Radiation-induced reaction mechanisms: interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2005
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Paralleltitel: Strahlungsinduzierte Reaktionsmechanismen |
| Beschreibung: | 113 S. graph. Darst. 30 cm |
Internformat
MARC
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| 245 | 1 | 0 | |a Radiation-induced reaction mechanisms |b interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer |c by Andrej Maroz |
| 264 | 1 | |c 2005 | |
| 300 | |a 113 S. |b graph. Darst. |c 30 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Paralleltitel: Strahlungsinduzierte Reaktionsmechanismen | ||
| 502 | |a Leipzig, Univ., Diss., 2005 | ||
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Datensatz im Suchindex
| _version_ | 1808225530661568512 |
|---|---|
| adam_text |
TABLE
OF
CONTENTS
1.
INTRODUCTION
.
1
1.1.
LIPID
PEROXIDATION
PROCESS
2
1.2.
FREE
RADICAL
FRAGMENTATION
4
1.3.
AROMATIC
AMINES:
ANTIOXIDANTS
AND
TOXINS
7
1.4.
RADIOLYTIC
INITIATION
OF
FREE
RADICAL
PROCESSES
8
1.5.
TASK
DEFINITION
9
2.
BASICS
OF
RADIATION
CHEMISTRY
.
10
2.1.
ABSORPTION
OF
IONIZING
RADIATION
10
2.2.
ABSORBED
DOSE
AND
RADIATION-CHEMICAL
YIELD
13
2.3.
REACTION
KINETICS
15
2.3.1.
HOMOGENEOUS
REACTION
KINETICS
16
2.3.1.
DIFFUSION-CONTROLLED
REACTIONS
17
2.4.
WATER
RADIOLYSIS
18
2.5.
RADIOLYSIS
OF
N-BUTYLCHLORIDE
20
3.
EXPERIMENTAL
METHODS
.
21
3.1.
PREPARATION
OF
SAMPLES
21
3.2.
STATIONARY
RADIOLYSIS
22
3.3.
ANALYSIS
OF
THE
PRODUCTS
BY
GAS-LIQUID
CHROMATOGRAPHY
22
3.4.
PULSE
RADIOLYSIS
23
3.5.
KINETIC
EVALUATION
25
UTILIZED
SUBSTANCES
26
4.
FREE-RADICAL
FRAGMENTATION
IN
DIOL
TEST
SYSTEMS
.
28
4.1.
DEVELOPMENT
OF
THE
MODEL
CHEMICAL
SYSTEM
28
4.2.
RADIOLYSIS
OF
WATER
SOLUTIONS
OF
ETHANOL
30
4.3.
RADIOLYSIS
OF
WATER
SOLUTIONS
OF
2,3-BUTANEDIOL
33
4.4.
RADIOLYSIS
OF
WATER
SOLUTIONS
OF
ETHYLENE
GLYCOL
36
4.5.
CONCLUSIONS
37
5.
TIME-RESOLVED
STUDY
OF
QUINONE
TRANSIENTS
.
38
5.1.
INTRODUCTION
3
8
5.2.
REACTIONS
IN
AQUEOUS
ALCOHOL
SOLUTIONS
42
5.3.
REACTIONS
IN
NON-POLAR
MEDIA
47
5.4.
OBSERVATION
OF
QUINONE
OXIDATION
52
5.5.
CONCLUSIONS
53
6.
PULSE
RADIOLYSIS
OF
ANILINE
AND
ITS
N-SUBSTITUTED
DERIVATIVES
.
55
6.1.
EXPERIMENTAL
RESULTS
56
6.1.1.
PULSE
RADIOLYSIS
OF
DIPHENYLAMINE
(DPA)
5
6
6.1.2.
PULSE
RADIOLYSIS
OF
ANILINE
(AN)
AND
N-METHYLANILINE
(MA)
59
6.1.3.
IONIZATION
OF
THE
TERTIARY
AMINES
TRIPHENYLAMINE
(TP
A)
AND
N,N-DIMETHYLANILINE
(DMA)
62
6.2.
DISCUSSION
65
6.2.1.
PRINCIPLES
OF
FREE
ELECTRON
TRANSFER
(FET)
65
6.2.2.
FET
INVOLVING
ANILINE
AND
SECONDARY
AROMATIC
AMINES
67
6.2.3.
SEMI-QUANTITATIVE
INTERPRETATION
OF
FET
INVOLVING
AROMATIC
AMINES
WITH
HELP
OF
DFT-CALUCLATIONS
70
6.2.4.
ENERGETICS
OF
THE
DEROTONATION
OF
THE
AMINE
RADICAL
CATIONS.
71
6.2.5.
ELECTRON
TRANSFER
FROM
TERTIARY
AROMATIC
AMINES
71
6.3.
CONCLUSIONS
73
7.
FET
WITH
CYCLIC
AROMATIC
AMINES
AS
ELECTRON
DONORS
.
75
7.1.
EXPERIMENTAL
RESULTS
76
7.1.1.
PULSE
RADIOLYSIS
OF
PHENOTHIAZINE
SOLUTIONS
76
7.1.2.
ACRIDANE
AS
AN
ELECTRON
DONOR
78
7.1.3.
PULSE
RADIOLYSIS
OF
CARBAZOLE
SAMPLES
80
7.2.
DISCUSSION
81
7.2.1.
IDENTIFICATION
OF
THE
AMINE
TRANSIENTS
81
7.2.2.
INTERPRETATION
OF
THE
ELECTRON
TRANSFER
INVOLVING
THE
CYCLIC
AMINES
83
7.2.3.
GEOMETRY,
ELECTRON
DISTRIBUTION
AND
DYNAMICS
-
DFT
CALCULATIONS
86
7.3.
CONCLUSIONS
87
8.
PULSE
RADIOLYSIS
OF
N-(ARYIMETHYL)-ANILME
DERIVATIVES
.
88
8.1.
EXPERIMENTAL
RESULTS
AND
DISCUSSION.
88
8.1.1.
PULSE
RADIOLYSIS
OF
N-BENZYLANILINE
(BPA)
SOLUTIONS
88
8.1.2.
PULSE
RADIOLYSIS
OFN-(DIPHENYLMETHYL)-ANILINE
(DPPA)
SOLUTIONS
92
8.1.3.
PULSE
RADIOLYSIS
OFN-TRITYLANILINE
(TRIPA) SOLUTIONS
94
8.1.4.
PULSE
RADIOLYSIS
OF
N-(2,2-DIMETHYL-L,L-DIPHENYLPROPYL)-ANILINE
(DPTBPA)
SOLUTIONS
96
8.2
CONCLUSIONS
97
9.
SUMMARY
.
99
LITERATURE
.
107 |
| adam_txt | |
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| author | Maroz, Andrej 1978- |
| author_GND | (DE-588)130613568 |
| author_facet | Maroz, Andrej 1978- |
| author_role | aut |
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| author_variant | a m am |
| building | Verbundindex |
| bvnumber | BV022203033 |
| ctrlnum | (OCoLC)181522327 (DE-599)BVBBV022203033 |
| dewey-full | 541.382 547.2 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry 547 - Organic chemistry |
| dewey-raw | 541.382 547.2 |
| dewey-search | 541.382 547.2 |
| dewey-sort | 3541.382 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| discipline_str_mv | Chemie / Pharmazie |
| format | Thesis Book |
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| index_date | 2024-07-02T16:24:35Z |
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| spelling | Maroz, Andrej 1978- Verfasser (DE-588)130613568 aut Radiation-induced reaction mechanisms interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer by Andrej Maroz 2005 113 S. graph. Darst. 30 cm txt rdacontent n rdamedia nc rdacarrier Paralleltitel: Strahlungsinduzierte Reaktionsmechanismen Leipzig, Univ., Diss., 2005 Radikal Chemie (DE-588)4076475-8 gnd rswk-swf Chinone (DE-588)4147707-8 gnd rswk-swf Phenole (DE-588)4045721-7 gnd rswk-swf Radiolyse (DE-588)4176835-8 gnd rswk-swf Bifunktionelle Verbindungen (DE-588)4298742-8 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Bifunktionelle Verbindungen (DE-588)4298742-8 s Radikal Chemie (DE-588)4076475-8 s Chinone (DE-588)4147707-8 s Radiolyse (DE-588)4176835-8 s DE-604 Phenole (DE-588)4045721-7 s b DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015414460&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Maroz, Andrej 1978- Radiation-induced reaction mechanisms interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer Radikal Chemie (DE-588)4076475-8 gnd Chinone (DE-588)4147707-8 gnd Phenole (DE-588)4045721-7 gnd Radiolyse (DE-588)4176835-8 gnd Bifunktionelle Verbindungen (DE-588)4298742-8 gnd |
| subject_GND | (DE-588)4076475-8 (DE-588)4147707-8 (DE-588)4045721-7 (DE-588)4176835-8 (DE-588)4298742-8 (DE-588)4113937-9 |
| title | Radiation-induced reaction mechanisms interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer |
| title_auth | Radiation-induced reaction mechanisms interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer |
| title_exact_search | Radiation-induced reaction mechanisms interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer |
| title_exact_search_txtP | Radiation-induced reaction mechanisms interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer |
| title_full | Radiation-induced reaction mechanisms interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer by Andrej Maroz |
| title_fullStr | Radiation-induced reaction mechanisms interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer by Andrej Maroz |
| title_full_unstemmed | Radiation-induced reaction mechanisms interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer by Andrej Maroz |
| title_short | Radiation-induced reaction mechanisms |
| title_sort | radiation induced reaction mechanisms interaction of organic radicals with quinones ionization of aromatic amines by free electron transfer |
| title_sub | interaction of organic radicals with quinones ; ionization of aromatic amines by free electron transfer |
| topic | Radikal Chemie (DE-588)4076475-8 gnd Chinone (DE-588)4147707-8 gnd Phenole (DE-588)4045721-7 gnd Radiolyse (DE-588)4176835-8 gnd Bifunktionelle Verbindungen (DE-588)4298742-8 gnd |
| topic_facet | Radikal Chemie Chinone Phenole Radiolyse Bifunktionelle Verbindungen Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015414460&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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