Inorganic structural chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English German |
| Veröffentlicht: |
Chichester
Wiley
2007
|
| Ausgabe: | 2. ed. |
| Schriftenreihe: | Inorganic chemistry
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 268 S. Ill., graph. Darst. |
| ISBN: | 9780470018644 9780470018651 047001864X 0470018658 |
Internformat
MARC
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| 100 | 1 | |a Müller, Ulrich |d 1940- |e Verfasser |0 (DE-588)130176184 |4 aut | |
| 240 | 1 | 0 | |a Anorganische Strukturchemie |
| 245 | 1 | 0 | |a Inorganic structural chemistry |c Ulrich Müller |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Chichester |b Wiley |c 2007 | |
| 300 | |a X, 268 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Inorganic chemistry | |
| 650 | 4 | |a Chemistry, Inorganic | |
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| 650 | 0 | 7 | |a Anorganischer Stoff |0 (DE-588)4142569-8 |2 gnd |9 rswk-swf |
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Datensatz im Suchindex
| _version_ | 1804135558149046272 |
|---|---|
| adam_text | Contents
Preface
................................................
x¡
1
Introduction
............................................. 1
2
Description
of
Chemical Structures
................................ 2
2.1
Coordination
Numbers and
Coordination Polyhedra
...................... 3
2.2
Description
of Crystal
Structures
................................ 7
2.3
Atomic Coordinates
....................................... 9
2.4
Isotypism
............................................ 10
2.5
Problems
............................................ 11
3
Symmetry
.............................................. 12
3.1
Symmetry Operations and Symmetry Elements
........................ 12
3.2
Point Groups
.......................................... 15
3.3
Space Groups and Space-Group Types
............................. 20
3.4
Positions
............................................. 22
3.5
Crystal Classes and Crystal Systems
.............................. 24
3.6
Aperiodic Crystals
....................................... 25
3.7
Disordered Crystals
....................................... 27
3.8
Problems
............................................ 28
4
Polymorphism and Phase Transitions
............................... 30
4.1
Thermodynamic Stability
.................................... 30
4.2
Kinetic Stability
......................................... 30
4.3
Polymorphism
.......................................... 31
4.4
Phase Transitions
........................................ 32
4.5
Phase Diagrams
......................................... 34
4.6
Probiems
............................................ 38
5
Chemical Bonding and Lattice Energy
.............................. 39
5.1
Chemical Bonding and Structure
................................ 39
5.2
Lattice Energy
.......................................... 40
5.3
Problems
............................................ 44
6
The Effective Size of Atoms
.................................... 45
6.1
Van
der Waals
Radii
....................................... 46
6.2
Atomic Radii in Metals
..................................... 46
6.3
Covalent Radii
......................................... 47
6.4
Ionic Radii
........................................... 48
6.5
Problems
............................................ 51
Vlil
7
Ionic Compounds
.......................................... 52
7.1
Radius Ratios
.......................................... 52
7.2
Ternary Ionic Compounds
................................... 55
7.3
Compounds with Complex Ions
................................ 56
7.4
The Rules of Pauling and Baur
................................. 58
7.5
Problem*
............................................ 61
8
Molecular Structures I: Compounds of Main Group Elements
................. 62
8.1
Valence Shell Electron-Pair Repulsion
............................. 62
8.2
Structures with Five Valence Electron Pairs
.......................... 71
8.3
Problems
............................................ 72
9
Molecular Structures II: Compounds of Transition Metals
................... 73
9.1
Ligand Field Theory
...................................... 73
9.2
Ligand Field Stabilization Energy
............................... 77
9.3
Coordination Polyhedra for Transition Metals
......................... 80
9.4
Isomerism
............................................ 81
9.5
Problems
............................................ 84
10
Molecular Orbital Theory and Chemical Bonding in Solids
................... 85
10.1
Molecular
Orbitals....................................... 85
10.2
Hybridization
.......................................... 87
10.3
The Electron Localization Function
.............................. 89
10.4
Band Theory. The Linear Chain of Hydrogen Atoms
..................... 90
10.5
The Peierls Distortion
...................................... 93
10.6
Crystal Orbital Overlap Population (COOP)
.......................... 96
10.7
Bonds in Two and Three Dimensions
.............................. 99
10.8
Bonding in Metals
........................................ 101
10.9
Problems
............................................ 102
11
The Element Structures of the Nonmetals
............................. 103
11.1
Hydrogen and the Halogens
. . ................................. 103
1
1.2
Chalcogens
........................................... 105
11.3
Elements of the Fifth Main Group
............................... 107
11.4
Elements of the Fifth and Sixth Main Groups under Pressure
.................
Ill
11.5
Carbon
.............................................. 113
11.6
Boron
.............................................. 116
12
Diamond-like Structures
...................................... 118
12.1
Cubic and Hexagonal Diamond
................................. 118
12.2
Binary Diamond-like Compounds
............................... 118
12.3
Diamond-like Compounds under Pressure
........................... 120
12.4
Polynary Diamond-like Compounds
.............................. 123
12.5
Widened Diamond Lattices. SiO2 Structures
.......................... 124
12.6
Problems
............................................ 127
13
Polyanionic and Polycationic Compounds. ZintI Phases
..................... 128
13.1
The Generalized
8
-Ν
Rule
.................................. 128
13.2
Polyanionic Compounds, Zintl Phases
............................. 130
13.3
Polycationic Compounds
....................................
]37
13.4
Cluster Compounds
....................................... 138
13.5
Problems
............................................ 149
14
Packings of Spheres. Metal Structures
.............................. 150
14.1
Closest-packings of Spheres
..................................
J50
14.2
Body-centered Cubic Packing of Spheres
........................... 153
14.3
Other Metal Structures
..................................... 154
14.4
Problems
............................................ 155
15
The Sphere-packing Principle for Compounds
.......................... 157
15.1
Ordered and Disordered Alloys
................................. 157
15.2
Compounds with Close-packed Atoms
............................. 158
15.3
Structures Derived of Body-centered Cubic Packing (CsCl Type)
............... 160
15.4
Hume-Rothery Phases
..................................... 161
15.5
Laves Phases
.......:.................................. 162
15.6
Problems
............................................ 165
16
Linked Polyhedra
.......................................... 166
16.1
Vertex-sharing Octahedra
.................................... 168
16.2
Edge-sharing Octahedra
..................................... 173
16.3
Face-sharing Octahedra
..................................... 175
16.4
Octahedra Sharing Vertices and Edges
............................. 176
16.5
Octahedra Sharing Edges and Faces
............................... 179
16.6
Linked Trigonal Prisms
..................................... 180
16.7
Vertex-sharing Tetrahedra. Silicates
. . ............................ 180
16.8
Edge-sharing Tetrahedra
.................................... 188
16.9
Problems
............................................ 189
17
Packings of Spheres with Occupied Interstices
.......................... 190
17.1
The Interstices in Closest-packings of Spheres
......................... 190
17.2
Interstitial Compounds
..................................... 194
17.3
Structure Types with Occupied Octahedral Interstices in Closest-packings of Spheres
.... 195
17.4
Perovskites
. .......................................... 202
17.5
Occupation of Tetrahedral Interstices in Closest-packings of Spheres
............. 206
17.6
Spinels
.............................................. 208
17.7
Problems
............................................ 21)
18
Symmetry as the Organizing Principle for Crystal Structures
................. 212
18.1
Crystallographic Group-Subgroup Relations
.......................... 212
18.2
The Symmetry Principle in Crystal Chemistry
......................... 214
18.3
Structural Relationships by Group-Subgroup Relations
.................... 215
18.4
Symmetry Relations at Phase Transitions. Twinned Crystals
................. 221
18.5
Problems
. ........................................... 225
19
Physical Properties of Solids
.................................... 226
19.1
Mechanical Properties
. .................................... 226
19.2
Piezoelectric and Ferroelectric Properties
........................... 227
19.3
Magnetic Properties
....................................... 231
20
Nanostructures
........................................... 241
21
Pitfalls and Linguistic Aberrations
................................ 246
References
................................................ 249
Answers to the Problems
........................................ 256
Index
................................................... 259
|
| adam_txt |
Contents
Preface
.
x¡
1
Introduction
. 1
2
Description
of
Chemical Structures
. 2
2.1
Coordination
Numbers and
Coordination Polyhedra
. 3
2.2
Description
of Crystal
Structures
. 7
2.3
Atomic Coordinates
. 9
2.4
Isotypism
. 10
2.5
Problems
. 11
3
Symmetry
. 12
3.1
Symmetry Operations and Symmetry Elements
. 12
3.2
Point Groups
. 15
3.3
Space Groups and Space-Group Types
. 20
3.4
Positions
. 22
3.5
Crystal Classes and Crystal Systems
. 24
3.6
Aperiodic Crystals
. 25
3.7
Disordered Crystals
. 27
3.8
Problems
. 28
4
Polymorphism and Phase Transitions
. 30
4.1
Thermodynamic Stability
. 30
4.2
Kinetic Stability
. 30
4.3
Polymorphism
. 31
4.4
Phase Transitions
. 32
4.5
Phase Diagrams
. 34
4.6
Probiems
. 38
5
Chemical Bonding and Lattice Energy
. 39
5.1
Chemical Bonding and Structure
. 39
5.2
Lattice Energy
. 40
5.3
Problems
. 44
6
The Effective Size of Atoms
. 45
6.1
Van
der Waals
Radii
. 46
6.2
Atomic Radii in Metals
. 46
6.3
Covalent Radii
. 47
6.4
Ionic Radii
. 48
6.5
Problems
. 51
Vlil
7
Ionic Compounds
. 52
7.1
Radius Ratios
. 52
7.2
Ternary Ionic Compounds
. 55
7.3
Compounds with Complex Ions
. 56
7.4
The Rules of Pauling and Baur
. 58
7.5
Problem*
. 61
8
Molecular Structures I: Compounds of Main Group Elements
. 62
8.1
Valence Shell Electron-Pair Repulsion
. 62
8.2
Structures with Five Valence Electron Pairs
. 71
8.3
Problems
. 72
9
Molecular Structures II: Compounds of Transition Metals
. 73
9.1
Ligand Field Theory
. 73
9.2
Ligand Field Stabilization Energy
. 77
9.3
Coordination Polyhedra for Transition Metals
. 80
9.4
Isomerism
. 81
9.5
Problems
. 84
10
Molecular Orbital Theory and Chemical Bonding in Solids
. 85
10.1
Molecular
Orbitals. 85
10.2
Hybridization
. 87
10.3
The Electron Localization Function
. 89
10.4
Band Theory. The Linear Chain of Hydrogen Atoms
. 90
10.5
The Peierls Distortion
. 93
10.6
Crystal Orbital Overlap Population (COOP)
. 96
10.7
Bonds in Two and Three Dimensions
. 99
10.8
Bonding in Metals
. 101
10.9
Problems
. 102
11
The Element Structures of the Nonmetals
. 103
11.1
Hydrogen and the Halogens
. . . 103
1
1.2
Chalcogens
. 105
11.3
Elements of the Fifth Main Group
. 107
11.4
Elements of the Fifth and Sixth Main Groups under Pressure
.
Ill
11.5
Carbon
. 113
11.6
Boron
. 116
12
Diamond-like Structures
. 118
12.1
Cubic and Hexagonal Diamond
. 118
12.2
Binary Diamond-like Compounds
. 118
12.3
Diamond-like Compounds under Pressure
. 120
12.4
Polynary Diamond-like Compounds
. 123
12.5
Widened Diamond Lattices. SiO2 Structures
. 124
12.6
Problems
. 127
13
Polyanionic and Polycationic Compounds. ZintI Phases
. 128
13.1
The Generalized
8
-Ν
Rule
. 128
13.2
Polyanionic Compounds, Zintl Phases
. 130
13.3
Polycationic Compounds
.
]37
13.4
Cluster Compounds
. 138
13.5
Problems
. 149
14
Packings of Spheres. Metal Structures
. 150
14.1
Closest-packings of Spheres
.
J50
14.2
Body-centered Cubic Packing of Spheres
. 153
14.3
Other Metal Structures
. 154
14.4
Problems
. 155
15
The Sphere-packing Principle for Compounds
. 157
15.1
Ordered and Disordered Alloys
. 157
15.2
Compounds with Close-packed Atoms
. 158
15.3
Structures Derived of Body-centered Cubic Packing (CsCl Type)
. 160
15.4
Hume-Rothery Phases
. 161
15.5
Laves Phases
.:. 162
15.6
Problems
. 165
16
Linked Polyhedra
. 166
16.1
Vertex-sharing Octahedra
. 168
16.2
Edge-sharing Octahedra
. 173
16.3
Face-sharing Octahedra
. 175
16.4
Octahedra Sharing Vertices and Edges
. 176
16.5
Octahedra Sharing Edges and Faces
. 179
16.6
Linked Trigonal Prisms
. 180
16.7
Vertex-sharing Tetrahedra. Silicates
. . . 180
16.8
Edge-sharing Tetrahedra
. 188
16.9
Problems
. 189
17
Packings of Spheres with Occupied Interstices
. 190
17.1
The Interstices in Closest-packings of Spheres
. 190
17.2
Interstitial Compounds
. 194
17.3
Structure Types with Occupied Octahedral Interstices in Closest-packings of Spheres
. 195
17.4
Perovskites
.". 202
17.5
Occupation of Tetrahedral Interstices in Closest-packings of Spheres
. 206
17.6
Spinels
. 208
17.7
Problems
. 21)
18
Symmetry as the Organizing Principle for Crystal Structures
. 212
18.1
Crystallographic Group-Subgroup Relations
. 212
18.2
The Symmetry Principle in Crystal Chemistry
. 214
18.3
Structural Relationships by Group-Subgroup Relations
. 215
18.4
Symmetry Relations at Phase Transitions. Twinned Crystals
. 221
18.5
Problems
. . 225
19
Physical Properties of Solids
. 226
19.1
Mechanical Properties
. . 226
19.2
Piezoelectric and Ferroelectric Properties
. 227
19.3
Magnetic Properties
. 231
20
Nanostructures
. 241
21
Pitfalls and Linguistic Aberrations
. 246
References
. 249
Answers to the Problems
. 256
Index
. 259 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Müller, Ulrich 1940- |
| author_GND | (DE-588)130176184 |
| author_facet | Müller, Ulrich 1940- |
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| author_sort | Müller, Ulrich 1940- |
| author_variant | u m um |
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| callnumber-sort | QD 3151.3 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VH 5800 VH 5801 |
| classification_tum | CHE 312f |
| ctrlnum | (OCoLC)70230778 (DE-599)BVBBV021717944 |
| dewey-full | 541.2 546 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry 546 - Inorganic chemistry |
| dewey-raw | 541.2 546 |
| dewey-search | 541.2 546 |
| dewey-sort | 3541.2 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| discipline_str_mv | Chemie / Pharmazie Chemie |
| edition | 2. ed. |
| format | Book |
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| genre | 1\p (DE-588)4006432-3 Bibliografie gnd-content 2\p (DE-588)4123623-3 Lehrbuch gnd-content |
| genre_facet | Bibliografie Lehrbuch |
| id | DE-604.BV021717944 |
| illustrated | Illustrated |
| index_date | 2024-07-02T15:22:30Z |
| indexdate | 2024-07-09T20:42:25Z |
| institution | BVB |
| isbn | 9780470018644 9780470018651 047001864X 0470018658 |
| language | English German |
| lccn | 2006049535 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-014931657 |
| oclc_num | 70230778 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-20 DE-19 DE-BY-UBM DE-384 DE-92 DE-83 DE-11 DE-703 |
| owner_facet | DE-91G DE-BY-TUM DE-20 DE-19 DE-BY-UBM DE-384 DE-92 DE-83 DE-11 DE-703 |
| physical | X, 268 S. Ill., graph. Darst. |
| publishDate | 2007 |
| publishDateSearch | 2007 |
| publishDateSort | 2007 |
| publisher | Wiley |
| record_format | marc |
| series2 | Inorganic chemistry |
| spelling | Müller, Ulrich 1940- Verfasser (DE-588)130176184 aut Anorganische Strukturchemie Inorganic structural chemistry Ulrich Müller 2. ed. Chichester Wiley 2007 X, 268 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Inorganic chemistry Chemistry, Inorganic Anorganische Chemie (DE-588)4002145-2 gnd rswk-swf Anorganischer Stoff (DE-588)4142569-8 gnd rswk-swf Kristallchemie (DE-588)4165759-7 gnd rswk-swf Strukturchemie (DE-588)4183790-3 gnd rswk-swf 1\p (DE-588)4006432-3 Bibliografie gnd-content 2\p (DE-588)4123623-3 Lehrbuch gnd-content Anorganische Chemie (DE-588)4002145-2 s Strukturchemie (DE-588)4183790-3 s DE-604 Anorganischer Stoff (DE-588)4142569-8 s Kristallchemie (DE-588)4165759-7 s 3\p DE-604 Digitalisierung UB Augsburg application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014931657&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Müller, Ulrich 1940- Inorganic structural chemistry Chemistry, Inorganic Anorganische Chemie (DE-588)4002145-2 gnd Anorganischer Stoff (DE-588)4142569-8 gnd Kristallchemie (DE-588)4165759-7 gnd Strukturchemie (DE-588)4183790-3 gnd |
| subject_GND | (DE-588)4002145-2 (DE-588)4142569-8 (DE-588)4165759-7 (DE-588)4183790-3 (DE-588)4006432-3 (DE-588)4123623-3 |
| title | Inorganic structural chemistry |
| title_alt | Anorganische Strukturchemie |
| title_auth | Inorganic structural chemistry |
| title_exact_search | Inorganic structural chemistry |
| title_exact_search_txtP | Inorganic structural chemistry |
| title_full | Inorganic structural chemistry Ulrich Müller |
| title_fullStr | Inorganic structural chemistry Ulrich Müller |
| title_full_unstemmed | Inorganic structural chemistry Ulrich Müller |
| title_short | Inorganic structural chemistry |
| title_sort | inorganic structural chemistry |
| topic | Chemistry, Inorganic Anorganische Chemie (DE-588)4002145-2 gnd Anorganischer Stoff (DE-588)4142569-8 gnd Kristallchemie (DE-588)4165759-7 gnd Strukturchemie (DE-588)4183790-3 gnd |
| topic_facet | Chemistry, Inorganic Anorganische Chemie Anorganischer Stoff Kristallchemie Strukturchemie Bibliografie Lehrbuch |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014931657&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT mullerulrich anorganischestrukturchemie AT mullerulrich inorganicstructuralchemistry |