely Apolar Liquids 213
Monopolar Liquids, Immiscible with Water 214
Dipolar Liquids, Immiscible with Water 214
Naphthalene 215
Monopolar and Dipolar Water-Miscible Liquids 216
Synthetic Polymers 217
Biopolymers 217
Plasma Proteins 217
Other Proteins 220
Carbohydrates 221
Nucleic Acids 224
Contact Angle Liquids 224
Surface Tension Properties of Clays and Other Minerals 225
Coda 226
Chapter XVIII Attractive LW- and AB-Forces: Hydrophobie Interactions 227
Interaction Between Two Identical Organic Molecules, Immersed in Water 227
Enthalpy and Entropy of Hydrophobie Interactions 229
Apolar (LW) and Polar (AB) Contributions to Hydrophobie Interactions 231
Hydrophobie Attractions (AGlwi) 231
Hydrophobie Hydration (AGiw) 233
Conclusions 234
Propagation at a Distance of Attractive Hydrophobie Interactions 235
Cavitation Is an Effect, Not a Cause of Hydrophobie Interactions;
When Wiw Is Smaller than Wiwi, Cavitation Is Favored Near the Interface 236
Attractive Interfacial Interactions in Non-Aqueous Media 237
Further to the Mechanism of Hydrophobie Interactions 237
Occurrence of Attractive Interfacial ( Hydrophobie ) Interactions
Between Similar Sites 238
Interactions Between Two Different Organic Compounds Immersed in Water 238
Occurrence of Attractive Interfacial ( Hydrophobie ) Interactions
Between Two Dissimilar Sites 240
Coda 240
Chapter XIX Repulsive AB-Forces: Hydrophilic Interactions—Osmotic
Pressures of PEO Solutions 243
Negative Interfacial Tensions and Polar Repulsion 243
Monopolar Surfaces 245
Quantitative Expression of Hydrophilicity and Hydrophobicity 246
Propagation at a Distance of Repulsive Hydrophilic Interactions 249
Linkage Between EL and AB Forces 250
Osmotic Pressure Effects 252
Osmotic Pressures of PEO-Water Solutions 253
Monopolar Repulsion Between Dissimilar Polar Entities 259
Monopolar Repulsion in Non-Aqueous Polar Media 259
Persistence of AGivvj Interactions at a Distance 260
Coda 261
Appendix: On the Interpolation of Values of yl: versus PEO Concentration 262
Chapter XX The Primary and Secondary Interactions 263
van der Waals Interactions (Primary) 264
Electrostatic, or Coulombic Interactions (Primary) 265
Lewis Acid-Base Interactions (Primary) 265
Brownian Movement Interactions 266
Primary Forces and Secondary Phenomena 267
Osmotic Pressure 267
Disjoining Pressure 2f)8
Structural Forces 268
Steric Interactions 26^
Depletion Interactions 270
Entropy-Driven and Enthalpy-Driven Interactions 272
Cross-Binding Interactions 27~
Specific Interactions ^
Coda 273
Chapter XXI Phase Separation in Polymer Solutions; Coacervation and
Complex Coacervation 275
Phase Separation of Polymers in Organic Media 275
Phase Separation of Polymers in Aqueous Media 280
Phase Separation of Water-Soluble Polymers in Polar Organic Media 282
Mechanism of Polymer Phase Separation in Apolar Systems 283
Mechanism of Polymer Phase Separation in Polar and Especially
in Aqueous Systems 283
The Interfacial Tension Between Aqueous Phases 284
Use of Aqueous Two-Phase Systems for Cell and Biopolymer Separation 285
Polymer Phase Separation Summarized 285
Coacervation and Complex Coacervation 286
Role of Low Molecular Weight Solutes in Coacervation 287
Complex Coacervation 288
Flocculation 291
Phase Formation in Microemulsions 293
Coda 296
Chapter XXII Solubility of Polymers and Other Solutes 297
Apolar Systems and Hildebrand s Solubility Parameter 297
Polar Systems 298
Solubility of Apolar Polymers 300
Miscibility of Polar Liquids 301
Miscibility and Solubility as Microscopic-Scale Phenomena 301
Miscibility and Immiscibility as Macroscopic-Scale Phenomena 303
Conclusion 304
Solubility of Polar Polymers 304
Solubility in Non-Aqueous Polar Liquids 307
Insolubilization of Biopolymers 309
The Flory-Huggins x-Parameter and the Solubility of Polar Compounds 311
Solubility and the cmc of Non-Ionic Surfactants 312
Relation Between AGT0T and the cmc 316
Solubility and the cmc of Anionic Surfactants 316
Solubility of Organic Liquids in Water 317
Solubility of Electrolytes 318
Coda 318
Chapter XXIII Cell and Particle Stability 319
Energy vs. Distance Plots in Aqueous Media 319
Particle Stability vs. Flocculation—The Schulze-Hardy Mechanism
of Flocculation with Plurivalent Counterions 325
Polymer Molecules, Very Small Particles and Protuberances with Small Radii
of Curvature 327
The Glycocalyx of Mammalian Cells 328
Blood Cell Stability 329
Rouleau Formation of Red Cells, or Pseudo-Attachment at the
Secondary Minimum 330
Hemagglutination 332
The IgG Molecule as a Probe for Determining the Intercellular Distance, (,
at the Secondary Minimum; Estimation of the Decay Length of Water 336
Cell and Particle Stability in the Absence and in the Presence of Polymers 339
Stability in the Absence of Polymers 339
Stability Induced by Attached Lyophilic Polymers; Depletion Phenomena 340
Coda 342
Chapter XXIV Adsorption and Adhesion in Aqueous Media, Including
Ligand-Receptor Interactions 345
Interaction Between Two Different Materials Immersed in Water 345
Macroscopic and Microscopic-Scale Interactions 346
Adsorption 347
Influence of the Size of the Solute 347
Blotting 347
Protein Adsorption 349
Change in Configuration and Denaturation 354
Liquid Chromatography 357
Cell Adhesion 360
Influence of Protein Adsorption 360
Adhesion to High- and Low-Energy Surfaces 361
Prevention of Adhesion 361
The Influence of Cell-Shape on Adhesiveness 363
Cell Adhesion to Low-Energy Surfaces 363
Aspecific and Specific Interactions in Microbial Adhesion 363
Microbial Pathogenicity and Negative and Positive Cell Adhesion 364
Opsonization and Phagocytosis 365
Cell Fusion 366
Cell Freezing and Negative and Positive Adhesion to Advancing Ice Fronts 368
Aspecific and Specific Interactions 371
Smallness of Specific Sites 372
Interfacial (LW + AB) Specific Interactions 373
Role of Direct Hydrogen Bonding in Specific Interactions 374
H-Bonds Used in Ag-Ab Modeling 375
Role of H-Bonding in Specific Interactions in General 375
Specific Electrostatic Interactions 376
Bridging with Plurivalent Counterions—Calcium Bridging 376
Antigen-Antibody Binding Hysteresis 377
Role of Hydration 377
The AG]w2 - AG12 Transition 379
Specific Recombination DNA-DNA Interactions 379
Summary of the Mechanism of Specific Ligand-Receptor Interactions 381
Coda 382
Chapter XXV Kinetics and Energetics of Protein Adsorption
onto Metal Oxide Surfaces 385
Measurement of the Kinetic On-Rate Constant of Protein Adsorption
onto Metal Oxide Surfaces—Experimental Constraints to Be Observed 385
Mass Transport 385
Steric Hindrance by Dissolved Protein Molecules 386
Decrease in the Adsorption of Protein onto Metal Oxide Surfaces
When Dissolved in Some Common Buffer Solutions 388
Macroscopic-Scale Repulsion Between Albumin and Glass or Silica 388
Microscopic-Scale Attraction Between Proteins and Discrete Cationic Sites
Imbedded in Hydrophilic Metal Oxide Surfaces 389
Extended DLVO (XDLVO) Analysis of Protein Adsorption as a Function
of Distance and Geometric Shape 389
Incorporation of both Macroscopic-Scale Repulsion and Microscopic-Scale
Attraction Energies in the Analysis of Measured Kinetic Association Rate
Constants, Using von Smoluchowski s Formalism 390
von Smoluchowski s Equation 390
von Smoluchowski s f Factor 391
Determination of Xmac and Xmic 392
Determination and Significance of k™c 393
Influence of Hysteresis on the Determination of Ka and kd and Method
for Obviating Its Effects 397
Coda 397
List of Symbols Used 399
References 407
Index 431
|
| adam_txt |
Contents
Chapter I Introduction „. ]
Non-Covalenl Interactions „„„„„.„., „, . .,., . . 1
van der Waals Forces.,. „,. . „.„„ „ ]
Polar, or Lewis Acid-Base (AB) Interactknis .„ .2
Electrostatic (EL) Interactions .„. .„„„.,„.,. 3
Other Non-Covalent Forces .„. „.„.,.,.,. 4
Browman Movement (BR) Forces .,. .4
Genera] B ibliography .„ 4
PARTI Theory
Chapter n Lifshitz-van der Waals(LW) Interactions 9
van der Waals Forces,.,. , „. 9
Macroscopic Approximation - 10
The Lifshkz Approach .r,. 12
Fnterfacial Lifshilz-van der Waals Interactions .— .r,. 16
Addirivity of the Three Elecbodynamk Contributions to the Surface Tension 17
Coda IS
Chapter III Relation Between the Hamaker Consent and the Apolar
Surface Tension Component 19
Proportionality Factor A/y^w 19
Significance of the Averaged €0 Value - - 20
Applicability of Eq. [III-l] to A,? A,2,, A,ä, .22
Coda ~ '- 24
Chapter IV Polar or Lewis Acid-Base Interactions 25
Interfacial Lewis Acid Base Interactions - 25
The Young-Dupre Equation — - 2S
Atlraclive and Repulsive Polar Forces,™ - - —— 29
Relative Values of the Electron-Acceptor and Eleelron-Donor Parameters of Y 31
Monopolar Surfaces and Substances - - - 33
Different Modes of Intera^iion Between Two Polar Substances 36
The Surface Tension of Liquids and Solids™. .„. 39
Inierfacial Tensions Between Polar Liquids,.-™- - - - —,.40
Earlier Approaches to Correlate Contact Angles and Surface Tensions
in Polar Systems. — -.-.— ¦- 41
Comparison Between Repulsive Lifsbia-van der Waals and Repulsive
Acid-Base Interactions.,-, --¦¦- ¦ - -¦¦-» -- -¦ ¦ - — 41
The Mechanisms Allowing AG": and AGm to Be Positive 45
Implications of AG^, 0 47
Implications of AG,32 0 47
Connection Between "Hydrophobie" and Hydrophilic Interactions 48
Coda 48
Chapter V Electrical Double Layer Interactions 51
Electrokinetic Potential and Ionic Double Layer 51
Free Energy of Electrostatic Interactions 53
Electrokinetic Phenomena 54
^-Potential, Ionic Strength and Electrokinetic Mobility 55
Influence of the Double Layer 56
Thick Double Layer 56
Thin Double Layer 58
Relaxation 60
Validity Ranges of the Equations 62
Confrontation of the Equations with Experimental Data 63
Small Ka 63
Large Ka 64
Transition 0.1 Ka 300 64
Calculation of ^-Potentials from Mobility Data 64
The Brooks Effect 67
Coda 68
Chapter VI Brownian Movement Forces—Osmotic Interactions
of Polymers 71
Brownian Movement Forces 71
Osmotic Interactions 72
Radius of Gyration 74
Polymer Concentration 75
Size and Shape of Polymer Molecules 75
Coda 78
Chapter VII Rate of Decay with Distance 79
Unretarded Lifshitz-van der Waals Forces 79
Retarded London-van der Waals Forces 80
Polar(AB) Interactions g|
Electrical Double Layer Interactions 84
Brownian Movement Interactions 84
Combined Interaction Forces Acting on Solids or on Suspended Particles
in Polymer Solutions 85
The Derjaguin Approximation 86
Energy-Balance Diagrams g6
Coda on
PART II Interfacial Properties and Structure
of Liquid Water
Chapter VIII Lifshitz-van der Waals and Lewis Acid-Base Properties
of Liquid Water—Physical and Physico-Chemical Effects 93
Dominance of the Lewis Acid-Base Properties of Water 93
Effect of Temperature on the y-Components of Water 94
The Surface Properties of Ice at 0°C 96
Cluster Formation in Liquid Water 97
Coda 99
Chapter IX Role of Water in Hydrophobie Attraction 101
The Hydrogen-Bonding (Lewis Acid-Base) Free Energy of Cohesion
of Water and "the Hydrophobie Effect" 101
Hydrophobie Hydration 102
Clathrate Formation 103
Action at a Distance 104
Modulation of the Hydrophobizing Capacity of Water 104
Decreasing IAG^ 1 104
Increasing IAG?^ 1 105
Coda 107
Chapter X Role of Water in Hydrophilic Repulsion 109
Water and Hydration Forces 109
Negative yiw Values and Hydrophilic Repulsion 110
Hydration Orientation and Action at a Distance 110
Hydrophilicity and Hydration Orientation 112
Hydration Orientation of Proteins 112
Modulation of the Hydrophilic Repulsion Through Temperature Changes 114
Raising AG^ 114
Lowering AGf^ 114
Coda 115
Chapter XI The Water-Air Interface 117
Hyper-Hydrophobicity of Air at the Water-Air Interface 117
Quantitative Expression of the Total Hydrophobie Attraction Energy
at the Water-Air Interface 119
Absence of Hydration of Air at the Water-Air Interface 120
Attraction of Partly Polar, or Amphiphilic Solutes to the Water-Air Interface.
Which decreases the Apparent Surface Tension of Water 121
Repulsion of Hydrophilic, or Near-Hydrophilic Solutes by the Air-Side of the
Water-Air Interface; the Increase of the Surface Tension of Aqueous Solutions
by the Admixture of Sugars and Salts 123
The ^-Potential of Air Bubbles in Water 124
Coda 126
PART III Experimental Measurement Methods
Chapter XII Contact Angle and Surface Tension Determination
and Preparation of Solid Surfaces 131
The Sessile Drop as a Force Balance 131
Spreading Pressure 131
Contact Angle Measurement in Air-Hysteresis 134
Contact Angles on Heterogeneous Surfaces—Cassie's Equation 135
Contact Angle Measurement in Liquids 137
Contact Angle Measurement by Wicking 139
Surface Tension of Liquids 141
Apolar and Polar Surface Tension Component of Liquids 142
Estimation of the Polar Surface Tension Parameters Yl and Yl of Liquids 143
Gel Method 143
Polar Solids Method 144
Purity of Contact Angle Liquids 148
Surface Tension and Surface Free Energy 149
Influence of Temperature on the Properties of Water as aContact Angle Liquid 149
Influence of the pH of Water as a Contact Angle Liquid on the
Surface Properties of Electrically Charged Solid Surfaces 150
Influence of the pH of Water on the Properties of Water Itself, in Connection
with Its Use as aContact Angle Liquid 151
Preparation of Solid Surfaces 152
Particles and Cells 152
Dried Solutes 153
Hydrated Solutes 153
Coda 155
Chapter XIII Interfacial Tension Determination—Influence
of Macroscopic- and Microscopic-Scale Interactions 157
Interfacial Tensions and Free Energies of Interfacial Interaction 157
Interfacial Tension Between Immiscible Liquids 158
Determination of Interfacial Tensions Between Condensed-Phase Materials
and Water 158
The Aqueous Solubility Approach for Determining Yow 160
Use of the cmc of Surfactant Molecules for Determining their YL 162
Contact Angle-Based Methods for Determining y"w 164
Chapter XIV Different Approaches for Interpreting Contact Angles
and Determining the Surface Tension and Surface Tension
Components of Solids 165
The Concept of Surface Tension of a Solid 165
Critical Surface Tensions of Solids 166
"Equation of State" Approaches 166
f5^
The Concept of a Single Polar Surface Tension Component, "yp".
in Conjunction with a Geometric Mean Combining Rule.169
Comparison Between the yff and the"y,p2" Approaches.170
Sedimentation of Particle Suspensions.173
Advancing Solidification Fronts.174
Adhesion Methods.176
Other Approaches.177
yLW and Hamaker Constants.177
Phase Separation.178
Electrophoretic Mobility.178
Coda.178
Chapter XV Electrokinetic Methods.179
Microelectrophoresis of Particles and Cells.179
Moving Boundary Electrophoresis.180
Zone Electrophoresis.180
Zone Electrophoresis of Particles and Cells.182
Descending Density Gradient Electrophoresis.182
Ascending Electrophoresis.183
Packed Column Cell Electrophoresis.183
Enhanced Electrophoretic Separation of Subclasses of Cells Through
Receptor-Tagging.184
Microgravity Electrophoresis.184
Molecular Sieve Zone Electrophoresis.186
Starch Gel Electrophoresis.186
Polyacrylamide Gel Electrophoresis.187
Sodium Dodecyl Sulfate Polyacrylamide Electrophoresis.187
Graded Porosity Gel Electrophoresis.188
Gel Electrophoresis of Nucleic Acids.188
Zone Electrophoresis of Adsorbed Proteins.189
Continuous Flow Electrophoresis.190
Curtain Electrophoresis.190
Free Flow Electrophoresis.192
Endless Belt Electrophoresis.192
Cylindrical Rotating Continuous Flow Electrophoresis.193
Stable Flow Electrophoresis.193
Electrophoretic Field Flow Fractionation.193
Horizontal Rotating Cylinder Electrophoresis.194
Capillary Electrophoresis.'94
Isoelectric Focusing.195
Cell Isoelectric Focusing.'97
Isotachophoresis.197
Bidimensional Methods.198
Electroosmosis.'98
Streaming Potential and Sedimentation Potential.199
Electrophoresis in Non-Aqueous Media 200
Coda and Limitations 201
Chapter XVI Direct Measurement Methods, Treating the Force Balance
in Particular 203
Force Balance 203
Other Approaches 204
Interfacial Attraction Effects (Hydrophobie Interactions) in Water 206
Interfacial Repulsion Effects (Hydration Repulsion) in Water 207
Interactions Between Adsorbed Polymer Layers in Apolar Media 208
Interaction Between Adsorbed Biopolymers and Between Adsorbed
Phospholipids in Aqueous Media 208
Measurement of the Decay-Length of Water 209
Electrostatic Effects 209
Oscillatory Effects 210
Atomic Force Microscopy 210
Coda 210
PART IV Associated Phenomena and Applications
Chapter XVII Surface Tension Components and Parameters of Liquids
and Solids 213
Completely Apolar Liquids 213
Monopolar Liquids, Immiscible with Water 214
Dipolar Liquids, Immiscible with Water 214
Naphthalene 215
Monopolar and Dipolar Water-Miscible Liquids 216
Synthetic Polymers 217
Biopolymers 217
Plasma Proteins 217
Other Proteins 220
Carbohydrates 221
Nucleic Acids 224
Contact Angle Liquids 224
Surface Tension Properties of Clays and Other Minerals 225
Coda 226
Chapter XVIII Attractive LW- and AB-Forces: Hydrophobie Interactions 227
Interaction Between Two Identical Organic Molecules, Immersed in Water 227
Enthalpy and Entropy of Hydrophobie Interactions 229
Apolar (LW) and Polar (AB) Contributions to Hydrophobie Interactions 231
Hydrophobie Attractions (AGlwi) 231
Hydrophobie Hydration (AGiw) 233
Conclusions 234
Propagation at a Distance of Attractive Hydrophobie Interactions 235
Cavitation Is an Effect, Not a Cause of Hydrophobie Interactions;
When Wiw Is Smaller than Wiwi, Cavitation Is Favored Near the Interface 236
Attractive Interfacial Interactions in Non-Aqueous Media 237
Further to the Mechanism of Hydrophobie Interactions 237
Occurrence of Attractive Interfacial ("Hydrophobie") Interactions
Between Similar Sites 238
Interactions Between Two Different Organic Compounds Immersed in Water 238
Occurrence of Attractive Interfacial ("Hydrophobie") Interactions
Between Two Dissimilar Sites 240
Coda 240
Chapter XIX Repulsive AB-Forces: Hydrophilic Interactions—Osmotic
Pressures of PEO Solutions 243
Negative Interfacial Tensions and Polar Repulsion 243
Monopolar Surfaces 245
Quantitative Expression of Hydrophilicity and Hydrophobicity 246
Propagation at a Distance of Repulsive Hydrophilic Interactions 249
Linkage Between EL and AB Forces 250
Osmotic Pressure Effects 252
Osmotic Pressures of PEO-Water Solutions 253
Monopolar Repulsion Between Dissimilar Polar Entities 259
Monopolar Repulsion in Non-Aqueous Polar Media 259
Persistence of AGivvj Interactions at a Distance 260
Coda 261
Appendix: On the Interpolation of Values of yl: versus PEO Concentration 262
Chapter XX The Primary and Secondary Interactions 263
van der Waals Interactions (Primary) 264
Electrostatic, or Coulombic Interactions (Primary) 265
Lewis Acid-Base Interactions (Primary) 265
Brownian Movement Interactions 266
Primary Forces and Secondary Phenomena 267
Osmotic Pressure 267
Disjoining Pressure 2f)8
Structural Forces 268
Steric Interactions 26^
Depletion Interactions 270
Entropy-Driven and Enthalpy-Driven Interactions 272
Cross-Binding Interactions 27~
Specific Interactions ^
Coda 273
Chapter XXI Phase Separation in Polymer Solutions; Coacervation and
Complex Coacervation 275
Phase Separation of Polymers in Organic Media 275
Phase Separation of Polymers in Aqueous Media 280
Phase Separation of Water-Soluble Polymers in Polar Organic Media 282
Mechanism of Polymer Phase Separation in Apolar Systems 283
Mechanism of Polymer Phase Separation in Polar and Especially
in Aqueous Systems 283
The Interfacial Tension Between Aqueous Phases 284
Use of Aqueous Two-Phase Systems for Cell and Biopolymer Separation 285
Polymer Phase Separation Summarized 285
Coacervation and Complex Coacervation 286
Role of Low Molecular Weight Solutes in Coacervation 287
Complex Coacervation 288
Flocculation 291
Phase Formation in Microemulsions 293
Coda 296
Chapter XXII Solubility of Polymers and Other Solutes 297
Apolar Systems and Hildebrand's Solubility Parameter 297
Polar Systems 298
Solubility of Apolar Polymers 300
Miscibility of Polar Liquids 301
Miscibility and Solubility as Microscopic-Scale Phenomena 301
Miscibility and Immiscibility as Macroscopic-Scale Phenomena 303
Conclusion 304
Solubility of Polar Polymers 304
Solubility in Non-Aqueous Polar Liquids 307
Insolubilization of Biopolymers 309
The Flory-Huggins x-Parameter and the Solubility of Polar Compounds 311
Solubility and the cmc of Non-Ionic Surfactants 312
Relation Between AGT0T and the cmc 316
Solubility and the cmc of Anionic Surfactants 316
Solubility of Organic Liquids in Water 317
Solubility of Electrolytes 318
Coda 318
Chapter XXIII Cell and Particle Stability 319
Energy vs. Distance Plots in Aqueous Media 319
Particle Stability vs. Flocculation—The Schulze-Hardy Mechanism
of Flocculation with Plurivalent Counterions 325
Polymer Molecules, Very Small Particles and Protuberances with Small Radii
of Curvature 327
The Glycocalyx of Mammalian Cells 328
Blood Cell Stability 329
Rouleau Formation of Red Cells, or Pseudo-Attachment at the
Secondary Minimum 330
Hemagglutination 332
The IgG Molecule as a Probe for Determining the Intercellular Distance, (,
at the Secondary Minimum; Estimation of the Decay Length of Water 336
Cell and Particle Stability in the Absence and in the Presence of Polymers 339
Stability in the Absence of Polymers 339
Stability Induced by Attached Lyophilic Polymers; Depletion Phenomena 340
Coda 342
Chapter XXIV Adsorption and Adhesion in Aqueous Media, Including
Ligand-Receptor Interactions 345
Interaction Between Two Different Materials Immersed in Water 345
Macroscopic and Microscopic-Scale Interactions 346
Adsorption 347
Influence of the Size of the Solute 347
Blotting 347
Protein Adsorption 349
Change in Configuration and Denaturation 354
Liquid Chromatography 357
Cell Adhesion 360
Influence of Protein Adsorption 360
Adhesion to High- and Low-Energy Surfaces 361
Prevention of Adhesion 361
The Influence of Cell-Shape on Adhesiveness 363
Cell Adhesion to Low-Energy Surfaces 363
Aspecific and Specific Interactions in Microbial Adhesion 363
Microbial Pathogenicity and Negative and Positive Cell Adhesion 364
Opsonization and Phagocytosis 365
Cell Fusion 366
Cell Freezing and Negative and Positive Adhesion to Advancing Ice Fronts 368
Aspecific and Specific Interactions 371
Smallness of Specific Sites 372
Interfacial (LW + AB) Specific Interactions 373
Role of Direct Hydrogen Bonding in Specific Interactions 374
H-Bonds Used in Ag-Ab Modeling 375
Role of H-Bonding in Specific Interactions in General 375
Specific Electrostatic Interactions 376
Bridging with Plurivalent Counterions—Calcium Bridging 376
Antigen-Antibody Binding Hysteresis 377
Role of Hydration 377
The AG]w2 - AG12 Transition 379
Specific Recombination DNA-DNA Interactions 379
Summary of the Mechanism of Specific Ligand-Receptor Interactions 381
Coda 382
Chapter XXV Kinetics and Energetics of Protein Adsorption
onto Metal Oxide Surfaces 385
Measurement of the Kinetic On-Rate Constant of Protein Adsorption
onto Metal Oxide Surfaces—Experimental Constraints to Be Observed 385
Mass Transport 385
Steric Hindrance by Dissolved Protein Molecules 386
Decrease in the Adsorption of Protein onto Metal Oxide Surfaces
When Dissolved in Some Common Buffer Solutions 388
Macroscopic-Scale Repulsion Between Albumin and Glass or Silica 388
Microscopic-Scale Attraction Between Proteins and Discrete Cationic Sites
Imbedded in Hydrophilic Metal Oxide Surfaces 389
Extended DLVO (XDLVO) Analysis of Protein Adsorption as a Function
of Distance and Geometric Shape 389
Incorporation of both Macroscopic-Scale Repulsion and Microscopic-Scale
Attraction Energies in the Analysis of Measured Kinetic Association Rate
Constants, Using von Smoluchowski's Formalism 390
von Smoluchowski's Equation 390
von Smoluchowski's f Factor 391
Determination of Xmac and Xmic 392
Determination and Significance of k™c 393
Influence of Hysteresis on the Determination of Ka and kd and Method
for Obviating Its Effects 397
Coda 397
List of Symbols Used 399
References 407
Index 431 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Van Oss, Carel J. 1923- |
| author_GND | (DE-588)172431549 |
| author_facet | Van Oss, Carel J. 1923- |
| author_role | aut |
| author_sort | Van Oss, Carel J. 1923- |
| author_variant | o c j v ocj ocjv |
| building | Verbundindex |
| bvnumber | BV022472741 |
| callnumber-first | Q - Science |
| callnumber-label | QD506 |
| callnumber-raw | QD506 |
| callnumber-search | QD506 |
| callnumber-sort | QD 3506 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VE 7000 |
| classification_tum | CHE 180f CHE 133f CHE 138f |
| ctrlnum | (OCoLC)62593477 (DE-599)BVBBV022472741 |
| dewey-full | 541/.33 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541/.33 |
| dewey-search | 541/.33 |
| dewey-sort | 3541 233 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| discipline_str_mv | Chemie / Pharmazie Physik Chemie |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV022472741 |
| illustrated | Illustrated |
| index_date | 2024-07-02T17:45:16Z |
| indexdate | 2024-07-09T20:58:21Z |
| institution | BVB |
| isbn | 9781574444827 1574444824 |
| language | English |
| lccn | 2005035590 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-015680198 |
| oclc_num | 62593477 |
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| owner | DE-M49 DE-BY-TUM DE-19 DE-BY-UBM |
| owner_facet | DE-M49 DE-BY-TUM DE-19 DE-BY-UBM |
| physical | 438 S. Ill., graph. Darst. 24 cm |
| publishDate | 2006 |
| publishDateSearch | 2006 |
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| publisher | Taylor & Francis |
| record_format | marc |
| spelling | Van Oss, Carel J. 1923- Verfasser (DE-588)172431549 aut Interfacial forces in aqueous media Carel J. van Oss 2. ed. Boca Raton, Fla. [u.a.] Taylor & Francis 2006 438 S. Ill., graph. Darst. 24 cm txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references (p. 407-430) and index Bioquímica larpcal Físico-química larpcal Química de superfície larpcal Soluções (química) larpcal Surface chemistry Solution (Chemistry) Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Hydrophobe Wechselwirkung (DE-588)4160926-8 gnd rswk-swf Grenzflächenchemie (DE-588)4246080-3 gnd rswk-swf Wässrige Lösung (DE-588)4124928-8 gnd rswk-swf Grenzflächenchemie (DE-588)4246080-3 s Wässrige Lösung (DE-588)4124928-8 s DE-604 Hydrophobe Wechselwirkung (DE-588)4160926-8 s Oberflächenchemie (DE-588)4126166-5 s 1\p DE-604 http://www.loc.gov/catdir/toc/ecip064/2005035590.html Table of contents only http://www.loc.gov/catdir/enhancements/fy0648/2005035590-d.html Publisher description HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015680198&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Van Oss, Carel J. 1923- Interfacial forces in aqueous media Bioquímica larpcal Físico-química larpcal Química de superfície larpcal Soluções (química) larpcal Surface chemistry Solution (Chemistry) Oberflächenchemie (DE-588)4126166-5 gnd Hydrophobe Wechselwirkung (DE-588)4160926-8 gnd Grenzflächenchemie (DE-588)4246080-3 gnd Wässrige Lösung (DE-588)4124928-8 gnd |
| subject_GND | (DE-588)4126166-5 (DE-588)4160926-8 (DE-588)4246080-3 (DE-588)4124928-8 |
| title | Interfacial forces in aqueous media |
| title_auth | Interfacial forces in aqueous media |
| title_exact_search | Interfacial forces in aqueous media |
| title_exact_search_txtP | Interfacial forces in aqueous media |
| title_full | Interfacial forces in aqueous media Carel J. van Oss |
| title_fullStr | Interfacial forces in aqueous media Carel J. van Oss |
| title_full_unstemmed | Interfacial forces in aqueous media Carel J. van Oss |
| title_short | Interfacial forces in aqueous media |
| title_sort | interfacial forces in aqueous media |
| topic | Bioquímica larpcal Físico-química larpcal Química de superfície larpcal Soluções (química) larpcal Surface chemistry Solution (Chemistry) Oberflächenchemie (DE-588)4126166-5 gnd Hydrophobe Wechselwirkung (DE-588)4160926-8 gnd Grenzflächenchemie (DE-588)4246080-3 gnd Wässrige Lösung (DE-588)4124928-8 gnd |
| topic_facet | Bioquímica Físico-química Química de superfície Soluções (química) Surface chemistry Solution (Chemistry) Oberflächenchemie Hydrophobe Wechselwirkung Grenzflächenchemie Wässrige Lösung |
| url | http://www.loc.gov/catdir/toc/ecip064/2005035590.html http://www.loc.gov/catdir/enhancements/fy0648/2005035590-d.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015680198&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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