Redox systems under nano-space control: with 19 tables
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Berlin ; Heidelberg
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2006
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| Beschreibung: | Literaturangaben |
| Beschreibung: | XVIII, 295 S. Ill., graph. Darst. 24 cm |
| ISBN: | 9783540295792 3540295798 |
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| 245 | 1 | 0 | |a Redox systems under nano-space control |b with 19 tables |c Toshikazu Hirao (ed.) |
| 264 | 1 | |a Berlin ; Heidelberg |b Springer |c 2006 | |
| 300 | |a XVIII, 295 S. |b Ill., graph. Darst. |c 24 cm | ||
| 336 | |b txt |2 rdacontent | ||
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| adam_text | CONTENTS
PARTI
REDOXSYSTEMSVIAD,
YY
-CONJUGATION
1
CONJUGATEDCOMPLEXESWITHQUINONEDIIMINEDERIVATIVES
TOSHIYUKIMORIUCHI,TOSHIKAZUHIRAO
.......................
3
1.1
INTRODUCTION
............................................
4
1.2
ARCHITECTURALLYCONTROLLED
FORMATION
OFCONJUGATEDCOMPLEXESWITH1,4-BENZOQUINONEDIIMINES....
5
1.3
REDOX-SWITCHING
PROPERTIES
OF
CONJUGATED
COMPLEXES
WITH1,4-BENZOQUINONEDIIMINES...........................
17
1.4
CONCLUSION..............................................
24
1.5
REFERENCES..............................................
25
2
REALIZINGTHEULTIMATEAMPLIFICATION
INCONDUCTINGPOLYMERSENSORS:
ISOLATEDNANOSCOPICPATHWAYS
TIMOTHY
M.
SWAGER
.......................................
29
2.1
DIMENSIONALITYINMOLECULAR-WIRESENSORS..................
29
2.2
ANALYTE-TRIGGEREDBARRIERCREATIONINCONDUCTINGPOLYMERS
..
32
2.3
ISOLATEDNANOSCOPICPATHWAYS.............................
34
2.4
LANGMUIR-BLODGETTAPPROACHESTONANOFIBRILS
..............
34
2.5
MOLECULARSCAFFOLDSFORTHEISOLATIONOFMOLECULARWIRES......
37
2.6
SUMMARYANDFUTUREPROSPECTS............................
43
2.7
REFERENCES..............................................
43
3
METAL-CONTAINING
YY
-CONJUGATEDMATERIALS
MICHAEL
O.
WOLF
..........................................
45
3.1
INTRODUCTION
............................................
46
3.1.1
YY
-CONJUGATEDMATERIALS...................................
46
3.1.2
NANOMATERIALS...........................................
46
3.2
METAL-COMPLEX-CONTAININGCONJUGATEDMATERIALS............
47
3.2.1
PREPARATION.............................................
47
3.2.2
PROPERTIES
..............................................
49
3.3
METAL-NANOPARTICLE-CONTAININGCONJUGATEDMATERIALS........
51
3.3.1
PREPARATION.............................................
51
VIII
CONTENTS
3.3.2
PROPERTIES
..............................................
51
3.4
APPLICATIONS
............................................
52
3.5
CONCLUSIONS.............................................
53
3.6
REFERENCES..............................................
53
4
REDOXACTIVEARCHITECTURESANDCARBON-RICHRUTHENIUMCOMPLEXES
ASMODELSFORMOLECULARWIRES
STEPHANERIGAUT,DANIELTOUCHARD,PIERREH.DIXNEUF
.........
55
4.1
INTRODUCTION
............................................
56
4.2
RUTHENIUMALLENYLIDENEANDACETYLIDEBUILDINGBLOCKS:
BASICPROPERTIES
.........................................
57
4.2.1
SYNTHETICROUTES.........................................
57
4.2.2
REDOXPROPERTIES
........................................
60
4.2.2.1
OXIDATIONOFRUTHENIUMMETALACETYLIDES:
STABLERU
II
/RU
III
SYSTEMS
AND
A
NEW
ROUTE
TOALLENYLIDENEMETALCOMPLEXES
..........................
60
4.2.2.2
REDUCTIONOFMETALALLENYLIDENES:
ACCESSTOSTABLE ORGANIC RADICALSANDAROUTETOACETYLIDES
.
61
4.3
BIMETALLICCOMPLEXESFROMTHERU(DPPE)
2
SYSTEM............
63
4.3.1
ABINUCLEARBIS-ACETYLIDERUTHENIUMCOMPLEX..............
63
4.3.2
BIS-ALLENYLIDENEBRIDGESLINKINGTWORUTHENIUMCOMPLEXES
.
64
4.3.3
C
7
BRIDGEDBINUCLEARRUTHENIUMCOMPLEXES................
67
4.4
CONNECTIONOFTWOCARBON-RICHCHAINS
WITHTHERUTHENIUMSYSTEM...............................
71
4.5
TRIMETALLICANDOLIGOMERICMETALCOMPLEXES
WITHCARBON-RICHBRIDGES
................................
74
4.6
STARORGANOMETALLIC-CONTAININGMULTIPLEIDENTICALMETALSITES.
77
4.7
CONCLUSION..............................................
79
4.8
REFERENCES..............................................
79
5
MOLECULAR
METAL
WIRES
BUILT
FROM
A
LINEAR
METAL
ATOM
CHAIN
SUPPORTEDBYOLIGOPYRIDYLAMIDOLIGANDS
CHEN-YUYEH,CHIH-CHIEHWANG,CHUN-HSIENCHEN,
SHIE-MINGPENG
..........................................
85
5.1
INTRODUCTION
............................................
86
5.2
SYNTHESISOFOLIGOPYRIDYLAMINELIGANDS
....................
87
5.3
DIMERIZATIONBYSELF-COMPLEMENTARYHYDROGENBONDING.....
90
5.4
COMPLEXATIONOFOLIGOPYRIDYLAMINELIGANDS................
91
5.5
MONO-ANDDINUCULEARCOMPLEXES.........................
91
5.6
STRUCTURESOFLINEARMULTINUCLEARNICKELCOMPLEXES..........
92
5.7
STRUCTURESOFLINEARMULTINUCLEARCOBALTCOMPLEXES
.........
98
5.8
STRUCTURESOFLINEARMULTINUCLEARCHROMIUMCOMPLEXES
.....100
5.9
STRUCTURESOFTRIRUTHENIUMANDTRIRHODIUMCOMPLEXES
......103
5.10
COMPLEXESOFMODIFIEDLIGANDS............................104
CONTENTS
IX
5.11
ELECTROCHEMICALPROPERTIESOFTHECOMPLEXES................105
5.12
SCANNINGTUNNELINGMICROSCOPYSTUDIES....................112
5.13
SUMMARY...............................................114
5.14
REFERENCES..............................................115
6
MULTIELECTRONREDOXCATALYSTS
INMETAL-ASSEMBLEDMACROMOLECULARSYSTEMS
TAKANEIMAOKA,KIMIHISAYAMAMOTO
.......................119
6.1
INTRODUCTION
............................................119
6.2
MULTIELECTRONREDOXSYSTEMS..............................120
6.3
MULTINUCLEARCOMPLEXESASREDOXCATALYSTS.................122
6.4
MACROMOLECULE-METALCOMPLEXES..........................123
6.5
METALIONASSEMBLYONDENDRITICMACROMOLECULES...........124
6.6
CONCLUSION..............................................129
6.7
REFERENCES..............................................129
PARTII
REDOXSYSTEMSVIACOORDINATIONCONTROL
7
TRIRUTHENIUMCLUSTEROLIGOMERS
THATSHOWMULTISTEP/MULTIELECTRONREDOXBEHAVIOR
TOMOHIKOHAMAGUCHI,TADASHIYAMAGUCHI,TASUKUITO
........133
7.1
INTRODUCTION
............................................133
7.2
SYNTHESESOFOLIGOMERS1AND2............................135
7.3
REDOXBEHAVIOROF1AND2
................................136
7.4
CONCLUSION..............................................139
7.5
REFERENCES..............................................139
8
MOLECULARARCHITECTURE
OFREDOX-ACTIVEMULTILAYEREDMETALCOMPLEXES
BASEDONSURFACECOORDINATIONCHEMISTRY
MASA-AKIHAGA
..........................................141
8.1
INTRODUCTION
............................................141
8.2
FABRICATIONOFMULTILAYERNANOARCHITECTURES
BYSURFACECOORDINATIONCHEMISTRY........................142
8.2.1
LAYER-BY-LAYERASSEMBLYONSOLIDSURFACES
.................142
8.2.2
MOLECULARDESIGNOFANCHORINGGROUPS
FORCONTROLOFMOLECULARORIENTATIONONSURFACES
............143
8.2.3
MOLECULARDESIGNOFREDOX-ACTIVEMETALCOMPLEXUNITS
FORTHECONTROLOFENERGYLEVELSONSURFACES.................146
8.3
CHEMICALFUNCTIONS
OFREDOX-ACTIVEMULTILAYEREDCOMPLEXESONSURFACE..........148
8.3.1
ELECTRONTRANSFEREVENTSINMULTILAYERNANOSTRUCTURES........148
X
CONTENTS
8.3.2
COMBINATORIALAPPROACH
TOELECTROCHEMICALMOLECULARDEVICES
INAMULTILAYERNANOSTRUCTUREONSURFACES...................149
8.3.3
SURFACEDNATRAPPINGBYIMMOBILIZEDMETALCOMPLEXES
WITHINTERCALATORMOIETYTOWARDNANOWIRING................151
8.4
CONCLUSION..............................................153
8.5
REFERENCES..............................................153
9
PROGRAMMEDMETALARRAYSBYMEANS
OFDESIGNABLEBIOLOGICALMACROMOLECULES
KENTAROTANAKA,
TOMOKO
OKADA,
MITSUHIKO
SHIONOYA
.........155
9.1
INTRODUCTION
............................................155
9.2
DNA-DIRECTEDMETALARRAYS...............................156
9.2.1
METAL-MEDIATEDBASEPAIRINGINDNA.......................156
9.2.2
SINGLE-SITEINCORPORATION
OFAMETAL-MEDIATEDBASEPAIRINTODNA
....................157
9.2.3
DISCRETESELF-ASSEMBLEDMETALARRAYSINDNA...............159
9.3
PEPTIDE-DIRECTEDMETALARRAYS.............................161
9.3.1
DESIGNCONCEPT..........................................161
9.3.2
HETEROGENEOUSMETALARRAYSUSINGCYCLICPEPTIDES...........162
9.3.3
METALIONSELECTIVITYINSUPRAMOLECULARCOMPLEXATION
.......163
9.4
CONCLUSION..............................................164
9.5
REFERENCES..............................................164
10
METAL-INCORPORATEDHOSTSFORCOOPERATIVE
ANDRESPONSIVERECOGNITIONTOEXTERNALSTIMULUS
TATSUYANABESHIMA,SHIGEHISAAKINE
........................167
10.1
INTRODUCTION
............................................167
10.2
PSEUDOMACROCYCLES
FORCOOPERATIVEMOLECULARFUNCTIONALSYSTEMS...............168
10.3
OLIGO(N
2
O
2
-CHELATE)MACROCYCLES..........................172
10.3.1
DESIGNOFMACROCYCLICOLIGO(N
2
O
2
-CHELATE)LIGANDS
ANDMETALLOHOSTS
........................................172
10.3.2
SYNTHESISANDSTRUCTUREOFTRIS(N
2
O
2
-CHELATE)MACROCYCLES
...
173
10.4
ACYCLICOLIGO(N
2
O
2
-CHELATE)LIGANDS.......................174
10.4.1
DESIGNOFACYCLICOLIGO(N
2
O
2
-CHELATE)LIGANDS..............174
10.4.2
COMPLEXESOFANEWN
2
O
2
-CHELATELIGAND,SALAMO...........175
10.4.3
SYNTHESIS,STRUCTURE,ANDPROPERTIES
OFACYCLICOLIGO(N
2
O
2
-CHELATE)LIGANDS
....................176
10.5
CONCLUSION..............................................177
10.6
REFERENCES..............................................177
CONTENTS
XI
11
SYNTHESISOFPOLY(BINAPHTHOL)VIACONTROLLEDOXIDATIVECOUPLING
SHIGEKIHABAUE,BUNPEIHATANO
............................179
11.1
INTRODUCTION
............................................179
11.2
ASYMMETRICOXIDATIVECOUPLING
WITHDINUCLEARMETALCOMPLEXES...........................181
11.3
OXIDATIVECOUPLINGPOLYMERIZATIONOFPHENOLS
..............183
11.4
OXIDATIVECOUPLINGPOLYMERIZATION
OF2,3-DIHYDROXYNAPHTHALENE..............................184
11.5
CONCLUSION..............................................188
11.6
REFERENCES..............................................188
PARTIII
REDOXSYSTEMSVIAMOLECULARCHAINCONTROL
12
NANOMECCANO
YILIU,AMARH.FLOOD,J.FRASERSTODDART
....................193
12.1
INTRODUCTION
............................................194
12.2
REDOX-CONTROLLABLEMOLECULARSWITCHESINSOLUTION
..........196
12.2.1
BISTABLE[2]CATENANES
....................................196
12.2.2
BISTABLE[2]ROTAXANES
....................................197
12.2.3
SELF-COMPLEXINGMOLECULARSWITCHES
.......................198
12.3
APPLICATIONOFREDOX-CONTROLLABLEMOLECULARMACHINES
INELECTRONICDEVICES.....................................201
12.4
APPLICATIONOFREDOX-CONTROLLABLEMOLECULARMACHINES
INMECHANICALDEVICES....................................204
12.4.1
SWITCHINGINLANGMUIR-BLODGETTFILM......................205
12.4.2
MOLECULARMACHINESFUNCTIONINGASNANOVALVES
.............207
12.4.3
ARTIFICIALMOLECULARMUSCLES...............................208
12.5
CONCLUSIONS.............................................211
12.6
REFERENCES..............................................212
13
THROUGH-SPACECONTROLOFREDOXREACTIONS
USINGINTERLOCKEDSTRUCTUREOFROTAXANES
NOBUHIROKIHARA,TOSHIKAZUTAKATA
........................215
13.1
INTRODUCTION
............................................215
13.2
REDOX
BEHAVIOR
AND
CONFORMATION
OFFERROCENE-END-CAPPEDROTAXANE........................217
13.3
REDUCTIONOFKETONEBYROTAXANE
BEARINGADIHYDRONICOTINAMIDEGROUP
.....................225
13.4
CONCLUSION..............................................230
13.5
REFERENCES..............................................231
XII
CONTENTS
14
METAL-CONTAININGSTARANDHYPERBRANCHEDPOLYMERS
MASAMIKAMIGAITO
.......................................233
14.1
INTRODUCTION
............................................233
14.2
METAL-CONTAININGSTARPOLYMERS...........................235
14.2.1
METAL-CONTAININGSTARPOLYMERSWITHASMALL
ANDWELL-DEFINEDNUMBEROFARMS.........................236
14.2.2
METAL-CONTAININGSTARPOLYMERS
WITHALARGEANDSTATISTICALLYDISTRIBUTEDNUMBEROFARMS....
240
14.3
METAL-CONTAININGHYPERBRANCHEDPOLYMERS.................243
14.4
CONCLUDINGREMARKS.....................................245
14.5
REFERENCES..............................................246
15
ELECTRONICPROPERTIESOFHELICALPEPTIDEDERIVATIVES
ATASINGLEMOLECULARLEVEL
SHUNSAKU
KIMURA,
KAZUYA
KITAGAWA,
KAZUYUKI
YANAGISAWA,
TOMOYUKI
MORITA
........................................
249
15.1
MOLECULARELECTRONICS
....................................249
15.2
ELECTRONTRANSFERTHROUGHMOLECULES
......................250
15.3
ELECTRONICPROPERTIESOFHELICALPEPTIDES....................251
15.4
ELECTRONTRANSFERMECHANISMOVERALONGDISTANCE
..........254
15.5
EFFECTOFLINKERSONELECTRONTRANSFER
......................254
15.6
HELICAL-PEPTIDESCAFFOLDFORELECTRONHOPPING...............256
15.7
PHOTOCURRENTGENERATIONWITHHELICALPEPTIDES
CARRYINGNAPHTHYLGROUPS................................259
15.8
CONCLUSION..............................................261
15.9
REFERENCES..............................................261
16
CONSTRUCTIONOFREDOX-INDUCEDSYSTEMS
USINGANTIGEN-COMBININGSITESOFANTIBODIES
ANDFUNCTIONALIZATIONOFANTIBODYSUPRAMOLECULES
HIROYASUYAMAGUCHI,AKIRAHARADA
........................263
16.1
INTRODUCTION
............................................264
16.2
PHOTOINDUCEDELECTRON
TRANSFER
FROM
PORPHYRINS
TOELECTRONACCEPTORMOLECULES............................266
16.2.1
MONOCLONALANTIBODIES
FOR
MESO
-TETRAKIS(4-CARBOXYPHENYL)PORPHYRIN(TCPP)
.......267
16.2.2
PHOTOINDUCEDELECTRONTRANSFERFROMAPORPHYRIN
TOANELECTRONACCEPTORINANANTIBODY-COMBININGSITE
......273
16.3
PEROXIDASEACTIVITYOFFE-PORPHYRIN-ANTIBODYCOMPLEXES
....
275
16.3.1
PREPARATIONOFMONOCLONALANTIBODIES
AGAINSTCATIONICPORPHYRINS
..............................276
16.3.2
PEROXIDASEACTIVITYOFANTIBODY-FE-TMPYPCOMPLEX.........280
16.4
DENDRITICANTIBODYSUPRAMOLECULES........................282
CONTENTS
XIII
16.5
LINEARANTIBODYSUPRAMOLECULES:APPLICATION
FORNOVELBIOSENSINGMETHOD..............................285
16.5.1
ANTIVIOLOGENANTIBODIES..................................286
16.5.2
APPLICATIONSFORHIGHLYSENSITIVEDETECTIONMETHOD
OFMETHYLVIOLOGENBYSUPRAMOLECULARCOMPLEXFORMATION
BETWEENANTIBODIESANDDIVALENTANTIGENS..................287
16.6
CONCLUSIONS.............................................289
16.7
REFERENCES..............................................290
SUBJECTINDEX
.....................................................293
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CONTENTS
PARTI
REDOXSYSTEMSVIAD,
YY
-CONJUGATION
1
CONJUGATEDCOMPLEXESWITHQUINONEDIIMINEDERIVATIVES
TOSHIYUKIMORIUCHI,TOSHIKAZUHIRAO
.
3
1.1
INTRODUCTION
.
4
1.2
ARCHITECTURALLYCONTROLLED
FORMATION
OFCONJUGATEDCOMPLEXESWITH1,4-BENZOQUINONEDIIMINES.
5
1.3
REDOX-SWITCHING
PROPERTIES
OF
CONJUGATED
COMPLEXES
WITH1,4-BENZOQUINONEDIIMINES.
17
1.4
CONCLUSION.
24
1.5
REFERENCES.
25
2
REALIZINGTHEULTIMATEAMPLIFICATION
INCONDUCTINGPOLYMERSENSORS:
ISOLATEDNANOSCOPICPATHWAYS
TIMOTHY
M.
SWAGER
.
29
2.1
DIMENSIONALITYINMOLECULAR-WIRESENSORS.
29
2.2
ANALYTE-TRIGGEREDBARRIERCREATIONINCONDUCTINGPOLYMERS
.
32
2.3
ISOLATEDNANOSCOPICPATHWAYS.
34
2.4
LANGMUIR-BLODGETTAPPROACHESTONANOFIBRILS
.
34
2.5
MOLECULARSCAFFOLDSFORTHEISOLATIONOFMOLECULARWIRES.
37
2.6
SUMMARYANDFUTUREPROSPECTS.
43
2.7
REFERENCES.
43
3
METAL-CONTAINING
YY
-CONJUGATEDMATERIALS
MICHAEL
O.
WOLF
.
45
3.1
INTRODUCTION
.
46
3.1.1
YY
-CONJUGATEDMATERIALS.
46
3.1.2
NANOMATERIALS.
46
3.2
METAL-COMPLEX-CONTAININGCONJUGATEDMATERIALS.
47
3.2.1
PREPARATION.
47
3.2.2
PROPERTIES
.
49
3.3
METAL-NANOPARTICLE-CONTAININGCONJUGATEDMATERIALS.
51
3.3.1
PREPARATION.
51
VIII
CONTENTS
3.3.2
PROPERTIES
.
51
3.4
APPLICATIONS
.
52
3.5
CONCLUSIONS.
53
3.6
REFERENCES.
53
4
REDOXACTIVEARCHITECTURESANDCARBON-RICHRUTHENIUMCOMPLEXES
ASMODELSFORMOLECULARWIRES
STEPHANERIGAUT,DANIELTOUCHARD,PIERREH.DIXNEUF
.
55
4.1
INTRODUCTION
.
56
4.2
RUTHENIUMALLENYLIDENEANDACETYLIDEBUILDINGBLOCKS:
BASICPROPERTIES
.
57
4.2.1
SYNTHETICROUTES.
57
4.2.2
REDOXPROPERTIES
.
60
4.2.2.1
OXIDATIONOFRUTHENIUMMETALACETYLIDES:
STABLERU
II
/RU
III
SYSTEMS
AND
A
NEW
ROUTE
TOALLENYLIDENEMETALCOMPLEXES
.
60
4.2.2.2
REDUCTIONOFMETALALLENYLIDENES:
ACCESSTOSTABLE"ORGANIC"RADICALSANDAROUTETOACETYLIDES
.
61
4.3
BIMETALLICCOMPLEXESFROMTHERU(DPPE)
2
SYSTEM.
63
4.3.1
ABINUCLEARBIS-ACETYLIDERUTHENIUMCOMPLEX.
63
4.3.2
BIS-ALLENYLIDENEBRIDGESLINKINGTWORUTHENIUMCOMPLEXES
.
64
4.3.3
C
7
BRIDGEDBINUCLEARRUTHENIUMCOMPLEXES.
67
4.4
CONNECTIONOFTWOCARBON-RICHCHAINS
WITHTHERUTHENIUMSYSTEM.
71
4.5
TRIMETALLICANDOLIGOMERICMETALCOMPLEXES
WITHCARBON-RICHBRIDGES
.
74
4.6
STARORGANOMETALLIC-CONTAININGMULTIPLEIDENTICALMETALSITES.
77
4.7
CONCLUSION.
79
4.8
REFERENCES.
79
5
MOLECULAR
METAL
WIRES
BUILT
FROM
A
LINEAR
METAL
ATOM
CHAIN
SUPPORTEDBYOLIGOPYRIDYLAMIDOLIGANDS
CHEN-YUYEH,CHIH-CHIEHWANG,CHUN-HSIENCHEN,
SHIE-MINGPENG
.
85
5.1
INTRODUCTION
.
86
5.2
SYNTHESISOFOLIGOPYRIDYLAMINELIGANDS
.
87
5.3
DIMERIZATIONBYSELF-COMPLEMENTARYHYDROGENBONDING.
90
5.4
COMPLEXATIONOFOLIGOPYRIDYLAMINELIGANDS.
91
5.5
MONO-ANDDINUCULEARCOMPLEXES.
91
5.6
STRUCTURESOFLINEARMULTINUCLEARNICKELCOMPLEXES.
92
5.7
STRUCTURESOFLINEARMULTINUCLEARCOBALTCOMPLEXES
.
98
5.8
STRUCTURESOFLINEARMULTINUCLEARCHROMIUMCOMPLEXES
.100
5.9
STRUCTURESOFTRIRUTHENIUMANDTRIRHODIUMCOMPLEXES
.103
5.10
COMPLEXESOFMODIFIEDLIGANDS.104
CONTENTS
IX
5.11
ELECTROCHEMICALPROPERTIESOFTHECOMPLEXES.105
5.12
SCANNINGTUNNELINGMICROSCOPYSTUDIES.112
5.13
SUMMARY.114
5.14
REFERENCES.115
6
MULTIELECTRONREDOXCATALYSTS
INMETAL-ASSEMBLEDMACROMOLECULARSYSTEMS
TAKANEIMAOKA,KIMIHISAYAMAMOTO
.119
6.1
INTRODUCTION
.119
6.2
MULTIELECTRONREDOXSYSTEMS.120
6.3
MULTINUCLEARCOMPLEXESASREDOXCATALYSTS.122
6.4
MACROMOLECULE-METALCOMPLEXES.123
6.5
METALIONASSEMBLYONDENDRITICMACROMOLECULES.124
6.6
CONCLUSION.129
6.7
REFERENCES.129
PARTII
REDOXSYSTEMSVIACOORDINATIONCONTROL
7
TRIRUTHENIUMCLUSTEROLIGOMERS
THATSHOWMULTISTEP/MULTIELECTRONREDOXBEHAVIOR
TOMOHIKOHAMAGUCHI,TADASHIYAMAGUCHI,TASUKUITO
.133
7.1
INTRODUCTION
.133
7.2
SYNTHESESOFOLIGOMERS1AND2.135
7.3
REDOXBEHAVIOROF1AND2
.136
7.4
CONCLUSION.139
7.5
REFERENCES.139
8
MOLECULARARCHITECTURE
OFREDOX-ACTIVEMULTILAYEREDMETALCOMPLEXES
BASEDONSURFACECOORDINATIONCHEMISTRY
MASA-AKIHAGA
.141
8.1
INTRODUCTION
.141
8.2
FABRICATIONOFMULTILAYERNANOARCHITECTURES
BYSURFACECOORDINATIONCHEMISTRY.142
8.2.1
LAYER-BY-LAYERASSEMBLYONSOLIDSURFACES
.142
8.2.2
MOLECULARDESIGNOFANCHORINGGROUPS
FORCONTROLOFMOLECULARORIENTATIONONSURFACES
.143
8.2.3
MOLECULARDESIGNOFREDOX-ACTIVEMETALCOMPLEXUNITS
FORTHECONTROLOFENERGYLEVELSONSURFACES.146
8.3
CHEMICALFUNCTIONS
OFREDOX-ACTIVEMULTILAYEREDCOMPLEXESONSURFACE.148
8.3.1
ELECTRONTRANSFEREVENTSINMULTILAYERNANOSTRUCTURES.148
X
CONTENTS
8.3.2
COMBINATORIALAPPROACH
TOELECTROCHEMICALMOLECULARDEVICES
INAMULTILAYERNANOSTRUCTUREONSURFACES.149
8.3.3
SURFACEDNATRAPPINGBYIMMOBILIZEDMETALCOMPLEXES
WITHINTERCALATORMOIETYTOWARDNANOWIRING.151
8.4
CONCLUSION.153
8.5
REFERENCES.153
9
PROGRAMMEDMETALARRAYSBYMEANS
OFDESIGNABLEBIOLOGICALMACROMOLECULES
KENTAROTANAKA,
TOMOKO
OKADA,
MITSUHIKO
SHIONOYA
.155
9.1
INTRODUCTION
.155
9.2
DNA-DIRECTEDMETALARRAYS.156
9.2.1
METAL-MEDIATEDBASEPAIRINGINDNA.156
9.2.2
SINGLE-SITEINCORPORATION
OFAMETAL-MEDIATEDBASEPAIRINTODNA
.157
9.2.3
DISCRETESELF-ASSEMBLEDMETALARRAYSINDNA.159
9.3
PEPTIDE-DIRECTEDMETALARRAYS.161
9.3.1
DESIGNCONCEPT.161
9.3.2
HETEROGENEOUSMETALARRAYSUSINGCYCLICPEPTIDES.162
9.3.3
METALIONSELECTIVITYINSUPRAMOLECULARCOMPLEXATION
.163
9.4
CONCLUSION.164
9.5
REFERENCES.164
10
METAL-INCORPORATEDHOSTSFORCOOPERATIVE
ANDRESPONSIVERECOGNITIONTOEXTERNALSTIMULUS
TATSUYANABESHIMA,SHIGEHISAAKINE
.167
10.1
INTRODUCTION
.167
10.2
PSEUDOMACROCYCLES
FORCOOPERATIVEMOLECULARFUNCTIONALSYSTEMS.168
10.3
OLIGO(N
2
O
2
-CHELATE)MACROCYCLES.172
10.3.1
DESIGNOFMACROCYCLICOLIGO(N
2
O
2
-CHELATE)LIGANDS
ANDMETALLOHOSTS
.172
10.3.2
SYNTHESISANDSTRUCTUREOFTRIS(N
2
O
2
-CHELATE)MACROCYCLES
.
173
10.4
ACYCLICOLIGO(N
2
O
2
-CHELATE)LIGANDS.174
10.4.1
DESIGNOFACYCLICOLIGO(N
2
O
2
-CHELATE)LIGANDS.174
10.4.2
COMPLEXESOFANEWN
2
O
2
-CHELATELIGAND,SALAMO.175
10.4.3
SYNTHESIS,STRUCTURE,ANDPROPERTIES
OFACYCLICOLIGO(N
2
O
2
-CHELATE)LIGANDS
.176
10.5
CONCLUSION.177
10.6
REFERENCES.177
CONTENTS
XI
11
SYNTHESISOFPOLY(BINAPHTHOL)VIACONTROLLEDOXIDATIVECOUPLING
SHIGEKIHABAUE,BUNPEIHATANO
.179
11.1
INTRODUCTION
.179
11.2
ASYMMETRICOXIDATIVECOUPLING
WITHDINUCLEARMETALCOMPLEXES.181
11.3
OXIDATIVECOUPLINGPOLYMERIZATIONOFPHENOLS
.183
11.4
OXIDATIVECOUPLINGPOLYMERIZATION
OF2,3-DIHYDROXYNAPHTHALENE.184
11.5
CONCLUSION.188
11.6
REFERENCES.188
PARTIII
REDOXSYSTEMSVIAMOLECULARCHAINCONTROL
12
NANOMECCANO
YILIU,AMARH.FLOOD,J.FRASERSTODDART
.193
12.1
INTRODUCTION
.194
12.2
REDOX-CONTROLLABLEMOLECULARSWITCHESINSOLUTION
.196
12.2.1
BISTABLE[2]CATENANES
.196
12.2.2
BISTABLE[2]ROTAXANES
.197
12.2.3
SELF-COMPLEXINGMOLECULARSWITCHES
.198
12.3
APPLICATIONOFREDOX-CONTROLLABLEMOLECULARMACHINES
INELECTRONICDEVICES.201
12.4
APPLICATIONOFREDOX-CONTROLLABLEMOLECULARMACHINES
INMECHANICALDEVICES.204
12.4.1
SWITCHINGINLANGMUIR-BLODGETTFILM.205
12.4.2
MOLECULARMACHINESFUNCTIONINGASNANOVALVES
.207
12.4.3
ARTIFICIALMOLECULARMUSCLES.208
12.5
CONCLUSIONS.211
12.6
REFERENCES.212
13
THROUGH-SPACECONTROLOFREDOXREACTIONS
USINGINTERLOCKEDSTRUCTUREOFROTAXANES
NOBUHIROKIHARA,TOSHIKAZUTAKATA
.215
13.1
INTRODUCTION
.215
13.2
REDOX
BEHAVIOR
AND
CONFORMATION
OFFERROCENE-END-CAPPEDROTAXANE.217
13.3
REDUCTIONOFKETONEBYROTAXANE
BEARINGADIHYDRONICOTINAMIDEGROUP
.225
13.4
CONCLUSION.230
13.5
REFERENCES.231
XII
CONTENTS
14
METAL-CONTAININGSTARANDHYPERBRANCHEDPOLYMERS
MASAMIKAMIGAITO
.233
14.1
INTRODUCTION
.233
14.2
METAL-CONTAININGSTARPOLYMERS.235
14.2.1
METAL-CONTAININGSTARPOLYMERSWITHASMALL
ANDWELL-DEFINEDNUMBEROFARMS.236
14.2.2
METAL-CONTAININGSTARPOLYMERS
WITHALARGEANDSTATISTICALLYDISTRIBUTEDNUMBEROFARMS.
240
14.3
METAL-CONTAININGHYPERBRANCHEDPOLYMERS.243
14.4
CONCLUDINGREMARKS.245
14.5
REFERENCES.246
15
ELECTRONICPROPERTIESOFHELICALPEPTIDEDERIVATIVES
ATASINGLEMOLECULARLEVEL
SHUNSAKU
KIMURA,
KAZUYA
KITAGAWA,
KAZUYUKI
YANAGISAWA,
TOMOYUKI
MORITA
.
249
15.1
MOLECULARELECTRONICS
.249
15.2
ELECTRONTRANSFERTHROUGHMOLECULES
.250
15.3
ELECTRONICPROPERTIESOFHELICALPEPTIDES.251
15.4
ELECTRONTRANSFERMECHANISMOVERALONGDISTANCE
.254
15.5
EFFECTOFLINKERSONELECTRONTRANSFER
.254
15.6
HELICAL-PEPTIDESCAFFOLDFORELECTRONHOPPING.256
15.7
PHOTOCURRENTGENERATIONWITHHELICALPEPTIDES
CARRYINGNAPHTHYLGROUPS.259
15.8
CONCLUSION.261
15.9
REFERENCES.261
16
CONSTRUCTIONOFREDOX-INDUCEDSYSTEMS
USINGANTIGEN-COMBININGSITESOFANTIBODIES
ANDFUNCTIONALIZATIONOFANTIBODYSUPRAMOLECULES
HIROYASUYAMAGUCHI,AKIRAHARADA
.263
16.1
INTRODUCTION
.264
16.2
PHOTOINDUCEDELECTRON
TRANSFER
FROM
PORPHYRINS
TOELECTRONACCEPTORMOLECULES.266
16.2.1
MONOCLONALANTIBODIES
FOR
MESO
-TETRAKIS(4-CARBOXYPHENYL)PORPHYRIN(TCPP)
.267
16.2.2
PHOTOINDUCEDELECTRONTRANSFERFROMAPORPHYRIN
TOANELECTRONACCEPTORINANANTIBODY-COMBININGSITE
.273
16.3
PEROXIDASEACTIVITYOFFE-PORPHYRIN-ANTIBODYCOMPLEXES
.
275
16.3.1
PREPARATIONOFMONOCLONALANTIBODIES
AGAINSTCATIONICPORPHYRINS
.276
16.3.2
PEROXIDASEACTIVITYOFANTIBODY-FE-TMPYPCOMPLEX.280
16.4
DENDRITICANTIBODYSUPRAMOLECULES.282
CONTENTS
XIII
16.5
LINEARANTIBODYSUPRAMOLECULES:APPLICATION
FORNOVELBIOSENSINGMETHOD.285
16.5.1
ANTIVIOLOGENANTIBODIES.286
16.5.2
APPLICATIONSFORHIGHLYSENSITIVEDETECTIONMETHOD
OFMETHYLVIOLOGENBYSUPRAMOLECULARCOMPLEXFORMATION
BETWEENANTIBODIESANDDIVALENTANTIGENS.287
16.6
CONCLUSIONS.289
16.7
REFERENCES.290
SUBJECTINDEX
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| illustrated | Illustrated |
| index_date | 2024-07-02T17:44:07Z |
| indexdate | 2024-07-09T20:58:17Z |
| institution | BVB |
| isbn | 9783540295792 3540295798 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-015677309 |
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| spelling | Redox systems under nano-space control with 19 tables Toshikazu Hirao (ed.) Berlin ; Heidelberg Springer 2006 XVIII, 295 S. Ill., graph. Darst. 24 cm txt rdacontent n rdamedia nc rdacarrier Literaturangaben Redoxsystem (DE-588)4177304-4 gnd rswk-swf Nanostruktur (DE-588)4204530-7 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Redoxsystem (DE-588)4177304-4 s Nanostruktur (DE-588)4204530-7 s DE-604 Hirao, Toshikazu (DE-588)13178661X edt text/html http://deposit.dnb.de/cgi-bin/dokserv?id=2682856&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015677309&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Redox systems under nano-space control with 19 tables Redoxsystem (DE-588)4177304-4 gnd Nanostruktur (DE-588)4204530-7 gnd |
| subject_GND | (DE-588)4177304-4 (DE-588)4204530-7 (DE-588)4143413-4 |
| title | Redox systems under nano-space control with 19 tables |
| title_auth | Redox systems under nano-space control with 19 tables |
| title_exact_search | Redox systems under nano-space control with 19 tables |
| title_exact_search_txtP | Redox systems under nano-space control with 19 tables |
| title_full | Redox systems under nano-space control with 19 tables Toshikazu Hirao (ed.) |
| title_fullStr | Redox systems under nano-space control with 19 tables Toshikazu Hirao (ed.) |
| title_full_unstemmed | Redox systems under nano-space control with 19 tables Toshikazu Hirao (ed.) |
| title_short | Redox systems under nano-space control |
| title_sort | redox systems under nano space control with 19 tables |
| title_sub | with 19 tables |
| topic | Redoxsystem (DE-588)4177304-4 gnd Nanostruktur (DE-588)4204530-7 gnd |
| topic_facet | Redoxsystem Nanostruktur Aufsatzsammlung |
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