Principles of chemical reactor analysis and design: new tools for industrial chemical reactor operations
Gespeichert in:
1. Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Hoboken, NJ
Wiley
2009
|
Ausgabe: | 2. ed. |
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XVIII, 473 S. graph. Darst. |
ISBN: | 9780471261803 |
Internformat
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Datensatz im Suchindex
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adam_text | CONTENTS
Preface
. xi
Notation xv
1
Overview of Chemical Reaction Engineering
1
1.1
Classification of Chemical Reactions,
2
1.2
Classification of Chemical Reactors,
3
1.3
Phenomena and Concepts,
8
1.3.1
Stoichiometry,
8
1.3.2
Chemical Kinetics,
9
1.3.3
Transport Effects,
9
1.3.4
Global Rate Expression,
14
1.3.5
Species Balance Equation and Reactor
Design Equation,
14
1.3.6
Energy Balance Equation,
15
1.3.7
Momentum Balance Equation,
15
1.4
Common Practices,
15
1.4.1
Experimental Reactors,
16
1.4.2
Selection of Reactor Configuration,
16
1.4.3
Selection of Operating Conditions,
18
1.4.4
Operational Considerations,
18
1.4.5
Scaleup,
19
1.4.6
Diagnostic Methods,
20
1.5
Industrial Reactors,
20
1.6
Summary,
21
References,
22
VII
viii CONTENTS
2
Stoichiometry
25
2.1
Four Contexts of
Chemical
Reaction,
25
2.2
Chemical Formulas and Stoichiometric Coefficients,
26
2.3
Extent of a Chemical Reaction,
28
2.4
Independent and Dependent Chemical Reactions,
39
2.5
Characterization of the Reactor Feed,
47
2.5.1
Limiting Reactant,
48
2.5.2
Excess Reactant,
49
2.6
Characterization of Reactor Performance,
54
2.6.1
Reactant Conversion,
54
2.6.2
Product Yield and Selectivity,
58
2.7
Dimensionless Extents,
64
2.8
Independent Species Composition Specifications,
68
2.9
Summary,
72
Problems,
72
Bibliography,
79
3
Chemical Kinetics
81
3.1
Species Formation Rates,
81
3.2
Rates of Chemical Reactions,
82
3.3
Rate Expressions of Chemical Reactions,
86
3.4
Effects of Transport Phenomena,
91
3.5
Characteristic Reaction Time,
91
3.6
Summary,
97
Problems,
97
Bibliography,
99
4
Species Balances and Design Equations
101
4.1
Macroscopic Species Balances
—
General Species-Based
Design Equations,
102
4.2
Species-Based Design Equations of Ideal Reactors,
104
4.2.1
Ideal Batch Reactor,
104
4.2.2
Continuous Stirred-Tank Reactor (CSTR),
105
4.2.3
Plug-Flow Reactor (PFR),
106
4.3
Reaction-Based Design Equations,
107
4.3.1
Ideal Batch Reactor,
107
4.3.2
Plug-How Reactor,
109
4.3.3
Continuous Stirred-Tank Reactor (CSTR),
111
4.3.4
Formulation Procedure,
112
4.4
Dimensionless Design Equations and
Operating Curves,
113
CONTENTS ix
4.5
Summary,
125
Problems, 126
Bibliography,
129
5 Energy
Balances
131
5.1 Review
of Thermodynamic Relations,
131
5.1.1
Heat of Reaction,
131
5.1.2
Effect of Temperature on Reaction
Equilibrium Constant,
134
5.2
Energy Balances,
135
5.2.1
Batch Reactors,
136
5.2.2
Flow Reactors,
147
5.3
Summary,
156
Problems,
157
Bibliography,
158
6
Ideal Batch Reactor
159
6.1
Design Equations and Auxiliary Relations,
160
6.2
Isothermal Operations with Single Reactions,
166
6.2.1
Constant-Volume Reactors,
167
6.2.2
Gaseous, Variable-Volume
Batch Reactors,
181
6.2.3
Determination of the Reaction
Rate Expression,
189
6.3
Isothermal Operations with Multiple Reactions,
198
6.4
Nonisothermal Operations,
216
6.5
Summary,
230
Problems,
231
Bibliography,
238
7
Plug-Flow Reactor
239
7.1
Design Equations and Auxiliary Relations,
240
7.2
Isothermal Operations with Single Reactions,
245
7.2.1
Design,
246
7.2.2
Determination of Reaction
Rate Expression,
261
7.3
Isothermal Operations with Multiple
Reactions,
265
7.4
Nonisothermal Operations,
281
7.5
Effects of Pressure Drop,
296
7.6
Summary,
308
Problems,
309
X
CONTENTS
8
Continuous Stirred-Tank Reactor
317
8.1
Design Equations and Auxiliary Relations,
318
8.2
Isothermal Operations with Single Reactions,
322
8.2.1
Design of a Single CSTR,
324
8.2.2
Determination of the Reaction Rate
Expression,
333
8.2.3
Cascade of CSTRs Connected in Series,
336
8.3
Isothermal Operations with Multiple Reactions,
341
8.4
Nonisothermal Operations,
358
8.5
Summary,
370
Problems,
370
9
Other Reactor Configurations
377
9.1
Semibatch
Reactors,
377
9.2
Plug-Flow Reactor with Distributed Feed,
400
9.3
Distillation Reactor,
416
9.4
Recycle Reactor,
425
9.5
Summary,
435
Problems,
435
10
Economic-Based Optimization
441
10.1
Economic-Based Performance Objective Functions,
442
10.2
Batch and
Semibatch
Reactors,
448
10.3
Flow Reactors,
450
10.4
Summary,
453
Problems,
453
Bibliography,
454
Appendix A Summary of Key Relationships
455
Appendix
В
Microscopic Species Balances
—
Species Continuity
Equations
465
Appendix
С
Summary of Numerical Differentiation and Integration
469
Index
471
|
adam_txt |
CONTENTS
Preface
. xi
Notation xv
1
Overview of Chemical Reaction Engineering
1
1.1
Classification of Chemical Reactions,
2
1.2
Classification of Chemical Reactors,
3
1.3
Phenomena and Concepts,
8
1.3.1
Stoichiometry,
8
1.3.2
Chemical Kinetics,
9
1.3.3
Transport Effects,
9
1.3.4
Global Rate Expression,
14
1.3.5
Species Balance Equation and Reactor
Design Equation,
14
1.3.6
Energy Balance Equation,
15
1.3.7
Momentum Balance Equation,
15
1.4
Common Practices,
15
1.4.1
Experimental Reactors,
16
1.4.2
Selection of Reactor Configuration,
16
1.4.3
Selection of Operating Conditions,
18
1.4.4
Operational Considerations,
18
1.4.5
Scaleup,
19
1.4.6
Diagnostic Methods,
20
1.5
Industrial Reactors,
20
1.6
Summary,
21
References,
22
VII
viii CONTENTS
2
Stoichiometry
25
2.1
Four Contexts of
Chemical
Reaction,
25
2.2
Chemical Formulas and Stoichiometric Coefficients,
26
2.3
Extent of a Chemical Reaction,
28
2.4
Independent and Dependent Chemical Reactions,
39
2.5
Characterization of the Reactor Feed,
47
2.5.1
Limiting Reactant,
48
2.5.2
Excess Reactant,
49
2.6
Characterization of Reactor Performance,
54
2.6.1
Reactant Conversion,
54
2.6.2
Product Yield and Selectivity,
58
2.7
Dimensionless Extents,
64
2.8
Independent Species Composition Specifications,
68
2.9
Summary,
72
Problems,
72
Bibliography,
79
3
Chemical Kinetics
81
3.1
Species Formation Rates,
81
3.2
Rates of Chemical Reactions,
82
3.3
Rate Expressions of Chemical Reactions,
86
3.4
Effects of Transport Phenomena,
91
3.5
Characteristic Reaction Time,
91
3.6
Summary,
97
Problems,
97
Bibliography,
99
4
Species Balances and Design Equations
101
4.1
Macroscopic Species Balances
—
General Species-Based
Design Equations,
102
4.2
Species-Based Design Equations of Ideal Reactors,
104
4.2.1
Ideal Batch Reactor,
104
4.2.2
Continuous Stirred-Tank Reactor (CSTR),
105
4.2.3
Plug-Flow Reactor (PFR),
106
4.3
Reaction-Based Design Equations,
107
4.3.1
Ideal Batch Reactor,
107
4.3.2
Plug-How Reactor,
109
4.3.3
Continuous Stirred-Tank Reactor (CSTR),
111
4.3.4
Formulation Procedure,
112
4.4
Dimensionless Design Equations and
Operating Curves,
113
CONTENTS ix
4.5
Summary,
125
Problems, 126
Bibliography,
129
5 Energy
Balances
131
5.1 Review
of Thermodynamic Relations,
131
5.1.1
Heat of Reaction,
131
5.1.2
Effect of Temperature on Reaction
Equilibrium Constant,
134
5.2
Energy Balances,
135
5.2.1
Batch Reactors,
136
5.2.2
Flow Reactors,
147
5.3
Summary,
156
Problems,
157
Bibliography,
158
6
Ideal Batch Reactor
159
6.1
Design Equations and Auxiliary Relations,
160
6.2
Isothermal Operations with Single Reactions,
166
6.2.1
Constant-Volume Reactors,
167
6.2.2
Gaseous, Variable-Volume
Batch Reactors,
181
6.2.3
Determination of the Reaction
Rate Expression,
189
6.3
Isothermal Operations with Multiple Reactions,
198
6.4
Nonisothermal Operations,
216
6.5
Summary,
230
Problems,
231
Bibliography,
238
7
Plug-Flow Reactor
239
7.1
Design Equations and Auxiliary Relations,
240
7.2
Isothermal Operations with Single Reactions,
245
7.2.1
Design,
246
7.2.2
Determination of Reaction
Rate Expression,
261
7.3
Isothermal Operations with Multiple
Reactions,
265
7.4
Nonisothermal Operations,
281
7.5
Effects of Pressure Drop,
296
7.6
Summary,
308
Problems,
309
X
CONTENTS
8
Continuous Stirred-Tank Reactor
317
8.1
Design Equations and Auxiliary Relations,
318
8.2
Isothermal Operations with Single Reactions,
322
8.2.1
Design of a Single CSTR,
324
8.2.2
Determination of the Reaction Rate
Expression,
333
8.2.3
Cascade of CSTRs Connected in Series,
336
8.3
Isothermal Operations with Multiple Reactions,
341
8.4
Nonisothermal Operations,
358
8.5
Summary,
370
Problems,
370
9
Other Reactor Configurations
377
9.1
Semibatch
Reactors,
377
9.2
Plug-Flow Reactor with Distributed Feed,
400
9.3
Distillation Reactor,
416
9.4
Recycle Reactor,
425
9.5
Summary,
435
Problems,
435
10
Economic-Based Optimization
441
10.1
Economic-Based Performance Objective Functions,
442
10.2
Batch and
Semibatch
Reactors,
448
10.3
Flow Reactors,
450
10.4
Summary,
453
Problems,
453
Bibliography,
454
Appendix A Summary of Key Relationships
455
Appendix
В
Microscopic Species Balances
—
Species Continuity
Equations
465
Appendix
С
Summary of Numerical Differentiation and Integration
469
Index
471 |
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index_date | 2024-07-02T14:46:02Z |
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isbn | 9780471261803 |
language | English |
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physical | XVIII, 473 S. graph. Darst. |
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spelling | Mann, Uzi Verfasser aut Principles of chemical reactor analysis and design new tools for industrial chemical reactor operations Uzi Mann 2. ed. Hoboken, NJ Wiley 2009 XVIII, 473 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Réacteurs chimiques - Design Museum ram Chemical reactors Design and construction Chemischer Reaktor (DE-588)4121085-2 gnd rswk-swf Chemischer Reaktor (DE-588)4121085-2 s DE-604 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014811182&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Mann, Uzi Principles of chemical reactor analysis and design new tools for industrial chemical reactor operations Réacteurs chimiques - Design Museum ram Chemical reactors Design and construction Chemischer Reaktor (DE-588)4121085-2 gnd |
subject_GND | (DE-588)4121085-2 |
title | Principles of chemical reactor analysis and design new tools for industrial chemical reactor operations |
title_auth | Principles of chemical reactor analysis and design new tools for industrial chemical reactor operations |
title_exact_search | Principles of chemical reactor analysis and design new tools for industrial chemical reactor operations |
title_exact_search_txtP | Principles of chemical reactor analysis and design new tools for industrial chemical reactor operations |
title_full | Principles of chemical reactor analysis and design new tools for industrial chemical reactor operations Uzi Mann |
title_fullStr | Principles of chemical reactor analysis and design new tools for industrial chemical reactor operations Uzi Mann |
title_full_unstemmed | Principles of chemical reactor analysis and design new tools for industrial chemical reactor operations Uzi Mann |
title_short | Principles of chemical reactor analysis and design |
title_sort | principles of chemical reactor analysis and design new tools for industrial chemical reactor operations |
title_sub | new tools for industrial chemical reactor operations |
topic | Réacteurs chimiques - Design Museum ram Chemical reactors Design and construction Chemischer Reaktor (DE-588)4121085-2 gnd |
topic_facet | Réacteurs chimiques - Design Museum Chemical reactors Design and construction Chemischer Reaktor |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014811182&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT mannuzi principlesofchemicalreactoranalysisanddesignnewtoolsforindustrialchemicalreactoroperations |