The physics of polymers: concepts for understanding their structures and behavior ; with 2 tables
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2007
|
| Ausgabe: | 3. rev. and expanded ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | Hier auch später erschienene, unveränderte Nachdrucke |
| Beschreibung: | XIII, 518 S. Ill., graph. Darst. |
| ISBN: | 9783642064494 9783540252788 |
Internformat
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| 245 | 1 | 0 | |a The physics of polymers |b concepts for understanding their structures and behavior ; with 2 tables |c Gert Strobl |
| 250 | |a 3. rev. and expanded ed. | ||
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 2007 | |
| 300 | |a XIII, 518 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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Datensatz im Suchindex
| _version_ | 1809403477022998528 |
|---|---|
| adam_text |
Contents
1 Constitution and Architecture of Chains 1
2 Single Chain Conformations 15
2.1 Rotational Isomeric States 15
2.2 Helices 19
2.3 Coils 22
2.3.1 The Ideal Chain 26
2.3.2 The Expanded Chain 45
2.4 The Persistent Chain 55
2.5 The Ising Chain 59
3 Polymer Solutions 69
3.1 Dilute and Semidilute Solutions 70
3.1.1 Osmotic Pressure 71
3.2 Screening of Excluded Volume Forces 82
3.3 Polyelectrolyte Solutions 89
3.3.1 Condensation and Screening of Charges 89
3.3.2 Chain Stretching, Salt Effects and Interchain Ordering . 95
3.3.3 Osmotic Pressure 100
4 Polymer Blends and Block Copolymers 105
4.1 The Flory-Huggins Treatment of Polymer Mixtures 106
4.1.1 Phase Diagrams: Upper and Lower Miscibility Gap . 117
4.2 Phase Separation Mechanisms 122
4.3 Critical Fluctuations and Spinodal Decomposition 129
4.3.1 Critical Scattering 132
4.3.2 Decomposition Kinetics 143
4.4 Block Copolymer Phases 151
4.4.1 Layered Structures 155
4.4.2 Pretransitional Phenomena 157
XII Contents
5 The Semicrystalline State 165
5.1 Structure Characteristics 167
5.1.1 Morphological Elements 167
5.1.2 Structure Parameters 173
5.2 Kinetics of Crystallization and Melting 181
5.3 Laws for the Structure Development 190
5.3.1 The Multistage Model 199
5.4 Mechanisms of Secondary Crystallization 205
5.4.1 The Insertion Mode 208
5.4.2 Surface Crystallization and Melting 212
5.5 Crystallization from Oriented Melts 216 ;
6 Mechanical and Dielectric Response 223
6.1 Response Functions 224
6.1.1 Viscoelasticity 224 ;
6.1.2 Orientational Polarization 228
6.1.3 General Relationships 229
6.2 Relaxatory Modes 236
6.2.1 Single-Time Relaxation Process 237
6.2.2 Retardation and Relaxation Time Spectra 242
6.3 Specific Relaxation Processes and Plow Behavior 245
6.3.1 Local Processes 246
6.3.2 Glass-Rubber Transition and Melt Flow 250
6.3.3 The Glass Transition Temperature 269
6.3.4 Relaxation in Partially Crystalline Systems 277
7 Conjugated Polymers 287
7.1 Electrooptic Activity 289 ;
7.1.1 Excitons and Free Charges 289 :
7.1.2 Electroluminescence 297
7.2 Effects of Doping 302
7.2.1 Electrical Conductivity 302
7.2.2 Magnetism and Reflectivity 306
8 Microscopic Dynamics 313
8.1 The Fluctuation-Dissipation Theorem 313 i
8.2 The Rouse Model 317 '
8.2.1 Stress Relaxation 325 ]
8.2.2 The Dielectric Normal Mode 330 \
8.3 Entanglement Effects in Polymer Melts 333 j
8.3.1 The Reptation Model 338 )
8.4 Solution Viscosities 343 I
8.4.1 Neutral Polymers: Hydrodynamic Interaction 344
8.4.2 Polyelectrolytes: Coulomb Interaction 352
Contents XIII
9 Non-Linear Mechanics 357
9.1 Rubber Elasticity 361
9.1.1 The Fixed Junction Model of Ideal Rubbers 364
9.1.2 The Cauchy Strain Tensor 371
9.1.3 Finger's Constitutive Equation 376
9.2 Swelling of Neutral and Electrolytic Gels 384
9.3 Non-Newtonian Melt Flow 390
9.3.1 Rheological Material Functions 391
9.3.2 The Lodge Liquid 398
9.3.3 The Stress-Optical Rule 404
10 Deformation, Yielding and Fracture 415
10.1 Shear Deformation in Semicrystalline Polymers 418
10.1.1 Critical Strains 418
10.1.2 Constituents of the Drawing Stress 426
10.1.3 The Mechanics of Neck Formation 429
10.1.4 Fibrillar State of Order 435
10.2 Crazing 444
10.3 Brittle Fracture 450
10.3.1 Linear Fracture Mechanics 453
10.3.2 The Slow Mode of Crack Growth 455
A Scattering Experiments 463
A.l Fundamentals 463
A.l.l Basic Equations 464
A.1.2 Time-Resolved Scattering Experiments 468
A.2 Absolute Intensities 471
A.3 Low Angle Scattering Properties 474
A.3.1 Guinier's Law 474
A.3.2 Forward Scattering 476
A.4 Special Polymer Systems 477
A.4.1 Binary Mixtures and Block Copolymers 477
A.4.2 Two-Phase Layer Systems 484
B Glossary of Symbols 493
C Bibliography 501
References 505
Index 511 |
| adam_txt |
Contents
1 Constitution and Architecture of Chains 1
2 Single Chain Conformations 15
2.1 Rotational Isomeric States 15
2.2 Helices 19
2.3 Coils 22
2.3.1 The Ideal Chain 26
2.3.2 The Expanded Chain 45
2.4 The Persistent Chain 55
2.5 The Ising Chain 59
3 Polymer Solutions 69
3.1 Dilute and Semidilute Solutions 70
3.1.1 Osmotic Pressure 71
3.2 Screening of Excluded Volume Forces 82
3.3 Polyelectrolyte Solutions 89
3.3.1 Condensation and Screening of Charges 89
3.3.2 Chain Stretching, Salt Effects and Interchain Ordering . 95
3.3.3 Osmotic Pressure 100
4 Polymer Blends and Block Copolymers 105
4.1 The Flory-Huggins Treatment of Polymer Mixtures 106
4.1.1 Phase Diagrams: Upper and Lower Miscibility Gap . 117
4.2 Phase Separation Mechanisms 122
4.3 Critical Fluctuations and Spinodal Decomposition 129
4.3.1 Critical Scattering 132
4.3.2 Decomposition Kinetics 143
4.4 Block Copolymer Phases 151
4.4.1 Layered Structures 155
4.4.2 Pretransitional Phenomena 157
XII Contents
5 The Semicrystalline State 165
5.1 Structure Characteristics 167
5.1.1 Morphological Elements 167
5.1.2 Structure Parameters 173
5.2 Kinetics of Crystallization and Melting 181
5.3 Laws for the Structure Development 190
5.3.1 The Multistage Model 199
5.4 Mechanisms of Secondary Crystallization 205
5.4.1 The Insertion Mode 208
5.4.2 Surface Crystallization and Melting 212
5.5 Crystallization from Oriented Melts 216 ;
6 Mechanical and Dielectric Response 223
6.1 Response Functions 224
6.1.1 Viscoelasticity 224 ;
6.1.2 Orientational Polarization 228
6.1.3 General Relationships 229
6.2 Relaxatory Modes 236
6.2.1 Single-Time Relaxation Process 237
6.2.2 Retardation and Relaxation Time Spectra 242
6.3 Specific Relaxation Processes and Plow Behavior 245
6.3.1 Local Processes 246
6.3.2 Glass-Rubber Transition and Melt Flow 250
6.3.3 The Glass Transition Temperature 269
6.3.4 Relaxation in Partially Crystalline Systems 277
7 Conjugated Polymers 287
7.1 Electrooptic Activity 289 ;
7.1.1 Excitons and Free Charges 289 :
7.1.2 Electroluminescence 297
7.2 Effects of Doping 302
7.2.1 Electrical Conductivity 302
7.2.2 Magnetism and Reflectivity 306
8 Microscopic Dynamics 313
8.1 The Fluctuation-Dissipation Theorem 313 i
8.2 The Rouse Model 317 '
8.2.1 Stress Relaxation 325 ]
8.2.2 The Dielectric Normal Mode 330 \
8.3 Entanglement Effects in Polymer Melts 333 j
8.3.1 The Reptation Model 338 )
8.4 Solution Viscosities 343 I
8.4.1 Neutral Polymers: Hydrodynamic Interaction 344
8.4.2 Polyelectrolytes: Coulomb Interaction 352
Contents XIII
9 Non-Linear Mechanics 357
9.1 Rubber Elasticity 361
9.1.1 The Fixed Junction Model of Ideal Rubbers 364
9.1.2 The Cauchy Strain Tensor 371
9.1.3 Finger's Constitutive Equation 376
9.2 Swelling of Neutral and Electrolytic Gels 384
9.3 Non-Newtonian Melt Flow 390
9.3.1 Rheological Material Functions 391
9.3.2 The Lodge Liquid 398
9.3.3 The Stress-Optical Rule 404
10 Deformation, Yielding and Fracture 415
10.1 Shear Deformation in Semicrystalline Polymers 418
10.1.1 Critical Strains 418
10.1.2 Constituents of the Drawing Stress 426
10.1.3 The Mechanics of Neck Formation 429
10.1.4 Fibrillar State of Order 435
10.2 Crazing 444
10.3 Brittle Fracture 450
10.3.1 Linear Fracture Mechanics 453
10.3.2 The Slow Mode of Crack Growth 455
A Scattering Experiments 463
A.l Fundamentals 463
A.l.l Basic Equations 464
A.1.2 Time-Resolved Scattering Experiments 468
A.2 Absolute Intensities 471
A.3 Low Angle Scattering Properties 474
A.3.1 Guinier's Law 474
A.3.2 Forward Scattering 476
A.4 Special Polymer Systems 477
A.4.1 Binary Mixtures and Block Copolymers 477
A.4.2 Two-Phase Layer Systems 484
B Glossary of Symbols 493
C Bibliography 501
References 505
Index 511 |
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| discipline | Physik Werkstoffwissenschaften / Fertigungstechnik |
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| spelling | Strobl, Gert R. 1941- Verfasser (DE-588)115460977 aut The physics of polymers concepts for understanding their structures and behavior ; with 2 tables Gert Strobl 3. rev. and expanded ed. Berlin [u.a.] Springer 2007 XIII, 518 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Hier auch später erschienene, unveränderte Nachdrucke Physik (DE-588)4045956-1 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Polymere (DE-588)4046699-1 s Physik (DE-588)4045956-1 s DE-604 text/html http://deposit.dnb.de/cgi-bin/dokserv?id=2874065&prov=M&dok_var=1&dok_ext=htm Inhaltstext HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015613136&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Strobl, Gert R. 1941- The physics of polymers concepts for understanding their structures and behavior ; with 2 tables Physik (DE-588)4045956-1 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4045956-1 (DE-588)4046699-1 (DE-588)4123623-3 |
| title | The physics of polymers concepts for understanding their structures and behavior ; with 2 tables |
| title_auth | The physics of polymers concepts for understanding their structures and behavior ; with 2 tables |
| title_exact_search | The physics of polymers concepts for understanding their structures and behavior ; with 2 tables |
| title_exact_search_txtP | The physics of polymers concepts for understanding their structures and behavior ; with 2 tables |
| title_full | The physics of polymers concepts for understanding their structures and behavior ; with 2 tables Gert Strobl |
| title_fullStr | The physics of polymers concepts for understanding their structures and behavior ; with 2 tables Gert Strobl |
| title_full_unstemmed | The physics of polymers concepts for understanding their structures and behavior ; with 2 tables Gert Strobl |
| title_short | The physics of polymers |
| title_sort | the physics of polymers concepts for understanding their structures and behavior with 2 tables |
| title_sub | concepts for understanding their structures and behavior ; with 2 tables |
| topic | Physik (DE-588)4045956-1 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Physik Polymere Lehrbuch |
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