Micro- and macro-properties of solids: thermal, mechanical and dielectric properties
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Hauptverfasser: | , , |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Berlin ; Heidelberg ; New York
Springer
2006
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Schriftenreihe: | Springer series in materials science
80 |
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Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
Beschreibung: | XVII, 403 S. Ill., graph. Darst. |
ISBN: | 9783540317852 3540317856 |
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100 | 1 | |a Sirdeshmukh, Dinker B. |d 1935- |e Verfasser |0 (DE-588)123042909 |4 aut | |
245 | 1 | 0 | |a Micro- and macro-properties of solids |b thermal, mechanical and dielectric properties |c D. B. Sirdeshmukh ; L. Sirdeshmukh ; K. G. Subhadra |
264 | 1 | |a Berlin ; Heidelberg ; New York |b Springer |c 2006 | |
300 | |a XVII, 403 S. |b Ill., graph. Darst. | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
490 | 1 | |a Springer series in materials science |v 80 | |
650 | 4 | |a Diélectriques | |
650 | 4 | |a Physique de l'état solide | |
650 | 4 | |a Solides - Propriétés mécaniques | |
650 | 4 | |a Solides - Propriétés thermiques | |
650 | 4 | |a Dielectrics | |
650 | 4 | |a Solid state physics | |
650 | 4 | |a Solids |x Mechanical properties | |
650 | 4 | |a Solids |x Thermal properties | |
650 | 0 | 7 | |a Festkörperphysik |0 (DE-588)4016921-2 |2 gnd |9 rswk-swf |
689 | 0 | 0 | |a Festkörperphysik |0 (DE-588)4016921-2 |D s |
689 | 0 | |5 DE-604 | |
700 | 1 | |a Sirdeshmukh, Lalitha |d 1935- |e Verfasser |0 (DE-588)123042941 |4 aut | |
700 | 1 | |a Subhadra, K. G. |d 1947- |e Verfasser |0 (DE-588)123042968 |4 aut | |
830 | 0 | |a Springer series in materials science |v 80 |w (DE-604)BV000683335 |9 80 | |
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Datensatz im Suchindex
_version_ | 1804136201140043776 |
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adam_text | D.B. SIRDESHMUKH L. SIRDESHMUKH K.G. SUBHADRA MICRO- AND
MACRO-PROPERTIES OFSOLIDS THERMAL, MECHANICAL AND DIELECTRIC PROPERTIES
WITH 209 FIGURES AND 153 TABLES SPRINGER CONTENTS 1 LATTICE CONSTANT * A
SOLID STATE PROBE 1 1.1 INTRODUCTION 1 1.2 EXPERIMENTAL METHODS 1 1.2.1
PRINCIPLE 1 1.2.2 EXPERIMENTAL TECHNIQUES 2 1.2.3 STRATEGIES FOR
ACCURACY 13 1.2.4 PRESENT LEVEL OF ACCURACY 15 1.3 AN OVERVIEW 15 1.3.1
CHARACTERISATION OF SEMICONDUCTOR MATERIALS 16 1.3.2 CHARACTERISATION OF
DOPED CRYSTALS 17 1.3.3 EFFECT OF DEUTERATION ON LATTICE CONSTANTS 18
1.3.4 EFFECT OF HYDROGEN ON LATTICE PARAMETERS OF RARE EARTH ELEMENTS 18
1.3.5 LATTICE CONSTANTS OF MIXED CRYSTALS 19 1.3.6 MIXED VALENCE EFFECTS
IN LATTICE CONSTANTS 21 1.3.7 TEMPERATURE VARIATION OF LATTICE CONSTANT
22 1.3.8 PRESSURE VARIATION OF LATTICE PARAMETERS 23 1.3.9 EFFECT OF
MAGNETIC FIELD ON LATTICE CONSTANT 23 1.3.10 RADIATION DAMAGE 24 1.3.11
EFFECT OF PARTICLE SIZE ON LATTICE CONSTANT 25 1.3.12 LATTICE CONSTANTS
AND POINT DEFECTS IN CRYSTALS .... 25 1.3.13 LATTICE CONSTANT VARIATIONS
DUE TO DISLOCATIONS 27 1.3.14 LATTICE CONSTANT AS A SCALING PARAMETER 29
1.4 SOME OF OUR RESULTS 29 1.4.1 LATTICE PARAMETERS - DATA GENERATION 29
1.4.2 LATTICE CONSTANT AS A SCALING PARAMETER 31 1.4.3 TEMPERATURE
VARIATION OF LATTICE CONSTANT 33 1.4.4 RADIATION INDUCED CHANGES IN
LATTICE CONSTANT OF NABROS 33 1.4.5 LATTICE CONSTANTS OF MIXED CRYSTALS
35 XII CONTENTS 2 THERMAL EXPANSION 37 2.1 INTRODUCTION 37 2.2
EXPERIMENTAL METHODS 39 2.2.1 GENERAL 39 2.2.2 OPTICAL METHODS 40 2.2.3
CAPACITANCE METHODS 40 2.2.4 DIFFRACTION METHODS 41 2.2.5 DILATOMETRIC
METHODS 42 2.2.6 OTHER METHODS 46 2.3 AN OVERVIEW 47 2.3.1 SOME NOVEL
EXPERIMENTAL TECHNIQUES 47 2.3.2 EXPERIMENTAL DATA ON THERMAL EXPANSION
OF CRYSTALS 50 2.3.3 INVAR 51 2.3.4 THERMAL EXPANSION OF INERT GAS
SOLIDS 51 2.3.5 CORRELATIONS OF THERMAL EXPANSION WITH OTHER PHYSICAL
PROPERTIES 52 2.3.6 THERMAL EXPANSION AND VACANCIES IN SOLIDS 52 2.3.7
EFFECT OF GROSS DEFECTS ON THERMAL EXPANSION 53 2.3.8 EFFECT OF
IRRADIATION 57 2.3.9 SURFACE THERMAL EXPANSION 57 2.3.10 PRESSURE
VARIATION OF THERMAL EXPANSION 59 2.3.11 THEORIES OF THERMAL EXPANSION
60 2.3.12 NEGATIVE THERMAL EXPANSION 61 2.3.13 ANISOTROPY OF THERMAL
EXPANSION 62 2.4 SOME OF OUR RESULTS 63 2.4.1 COEFFICIENTS OF THERMAL
EXPANSION - DATA GENERATION 63 2.4.2 USBM INTER-LABORATORY PROJECT ON
THERMAL EXPANSION OF MGO 64 2.4.3 ASPECTS OF GRUNEISEN THEORY 65 2.4.4
STUDIES OF SOME ANOMALOUS PHENOMENA 68 2.4.5 EMPIRICAL RELATIONS 71 3
DEBYE-WALLER FACTORS OF CRYSTALS 77 3.1 INTRODUCTION 77 3.2 BRIEF
OUTLINE OF THE DEBYE-WALLER THEORY 77 3.3 EXPERIMENTAL PROCEDURES 82
3.3.1 MEASUREMENT OF INTEGRATED INTENSITY 82 3.3.2 ANALYSIS OF INTENSITY
DATA 87 3.3.3 OTHER METHODS 92 3.4 AN OVERVIEW 93 3.4.1 EARLIER WORK OF
HISTORICAL IMPORTANCE 93 3.4.2 EXPERIMENTAL VALUES OF DEBYE-WALLER
FACTORS AT ROOM TEMPERATURE 93 CONTENTS XIII 3.4.3 EFFECT OF CHOICE OF
ATOMIC SCATTERING FACTORS ON MEASURED B-VALUES 94 3.4.4 DEBYE-WALLER
FACTOR FOR A REAL CRYSTAL 95 3.4.5 DEBYE TEMPERATURES OF THIN FILMS AND
FINE PARTICLES 96 3.4.6 EFFECT OF LATTICE STRAIN ON B 97 3.4.7
ANISOTROPY OF DEBYE-WALLER FACTORS 98 3.4.8 PRESSURE VARIATION OF 0M 100
3.4.9 TEMPERATURE VARIATION OF B AND 0M 101 3.4.10 ANHARMONIC EFFECTS IN
DEBYE-WALLER FACTORS AND DEBYE TEMPERATURE 101 3.4.11 DEBYE-WALLER
FACTORS FROM LATTICE DYNAMICS 103 3.4.12 DEBYE-WALLER FACTORS AND
MELTING 106 3.4.13 DEBYE-WALLER FACTORS AND TEMPERATURE DEPENDENCE OF
BAND-GAP IN SEMICONDUCTORS 106 3.4.14 DEBYE TEMPERATURE IN AN
ANTIFERROMAGNETIC TRANSITION 107 3.4.15 NANO EFFECT ON DEBYE-WALLER
FACTOR AND DEBYE TEMPERATURE 108 3.4.16 ENERGY OF DEFECT FORMATION FROM
DEBYE TEMPERATURE 108 3.4.17 EFFECT OF ELECTRONIC ENVIRONMENT ON
DEBYE-WALLER FACTOR 109 3.4.18 DEBYE-WALLER FACTOR OF MIXED CRYSTALS 110
3.4.19 DEBYE-WALLER FACTORS OF PROTEIN STRUCTURES 110 3.5 SOME OF OUR
RESULTS 111 3.5.1 DEBYE-WALLER FACTORS - DATA GENERATION 111 3.5.2
DEBYE-WALLER FACTORS AND MASS RATIO 113 3.5.3 COMPARISON OF EXPERIMENTAL
RESULTS WITH LATTICE DYNAMICAL RESULTS 118 3.5.4 ANISOTROPY OF
DEBYE-WALLER FACTORS 120 3.5.5 EFFECT OF STRAIN ON DEBYE-WALLER FACTORS
122 3.5.6 EFFECT OF ATOMIC SCATTERING FACTORS ON B 123 3.5.7
DEBYE-WALLER FACTORS AND THE ELECTRONIC ENVIRONMENT 124 3.5.8
DEBYE-WALLER FACTORS IN MIXED CRYSTALS 125 3.5.9 X-RAY DEBYE
TEMPERATURES DERIVED FROM DEBYE-WALLER FACTORS 126 3.5.10 COMPARISON OF
6 FROM DIFFERENT METHODS 126 3.5.11 A MODIFIED EXPRESSION FOR THE X-RAY
DEBYE TEMPERATURE (0M) 129 3.5.12 ENERGY OF DEFECT FORMATION FROM DEBYE
TEMPERATURES 130 XIV CONTENTS 4 HARDNESS 135 4.1 INTRODUCTION 135 4.2
EXPERIMENTAL METHODS 136 4.2.1 GENERAL 136 4.2.2 LEITZ-WETZLAR MINI-LOAD
2 MICROHARDNESS TESTER 137 4.2.3 SHIMADZU DYNAMIC ULTRA HARDNESS TESTER
DUH 202 139 4.2.4 NANOINDENTATION 140 4.2.5 RELATIVE HARDNESS
MEASUREMENT 143 4.3 AN OVERVIEW 146 4.3.1 GENERAL 146 4.3.2 LOAD
VARIATION OF HARDNESS 146 4.3.3 SOLID SOLUTION HARDENING 148 4.3.4
IMPURITY HARDENING 148 4.3.5 DISLOCATION HARDENING 149 4.3.6 RADIATION
HARDENING 149 4.3.7 HARDNESS AND CHEMICAL BOND 151 4.3.8 PRESSURE
VARIATION OF HARDNESS 152 4.3.9 TEMPERATURE VARIATION OF HARDNESS 153
4.3.10 EMPIRICAL RELATIONS WITH OTHER PHYSICAL PROPERTIES . . 153 4.3.11
ANISOTROPY OF HARDNESS 154 4.3.12 SURFACE HARDNESS 157 4.3.13
NANOHARDNESS OF THIN FILMS 158 4.3.14 EFFECT OF MAGNETIC FIELD ON
HARDNESS 158 4.3.15 HARDNESS OF ORGANIC CRYSTALS 159 4.3.16 MICRO-RAMAN
SPECTROSCOPY OF INDENTATIONS 159 4.4 SOME OF OUR RESULTS 160 4.4.1 LOAD
VARIATION OF HARDNESS 160 4.4.2 HARDNESS AND BONDING 167 4.4.3 RADIATION
HARDENING 176 4.4.4 HARDNESS OF DOPED CRYSTALS 180 4.4.5 HARDNESS OF
MIXED CRYSTALS 182 4.4.6 EMPIRICAL RELATIONS WITH OTHER PHYSICAL
PROPERTIES . . 182 4.4.7 TEMPERATURE VARIATION OF HARDNESS 184 4.4.8
SURFACE HARDNESS OF CRYSTALS 187 4.4.9 ANISOTROPY OF HARDNESS 192 5
DIELECTRIC AND ELECTRICAL PROPERTIES OF SOLIDS 199 5.1 INTRODUCTION 199
5.1.1 DIELECTRIC POLARIZATION 199 5.1.2 DIELECTRIC DISPERSION AND
DIELECTRIC LOSS 201 5.1.3 DIELECTRIC LOSS AND CONDUCTION 202 5.1.4
TEMPERATURE VARIATION OF DIELECTRIC CONSTANT AND LOSS 203 CONTENTS XV
5.2 EXPERIMENTAL 204 5.2.1 MEASURING INSTRUMENTS 204 5.2.2 CELL DESIGNS
207 5.2.3 PROCEDURAL DETAILS 210 5.2.4 MEASUREMENT IN THE MICROWAVE
REGION 213 5.2.5 DIELECTRIC CONSTANTS FROM IR REFLECTIVITY 213 5.2.6
IMPEDANCE SPECTROSCOPY 215 5.2.7 COMPARISON OF METHODS 215 5.3 AN
OVERVIEW 216 5.3.1 SOME IMPORTANT EXPERIMENTAL RESULTS 216 5.3.2
TEMPERATURE VARIATION OF DIELECTRIC CONSTANT 219 5.3.3 SZIGETI S THEORY
(EFFECTIVE IONIC CHARGE AND ANHARMONICITY) 221 5.3.4 SPECTROSCOPIC
ASPECTS 224 5.3.5 CONDUCTIVITY OF IONIC CRYSTALS 228 5.3.6 DIELECTRIC
CONSTANT AND POLARON CONDUCTION 229 5.3.7 DIELECTRIC CONSTANT AND
ADDITIVITY OF POLARIZABILITY 231 5.3.8 DIELECTRIC BEHAVIOUR OF PROTEINS
DIELECTRIC PROPERTIES AND PROTEIN HYDRATION 231 5.3.9 IRRADIATION
EFFECTS 234 5.4 SOME OF OUR RESULTS 235 5.4.1 DIELECTRIC PROPERTIES -
DATA GENERATION 235 5.4.2 ANALYSIS OF TEMPERATURE VARIATION OF
DIELECTRIC CONSTANT 235 5.4.3 APPLICATION OF SZIGETI S THEORY 241 5.4.4
SPECTROSCOPIC ASPECTS 242 5.4.5 POLARON CONDUCTION IN GARNETS 245 5.4.6
DIELECTRIC CONSTANT AND ADDITIVITY OF POLARIZABILITY 246 5.4.7
FERROELECTRIC BEHAVIOUR IN NACI0 3 AND NABR0 3 .... 247 5.4.8 ANALYSIS
OF CONDUCTIVITY DATA 248 5.4.9 Y-I RRA DIATION STUDIES 251 5.4.10
DIELECTRIC PROPERTIES AND PROTEIN HYDRATION 254 6 THEORETICAL EVALUATION
OF SOME CRYSTAL PROPERTIES 257 6.1 INTRODUCTION 257 6.2 ELASTIC
CONSTANTS OF IONIC CRYSTALS 257 6.3 COEFFICIENT OF THERMAL EXPANSION
FROM INTERATOMIC POTENTIALS 259 6.3.1 THERMAL EXPANSION COEFFICIENT OF
CRYSTALS WITH FLUORITE STRUCTURE 259 6.3.2 THERMAL EXPANSION COEFNCIENTS
OF SOME ANISOTROPIE ELEMENTS 260 XVI CONTENTS 6.4 DEBYE TEMPERATURES
FROM ELASTIC CONSTANTS 261 6.4.1 GENERAL 261 6.4.2 DEBYE TEMPERATURES
FROM SINGLE CRYSTAL ELASTIC CONSTANTS 262 6.4.3 9 FROM POLYCRY ST ALLINE
ELASTIC DATA 265 6.4.4 BRIEF REVIEW OF EARLIER WORK 266 6.4.5 SOME OF
OUR RESULTS 268 6.5 GRUNEISEN PARAMETER 272 6.5.1 GRUNEISEN PARAMETER
FROM INTERATOMIC POTENTIALS . . . 273 6.5.2 7 FROM PRESSURE VARIATION OF
DEBYE TEMPERATURE.... 275 6.5.3 EVALUATION OF 7 FROM PRESSURE
DERIVATIVES OF ELASTIC MODULI 277 6.5.4 MODE GRUNEISEN PARAMETERS OF
FLUORITE-TYPE CRYSTALS 282 7 THE PHYSICS OF MIXED CRYSTALS 285 7.1
INTRODUCTION , 285 7.1.1 GENERAL 285 7.1.2 EARLIER REVIEWS ON MIXED
CRYSTALS 286 7.1.3 THEORETICAL MODELS 287 7.2 AN OVERVIEW 288 7.2.1
MOLAR VOLUME AND LATTICE PARAMETERS 288 7.2.2 DEBYE-WALLER FACTORS 292
7.2.3 DEBYE TEMPERATURES 294 7.2.4 HARDNESS OF MIXED CRYSTALS 294 7.2.5
DIELECTRIC CONSTANT 298 7.2.6 EFFECTIVE IONIC CHARGE IN MIXED CRYSTALS
299 7.2.7 COLOUR CENTRES IN ALKALI HALIDE MIXED CRYSTALS 300 7.2.8
DEFECTS IN MIXED CRYSTALS 302 7.2.9 MELTING TEMPERATURE 303 7.2.10 PM3M
- FM3M TRANSITION IN MIXED CRYSTALS 304 7.3 SOME OF OUR RESULTS 306
7.3.1 LATTICE CONSTANTS OF MIXED CRYSTALS 306 7.3.2 DEBYE-WALLER FACTORS
310 7.3.3 DEBYE TEMPERATURES OF MIXED CRYSTALS 312 7.3.4 HARDNESS OF
MIXED CRYSTALS 315 7.3.5 DIELECTRIC PROPERTIES 317 7.3.6 EFFECTIVE IONIC
CHARGE 320 7.3.7 COLOUR CENTRES IN RBCL-RBBR MIXED CRYSTALS 322 7.3.8
DEFECTS IN MIXED CRYSTALS 324 7.3.9 MELTING TEMPERATURES OF MIXED
CRYSTALS 325 7.3.10 PM3M -» FM3M TRANSITION IN NH 4 CL-NH 4 BR SYSTEM
327 CONTENTS XVII 8 ELASTIC PROPERTIES OF SOLIDS * A CRITICAL ANALYSIS
331 8.1 INTRODUCTION 331 8.2 EXPERIMENTAL METHODS 331 8.2.1 PISTON
DISPLACEMENT METHOD 331 8.2.2 SHOCK WAVE METHOD 333 8.2.3 X-RAY
DIFFRACTION METHOD 334 8.2.4 OPTICAL INTERFEROMETRIC METHOD 334 8.2.5
ULTRASONIC METHOD 336 8.2.6 OTHER METHODS 337 8.2.7 RELATIVE MERITS AND
LIMITATIONS 337 8.3 DISCREPANCIES IN ELASTIC PROPERTIES 337 8.4
CONSISTENCY CHECKS FOR BULK MODULI 338 8.4.1 PHENOMENOLOGICAL RELATIONS
AS CONSISTENCY CHECKS . . 338 8.4.2 THEORETICAL CONSISTENCY CHECKS 343
8.4.3 EMPIRICAL RELATIONS AS CONSISTENCY CHECKS 352 8.5 CONSISTENCY
CHECKS FOR SINGLE CRYSTAL ELASTIC CONSTANTS .... 356 8.5.1 CUBIC
CRYSTALS 357 8.5.2 TETRAGONAL CRYSTALS 357 8.5.3 TRIGONAL AND HEXAGONAL
CRYSTALS 360 8.6 CONCLUSIONS 361 REFERENCES 363 INDEX 399
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adam_txt |
D.B. SIRDESHMUKH L. SIRDESHMUKH K.G. SUBHADRA MICRO- AND
MACRO-PROPERTIES OFSOLIDS THERMAL, MECHANICAL AND DIELECTRIC PROPERTIES
WITH 209 FIGURES AND 153 TABLES SPRINGER CONTENTS 1 LATTICE CONSTANT * A
SOLID STATE PROBE 1 1.1 INTRODUCTION 1 1.2 EXPERIMENTAL METHODS 1 1.2.1
PRINCIPLE 1 1.2.2 EXPERIMENTAL TECHNIQUES 2 1.2.3 STRATEGIES FOR
ACCURACY 13 1.2.4 PRESENT LEVEL OF ACCURACY 15 1.3 AN OVERVIEW 15 1.3.1
CHARACTERISATION OF SEMICONDUCTOR MATERIALS 16 1.3.2 CHARACTERISATION OF
DOPED CRYSTALS 17 1.3.3 EFFECT OF DEUTERATION ON LATTICE CONSTANTS 18
1.3.4 EFFECT OF HYDROGEN ON LATTICE PARAMETERS OF RARE EARTH ELEMENTS 18
1.3.5 LATTICE CONSTANTS OF MIXED CRYSTALS 19 1.3.6 MIXED VALENCE EFFECTS
IN LATTICE CONSTANTS 21 1.3.7 TEMPERATURE VARIATION OF LATTICE CONSTANT
22 1.3.8 PRESSURE VARIATION OF LATTICE PARAMETERS 23 1.3.9 EFFECT OF
MAGNETIC FIELD ON LATTICE CONSTANT 23 1.3.10 RADIATION DAMAGE 24 1.3.11
EFFECT OF PARTICLE SIZE ON LATTICE CONSTANT 25 1.3.12 LATTICE CONSTANTS
AND POINT DEFECTS IN CRYSTALS . 25 1.3.13 LATTICE CONSTANT VARIATIONS
DUE TO DISLOCATIONS 27 1.3.14 LATTICE CONSTANT AS A SCALING PARAMETER 29
1.4 SOME OF OUR RESULTS 29 1.4.1 LATTICE PARAMETERS - DATA GENERATION 29
1.4.2 LATTICE CONSTANT AS A SCALING PARAMETER 31 1.4.3 TEMPERATURE
VARIATION OF LATTICE CONSTANT 33 1.4.4 RADIATION INDUCED CHANGES IN
LATTICE CONSTANT OF NABROS 33 1.4.5 LATTICE CONSTANTS OF MIXED CRYSTALS
35 XII CONTENTS 2 THERMAL EXPANSION 37 2.1 INTRODUCTION 37 2.2
EXPERIMENTAL METHODS 39 2.2.1 GENERAL 39 2.2.2 OPTICAL METHODS 40 2.2.3
CAPACITANCE METHODS 40 2.2.4 DIFFRACTION METHODS 41 2.2.5 DILATOMETRIC
METHODS 42 2.2.6 OTHER METHODS 46 2.3 AN OVERVIEW 47 2.3.1 SOME NOVEL
EXPERIMENTAL TECHNIQUES 47 2.3.2 EXPERIMENTAL DATA ON THERMAL EXPANSION
OF CRYSTALS 50 2.3.3 'INVAR' 51 2.3.4 THERMAL EXPANSION OF INERT GAS
SOLIDS 51 2.3.5 CORRELATIONS OF THERMAL EXPANSION WITH OTHER PHYSICAL
PROPERTIES 52 2.3.6 THERMAL EXPANSION AND VACANCIES IN SOLIDS 52 2.3.7
EFFECT OF GROSS DEFECTS ON THERMAL EXPANSION 53 2.3.8 EFFECT OF
IRRADIATION 57 2.3.9 SURFACE THERMAL EXPANSION 57 2.3.10 PRESSURE
VARIATION OF THERMAL EXPANSION 59 2.3.11 THEORIES OF THERMAL EXPANSION
60 2.3.12 NEGATIVE THERMAL EXPANSION 61 2.3.13 ANISOTROPY OF THERMAL
EXPANSION 62 2.4 SOME OF OUR RESULTS 63 2.4.1 COEFFICIENTS OF THERMAL
EXPANSION - DATA GENERATION 63 2.4.2 USBM INTER-LABORATORY PROJECT ON
THERMAL EXPANSION OF MGO 64 2.4.3 ASPECTS OF GRUNEISEN THEORY 65 2.4.4
STUDIES OF SOME ANOMALOUS PHENOMENA 68 2.4.5 EMPIRICAL RELATIONS 71 3
DEBYE-WALLER FACTORS OF CRYSTALS 77 3.1 INTRODUCTION 77 3.2 BRIEF
OUTLINE OF THE DEBYE-WALLER THEORY 77 3.3 EXPERIMENTAL PROCEDURES 82
3.3.1 MEASUREMENT OF INTEGRATED INTENSITY 82 3.3.2 ANALYSIS OF INTENSITY
DATA 87 3.3.3 OTHER METHODS 92 3.4 AN OVERVIEW 93 3.4.1 EARLIER WORK OF
HISTORICAL IMPORTANCE 93 3.4.2 EXPERIMENTAL VALUES OF DEBYE-WALLER
FACTORS AT ROOM TEMPERATURE 93 CONTENTS XIII 3.4.3 EFFECT OF CHOICE OF
ATOMIC SCATTERING FACTORS ON MEASURED B-VALUES 94 3.4.4 DEBYE-WALLER
FACTOR FOR A REAL CRYSTAL 95 3.4.5 DEBYE TEMPERATURES OF THIN FILMS AND
FINE PARTICLES 96 3.4.6 EFFECT OF LATTICE STRAIN ON B 97 3.4.7
ANISOTROPY OF DEBYE-WALLER FACTORS 98 3.4.8 PRESSURE VARIATION OF 0M 100
3.4.9 TEMPERATURE VARIATION OF B AND 0M 101 3.4.10 ANHARMONIC EFFECTS IN
DEBYE-WALLER FACTORS AND DEBYE TEMPERATURE 101 3.4.11 DEBYE-WALLER
FACTORS FROM LATTICE DYNAMICS 103 3.4.12 DEBYE-WALLER FACTORS AND
MELTING 106 3.4.13 DEBYE-WALLER FACTORS AND TEMPERATURE DEPENDENCE OF
BAND-GAP IN SEMICONDUCTORS 106 3.4.14 DEBYE TEMPERATURE IN AN
ANTIFERROMAGNETIC TRANSITION 107 3.4.15 NANO EFFECT ON DEBYE-WALLER
FACTOR AND DEBYE TEMPERATURE 108 3.4.16 ENERGY OF DEFECT FORMATION FROM
DEBYE TEMPERATURE 108 3.4.17 EFFECT OF ELECTRONIC ENVIRONMENT ON
DEBYE-WALLER FACTOR 109 3.4.18 DEBYE-WALLER FACTOR OF MIXED CRYSTALS 110
3.4.19 DEBYE-WALLER FACTORS OF PROTEIN STRUCTURES 110 3.5 SOME OF OUR
RESULTS 111 3.5.1 DEBYE-WALLER FACTORS - DATA GENERATION 111 3.5.2
DEBYE-WALLER FACTORS AND MASS RATIO 113 3.5.3 COMPARISON OF EXPERIMENTAL
RESULTS WITH LATTICE DYNAMICAL RESULTS 118 3.5.4 ANISOTROPY OF
DEBYE-WALLER FACTORS 120 3.5.5 EFFECT OF STRAIN ON DEBYE-WALLER FACTORS
122 3.5.6 EFFECT OF ATOMIC SCATTERING FACTORS ON B 123 3.5.7
DEBYE-WALLER FACTORS AND THE ELECTRONIC ENVIRONMENT 124 3.5.8
DEBYE-WALLER FACTORS IN MIXED CRYSTALS 125 3.5.9 X-RAY DEBYE
TEMPERATURES DERIVED FROM DEBYE-WALLER FACTORS 126 3.5.10 COMPARISON OF
6 FROM DIFFERENT METHODS 126 3.5.11 A MODIFIED EXPRESSION FOR THE X-RAY
DEBYE TEMPERATURE (0M) 129 3.5.12 ENERGY OF DEFECT FORMATION FROM DEBYE
TEMPERATURES 130 XIV CONTENTS 4 HARDNESS 135 4.1 INTRODUCTION 135 4.2
EXPERIMENTAL METHODS 136 4.2.1 GENERAL 136 4.2.2 LEITZ-WETZLAR MINI-LOAD
2 MICROHARDNESS TESTER 137 4.2.3 SHIMADZU DYNAMIC ULTRA HARDNESS TESTER
DUH 202 139 4.2.4 NANOINDENTATION 140 4.2.5 RELATIVE HARDNESS
MEASUREMENT 143 4.3 AN OVERVIEW 146 4.3.1 GENERAL 146 4.3.2 LOAD
VARIATION OF HARDNESS 146 4.3.3 SOLID SOLUTION HARDENING 148 4.3.4
IMPURITY HARDENING 148 4.3.5 DISLOCATION HARDENING 149 4.3.6 RADIATION
HARDENING 149 4.3.7 HARDNESS AND CHEMICAL BOND 151 4.3.8 PRESSURE
VARIATION OF HARDNESS 152 4.3.9 TEMPERATURE VARIATION OF HARDNESS 153
4.3.10 EMPIRICAL RELATIONS WITH OTHER PHYSICAL PROPERTIES . . 153 4.3.11
ANISOTROPY OF HARDNESS 154 4.3.12 SURFACE HARDNESS 157 4.3.13
NANOHARDNESS OF THIN FILMS 158 4.3.14 EFFECT OF MAGNETIC FIELD ON
HARDNESS 158 4.3.15 HARDNESS OF ORGANIC CRYSTALS 159 4.3.16 MICRO-RAMAN
SPECTROSCOPY OF INDENTATIONS 159 4.4 SOME OF OUR RESULTS 160 4.4.1 LOAD
VARIATION OF HARDNESS 160 4.4.2 HARDNESS AND BONDING 167 4.4.3 RADIATION
HARDENING 176 4.4.4 HARDNESS OF DOPED CRYSTALS 180 4.4.5 HARDNESS OF
MIXED CRYSTALS 182 4.4.6 EMPIRICAL RELATIONS WITH OTHER PHYSICAL
PROPERTIES . . 182 4.4.7 TEMPERATURE VARIATION OF HARDNESS 184 4.4.8
SURFACE HARDNESS OF CRYSTALS 187 4.4.9 ANISOTROPY OF HARDNESS 192 5
DIELECTRIC AND ELECTRICAL PROPERTIES OF SOLIDS 199 5.1 INTRODUCTION 199
5.1.1 DIELECTRIC POLARIZATION 199 5.1.2 DIELECTRIC DISPERSION AND
DIELECTRIC LOSS 201 5.1.3 DIELECTRIC LOSS AND CONDUCTION 202 5.1.4
TEMPERATURE VARIATION OF DIELECTRIC CONSTANT AND LOSS 203 CONTENTS XV
5.2 EXPERIMENTAL 204 5.2.1 MEASURING INSTRUMENTS 204 5.2.2 CELL DESIGNS
207 5.2.3 PROCEDURAL DETAILS 210 5.2.4 MEASUREMENT IN THE MICROWAVE
REGION 213 5.2.5 DIELECTRIC CONSTANTS FROM IR REFLECTIVITY 213 5.2.6
IMPEDANCE SPECTROSCOPY 215 5.2.7 COMPARISON OF METHODS 215 5.3 AN
OVERVIEW 216 5.3.1 SOME IMPORTANT EXPERIMENTAL RESULTS 216 5.3.2
TEMPERATURE VARIATION OF DIELECTRIC CONSTANT 219 5.3.3 SZIGETI'S THEORY
(EFFECTIVE IONIC CHARGE AND ANHARMONICITY) 221 5.3.4 SPECTROSCOPIC
ASPECTS 224 5.3.5 CONDUCTIVITY OF IONIC CRYSTALS 228 5.3.6 DIELECTRIC
CONSTANT AND POLARON CONDUCTION 229 5.3.7 DIELECTRIC CONSTANT AND
ADDITIVITY OF POLARIZABILITY 231 5.3.8 DIELECTRIC BEHAVIOUR OF PROTEINS
DIELECTRIC PROPERTIES AND PROTEIN HYDRATION 231 5.3.9 IRRADIATION
EFFECTS 234 5.4 SOME OF OUR RESULTS 235 5.4.1 DIELECTRIC PROPERTIES -
DATA GENERATION 235 5.4.2 ANALYSIS OF TEMPERATURE VARIATION OF
DIELECTRIC CONSTANT 235 5.4.3 APPLICATION OF SZIGETI'S THEORY 241 5.4.4
SPECTROSCOPIC ASPECTS 242 5.4.5 POLARON CONDUCTION IN GARNETS 245 5.4.6
DIELECTRIC CONSTANT AND ADDITIVITY OF POLARIZABILITY 246 5.4.7
FERROELECTRIC BEHAVIOUR IN NACI0 3 AND NABR0 3 . 247 5.4.8 ANALYSIS
OF CONDUCTIVITY DATA 248 5.4.9 Y-I RRA DIATION STUDIES 251 5.4.10
DIELECTRIC PROPERTIES AND PROTEIN HYDRATION 254 6 THEORETICAL EVALUATION
OF SOME CRYSTAL PROPERTIES 257 6.1 INTRODUCTION 257 6.2 ELASTIC
CONSTANTS OF IONIC CRYSTALS 257 6.3 COEFFICIENT OF THERMAL EXPANSION
FROM INTERATOMIC POTENTIALS 259 6.3.1 THERMAL EXPANSION COEFFICIENT OF
CRYSTALS WITH FLUORITE STRUCTURE 259 6.3.2 THERMAL EXPANSION COEFNCIENTS
OF SOME ANISOTROPIE ELEMENTS 260 XVI CONTENTS 6.4 DEBYE TEMPERATURES
FROM ELASTIC CONSTANTS 261 6.4.1 GENERAL 261 6.4.2 DEBYE TEMPERATURES
FROM SINGLE CRYSTAL ELASTIC CONSTANTS 262 6.4.3 9 FROM POLYCRY ST ALLINE
ELASTIC DATA 265 6.4.4 BRIEF REVIEW OF EARLIER WORK 266 6.4.5 SOME OF
OUR RESULTS 268 6.5 GRUNEISEN PARAMETER 272 6.5.1 GRUNEISEN PARAMETER
FROM INTERATOMIC POTENTIALS . . . 273 6.5.2 7 FROM PRESSURE VARIATION OF
DEBYE TEMPERATURE. 275 6.5.3 EVALUATION OF 7 FROM PRESSURE
DERIVATIVES OF ELASTIC MODULI 277 6.5.4 MODE GRUNEISEN PARAMETERS OF
FLUORITE-TYPE CRYSTALS 282 7 THE PHYSICS OF MIXED CRYSTALS 285 7.1
INTRODUCTION , 285 7.1.1 GENERAL 285 7.1.2 EARLIER REVIEWS ON MIXED
CRYSTALS 286 7.1.3 THEORETICAL MODELS 287 7.2 AN OVERVIEW 288 7.2.1
MOLAR VOLUME AND LATTICE PARAMETERS 288 7.2.2 DEBYE-WALLER FACTORS 292
7.2.3 DEBYE TEMPERATURES 294 7.2.4 HARDNESS OF MIXED CRYSTALS 294 7.2.5
DIELECTRIC CONSTANT 298 7.2.6 EFFECTIVE IONIC CHARGE IN MIXED CRYSTALS
299 7.2.7 COLOUR CENTRES IN ALKALI HALIDE MIXED CRYSTALS 300 7.2.8
DEFECTS IN MIXED CRYSTALS 302 7.2.9 MELTING TEMPERATURE 303 7.2.10 PM3M
- FM3M TRANSITION IN MIXED CRYSTALS 304 7.3 SOME OF OUR RESULTS 306
7.3.1 LATTICE CONSTANTS OF MIXED CRYSTALS 306 7.3.2 DEBYE-WALLER FACTORS
310 7.3.3 DEBYE TEMPERATURES OF MIXED CRYSTALS 312 7.3.4 HARDNESS OF
MIXED CRYSTALS 315 7.3.5 DIELECTRIC PROPERTIES 317 7.3.6 EFFECTIVE IONIC
CHARGE 320 7.3.7 COLOUR CENTRES IN RBCL-RBBR MIXED CRYSTALS 322 7.3.8
DEFECTS IN MIXED CRYSTALS 324 7.3.9 MELTING TEMPERATURES OF MIXED
CRYSTALS 325 7.3.10 PM3M -» FM3M TRANSITION IN NH 4 CL-NH 4 BR SYSTEM
327 CONTENTS XVII 8 ELASTIC PROPERTIES OF SOLIDS * A CRITICAL ANALYSIS
331 8.1 INTRODUCTION 331 8.2 EXPERIMENTAL METHODS 331 8.2.1 PISTON
DISPLACEMENT METHOD 331 8.2.2 SHOCK WAVE METHOD 333 8.2.3 X-RAY
DIFFRACTION METHOD 334 8.2.4 OPTICAL INTERFEROMETRIC METHOD 334 8.2.5
ULTRASONIC METHOD 336 8.2.6 OTHER METHODS 337 8.2.7 RELATIVE MERITS AND
LIMITATIONS 337 8.3 DISCREPANCIES IN ELASTIC PROPERTIES 337 8.4
CONSISTENCY CHECKS FOR BULK MODULI 338 8.4.1 PHENOMENOLOGICAL RELATIONS
AS CONSISTENCY CHECKS . . 338 8.4.2 THEORETICAL CONSISTENCY CHECKS 343
8.4.3 EMPIRICAL RELATIONS AS CONSISTENCY CHECKS 352 8.5 CONSISTENCY
CHECKS FOR SINGLE CRYSTAL ELASTIC CONSTANTS . 356 8.5.1 CUBIC
CRYSTALS 357 8.5.2 TETRAGONAL CRYSTALS 357 8.5.3 TRIGONAL AND HEXAGONAL
CRYSTALS 360 8.6 CONCLUSIONS 361 REFERENCES 363 INDEX 399 |
any_adam_object | 1 |
any_adam_object_boolean | 1 |
author | Sirdeshmukh, Dinker B. 1935- Sirdeshmukh, Lalitha 1935- Subhadra, K. G. 1947- |
author_GND | (DE-588)123042909 (DE-588)123042941 (DE-588)123042968 |
author_facet | Sirdeshmukh, Dinker B. 1935- Sirdeshmukh, Lalitha 1935- Subhadra, K. G. 1947- |
author_role | aut aut aut |
author_sort | Sirdeshmukh, Dinker B. 1935- |
author_variant | d b s db dbs l s ls k g s kg kgs |
building | Verbundindex |
bvnumber | BV022218676 |
callnumber-first | Q - Science |
callnumber-label | QC176 |
callnumber-raw | QC176 |
callnumber-search | QC176 |
callnumber-sort | QC 3176 |
callnumber-subject | QC - Physics |
classification_rvk | UP 1000 UQ 1100 |
ctrlnum | (OCoLC)71336181 (DE-599)BVBBV022218676 |
dewey-full | 530.4/1 |
dewey-hundreds | 500 - Natural sciences and mathematics |
dewey-ones | 530 - Physics |
dewey-raw | 530.4/1 |
dewey-search | 530.4/1 |
dewey-sort | 3530.4 11 |
dewey-tens | 530 - Physics |
discipline | Physik |
discipline_str_mv | Physik |
format | Book |
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id | DE-604.BV022218676 |
illustrated | Illustrated |
index_date | 2024-07-02T16:28:22Z |
indexdate | 2024-07-09T20:52:38Z |
institution | BVB |
isbn | 9783540317852 3540317856 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-015429925 |
oclc_num | 71336181 |
open_access_boolean | |
owner | DE-703 DE-83 DE-11 |
owner_facet | DE-703 DE-83 DE-11 |
physical | XVII, 403 S. Ill., graph. Darst. |
publishDate | 2006 |
publishDateSearch | 2006 |
publishDateSort | 2006 |
publisher | Springer |
record_format | marc |
series | Springer series in materials science |
series2 | Springer series in materials science |
spelling | Sirdeshmukh, Dinker B. 1935- Verfasser (DE-588)123042909 aut Micro- and macro-properties of solids thermal, mechanical and dielectric properties D. B. Sirdeshmukh ; L. Sirdeshmukh ; K. G. Subhadra Berlin ; Heidelberg ; New York Springer 2006 XVII, 403 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer series in materials science 80 Diélectriques Physique de l'état solide Solides - Propriétés mécaniques Solides - Propriétés thermiques Dielectrics Solid state physics Solids Mechanical properties Solids Thermal properties Festkörperphysik (DE-588)4016921-2 gnd rswk-swf Festkörperphysik (DE-588)4016921-2 s DE-604 Sirdeshmukh, Lalitha 1935- Verfasser (DE-588)123042941 aut Subhadra, K. G. 1947- Verfasser (DE-588)123042968 aut Springer series in materials science 80 (DE-604)BV000683335 80 text/html http://deposit.dnb.de/cgi-bin/dokserv?id=2754961&prov=M&dok_var=1&dok_ext=htm Inhaltstext GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015429925&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Sirdeshmukh, Dinker B. 1935- Sirdeshmukh, Lalitha 1935- Subhadra, K. G. 1947- Micro- and macro-properties of solids thermal, mechanical and dielectric properties Springer series in materials science Diélectriques Physique de l'état solide Solides - Propriétés mécaniques Solides - Propriétés thermiques Dielectrics Solid state physics Solids Mechanical properties Solids Thermal properties Festkörperphysik (DE-588)4016921-2 gnd |
subject_GND | (DE-588)4016921-2 |
title | Micro- and macro-properties of solids thermal, mechanical and dielectric properties |
title_auth | Micro- and macro-properties of solids thermal, mechanical and dielectric properties |
title_exact_search | Micro- and macro-properties of solids thermal, mechanical and dielectric properties |
title_exact_search_txtP | Micro- and macro-properties of solids thermal, mechanical and dielectric properties |
title_full | Micro- and macro-properties of solids thermal, mechanical and dielectric properties D. B. Sirdeshmukh ; L. Sirdeshmukh ; K. G. Subhadra |
title_fullStr | Micro- and macro-properties of solids thermal, mechanical and dielectric properties D. B. Sirdeshmukh ; L. Sirdeshmukh ; K. G. Subhadra |
title_full_unstemmed | Micro- and macro-properties of solids thermal, mechanical and dielectric properties D. B. Sirdeshmukh ; L. Sirdeshmukh ; K. G. Subhadra |
title_short | Micro- and macro-properties of solids |
title_sort | micro and macro properties of solids thermal mechanical and dielectric properties |
title_sub | thermal, mechanical and dielectric properties |
topic | Diélectriques Physique de l'état solide Solides - Propriétés mécaniques Solides - Propriétés thermiques Dielectrics Solid state physics Solids Mechanical properties Solids Thermal properties Festkörperphysik (DE-588)4016921-2 gnd |
topic_facet | Diélectriques Physique de l'état solide Solides - Propriétés mécaniques Solides - Propriétés thermiques Dielectrics Solid state physics Solids Mechanical properties Solids Thermal properties Festkörperphysik |
url | http://deposit.dnb.de/cgi-bin/dokserv?id=2754961&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015429925&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
volume_link | (DE-604)BV000683335 |
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