Physics and chemistry of interfaces:
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
WILEY-VCH
2006
|
| Ausgabe: | 2., rev. and enl. ed. |
| Schriftenreihe: | Physics textbook
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | Früher mit der ISBN 3527404139 |
| Beschreibung: | XII, 386 S. Ill., graph. Darst. 240 mm x 170 mm |
| ISBN: | 3527406298 9783527406296 |
Internformat
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV021295757 | ||
| 003 | DE-604 | ||
| 005 | 20080811 | ||
| 007 | t | ||
| 008 | 060117s2006 gw ad|| |||| 00||| eng d | ||
| 015 | |a 05,N44,0498 |2 dnb | ||
| 016 | 7 | |a 976614871 |2 DE-101 | |
| 020 | |a 3527406298 |c Pb. : ca. EUR 59.00 (freier Pr.), ca. sfr 94.00 (freier Pr.) |9 3-527-40629-8 | ||
| 020 | |a 9783527406296 |9 978-3-527-40629-6 | ||
| 024 | 3 | |a 9783527406296 | |
| 028 | 5 | 2 | |a 1140629 000 |
| 035 | |a (OCoLC)181485166 | ||
| 035 | |a (DE-599)BVBBV021295757 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 044 | |a gw |c XA-DE-BW | ||
| 049 | |a DE-91G |a DE-703 |a DE-1051 |a DE-355 |a DE-20 |a DE-19 |a DE-384 |a DE-526 |a DE-634 |a DE-83 |a DE-11 |a DE-188 | ||
| 084 | |a UP 7500 |0 (DE-625)146433: |2 rvk | ||
| 084 | |a VE 7000 |0 (DE-625)147134:253 |2 rvk | ||
| 084 | |a VN 7000 |0 (DE-625)147598:253 |2 rvk | ||
| 084 | |a PHY 650f |2 stub | ||
| 084 | |a 540 |2 sdnb | ||
| 084 | |a PHY 629f |2 stub | ||
| 084 | |a CHE 180f |2 stub | ||
| 084 | |a 530 |2 sdnb | ||
| 100 | 1 | |a Butt, Hans-Jürgen |d 1961- |e Verfasser |0 (DE-588)110921550 |4 aut | |
| 245 | 1 | 0 | |a Physics and chemistry of interfaces |c Hans Jürgen Butt ; Karlheinz Graf ; Michael Kappl |
| 250 | |a 2., rev. and enl. ed. | ||
| 264 | 1 | |a Weinheim |b WILEY-VCH |c 2006 | |
| 300 | |a XII, 386 S. |b Ill., graph. Darst. |c 240 mm x 170 mm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Physics textbook | |
| 500 | |a Früher mit der ISBN 3527404139 | ||
| 650 | 4 | |a Surface chemistry | |
| 650 | 4 | |a Surfaces (Physics) | |
| 650 | 0 | 7 | |a Oberflächenchemie |0 (DE-588)4126166-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Grenzflächenphysik |0 (DE-588)4452968-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Grenzflächenchemie |0 (DE-588)4246080-3 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Oberflächenphysik |0 (DE-588)4134881-3 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4123623-3 |a Lehrbuch |2 gnd-content | |
| 689 | 0 | 0 | |a Oberflächenphysik |0 (DE-588)4134881-3 |D s |
| 689 | 0 | 1 | |a Oberflächenchemie |0 (DE-588)4126166-5 |D s |
| 689 | 0 | |8 1\p |5 DE-604 | |
| 689 | 1 | 0 | |a Grenzflächenphysik |0 (DE-588)4452968-5 |D s |
| 689 | 1 | 1 | |a Grenzflächenchemie |0 (DE-588)4246080-3 |D s |
| 689 | 1 | |8 2\p |5 DE-604 | |
| 700 | 1 | |a Graf, Karlheinz |d 1966- |e Verfasser |0 (DE-588)120729075 |4 aut | |
| 700 | 1 | |a Kappl, Michael |d 1963- |e Verfasser |0 (DE-588)128798548 |4 aut | |
| 856 | 4 | 2 | |q text/html |u http://deposit.dnb.de/cgi-bin/dokserv?id=2686609&prov=M&dok_var=1&dok_ext=htm |3 Inhaltstext |
| 856 | 4 | 2 | |m HBZ Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014616522&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-014616522 | ||
| 883 | 1 | |8 1\p |a cgwrk |d 20201028 |q DE-101 |u https://d-nb.info/provenance/plan#cgwrk | |
| 883 | 1 | |8 2\p |a cgwrk |d 20201028 |q DE-101 |u https://d-nb.info/provenance/plan#cgwrk | |
Datensatz im Suchindex
| _version_ | 1804135090579570688 |
|---|---|
| adam_text | Contents
Preface XI
1 Introduction 1
2 Liquid surfaces 5
2.1 Microscopic picture of the liquid surface 5
2.2 Surface tension 6
2.3 Equation of Young and Laplace 9
2.3.1 Curved liquid surfaces 9
2.3.2 Derivation of the Young Laplace equation 11
2.3.3 Applying the Young Laplace equation 12
2.4 Techniques to measure the surface tension 13
2.5 The Kelvin equation 16
2.6 Capillary condensation 19
2.7 Nucleation theory 22
2.8 Summary 25
2.9 Exercises 26
3 Thermodynamics of interfaces 29
3.1 The surface excess 29
3.2 Fundamental thermodynamic relations 32
3.2.1 Internal energy and Helmholtz energy 32
3.2.2 Equilibrium conditions 33
3.2.3 Location of the interface 34
3.2.4 Gibbs energy and definition of the surface tension 35
3.2.5 Helmholtz surface energy, interfacial enthalpy, and Gibbs surface energy 36
3.3 The surface tension of pure liquids 37
3.4 Gibbs adsorption isotherm 39
3.4.1 Derivation 39
3.4.2 System of two components 40
3.4.3 Experimental aspects 41
3.4.4 The Marangoni effect 42
3.5 Summary 43
3.6 Exercises 44
Physics and Chemistry of Interfaces. Second, Revised and Enlarged Edition. Hans Jurgen Butt. Karlheinz Graf. Michael Kappl
Copyright © 2006 Wiley VCH Verlag GmbH Co. KGaA, Weinheim
ISBN: 3 527 40629 8
yj Contents
4 The electric double layer 45
4.1 Introduction 45
4.2 Poisson Boltzmann theory of the diffuse double layer 46
4.2.1 The Poisson Boltzmann equation 46
4.2.2 Planar surfaces 47
4.2.3 The full one dimensional case 49
4.2.4 The Grahame equation 52
4.2.5 Capacity of the diffuse electric double layer 53
4.3 Beyond Poisson Boltzmann theory 54
4.3.1 Limitations of the Poisson Boltzmann theory 54
4.3.2 The Stern layer 55
4.4 The Gibbs free energy of the electric double layer 57
4.5 Summary 58
4.6 Exercises 59
5 Effects at charged interfaces 61
5.1 Electrocapillarity 61
5.1.1 Theory 62
5.1.2 Measurement of electrocapillarity 64
5.2 Examples of charged surfaces 65
5.2.1 Mercury ¦ 66
5.2.2 Silver iodide 67
5.2.3 Oxides 69
5.2.4 Mica ¦ 70
5.2.5 Semiconductors ¦ 71
5.3 Measuring surface charge densities 73
5.3.1 Potentiometric colloid titration 73
5.3.2 Capacitances • 74
5.4 Electrokinetic phenomena: The zeta potential • 76
5.4.1 The Navier Stokes equation ¦ 77
5.4.2 Electro osmosis and streaming potential ¦ 78
5.4.3 Electrophoresis and sedimentation potential • 80
5.5 Types of potentials ¦ 82
5.6 Summary • 84
5.7 Exercises ¦ 84
6 Surface forces 85
6.1 Van der Waals forces between molecules 85
6.2 The van der Waals force between macroscopic solids • 89
6.2.1 Microscopic approach • 89
6.2.2 Macroscopic calculation — Lifshitz theory . • 92
6.2.3 Surface energy and Hamaker constant • 96
6.3 Concepts for the description of surface forces • 98
6.3.1 The Derjaguin approximation • 98
6.3.2 The disjoining pressure ¦ 101
6.4 Measurement of surface forces • 101
Contents VII
6.5 The electrostatic double layer force 103
6.5.1 General equations 103
6.5.2 Electrostatic interaction between two identical surfaces 106
6.5.3 The DLVO theory 108
6.6 Beyond DLVO theory 110
6.6.1 The solvation force and confined liquids 110
6.6.2 Non DLVO forces in an aqueous medium 110
6.7 Steric and depletion interaction 113
6.7.1 Properties of polymers 113
6.7.2 Force between polymer coated surfaces 114
6.7.3 Depletion forces 116
6.8 Spherical particles in contact 117
6.9 Summary 121
6.10 Exercises 122
7 Contact angle phenomena and wetting 125
7.1 Young s equation 125
7.1.1 The contact angle 125
7.1.2 Derivation 126
7.1.3 The line tension 128
7.1.4 Complete wetting and wetting transitions 128
7.2 Important wetting geometries 130
7.2.1 Capillary rise 130
7.2.2 Particles in the liquid gas interface 131
7.2.3 Network of fibers 132
7.3 Measurement of the contact angle 133
7.3.1 Experimental methods 133
7.3.2 Hysteresis in contact angle measurements 135
7.3.3 Surface roughness and heterogeneity 137
7.4 Theoretical aspects of contact angle phenomena 139
7.5 Dynamics of wetting and dewetting 141
7.5.1 Wetting 141
7.5.2 Dewetting 145
7.6 Applications 146
7.6.1 Flotation 146
7.6.2 Detergency 147
7.6.3 Microfluidics 148
7.6.4 Adjustable wetting 150
7.7 Summary 151
7.8 Exercises 152
8 Solid surfaces 153
8.1 Introduction 153
8.2 Description of crystalline surfaces 154
8.2.1 The substrate structure 154
yjjj Contents
8.2.2 Surface relaxation and reconstruction 155
8.2.3 Description of adsorbate structures 158
8.3 Preparation of clean surfaces 158
8.4 Thermodynamics of solid surfaces 161
8.4.1 Surface stress and surface tension 161
8.4.2 Determination of the surface energy 164
8.4.3 Surface steps and defects 167
8.5 Solid solid interfaces 169
8.6 Microscopy of solid surfaces 171
8.6.1 Optical microscopy l^1
8.6.2 Electron microscopy 172
8.6.3 Scanning probe microscopy 174
8.7 Diffraction methods I77
8.7.1 Diffraction patterns of two dimensional periodic structures 177
8.7.2 Diffraction with electrons, X rays, and atoms 179
8.8 Spectroscopic methods 181
8.8.1 Spectroscopy using mainly inner electrons 181
8.8.2 Spectroscopy with outer electrons 182
8.8.3 Secondary ion mass spectrometry 183
8.9 Summary 185
8.10 Exercises 185
9 Adsorption 187
9.1 Introduction 187
9.1.1 Definitions I87
9.1.2 The adsorption time 188
9.1.3 Classification of adsorption isotherms 189
9.1.4 Presentation of adsorption isotherms 191
9.2 Thermodynamics of adsorption 192
9.2.1 Heats of adsorption 192
9.2.2 Differential quantities of adsorption and experimental results 193
9.3 Adsorption models 195
9.3.1 The Langmuir adsorption isotherm 195
9.3.2 The Langmuir constant and the Gibbs energy of adsorption 198
9.3.3 Langmuir adsorption with lateral interactions 199
9.3.4 The BET adsorption isotherm 199
9.3.5 Adsorption on heterogeneous surfaces 202
9.3.6 The potential theory of Polanyi 203
9.4 Experimental aspects of adsorption from the gas phase 206
9.4.1 Measurement of adsorption isotherms 206
9.4.2 Procedures to measure the specific surface area 209
9.4.3 Adsorption on porous solids — hysteresis 211
9.4.4 Special aspects of chemisorption 214
9.5 Adsorption from solution 215
9.6 Summary 217
9.7 Exercises 217
Contents IX
10 Surface modification 219
10.1 Introduction 219
10.2 Chemical vapor deposition 220
10.3 Soft matter deposition 222
10.3.1 Self assembled monolayers 222
10.3.2 Physisorption of Polymers 226
10.3.3 Polymerization on surfaces 228
10.3.4 Plasma polymerization 230
10.4 Etching techniques 232
10.5 Lithography 235
10.6 Summary 237
10.7 Exercises 238
11 Friction, lubrication, and wear 241
11.1 Friction 241
11.1.1 Introduction 241
11.1.2 Amontons and Coulomb s Law 242
11.1.3 Static, kinetic, and stick slip friction 244
11.1.4 Rolling friction 245
11.1.5 Friction and adhesion 247
11.1.6 Experimental Aspects 247
11.1.7 Techniques to measure friction 247
11.1.8 Macroscopic friction 249
11.1.9 Microscopic friction 250
11.2 Lubrication 253
11.2.1 Hydrodynamic lubrication 254
11.2.2 Boundary lubrication 256
11.2.3 Thin film lubrication 257
11.2.4 Lubricants 258
11.3 Wear 259
11.4 Summary 261
11.5 Exercises 262
12 Surfactants, micelles, emulsions, and foams 265
12.1 Surfactants 265
12.2 Spherical micelles, cylinders, and bilayers 269
12.2.1 The critical micelle concentration 269
12.2.2 Influence of temperature 271
12.2.3 Thermodynamics of micellization 272
12.2.4 Structure of surfactant aggregates 274
12.2.5 Biological membranes 277
12.3 Macroemulsions 278
12.3.1 General properties 278
12.3.2 Formation 280
12.3.3 Stabilization 282
X Contents
12.3 A Evolution and aging 285
12.3.5 Coalescence and demulsification 287
12.4 Microemulsions 287
12.4.1 Size of droplets 288
12.4.2 Elastic properties of surfactant films 289
12.4.3 Factors influencing the structure of microemulsions 290
12.5 Foams 292
12.5.1 Classification, application and formation 292
12.5.2 Structure of foams 293
12.5.3 Soap films 294
12.5.4 Evolution of foams 297
12.6 Summary 298
12.7 Exercises 298
13 Thin films on surfaces of liquids 301
13.1 Introduction 301
13.2 Phases of monomolecular films 304
13.3 Experimental techniques to study monolayers 307
13.3.1 Optical methods 307
13.3.2 X ray reflection and diffraction 308
13.3.3 The surface potential 311
13.3.4 Surface elasticity and viscosity 313
13.4 Langmuir Blodgett transfer 314
13.5 Thick films spreading of one liquid on another 316
13.6 Summary 318
13.7 Exercises 319
14 Solutions to exercises 321
Appendix
A Analysis of diffraction patterns 343
A. 1 Diffraction at three dimensional crystals 343
A. 1.1 Bragg condition 343
A. 1.2 Laue condition 344
A. 1.3 The reciprocal lattice 345
A. 1.4 Ewald construction 347
A.2 Diffraction at Surfaces 347
A.3 Intensity of diffraction peaks 349
B Symbols and abbreviations 353
Bibliography 357
Index 379
|
| adam_txt |
Contents
Preface XI
1 Introduction 1
2 Liquid surfaces 5
2.1 Microscopic picture of the liquid surface 5
2.2 Surface tension 6
2.3 Equation of Young and Laplace 9
2.3.1 Curved liquid surfaces 9
2.3.2 Derivation of the Young Laplace equation 11
2.3.3 Applying the Young Laplace equation 12
2.4 Techniques to measure the surface tension 13
2.5 The Kelvin equation 16
2.6 Capillary condensation 19
2.7 Nucleation theory 22
2.8 Summary 25
2.9 Exercises 26
3 Thermodynamics of interfaces 29
3.1 The surface excess 29
3.2 Fundamental thermodynamic relations 32
3.2.1 Internal energy and Helmholtz energy 32
3.2.2 Equilibrium conditions 33
3.2.3 Location of the interface 34
3.2.4 Gibbs energy and definition of the surface tension 35
3.2.5 Helmholtz surface energy, interfacial enthalpy, and Gibbs surface energy 36
3.3 The surface tension of pure liquids 37
3.4 Gibbs adsorption isotherm 39
3.4.1 Derivation 39
3.4.2 System of two components 40
3.4.3 Experimental aspects 41
3.4.4 The Marangoni effect 42
3.5 Summary 43
3.6 Exercises 44
Physics and Chemistry of Interfaces. Second, Revised and Enlarged Edition. Hans Jurgen Butt. Karlheinz Graf. Michael Kappl
Copyright © 2006 Wiley VCH Verlag GmbH Co. KGaA, Weinheim
ISBN: 3 527 40629 8
yj Contents
4 The electric double layer 45
4.1 Introduction 45
4.2 Poisson Boltzmann theory of the diffuse double layer 46
4.2.1 The Poisson Boltzmann equation 46
4.2.2 Planar surfaces 47
4.2.3 The full one dimensional case 49
4.2.4 The Grahame equation 52
4.2.5 Capacity of the diffuse electric double layer 53
4.3 Beyond Poisson Boltzmann theory 54
4.3.1 Limitations of the Poisson Boltzmann theory 54
4.3.2 The Stern layer 55
4.4 The Gibbs free energy of the electric double layer 57
4.5 Summary 58
4.6 Exercises 59
5 Effects at charged interfaces 61
5.1 Electrocapillarity 61
5.1.1 Theory 62
5.1.2 Measurement of electrocapillarity 64
5.2 Examples of charged surfaces 65
5.2.1 Mercury ¦ 66
5.2.2 Silver iodide 67
5.2.3 Oxides 69
5.2.4 Mica ¦ 70
5.2.5 Semiconductors ¦ 71
5.3 Measuring surface charge densities 73
5.3.1 Potentiometric colloid titration 73
5.3.2 Capacitances • 74
5.4 Electrokinetic phenomena: The zeta potential • 76
5.4.1 The Navier Stokes equation ¦ 77
5.4.2 Electro osmosis and streaming potential ¦ 78
5.4.3 Electrophoresis and sedimentation potential • 80
5.5 Types of potentials ¦ 82
5.6 Summary • 84
5.7 Exercises ¦ 84
6 Surface forces 85
6.1 Van der Waals forces between molecules 85
6.2 The van der Waals force between macroscopic solids • 89
6.2.1 Microscopic approach • 89
6.2.2 Macroscopic calculation — Lifshitz theory . • 92
6.2.3 Surface energy and Hamaker constant • 96
6.3 Concepts for the description of surface forces • 98
6.3.1 The Derjaguin approximation • 98
6.3.2 The disjoining pressure ¦ 101
6.4 Measurement of surface forces • 101
Contents VII
6.5 The electrostatic double layer force 103
6.5.1 General equations 103
6.5.2 Electrostatic interaction between two identical surfaces 106
6.5.3 The DLVO theory 108
6.6 Beyond DLVO theory 110
6.6.1 The solvation force and confined liquids 110
6.6.2 Non DLVO forces in an aqueous medium 110
6.7 Steric and depletion interaction 113
6.7.1 Properties of polymers 113
6.7.2 Force between polymer coated surfaces 114
6.7.3 Depletion forces 116
6.8 Spherical particles in contact 117
6.9 Summary 121
6.10 Exercises 122
7 Contact angle phenomena and wetting 125
7.1 Young's equation 125
7.1.1 The contact angle 125
7.1.2 Derivation 126
7.1.3 The line tension 128
7.1.4 Complete wetting and wetting transitions 128
7.2 Important wetting geometries 130
7.2.1 Capillary rise 130
7.2.2 Particles in the liquid gas interface 131
7.2.3 Network of fibers 132
7.3 Measurement of the contact angle 133
7.3.1 Experimental methods 133
7.3.2 Hysteresis in contact angle measurements 135
7.3.3 Surface roughness and heterogeneity 137
7.4 Theoretical aspects of contact angle phenomena 139
7.5 Dynamics of wetting and dewetting 141
7.5.1 Wetting 141
7.5.2 Dewetting 145
7.6 Applications 146
7.6.1 Flotation 146
7.6.2 Detergency 147
7.6.3 Microfluidics 148
7.6.4 Adjustable wetting 150
7.7 Summary 151
7.8 Exercises 152
8 Solid surfaces 153
8.1 Introduction 153
8.2 Description of crystalline surfaces 154
8.2.1 The substrate structure 154
yjjj Contents
8.2.2 Surface relaxation and reconstruction 155
8.2.3 Description of adsorbate structures 158
8.3 Preparation of clean surfaces 158
8.4 Thermodynamics of solid surfaces 161
8.4.1 Surface stress and surface tension 161
8.4.2 Determination of the surface energy 164
8.4.3 Surface steps and defects 167
8.5 Solid solid interfaces 169
8.6 Microscopy of solid surfaces 171
8.6.1 Optical microscopy l^1
8.6.2 Electron microscopy 172
8.6.3 Scanning probe microscopy 174
8.7 Diffraction methods I77
8.7.1 Diffraction patterns of two dimensional periodic structures 177
8.7.2 Diffraction with electrons, X rays, and atoms 179
8.8 Spectroscopic methods 181
8.8.1 Spectroscopy using mainly inner electrons 181
8.8.2 Spectroscopy with outer electrons 182
8.8.3 Secondary ion mass spectrometry 183
8.9 Summary 185
8.10 Exercises 185
9 Adsorption 187
9.1 Introduction 187
9.1.1 Definitions I87
9.1.2 The adsorption time 188
9.1.3 Classification of adsorption isotherms 189
9.1.4 Presentation of adsorption isotherms 191
9.2 Thermodynamics of adsorption 192
9.2.1 Heats of adsorption 192
9.2.2 Differential quantities of adsorption and experimental results 193
9.3 Adsorption models 195
9.3.1 The Langmuir adsorption isotherm 195
9.3.2 The Langmuir constant and the Gibbs energy of adsorption 198
9.3.3 Langmuir adsorption with lateral interactions 199
9.3.4 The BET adsorption isotherm 199
9.3.5 Adsorption on heterogeneous surfaces 202
9.3.6 The potential theory of Polanyi 203
9.4 Experimental aspects of adsorption from the gas phase 206
9.4.1 Measurement of adsorption isotherms 206
9.4.2 Procedures to measure the specific surface area 209
9.4.3 Adsorption on porous solids — hysteresis 211
9.4.4 Special aspects of chemisorption 214
9.5 Adsorption from solution 215
9.6 Summary 217
9.7 Exercises 217
Contents IX
10 Surface modification 219
10.1 Introduction 219
10.2 Chemical vapor deposition 220
10.3 Soft matter deposition 222
10.3.1 Self assembled monolayers 222
10.3.2 Physisorption of Polymers 226
10.3.3 Polymerization on surfaces 228
10.3.4 Plasma polymerization 230
10.4 Etching techniques 232
10.5 Lithography 235
10.6 Summary 237
10.7 Exercises 238
11 Friction, lubrication, and wear 241
11.1 Friction 241
11.1.1 Introduction 241
11.1.2 Amontons' and Coulomb's Law 242
11.1.3 Static, kinetic, and stick slip friction 244
11.1.4 Rolling friction 245
11.1.5 Friction and adhesion 247
11.1.6 Experimental Aspects 247
11.1.7 Techniques to measure friction 247
11.1.8 Macroscopic friction 249
11.1.9 Microscopic friction 250
11.2 Lubrication 253
11.2.1 Hydrodynamic lubrication 254
11.2.2 Boundary lubrication 256
11.2.3 Thin film lubrication 257
11.2.4 Lubricants 258
11.3 Wear 259
11.4 Summary 261
11.5 Exercises 262
12 Surfactants, micelles, emulsions, and foams 265
12.1 Surfactants 265
12.2 Spherical micelles, cylinders, and bilayers 269
12.2.1 The critical micelle concentration 269
12.2.2 Influence of temperature 271
12.2.3 Thermodynamics of micellization 272
12.2.4 Structure of surfactant aggregates 274
12.2.5 Biological membranes 277
12.3 Macroemulsions 278
12.3.1 General properties 278
12.3.2 Formation 280
12.3.3 Stabilization 282
X Contents
12.3 A Evolution and aging 285
12.3.5 Coalescence and demulsification 287
12.4 Microemulsions 287
12.4.1 Size of droplets 288
12.4.2 Elastic properties of surfactant films 289
12.4.3 Factors influencing the structure of microemulsions 290
12.5 Foams 292
12.5.1 Classification, application and formation 292
12.5.2 Structure of foams 293
12.5.3 Soap films 294
12.5.4 Evolution of foams 297
12.6 Summary 298
12.7 Exercises 298
13 Thin films on surfaces of liquids 301
13.1 Introduction 301
13.2 Phases of monomolecular films 304
13.3 Experimental techniques to study monolayers 307
13.3.1 Optical methods 307
13.3.2 X ray reflection and diffraction 308
13.3.3 The surface potential 311
13.3.4 Surface elasticity and viscosity 313
13.4 Langmuir Blodgett transfer 314
13.5 Thick films spreading of one liquid on another 316
13.6 Summary 318
13.7 Exercises 319
14 Solutions to exercises 321
Appendix
A Analysis of diffraction patterns 343
A. 1 Diffraction at three dimensional crystals 343
A. 1.1 Bragg condition 343
A. 1.2 Laue condition 344
A. 1.3 The reciprocal lattice 345
A. 1.4 Ewald construction 347
A.2 Diffraction at Surfaces 347
A.3 Intensity of diffraction peaks 349
B Symbols and abbreviations 353
Bibliography 357
Index 379 |
| any_adam_object | 1 |
| any_adam_object_boolean | 1 |
| author | Butt, Hans-Jürgen 1961- Graf, Karlheinz 1966- Kappl, Michael 1963- |
| author_GND | (DE-588)110921550 (DE-588)120729075 (DE-588)128798548 |
| author_facet | Butt, Hans-Jürgen 1961- Graf, Karlheinz 1966- Kappl, Michael 1963- |
| author_role | aut aut aut |
| author_sort | Butt, Hans-Jürgen 1961- |
| author_variant | h j b hjb k g kg m k mk |
| building | Verbundindex |
| bvnumber | BV021295757 |
| classification_rvk | UP 7500 VE 7000 VN 7000 |
| classification_tum | PHY 650f PHY 629f CHE 180f |
| ctrlnum | (OCoLC)181485166 (DE-599)BVBBV021295757 |
| discipline | Chemie / Pharmazie Physik Chemie |
| discipline_str_mv | Chemie / Pharmazie Physik Chemie |
| edition | 2., rev. and enl. ed. |
| format | Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>02921nam a2200685 c 4500</leader><controlfield tag="001">BV021295757</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20080811 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">060117s2006 gw ad|| |||| 00||| eng d</controlfield><datafield tag="015" ind1=" " ind2=" "><subfield code="a">05,N44,0498</subfield><subfield code="2">dnb</subfield></datafield><datafield tag="016" ind1="7" ind2=" "><subfield code="a">976614871</subfield><subfield code="2">DE-101</subfield></datafield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">3527406298</subfield><subfield code="c">Pb. : ca. EUR 59.00 (freier Pr.), ca. sfr 94.00 (freier Pr.)</subfield><subfield code="9">3-527-40629-8</subfield></datafield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">9783527406296</subfield><subfield code="9">978-3-527-40629-6</subfield></datafield><datafield tag="024" ind1="3" ind2=" "><subfield code="a">9783527406296</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">1140629 000</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)181485166</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV021295757</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="044" ind1=" " ind2=" "><subfield code="a">gw</subfield><subfield code="c">XA-DE-BW</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-91G</subfield><subfield code="a">DE-703</subfield><subfield code="a">DE-1051</subfield><subfield code="a">DE-355</subfield><subfield code="a">DE-20</subfield><subfield code="a">DE-19</subfield><subfield code="a">DE-384</subfield><subfield code="a">DE-526</subfield><subfield code="a">DE-634</subfield><subfield code="a">DE-83</subfield><subfield code="a">DE-11</subfield><subfield code="a">DE-188</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">UP 7500</subfield><subfield code="0">(DE-625)146433:</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VE 7000</subfield><subfield code="0">(DE-625)147134:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">VN 7000</subfield><subfield code="0">(DE-625)147598:253</subfield><subfield code="2">rvk</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">PHY 650f</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">540</subfield><subfield code="2">sdnb</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">PHY 629f</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 180f</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">530</subfield><subfield code="2">sdnb</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Butt, Hans-Jürgen</subfield><subfield code="d">1961-</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)110921550</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Physics and chemistry of interfaces</subfield><subfield code="c">Hans Jürgen Butt ; Karlheinz Graf ; Michael Kappl</subfield></datafield><datafield tag="250" ind1=" " ind2=" "><subfield code="a">2., rev. and enl. ed.</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Weinheim</subfield><subfield code="b">WILEY-VCH</subfield><subfield code="c">2006</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">XII, 386 S.</subfield><subfield code="b">Ill., graph. Darst.</subfield><subfield code="c">240 mm x 170 mm</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="490" ind1="0" ind2=" "><subfield code="a">Physics textbook</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">Früher mit der ISBN 3527404139</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Surface chemistry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Surfaces (Physics)</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Oberflächenchemie</subfield><subfield code="0">(DE-588)4126166-5</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Grenzflächenphysik</subfield><subfield code="0">(DE-588)4452968-5</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Grenzflächenchemie</subfield><subfield code="0">(DE-588)4246080-3</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Oberflächenphysik</subfield><subfield code="0">(DE-588)4134881-3</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="655" ind1=" " ind2="7"><subfield code="0">(DE-588)4123623-3</subfield><subfield code="a">Lehrbuch</subfield><subfield code="2">gnd-content</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Oberflächenphysik</subfield><subfield code="0">(DE-588)4134881-3</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="1"><subfield code="a">Oberflächenchemie</subfield><subfield code="0">(DE-588)4126166-5</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="8">1\p</subfield><subfield code="5">DE-604</subfield></datafield><datafield tag="689" ind1="1" ind2="0"><subfield code="a">Grenzflächenphysik</subfield><subfield code="0">(DE-588)4452968-5</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="1" ind2="1"><subfield code="a">Grenzflächenchemie</subfield><subfield code="0">(DE-588)4246080-3</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="1" ind2=" "><subfield code="8">2\p</subfield><subfield code="5">DE-604</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Graf, Karlheinz</subfield><subfield code="d">1966-</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)120729075</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kappl, Michael</subfield><subfield code="d">1963-</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)128798548</subfield><subfield code="4">aut</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="q">text/html</subfield><subfield code="u">http://deposit.dnb.de/cgi-bin/dokserv?id=2686609&prov=M&dok_var=1&dok_ext=htm</subfield><subfield code="3">Inhaltstext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">HBZ Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014616522&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-014616522</subfield></datafield><datafield tag="883" ind1="1" ind2=" "><subfield code="8">1\p</subfield><subfield code="a">cgwrk</subfield><subfield code="d">20201028</subfield><subfield code="q">DE-101</subfield><subfield code="u">https://d-nb.info/provenance/plan#cgwrk</subfield></datafield><datafield tag="883" ind1="1" ind2=" "><subfield code="8">2\p</subfield><subfield code="a">cgwrk</subfield><subfield code="d">20201028</subfield><subfield code="q">DE-101</subfield><subfield code="u">https://d-nb.info/provenance/plan#cgwrk</subfield></datafield></record></collection> |
| genre | (DE-588)4123623-3 Lehrbuch gnd-content |
| genre_facet | Lehrbuch |
| id | DE-604.BV021295757 |
| illustrated | Illustrated |
| index_date | 2024-07-02T13:51:07Z |
| indexdate | 2024-07-09T20:34:59Z |
| institution | BVB |
| isbn | 3527406298 9783527406296 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-014616522 |
| oclc_num | 181485166 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-703 DE-1051 DE-355 DE-BY-UBR DE-20 DE-19 DE-BY-UBM DE-384 DE-526 DE-634 DE-83 DE-11 DE-188 |
| owner_facet | DE-91G DE-BY-TUM DE-703 DE-1051 DE-355 DE-BY-UBR DE-20 DE-19 DE-BY-UBM DE-384 DE-526 DE-634 DE-83 DE-11 DE-188 |
| physical | XII, 386 S. Ill., graph. Darst. 240 mm x 170 mm |
| publishDate | 2006 |
| publishDateSearch | 2006 |
| publishDateSort | 2006 |
| publisher | WILEY-VCH |
| record_format | marc |
| series2 | Physics textbook |
| spelling | Butt, Hans-Jürgen 1961- Verfasser (DE-588)110921550 aut Physics and chemistry of interfaces Hans Jürgen Butt ; Karlheinz Graf ; Michael Kappl 2., rev. and enl. ed. Weinheim WILEY-VCH 2006 XII, 386 S. Ill., graph. Darst. 240 mm x 170 mm txt rdacontent n rdamedia nc rdacarrier Physics textbook Früher mit der ISBN 3527404139 Surface chemistry Surfaces (Physics) Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Grenzflächenphysik (DE-588)4452968-5 gnd rswk-swf Grenzflächenchemie (DE-588)4246080-3 gnd rswk-swf Oberflächenphysik (DE-588)4134881-3 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Oberflächenphysik (DE-588)4134881-3 s Oberflächenchemie (DE-588)4126166-5 s 1\p DE-604 Grenzflächenphysik (DE-588)4452968-5 s Grenzflächenchemie (DE-588)4246080-3 s 2\p DE-604 Graf, Karlheinz 1966- Verfasser (DE-588)120729075 aut Kappl, Michael 1963- Verfasser (DE-588)128798548 aut text/html http://deposit.dnb.de/cgi-bin/dokserv?id=2686609&prov=M&dok_var=1&dok_ext=htm Inhaltstext HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014616522&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Butt, Hans-Jürgen 1961- Graf, Karlheinz 1966- Kappl, Michael 1963- Physics and chemistry of interfaces Surface chemistry Surfaces (Physics) Oberflächenchemie (DE-588)4126166-5 gnd Grenzflächenphysik (DE-588)4452968-5 gnd Grenzflächenchemie (DE-588)4246080-3 gnd Oberflächenphysik (DE-588)4134881-3 gnd |
| subject_GND | (DE-588)4126166-5 (DE-588)4452968-5 (DE-588)4246080-3 (DE-588)4134881-3 (DE-588)4123623-3 |
| title | Physics and chemistry of interfaces |
| title_auth | Physics and chemistry of interfaces |
| title_exact_search | Physics and chemistry of interfaces |
| title_exact_search_txtP | Physics and chemistry of interfaces |
| title_full | Physics and chemistry of interfaces Hans Jürgen Butt ; Karlheinz Graf ; Michael Kappl |
| title_fullStr | Physics and chemistry of interfaces Hans Jürgen Butt ; Karlheinz Graf ; Michael Kappl |
| title_full_unstemmed | Physics and chemistry of interfaces Hans Jürgen Butt ; Karlheinz Graf ; Michael Kappl |
| title_short | Physics and chemistry of interfaces |
| title_sort | physics and chemistry of interfaces |
| topic | Surface chemistry Surfaces (Physics) Oberflächenchemie (DE-588)4126166-5 gnd Grenzflächenphysik (DE-588)4452968-5 gnd Grenzflächenchemie (DE-588)4246080-3 gnd Oberflächenphysik (DE-588)4134881-3 gnd |
| topic_facet | Surface chemistry Surfaces (Physics) Oberflächenchemie Grenzflächenphysik Grenzflächenchemie Oberflächenphysik Lehrbuch |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=2686609&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014616522&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT butthansjurgen physicsandchemistryofinterfaces AT grafkarlheinz physicsandchemistryofinterfaces AT kapplmichael physicsandchemistryofinterfaces |