Handbook of industrial infrared analysis:
Gespeichert in:
1. Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
New York
Plenum Press
1964
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | 440 S. |
ISBN: | 0306301741 |
Internformat
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100 | 1 | |a White, Robert G. |e Verfasser |4 aut | |
245 | 1 | 0 | |a Handbook of industrial infrared analysis |c by Robert G. White |
264 | 1 | |a New York |b Plenum Press |c 1964 | |
300 | |a 440 S. | ||
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650 | 4 | |a Spectroscopie infrarouge | |
650 | 4 | |a Infrared spectroscopy | |
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adam_text | CONTENTS
Introduction................................. xiii
Chapter 1: History, Theory, and Terminology....... 1
1.1 Historical Development of IR Spectrometry........ 1
1.2 The Origin and Measurement of Infrared Absorption
Spectra.............................. 4
1.2.1 The Electromagnetic Spectrum.............. 4
1.2.2 Energy Associated with Spectra............. 6
1.2.3 Origin of Spectra....................... 7
1.2.4 Presentation of Spectra................... 10
1.3 Nomenclature and Symbols................... 12
Chapter 2: Instrumentation.................... 17
2.1 Spectrometers........................... 17
2.1.1 Introduction........................... 17
2.1.2 Baird-Atomic......................... 18
2.1.3 Beckman............................. 22
2.1.4 Hilger Watts......................... 27
2.1.5 Cary-White........................... 31
2.1.6 Unicam.............................. 35
2.1.7 Perkin-Elmer......................... 36
2.1.8 Other Foreign Spectrometers............... 40
2.1.9 Quartz NIR Spectrometers................. 41
2.1.10 Recent Spectrometer Literature............ 43
2.1.11 Design Considerations................... 44
2.1.11.1 Sources.......................... 45
2.1.11.2 Detectors......................... 46
2.1.11.3 Amplifiers and Recorders.............. 48
2.1.11.4 Dispersive Systems.................. 48
2.2 Wavelength Calibration...................... 49
2.3 Spectrometer Performance Evaluation........... 57
2.4 Photometric Calibration..................... 69
2.5 The Laboratory........................... 71
vii
viii CONTENTS
Chapter 3: Techniques........................ 73
3.1 Gas Sampling............................ 73
3.2 Liquid Sampling.......................... 80
3.2.1 Absorption Cells....................... 80
3.2.1.1 General Discussion................... 80
3.2.1.2 Window Materials.................... 81
3.2.1.3 Makers orVendors of Cells and Cell Components. 84
3.2.1.4 Some Special Purpose Cells............. 85
3.2.1.5 Variable-Path Cells................... 87
3.2.1.6 Low-Temperature Cells................ 88
3.2.1.7 Heated Cells........................ 89
3.2.1.8 Cells for Aqueous Solutions.............. 90
3.2.1.9 Construction and Repair of Cells.......... 92
3.2.1.9.1 Cleaving Salt..................... 93
3.2.1.9.2 Grinding Salt..................... 94
3.2.1.9.3 Polishing....................... 95
3.2.1.9.4 Drilling Salt Plates................. 98
3.2.1.9.5 Assembly and Disassembly........... 98
3.2.1.9.6 Measurement of Cell Thickness........ 99
3.2.2 Solvents............................. 102
3.2.2.1 Tabulation of Data.................... 102
3.2.2.2 Discussion......................... 108
3.2.3 Solution Preparation..................... Ill
3.2.4 Handling Absorption Cells................. 113
3.3 Solid Sampling........................... 116
3.3.1 Pressed Discs......................... 116
3.3.1.1 General........................... 116
3.3.1.2 Some Qualitative Applications............ 121
3.3.1.3 Some Quantitative Applications........... 121
3.3.1.4 Pretreatment of Alkali Halides........... 124
3.3.1.5 Effects of Grinding................... 125
3.3.1.6 Dies............................. 127
3.3.1.7 Presses, Pressing Techniques............ 129
3.3.1.8 Pellet Holders...................... 130
3.3.1.9 Micropellets........................ 132
3.3.1.10 Anomalous Spectra................... 135
3.3.1.11 Matrices Other Than Halides............ 138
3.3.2 Mull Techniques........................ 139
3.3.2.1 Mineral Oil Mulls.................... 139
3.3.2.2 Other Mulling Liquids................. 141
3.3.3 Other Solid-Phase Sampling Methods.......... 141
3.3.3.1 The Powder Method................... 141
CONTENTS ix
3.3.3.2 Suspensions........................ 142
3.3.3.3 Fused Salts........................ 143
3.3.3.4 Films............................ 143
3.3.3.5 Cast Films......................... 143
3.3.3.6 Lamination and Impregnation............. 144
3.3.3.7 Sublimation........................ 144
3.3.3.8 Pyrolysis.......................... 144
3.4 Microtechniques.......................... 145
3.4.1 Introduction........................... 145
3.4.2 Microcells........................... 146
3.4.3 Scale Expansion........................ 149
3.4.4 Beam Condensers....................... 151
3.4.5 Sampling Gas Chromatograph Effluents........ 151
3.4.6 Manipulation of Microsamples.............. 153
3.5 Reflectance Measurements................... 154
3.5.1 Diffuse and Specular Reflectance............. 154
3.5.2 Attenuated Total Reflectance............... 156
3.6 Beam Attenuators......................... 159
3.7 Matrix Isolation.......................... 160
3.8 Polarized Radiation........................ 161
3.9 NIR Techniques........................... 162
3.9.1 Sample Preparation..................... 162
3.9.2 Absorption Cells....................... 163
3.9.3 Solvents for the NIR..................... 164
3.9.3.1 Tabular Data....................... 164
3.9.3.2 Discussion......................... 166
3.10 Far IR Techniques........................ 168
3.11 Derivative Spectroscopy.................... 170
3.12 Miscellaneous Accessories.................. 172
3.12.1 Chart Paper.......................... 172
3.12.2 Recorder Pens and Inks.................. 172
3.12.3 Purging the Spectrometer................. 172
3.12.4 External Source....................... 173
3.12.5 External Detector...................... 173
Chapter 4: Qualitative Analysis................. 175
4.1 Spectra-Structure Correlation................. 175
General Discussion.......................... 175
Table 4.1.1 C—H Stretching Vibrations............ 190
Table 4.1.2 C—H Deformation and Skeletal Vibrations . . 192
Table 4.1.3 C-C, C=C, and C=C Vibrations........ 195
Table 4.1.4 N—H Stretching Vibrations............ 197
x CONTENTS
Table 4.1.5 N—H Deformation Vibrations........... 198
Table 4.1.6 Some Charged Amine Vibrations......... 198
Table 4.1.7 Vibrations Involving Nitrogen and Oxygen. . . 199
Table 4.1.8 Miscellaneous Vibrations Involving Nitrogen. 201
Table 4.1.9 C-0 Stretching and Related Vibrations .... 202
Table 4.1.10 C=O Stretching Vibrations............ 204
Table 4.1.11 OH Stretching Vibrations............. 208
Table 4.1.12 Vibrations Involving Phosphorus........ 210
Table 4.1.13 Vibrations Involving Sulfur............ 211
Table 4.1.14 Vibrations Involving Silicon........... 212
Table 4.1.15 Vibrations Involving Halogens.......... 213
Table 4.1.16 Some Organic Vibrations of Boron....... 213
Table 4.1.17 Some Inorganic Vibrations............ 214
Table 4.1.18 Nonstandard Abbreviations Used in Spectra-
Structure Correlation Tables............... 216
Artifacts................................. 216
Examples................................ 221
4.2 Data Storage and Retrieval................... 224
Sadtler Catalog............................ 224
DMS System.............................. 234
IRDC Cards............................... 235
Wyandotte-ASTM Punched Card Index............. 235
ASTM Infrared Optical Coincidence Index........... 236
Chapter 5: Quantitative Analysis................ 241
5.1 One Component........................... 241
5.1.1 The Laws of Absorption................... 241
5.1.2 One Component, No Irrelevant Absorption....... 245
5.1.3 One Component, Basing Point Correction....... 247
5.1.4 Baseline Method........................ 248
5.2 Multicomponent Analysis.................... 249
5.3 Differential Analysis....................... 255
5.4 Kinetic Studies........................... 266
5.5 Hydrogen Bonding......................... 267
5.6 Temperature Effect........................ 268
5.7 Finite Slit Width.......................... 269
5.8 Effect of Stray Light....................... 272
5.9 Reproducibility........................... 273
Chapter 6: Applications....................... 277
6.1 Acids (Mineral)........................... 277
6.2 Acids (Carboxylic)......................... 277
6.3 Adsorbed Phases.......................... 279
CONTENTS xi
6.4 Air Analysis............................. 279
6.5 Alcohols............................... 280
6.6 Aldehydes.............................. 281
6.7 Amides................................ 282
6.8 Amines................................ 283
6.9 Boron Compounds......................... 285
6.10 Bromine Compounds....................... 285
6.11 Carbohydrates........................... 286
6.12 Carbonyl Compounds...................... 286
6.13 Chlorine Compounds (Organic)................ 287
6.14 Coatings............................... 289
6.15 Cosmetics............................. 290
6.16 Detergents............................. 290
6.17 Dyes, Dye Intermediates, and Pigments.......... 291
6.18 Essential Oils........................... 293
6.19 Esters................................ 295
6.20 Ethers................................ 296
6.21 Fats and Oils........................... 297
6.22 Fluoroorganics.......................... 301
6.23 Foods................................ 301
6.24 Gas Analysis............................ 302
6.25 Hydrocarbons, Aromatic (Monocyclic)........... 304
6.26 Hydrocarbons, Nonaromatic.................. 306
6.27 Hydrocarbons, Polynuclear.................. 308
6.28 Hydroxyl.............................. 309
6.29 Inorganic Compounds...................... 310
6.30 Iodine and Iodine Compounds................. 314
6.31 Ketones............................... 315
6.32 Lactams and Lactones..................... 316
6.33 Metal Organics.......................... 316
6.34 Miscellaneous........................... 317
6.35 Nitrates, Nitro and Nitroso Compounds, and Related
Substances............................ 317
6.36 Nitriles and Related Compounds............... 319
6.37 Nitrogen............................... 320
6.38 Nitrogen Compounds (Polycyclic).............. 320
6.39 Oximes............................... 321
6.40 Oxirane Compounds....................... 321
6.41 Paper and Wood.......................... 321
6.42 Peroxides and Hydroperoxides................ 322
6.43 Pesticides............................. 322
6.44 Petroleum Products....................... 326
xii CONTENTS
6.45 Pharmaceuticals......................... 327
6.46 Phenols............................... 332
6.47 Phosphoro-Organics....................... 334
6.48 Plastics............................... 335
6.49 Polymorphism........................... 339
6.50 Polyurethanes........................... 340
6.51 Pyridine, Quinoline, and Related Compounds....... 340
6.52 Rubber and Other Elastomers................ 341
6.53 Quinones.............................. 343
6.54 Silicones.............................. 343
6.55 Sulfur Compounds........................ 344
6.56 Terpenes.............................. 345
6.57 Textiles............................... 345
6.58 Thickness Measurement.................... 346
6.59 Tobacco............................... 347
6.60 Water................................ 347
Chapter 7: Literature........................ 351
7.1 Books................................. 351
7.2 Spectrum Atlases......................... 354
7.3 Bibliographies........................... 356
7.4 Review Papers........................... 357
7.5 Journals............................... 359
References.................................. 361
Appendix I: Table of Reciprocals................... 405
Appendix II: Conversion from Percent Transmittance to
Absorbance........................... 413
Index...................................... 421
|
adam_txt |
CONTENTS
Introduction. xiii
Chapter 1: History, Theory, and Terminology. 1
1.1 Historical Development of IR Spectrometry. 1
1.2 The Origin and Measurement of Infrared Absorption
Spectra. 4
1.2.1 The Electromagnetic Spectrum. 4
1.2.2 Energy Associated with Spectra. 6
1.2.3 Origin of Spectra. 7
1.2.4 Presentation of Spectra. 10
1.3 Nomenclature and Symbols. 12
Chapter 2: Instrumentation. 17
2.1 Spectrometers. 17
2.1.1 Introduction. 17
2.1.2 Baird-Atomic. 18
2.1.3 Beckman. 22
2.1.4 Hilger Watts. 27
2.1.5 Cary-White. 31
2.1.6 Unicam. 35
2.1.7 Perkin-Elmer. 36
2.1.8 Other Foreign Spectrometers. 40
2.1.9 Quartz NIR Spectrometers. 41
2.1.10 Recent Spectrometer Literature. 43
2.1.11 Design Considerations. 44
2.1.11.1 Sources. 45
2.1.11.2 Detectors. 46
2.1.11.3 Amplifiers and Recorders. 48
2.1.11.4 Dispersive Systems. 48
2.2 Wavelength Calibration. 49
2.3 Spectrometer Performance Evaluation. 57
2.4 Photometric Calibration. 69
2.5 The Laboratory. 71
vii
viii CONTENTS
Chapter 3: Techniques. 73
3.1 Gas Sampling. 73
3.2 Liquid Sampling. 80
3.2.1 Absorption Cells. 80
3.2.1.1 General Discussion. 80
3.2.1.2 Window Materials. 81
3.2.1.3 Makers orVendors of Cells and Cell Components. 84
3.2.1.4 Some Special Purpose Cells. 85
3.2.1.5 Variable-Path Cells. 87
3.2.1.6 Low-Temperature Cells. 88
3.2.1.7 Heated Cells. 89
3.2.1.8 Cells for Aqueous Solutions. 90
3.2.1.9 Construction and Repair of Cells. 92
3.2.1.9.1 Cleaving Salt. 93
3.2.1.9.2 Grinding Salt. 94
3.2.1.9.3 Polishing. 95
3.2.1.9.4 Drilling Salt Plates. 98
3.2.1.9.5 Assembly and Disassembly. 98
3.2.1.9.6 Measurement of Cell Thickness. 99
3.2.2 Solvents. 102
3.2.2.1 Tabulation of Data. 102
3.2.2.2 Discussion. 108
3.2.3 Solution Preparation. Ill
3.2.4 Handling Absorption Cells. 113
3.3 Solid Sampling. 116
3.3.1 Pressed Discs. 116
3.3.1.1 General. 116
3.3.1.2 Some Qualitative Applications. 121
3.3.1.3 Some Quantitative Applications. 121
3.3.1.4 Pretreatment of Alkali Halides. 124
3.3.1.5 Effects of Grinding. 125
3.3.1.6 Dies. 127
3.3.1.7 Presses, Pressing Techniques. 129
3.3.1.8 Pellet Holders. 130
3.3.1.9 Micropellets. 132
3.3.1.10 Anomalous Spectra. 135
3.3.1.11 Matrices Other Than Halides. 138
3.3.2 Mull Techniques. 139
3.3.2.1 Mineral Oil Mulls. 139
3.3.2.2 Other Mulling Liquids. 141
3.3.3 Other Solid-Phase Sampling Methods. 141
3.3.3.1 The Powder Method. 141
CONTENTS ix
3.3.3.2 Suspensions. 142
3.3.3.3 Fused Salts. 143
3.3.3.4 Films. 143
3.3.3.5 Cast Films. 143
3.3.3.6 Lamination and Impregnation. 144
3.3.3.7 Sublimation. 144
3.3.3.8 Pyrolysis. 144
3.4 Microtechniques. 145
3.4.1 Introduction. 145
3.4.2 Microcells. 146
3.4.3 Scale Expansion. 149
3.4.4 Beam Condensers. 151
3.4.5 Sampling Gas Chromatograph Effluents. 151
3.4.6 Manipulation of Microsamples. 153
3.5 Reflectance Measurements. 154
3.5.1 Diffuse and Specular Reflectance. 154
3.5.2 Attenuated Total Reflectance. 156
3.6 Beam Attenuators. 159
3.7 Matrix Isolation. 160
3.8 Polarized Radiation. 161
3.9 NIR Techniques. 162
3.9.1 Sample Preparation. 162
3.9.2 Absorption Cells. 163
3.9.3 Solvents for the NIR. 164
3.9.3.1 Tabular Data. 164
3.9.3.2 Discussion. 166
3.10 Far IR Techniques. 168
3.11 Derivative Spectroscopy. 170
3.12 Miscellaneous Accessories. 172
3.12.1 Chart Paper. 172
3.12.2 Recorder Pens and Inks. 172
3.12.3 Purging the Spectrometer. 172
3.12.4 External Source. 173
3.12.5 External Detector. 173
Chapter 4: Qualitative Analysis. 175
4.1 Spectra-Structure Correlation. 175
General Discussion. 175
Table 4.1.1 C—H Stretching Vibrations. 190
Table 4.1.2 C—H Deformation and Skeletal Vibrations . . 192
Table 4.1.3 C-C, C=C, and C=C Vibrations. 195
Table 4.1.4 N—H Stretching Vibrations. 197
x CONTENTS
Table 4.1.5 N—H Deformation Vibrations. 198
Table 4.1.6 Some Charged Amine Vibrations. 198
Table 4.1.7 Vibrations Involving Nitrogen and Oxygen. . . 199
Table 4.1.8 Miscellaneous Vibrations Involving Nitrogen. 201
Table 4.1.9 C-0 Stretching and Related Vibrations . 202
Table 4.1.10 C=O Stretching Vibrations. 204
Table 4.1.11 OH Stretching Vibrations. 208
Table 4.1.12 Vibrations Involving Phosphorus. 210
Table 4.1.13 Vibrations Involving Sulfur. 211
Table 4.1.14 Vibrations Involving Silicon. 212
Table 4.1.15 Vibrations Involving Halogens. 213
Table 4.1.16 Some Organic Vibrations of Boron. 213
Table 4.1.17 Some Inorganic Vibrations. 214
Table 4.1.18 Nonstandard Abbreviations Used in Spectra-
Structure Correlation Tables. 216
Artifacts. 216
Examples. 221
4.2 Data Storage and Retrieval. 224
Sadtler Catalog. 224
DMS System. 234
IRDC Cards. 235
Wyandotte-ASTM Punched Card Index. 235
ASTM Infrared Optical Coincidence Index. 236
Chapter 5: Quantitative Analysis. 241
5.1 One Component. 241
5.1.1 The Laws of Absorption. 241
5.1.2 One Component, No Irrelevant Absorption. 245
5.1.3 One Component, Basing Point Correction. 247
5.1.4 Baseline Method. 248
5.2 Multicomponent Analysis. 249
5.3 Differential Analysis. 255
5.4 Kinetic Studies. 266
5.5 Hydrogen Bonding. 267
5.6 Temperature Effect. 268
5.7 Finite Slit Width. 269
5.8 Effect of Stray Light. 272
5.9 Reproducibility. 273
Chapter 6: Applications. 277
6.1 Acids (Mineral). 277
6.2 Acids (Carboxylic). 277
6.3 Adsorbed Phases. 279
CONTENTS xi
6.4 Air Analysis. 279
6.5 Alcohols. 280
6.6 Aldehydes. 281
6.7 Amides. 282
6.8 Amines. 283
6.9 Boron Compounds. 285
6.10 Bromine Compounds. 285
6.11 Carbohydrates. 286
6.12 Carbonyl Compounds. 286
6.13 Chlorine Compounds (Organic). 287
6.14 Coatings. 289
6.15 Cosmetics. 290
6.16 Detergents. 290
6.17 Dyes, Dye Intermediates, and Pigments. 291
6.18 Essential Oils. 293
6.19 Esters. 295
6.20 Ethers. 296
6.21 Fats and Oils. 297
6.22 Fluoroorganics. 301
6.23 Foods. 301
6.24 Gas Analysis. 302
6.25 Hydrocarbons, Aromatic (Monocyclic). 304
6.26 Hydrocarbons, Nonaromatic. 306
6.27 Hydrocarbons, Polynuclear. 308
6.28 Hydroxyl. 309
6.29 Inorganic Compounds. 310
6.30 Iodine and Iodine Compounds. 314
6.31 Ketones. 315
6.32 Lactams and Lactones. 316
6.33 Metal Organics. 316
6.34 Miscellaneous. 317
6.35 Nitrates, Nitro and Nitroso Compounds, and Related
Substances. 317
6.36 Nitriles and Related Compounds. 319
6.37 Nitrogen. 320
6.38 Nitrogen Compounds (Polycyclic). 320
6.39 Oximes. 321
6.40 Oxirane Compounds. 321
6.41 Paper and Wood. 321
6.42 Peroxides and Hydroperoxides. 322
6.43 Pesticides. 322
6.44 Petroleum Products. 326
xii CONTENTS
6.45 Pharmaceuticals. 327
6.46 Phenols. 332
6.47 Phosphoro-Organics. 334
6.48 Plastics. 335
6.49 Polymorphism. 339
6.50 Polyurethanes. 340
6.51 Pyridine, Quinoline, and Related Compounds. 340
6.52 Rubber and Other Elastomers. 341
6.53 Quinones. 343
6.54 Silicones. 343
6.55 Sulfur Compounds. 344
6.56 Terpenes. 345
6.57 Textiles. 345
6.58 Thickness Measurement. 346
6.59 Tobacco. 347
6.60 Water. 347
Chapter 7: Literature. 351
7.1 Books. 351
7.2 Spectrum Atlases. 354
7.3 Bibliographies. 356
7.4 Review Papers. 357
7.5 Journals. 359
References. 361
Appendix I: Table of Reciprocals. 405
Appendix II: Conversion from Percent Transmittance to
Absorbance. 413
Index. 421 |
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author | White, Robert G. |
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discipline_str_mv | Chemie / Pharmazie |
format | Book |
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id | DE-604.BV021994251 |
illustrated | Not Illustrated |
index_date | 2024-07-02T16:10:45Z |
indexdate | 2024-07-09T20:48:57Z |
institution | BVB |
isbn | 0306301741 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-015208964 |
oclc_num | 2330101 |
open_access_boolean | |
owner | DE-706 DE-83 DE-11 DE-210 |
owner_facet | DE-706 DE-83 DE-11 DE-210 |
physical | 440 S. |
psigel | TUB-nveb |
publishDate | 1964 |
publishDateSearch | 1964 |
publishDateSort | 1964 |
publisher | Plenum Press |
record_format | marc |
spelling | White, Robert G. Verfasser aut Handbook of industrial infrared analysis by Robert G. White New York Plenum Press 1964 440 S. txt rdacontent n rdamedia nc rdacarrier Spectroscopie infrarouge Infrared spectroscopy Infrarotspektroskopie (DE-588)4135411-4 gnd rswk-swf Infrarotspektroskopie (DE-588)4135411-4 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015208964&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | White, Robert G. Handbook of industrial infrared analysis Spectroscopie infrarouge Infrared spectroscopy Infrarotspektroskopie (DE-588)4135411-4 gnd |
subject_GND | (DE-588)4135411-4 |
title | Handbook of industrial infrared analysis |
title_auth | Handbook of industrial infrared analysis |
title_exact_search | Handbook of industrial infrared analysis |
title_exact_search_txtP | Handbook of industrial infrared analysis |
title_full | Handbook of industrial infrared analysis by Robert G. White |
title_fullStr | Handbook of industrial infrared analysis by Robert G. White |
title_full_unstemmed | Handbook of industrial infrared analysis by Robert G. White |
title_short | Handbook of industrial infrared analysis |
title_sort | handbook of industrial infrared analysis |
topic | Spectroscopie infrarouge Infrared spectroscopy Infrarotspektroskopie (DE-588)4135411-4 gnd |
topic_facet | Spectroscopie infrarouge Infrared spectroscopy Infrarotspektroskopie |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=015208964&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT whiterobertg handbookofindustrialinfraredanalysis |