Supercritical carbon dioxide in polymer reaction engineering:
Gespeichert in:
Format: | Buch |
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Sprache: | English |
Veröffentlicht: |
Weinheim
Wiley-VCH
2005
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Schriftenreihe: | Green chemistry
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Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XIX, 339 S. Ill., graph. Darst. |
ISBN: | 9783527310920 3527310924 |
Internformat
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245 | 1 | 0 | |a Supercritical carbon dioxide in polymer reaction engineering |c ed. by Maartje F. Kemmere ... |
264 | 1 | |a Weinheim |b Wiley-VCH |c 2005 | |
300 | |a XIX, 339 S. |b Ill., graph. Darst. | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
490 | 0 | |a Green chemistry | |
650 | 4 | |a Überkritischer Zustand - Kohlendioxid - Kunststoffverarbeitung | |
650 | 4 | |a Liquid carbon dioxide | |
650 | 4 | |a Polymerization | |
650 | 4 | |a Supercritical fluid extraction | |
650 | 0 | 7 | |a Kohlendioxid |0 (DE-588)4031648-8 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Überkritischer Zustand |0 (DE-588)4186602-2 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Kunststoffverarbeitung |0 (DE-588)4114335-8 |2 gnd |9 rswk-swf |
655 | 7 | |0 (DE-588)4143413-4 |a Aufsatzsammlung |2 gnd-content | |
689 | 0 | 0 | |a Überkritischer Zustand |0 (DE-588)4186602-2 |D s |
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689 | 0 | 2 | |a Kunststoffverarbeitung |0 (DE-588)4114335-8 |D s |
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Datensatz im Suchindex
_version_ | 1804135019210342400 |
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adam_text | CONTENTS FOREWORD V PREFACE VII LIST OF CONTRIBUTORS XVII SUPERCRITICAL
CARBON DIOXIDE FOR SUSTAINABLE POLYMER PROCESSES 1 MAARTJE KEMMERE
INTRODUCTION 1 STRATEGIC ORGANIC SOLVENT REPLACEMENT 3 PHYSICAL AND
CHEMICAL PROPERTIES OF SUPERCRITICAL CO2 5 INTERACTIONS OF CARBON
DIOXIDE WITH POLYMERS AND MONOMERS 8 CONCLUDING REMARKS AND OUTLOOK 11
NOTATION 12 REFERENCES 13 PHASE BEHAVIOR OF POLYMER SYSTEMS IN
HIGH-PRESSURE CARBON DIOXIDE 15 GABRIELE SADOWSKI INTRODUCTION 15
GENERAL PHASE BEHAVIOR IN POLYMER/SOLVENT SYSTEMS 15 POLYMER SOLUBILITY
IN CO2 19 THERMODYNAMIC MODELING 27 CONCLUSIONS 32 NOTATION 33
REFERENCES 34 SUPERCRITICAL CARBON DIOXIDE: IN POLYMER REACTION
ENGINEERING EDITED BY MAARTJE F. KEMMERE AND THIERRY MEYER COPYRIGHT 0
2005 WILEY-VCW VERLAG GMBH & CO. KGAA, WEINHEIM ISBN: 3-527-31092-4 X
CONTENTS I TRANSPORT PROPERTIES OF SUPERCRITICAL CARBON DIOXIDE 37
FREDET-IC LAVANCHY, ERIC FOURCADE, EVERT DE KOEGER, JOHAN WBERS, THIERRY
MEYER, AND JOS KEURENTJES INTRODUCTION 3 7 HYDRODYNAMICS AND MIXING 39
LASER-DOPPLER VELOCIMETRY AND COMPUTATIONAL FLUID DYNAMICS 39 FLOW
CHARACTERISTICS 41 HEAT TRANSFER 44 SPECIFIC FOR NEAR-CRITICAL FLUIDS:
TBE PISTON EFFECT 45 REACTION CALORIMETRY 46 HEAT TRANSFER IN STIRRED
VESSEL WITH SCFS 48 CONCLUSIONS 53 NOTATION 53 RFERENCES 54 KINETICS OF
FREE-RADICAL POLY M ERIZATION IN HO M OGENEOUS PHASE OF SUPERCRITICAL
CARBON DIOXIDE 55 SABINE BEUERMANN UND MICHAEL BUBACK INTRODUCTION 55
EXPERIMENTAL 57 INITIATION 57 PROPAGATION 62 PROPAGATION RATE
COEFFICIENTS 62 REACTIVITY RATIOS 67 TERMINATION 69 CHAIN TRANSFER 73
CONCLUSIONS 75 NOTATION 76 REFEERENCES 79 MONITORING READIONS IN
SUPERCRITICAL MEDIA 81 THIERRY MEYER, SOPHIE FORTINI, AND CHARALAMPOS
MANTELIS INTRODUCTION 81 ON-LINE ANALYTICAL METHODS USED IN SCF 82
SPECTROSCOPIC METHODS 82 FTIR 82 RAMAN SPECTROSCOPY 84 UV/VIS 85 NMR 87
REFLECTOMETRY 89 ACOUSTIC METHODS 89 CALORIMETRIC METHODS 90 POWER
COMPENSATION CALORIMETRY 90 HEAT FLOW CALORIMETRY 91 HEAT BALANCE
EQUATIONS 92 DETERMINATION OF PHYSICO-CHEMICAL PARAMETERS 95 CALORIMETER
VALIDATION BY HEAT GENERATION SIMULATION 96 MMA POLYMERIZATION AS AN
EXAMPLE 97 CALORIMETRIC RESULTS 97 THE COUPLING OF CALORIMETRY AND
ON-LINE ANALYSIS 100 CONCLUSIONS 101 NOTATION 102 REFE RE NCES 103
HETEROGENEOUS POLYMERIZATION IN SUPERCRITICAL CARBON DIOXIDE 105 PHILIPP
A. MUELLER, BARBARA BONAVOGLIA, CIUSEPPE STORTI, AND MASSIMO MORBIDELLI
INTRODUCTION 105 LITERATURE REVIEW 106 MODELING OF THE PROCESS 108 CASE
STUDY I: MMA DISPERSION POLYMERIZATION 115 CASE STUDY 11: VDF
PRECIPITATION POLYMERIZATION 124 CONCLUDING RE M ARKS AND OUTLOOK 132
NOTATION 133 REFERENCES 13 6 INVERSE EMULSION POLYMERIZATION IN CARBON
DIOXIDE 139 ERIC J. BECKMAN INTRODUCTION 13 9 INVERSE EMULSION
POLYMERIZATION IN COZ: DESIGN CONSTRAINTS 141 SURFACTANT DESIGN FOR
INVERSE EMULSION POLYMERIZATION 142 DESIGNING CO2-PHILIC COMPOUNDS: WHAT
CAN WE LEARN FROM FLUOROPOLYMER BEHAVIOR? 143 NON-FLUOROUS CO2-PHILES:
THE ROLE OF OXYGEN 144 INVERSE EMULSION POLYRNERIZATION IN CO2: RESULTS
148 FUTURE CHALLENGES 154 REFERENCES 154 CATALYTIC POLYMERIZATION OF
OLEFINS IN SUPERCRITICAL CARBON DIOXIDE 157 MAARTJE KEMMERE, TJERK J. DE
VRIES, AND JOS KEURENTJES INTRODUCTION 157 PHASE BEHAVIOR OF
POLYOLEFIN-MONOMER-CO2 SYSTEMS 158 CLOUD-POINT MEASUREMENTS ON THE
PEP-ETHYLENE-CO2 SYSTEM 158 SAFT MODELING OF THE PEP-ETHYLENE-CO2 SYSTEM
161 CATALYST SYSTEM 162 SOLUBILITY OF THE BROOKHART CATALYST IN SCC02
163 XI1 CONTENTS I 8.3.2 8.3.3 8.4 8.4.1 8.4.2 8.4.2.1 8.4.2.2 8.4.2.3
8.4.2.4 8.4.2.5 8.4.3 8.5 9 9.1 9.2 9.2.1 9.2.2 9.2.3 9.2.4 9.2.5 9.3
9.4 9.5 9.6 9.7 10 10.1 10.2 10.2.1 10.2.2 10.2.3 COPOLYRNERIZATION OF
ETHYLENE AND NORBORNENE USING A NEUTRAL PD-CATALYS T 165 RING-OPENING
METATHESIS POLYMERIZATION OF NORBORNENE USING AN MT0 CATALYST 166
POLYMERIZATION OF OLEFINS IN SUPERCRITICAL CO2 USING BROOKHART CATALYST
168 CATALYTIC POLYMERIZATION OF 1-HEXENE IN SUPERCRITICAL CO2 168
CATALYTIC POLYMERIZATION OF ETHYLENE IN SUPERCRITICAL CO2 170
EXPERIMENTAL PROCEDURE FOR POLYMERIZATION EXPERIMENTS 170 DETERMINATION
OF REACTION RATE 171 RESULTS OF THE ETHYLENE POLYRNERIZATIONS 173
MONITORING REACTION RATE USING SAFT-LKP AND SAFT-PR 175 TOPOLOGY OF
SYNTHESIZED POLYETHYLENES 177 COPOLYRNERIZATION OF ETHYLENE AND METHYL
ACRYLATE IN SUPERCRITICAL CO2 180 CONCLUDING REMARKS AND OUTLOOK 183
NOTATION 185 REFERENCES 186 PRODUCTION OF FLUOROPOLYMERS IN
SUPERCRITICAL CARBON DIOXIDE 189 COLIN D. WOOD, JASON C. YARBROUGH,
GEORGE ROBERTS, AND JOSEPH M. DESIMONE INTRODUCTION 189 FLUOROOLEFIN
POLYMERIZATION IN CO2 189 OVEWIEW 189 TFE-BASED MATERIALS 192 IONORNER
RESINS AND ~AFION@ 195 VF2-BASED MATERIALS 195 VF2 AND TFE
TELORNERIZATION 196 FLUOROALKYL ACRYLATE POLYRNERIZATIONS IN CO2 197
AMPHIPHILIC POLY(ALKYLACRY1ATES) 199 PHOTOOXIDATION OF FLUOROOLEFINS IN
LIQUID CO2 200 C02/AQUEOUS HYBRID SYSTEMS 202 CONCLUSIONS 202 REFERENC
203 POLYMER PROCESSING WITH SUPERCRITICAL FLUIDS 205 OLIVER 5. FLEMING
AND SERGE; G. KAZARIAN INTRODUCTION 205 PHASE BEHAVIOR OF C02/POLYRNER
SYSTEMS AND THE EFFECT OF CO2 ON POLYMERS 206 SOLUBILITY OF CO2 IN
POLYMERS 206 CO2-INDUCED PLASTICIZATION OF POLYMERS 207 CO2-INDUCED
CRYSTALLIZATION OF POLYMERS 208 INTERFACIAL TENSION IN C02/POLYRNER
SYSTEMS 21 1 DIFF U SION OF CO2 IN POLYMERS AND SOLUTES IN POLYMERS
SUBJECTED TO CO2 213 FOAMING 215 RHEOLOGY OF POLY M ERS UNDER
HIGH-PRESSURE CO2 218 METHODS FOR THE MEASUREMENTS OF POLYMER VISCOSITY
UNDER HIGH-PRESSURE CO2 218 VISCOSITY OF POLER MELTS SUBJECTED TO CO2
21 9 IMPLICATIONS FOR PROCESSING: EXTRUSION 220 POLYMER BLENDS AND CO2
222 CO2-ASSISTED BLENDING OF POLYMERS 222 CO2-INDUCED PHASE SEPARATION
IN POLYMER BLENDS 224 IMAGING OF POLYMERIC MATERIALS SUBJECTED TO
HIGH-PRESSURE CO2 226 SUPERCRITICAL IMPREGNATION OF POLYMERIC MATERIALS
228 DYEING OF POLYMERIC MATERIALS 229 PREPARATION OF MATERIALS FOR
OPTICAL APPLICATION 230 PREPARATION OF BIOMATERIALS AND PHARMACEUTICAL
FORRNULATIONS 230 CONCLUSIONS AND OUTLOOLC 232 NOTATION 233 REFERENCES
234 SYNTHESIS OF ADVANCED MATERIALS USING SUPERCRITICAL FLUIDS 239
ANDREW I. COOPER INTRODUCTION 239 POLYMER SYNTHESIS 239 REACTION
PRESSURE 240 INEXPENSIVE SURFACTANTS 240 POROUS MATERIALS 243 POROUS
MATERIALS BY SCF PROCESSING 243 POROUS MATERIALS BY CHEMICAL SYNTHESIS
245 NANOSCALE MATERIALS AND NANOCOMPOSITES 247 CONFORMAL META1 FILMS 247
SYNTHESIS OF NANOPARTICLES 247 SYNTHESIS OF NANOWIRES 248 LITHOGRAPHY
AND MICROELECTRONICS 249 SPIN COATING AND RESIST DEPOSITION 249
LITHOGRAPHIC DEVELOPMENT AND PHOTORESIST DRYING 250 ETCHING USING SCF
SOLVENTS 250 DRY CHEMICAL MECHANICAL PLANARIZATION 251 CONCLUSION AND
FUTURE OUTLOOK 251 REFERENCES 253 XIV CONTENTS I 12 12.1 12.2 12.3 12.4
12.4.1 12.4.2 12.5 12.5.1 12.5.2 12.5.3 12.5.4 12.6 7 3 13.1 13.2 13.3
13.3.1 13.3.1.1 13.3.2 13.3.2.1 13.3.2.2 13.3.2.3 13.3.3 13.3.3.1
13.3.3.2 13.3.4 13.3.4.1 13.3.4.2 13.3.4.3 13.3.5 13.4 13.4.1 13.4.2
POLYMER EXTRUSION WITH SUPERCRITICAL CARBON DIOXIDE 255 LEON P. B. M.
JANSSEN AND SAMEER P. NALAWADE INTRODUCTION 255 PRACTICAL BACKGROUND ON
EXTRUSION 256 SUPERCRITICAL CO2-ASSISTED E XTR USION 257 MIXING AND
HOMOGENIZATION 260 DISSOLUTION OF GAS INTO POLY M ER MELT 260 DIFFUSION
INTO THE POLYMER MELT 261 APPLICATIONS 262 POLYMER BLENDING 262
MICROCELLULAR FOAMING 265 PARTICLE PRODUCTION 268 REACTIVE EXTRUSION 269
CONCLUDING REMARKS 270 NOTATION 271 REFERENCES 271 CHEMICAL MODIFICATION
OF POLYMERS IN SUPERCRITICAL CARBON DIOXIDE 273 JESSE M. DE COOIJER UND
COR E. KONING INTRODUCTION 273 BRIEF REVIEW OF THE STATE OF THE ART 275
END-GROUP MODIFICATION OF POLYAMIDE G IN SUPERCRITICAL C02 277
BACKGROUND 277 SORPTION AND DIFFUSION 278 AMINE END-GROUP MODIFICATION
WITH SUCCINIC ANHYDRIDE 279 SORPTION MEASUREMENTS 28 1 MELT STABILITY OF
MODIFIED AND UNRNODIFIED PA4 285 CONCLUSIONS 286 AMINE AND CARBOXYLIC
ACID END-GROUP MODIFICATION WITH 1,2-EPOXYBUTANE 286 MELT STABILITY OF
MODIFIED AND UNMODIFIED PA-G 289 CONCLUSIONS 289 AMINE END-GROUP
MODIFICATION WITH DIKETENE AND DIKETENE ACETONE ADDUCT 289 MODIFICATION
OF PA-G GRANULES WITH DIKETENE AND DIKETENE ACETONE ADDUCT IN
SUPERCRITICAL AND SUBCRITICAL CO2 290 MOLECULAR CHARACTERIZATION 291
CONCLUSIONS 292 GENERAL CONCLUSIONS ON POLYAMIDE MODIFICATION 292
CARBOXYLIC ACID END-GROUP MODIFICATION OF POLY(BUTY1ENE TEREPHTHALATE)
WITH 1,2-EPOXYBUTANE IN SUPERCRITICAL CO2 292 BACKGROUND 292 CHERNICAL
MODIFICATION OF PBT WITH 1,2-EPOXYBUTANE 293 INFLUENCE OF ACID
END-GROUP CONCENTRATION ON HYDROLYTIC STABILITY 296 DETERMINATION OF
MOLECULAR WEIGHTS 296 GENERAL CONCLUSIONS CONCERNING PBT MODIFICATION
297 CONCLUDING REMARKS AND OUTLOOK 297 NOTATION 298 REFERENCES 299
REDUCTION OF RESIDUAL MONOMER IN LATEX PRODUCTS USING HIGH-PRESSURE
CARBON DIOXIDE 303 MAAR TJ E F. KEMMERE, MARCUS VAN SCHILT, MARC JACOBS,
AND JOS KEURENTJES INTRODUCTION 303 OVERVIEW OF TECHNIQUES FOR REDUCTION
OF RESIDUAL MONOMER 304 CONVERSION OF RESIDUAL MONOMER 305 REMOVAL OF
RESIDUAL MONOMER 305 ALTERNATIVE TECHNOLOGY HIGH-PRESSURE CARBON DIOXIDE
307 ENHANCED POLYMERIZATION IN HIGH-PRESSURE CARBON DIOXIDE 307
PROCEDURE FOR PULSED ELECTRON BEAM EXPERIMENTS 308 RESULTS AND
DISCUSSION 308 EXTRACTION CAPACITY OF CARBON DIOXIDE 3 10 MODELING PHASE
BEHAVIOR WITH THE PENG-ROBINSON EQUATION OF STATE 3 11 PROCEDURE FOR
MEASURING MONOMER PARTITION COEFFICIENTS 3 13 VALIDATION OF THE
EXPERIMENTAL DETERMINATION OF PARTITION COEFFICIENTS 3 15 MEASURED
PARTITION COEFFICIENTS OF MMA OVER WATER AND CO2 31 6 PREDICTION OF
PARTITION COEFFICIENTS OF MMA OVER WATER AND CO2 31 9 MODELING THE
TWO-COMPONENT SYSTEMS CO2-H20, MMA-CO2 AND MMA-H20 320 MODELING THE
THREE-COMPONENT SYSTEM CO2-H20-MMA 320 PROCESS DESIGN FOR THE REMOVAL OF
MMA FROM A PMMA LATEX USING COZ 323 EXTRACTION MODEL 323 DIFFUSION AND
MASS TRANSFER COEFFICIENTS 324 PARTITION COEFFICIENTS 326 INTERFACIAL
SURFACE AREAS 326 PROCESS FLOW DIAGRAM, EQUIPMENT SELECTION, AND
EQUIPMENT SIZING 326 ECONOMIC EVALUATION 328 CONCLUSION AND FUTURE
OUTLOO K 330 NOTATION 330 REFERENCES 332 SUBJECT INDEX 335
|
adam_txt |
CONTENTS FOREWORD V PREFACE VII LIST OF CONTRIBUTORS XVII SUPERCRITICAL
CARBON DIOXIDE FOR SUSTAINABLE POLYMER PROCESSES 1 MAARTJE KEMMERE
INTRODUCTION 1 STRATEGIC ORGANIC SOLVENT REPLACEMENT 3 PHYSICAL AND
CHEMICAL PROPERTIES OF SUPERCRITICAL CO2 5 INTERACTIONS OF CARBON
DIOXIDE WITH POLYMERS AND MONOMERS 8 CONCLUDING REMARKS AND OUTLOOK 11
NOTATION 12 REFERENCES 13 PHASE BEHAVIOR OF POLYMER SYSTEMS IN
HIGH-PRESSURE CARBON DIOXIDE 15 GABRIELE SADOWSKI INTRODUCTION 15
GENERAL PHASE BEHAVIOR IN POLYMER/SOLVENT SYSTEMS 15 POLYMER SOLUBILITY
IN CO2 19 THERMODYNAMIC MODELING 27 CONCLUSIONS 32 NOTATION 33
REFERENCES 34 SUPERCRITICAL CARBON DIOXIDE: IN POLYMER REACTION
ENGINEERING EDITED BY MAARTJE F. KEMMERE AND THIERRY MEYER COPYRIGHT 0
2005 WILEY-VCW VERLAG GMBH & CO. KGAA, WEINHEIM ISBN: 3-527-31092-4 X
CONTENTS I TRANSPORT PROPERTIES OF SUPERCRITICAL CARBON DIOXIDE 37
FREDET-IC LAVANCHY, ERIC FOURCADE, EVERT DE KOEGER, JOHAN WBERS, THIERRY
MEYER, AND JOS KEURENTJES INTRODUCTION 3 7 HYDRODYNAMICS AND MIXING 39
LASER-DOPPLER VELOCIMETRY AND COMPUTATIONAL FLUID DYNAMICS 39 FLOW
CHARACTERISTICS 41 HEAT TRANSFER 44 SPECIFIC FOR NEAR-CRITICAL FLUIDS:
TBE PISTON EFFECT 45 REACTION CALORIMETRY 46 HEAT TRANSFER IN STIRRED
VESSEL WITH SCFS 48 CONCLUSIONS 53 NOTATION 53 RFERENCES 54 KINETICS OF
FREE-RADICAL POLY M ERIZATION IN HO M OGENEOUS PHASE OF SUPERCRITICAL
CARBON DIOXIDE 55 SABINE BEUERMANN UND MICHAEL BUBACK INTRODUCTION 55
EXPERIMENTAL 57 INITIATION 57 PROPAGATION 62 PROPAGATION RATE
COEFFICIENTS 62 REACTIVITY RATIOS 67 TERMINATION 69 CHAIN TRANSFER 73
CONCLUSIONS 75 NOTATION 76 REFEERENCES 79 MONITORING READIONS IN
SUPERCRITICAL MEDIA 81 THIERRY MEYER, SOPHIE FORTINI, AND CHARALAMPOS
MANTELIS INTRODUCTION 81 ON-LINE ANALYTICAL METHODS USED IN SCF 82
SPECTROSCOPIC METHODS 82 FTIR 82 RAMAN SPECTROSCOPY 84 UV/VIS 85 NMR 87
REFLECTOMETRY 89 ACOUSTIC METHODS 89 CALORIMETRIC METHODS 90 POWER
COMPENSATION CALORIMETRY 90 HEAT FLOW CALORIMETRY 91 HEAT BALANCE
EQUATIONS 92 DETERMINATION OF PHYSICO-CHEMICAL PARAMETERS 95 CALORIMETER
VALIDATION BY HEAT GENERATION SIMULATION 96 MMA POLYMERIZATION AS AN
EXAMPLE 97 CALORIMETRIC RESULTS 97 THE COUPLING OF CALORIMETRY AND
ON-LINE ANALYSIS 100 CONCLUSIONS 101 NOTATION 102 REFE RE NCES 103
HETEROGENEOUS POLYMERIZATION IN SUPERCRITICAL CARBON DIOXIDE 105 PHILIPP
A. MUELLER, BARBARA BONAVOGLIA, CIUSEPPE STORTI, AND MASSIMO MORBIDELLI
INTRODUCTION 105 LITERATURE REVIEW 106 MODELING OF THE PROCESS 108 CASE
STUDY I: MMA DISPERSION POLYMERIZATION 115 CASE STUDY 11: VDF
PRECIPITATION POLYMERIZATION 124 CONCLUDING RE M ARKS AND OUTLOOK 132
NOTATION 133 REFERENCES 13 6 INVERSE EMULSION POLYMERIZATION IN CARBON
DIOXIDE 139 ERIC J. BECKMAN INTRODUCTION 13 9 INVERSE EMULSION
POLYMERIZATION IN COZ: DESIGN CONSTRAINTS 141 SURFACTANT DESIGN FOR
INVERSE EMULSION POLYMERIZATION 142 DESIGNING CO2-PHILIC COMPOUNDS: WHAT
CAN WE LEARN FROM FLUOROPOLYMER BEHAVIOR? 143 NON-FLUOROUS CO2-PHILES:
THE ROLE OF OXYGEN 144 INVERSE EMULSION POLYRNERIZATION IN CO2: RESULTS
148 FUTURE CHALLENGES 154 REFERENCES 154 CATALYTIC POLYMERIZATION OF
OLEFINS IN SUPERCRITICAL CARBON DIOXIDE 157 MAARTJE KEMMERE, TJERK J. DE
VRIES, AND JOS KEURENTJES INTRODUCTION 157 PHASE BEHAVIOR OF
POLYOLEFIN-MONOMER-CO2 SYSTEMS 158 CLOUD-POINT MEASUREMENTS ON THE
PEP-ETHYLENE-CO2 SYSTEM 158 SAFT MODELING OF THE PEP-ETHYLENE-CO2 SYSTEM
161 CATALYST SYSTEM 162 SOLUBILITY OF THE BROOKHART CATALYST IN SCC02
163 XI1 CONTENTS I 8.3.2 8.3.3 8.4 8.4.1 8.4.2 8.4.2.1 8.4.2.2 8.4.2.3
8.4.2.4 8.4.2.5 8.4.3 8.5 9 9.1 9.2 9.2.1 9.2.2 9.2.3 9.2.4 9.2.5 9.3
9.4 9.5 9.6 9.7 10 10.1 10.2 10.2.1 10.2.2 10.2.3 COPOLYRNERIZATION OF
ETHYLENE AND NORBORNENE USING A NEUTRAL PD-CATALYS T 165 RING-OPENING
METATHESIS POLYMERIZATION OF NORBORNENE USING AN MT0 CATALYST 166
POLYMERIZATION OF OLEFINS IN SUPERCRITICAL CO2 USING BROOKHART CATALYST
168 CATALYTIC POLYMERIZATION OF 1-HEXENE IN SUPERCRITICAL CO2 168
CATALYTIC POLYMERIZATION OF ETHYLENE IN SUPERCRITICAL CO2 170
EXPERIMENTAL PROCEDURE FOR POLYMERIZATION EXPERIMENTS 170 DETERMINATION
OF REACTION RATE 171 RESULTS OF THE ETHYLENE POLYRNERIZATIONS 173
MONITORING REACTION RATE USING SAFT-LKP AND SAFT-PR 175 TOPOLOGY OF
SYNTHESIZED POLYETHYLENES 177 COPOLYRNERIZATION OF ETHYLENE AND METHYL
ACRYLATE IN SUPERCRITICAL CO2 180 CONCLUDING REMARKS AND OUTLOOK 183
NOTATION 185 REFERENCES 186 PRODUCTION OF FLUOROPOLYMERS IN
SUPERCRITICAL CARBON DIOXIDE 189 COLIN D. WOOD, JASON C. YARBROUGH,
GEORGE ROBERTS, AND JOSEPH M. DESIMONE INTRODUCTION 189 FLUOROOLEFIN
POLYMERIZATION IN CO2 189 OVEWIEW 189 TFE-BASED MATERIALS 192 IONORNER
RESINS AND ~AFION@ 195 VF2-BASED MATERIALS 195 VF2 AND TFE
TELORNERIZATION 196 FLUOROALKYL ACRYLATE POLYRNERIZATIONS IN CO2 197
AMPHIPHILIC POLY(ALKYLACRY1ATES) 199 PHOTOOXIDATION OF FLUOROOLEFINS IN
LIQUID CO2 200 C02/AQUEOUS HYBRID SYSTEMS 202 CONCLUSIONS 202 REFERENC
203 POLYMER PROCESSING WITH SUPERCRITICAL FLUIDS 205 OLIVER 5. FLEMING
AND SERGE; G. KAZARIAN INTRODUCTION 205 PHASE BEHAVIOR OF C02/POLYRNER
SYSTEMS AND THE EFFECT OF CO2 ON POLYMERS 206 SOLUBILITY OF CO2 IN
POLYMERS 206 CO2-INDUCED PLASTICIZATION OF POLYMERS 207 CO2-INDUCED
CRYSTALLIZATION OF POLYMERS 208 INTERFACIAL TENSION IN C02/POLYRNER
SYSTEMS 21 1 DIFF U SION OF CO2 IN POLYMERS AND SOLUTES IN POLYMERS
SUBJECTED TO CO2 213 FOAMING 215 RHEOLOGY OF POLY M ERS UNDER
HIGH-PRESSURE CO2 218 METHODS FOR THE MEASUREMENTS OF POLYMER VISCOSITY
UNDER HIGH-PRESSURE CO2 218 VISCOSITY OF POLER MELTS SUBJECTED TO CO2
21 9 IMPLICATIONS FOR PROCESSING: EXTRUSION 220 POLYMER BLENDS AND CO2
222 CO2-ASSISTED BLENDING OF POLYMERS 222 CO2-INDUCED PHASE SEPARATION
IN POLYMER BLENDS 224 IMAGING OF POLYMERIC MATERIALS SUBJECTED TO
HIGH-PRESSURE CO2 226 SUPERCRITICAL IMPREGNATION OF POLYMERIC MATERIALS
228 DYEING OF POLYMERIC MATERIALS 229 PREPARATION OF MATERIALS FOR
OPTICAL APPLICATION 230 PREPARATION OF BIOMATERIALS AND PHARMACEUTICAL
FORRNULATIONS 230 CONCLUSIONS AND OUTLOOLC 232 NOTATION 233 REFERENCES
234 SYNTHESIS OF ADVANCED MATERIALS USING SUPERCRITICAL FLUIDS 239
ANDREW I. COOPER INTRODUCTION 239 POLYMER SYNTHESIS 239 REACTION
PRESSURE 240 INEXPENSIVE SURFACTANTS 240 POROUS MATERIALS 243 POROUS
MATERIALS BY SCF PROCESSING 243 POROUS MATERIALS BY CHEMICAL SYNTHESIS
245 NANOSCALE MATERIALS AND NANOCOMPOSITES 247 CONFORMAL META1 FILMS 247
SYNTHESIS OF NANOPARTICLES 247 SYNTHESIS OF NANOWIRES 248 LITHOGRAPHY
AND MICROELECTRONICS 249 SPIN COATING AND RESIST DEPOSITION 249
LITHOGRAPHIC DEVELOPMENT AND PHOTORESIST DRYING 250 ETCHING USING SCF
SOLVENTS 250 "DRY" CHEMICAL MECHANICAL PLANARIZATION 251 CONCLUSION AND
FUTURE OUTLOOK 251 REFERENCES 253 XIV CONTENTS I 12 12.1 12.2 12.3 12.4
12.4.1 12.4.2 12.5 12.5.1 12.5.2 12.5.3 12.5.4 12.6 7 3 13.1 13.2 13.3
13.3.1 13.3.1.1 13.3.2 13.3.2.1 13.3.2.2 13.3.2.3 13.3.3 13.3.3.1
13.3.3.2 13.3.4 13.3.4.1 13.3.4.2 13.3.4.3 13.3.5 13.4 13.4.1 13.4.2
POLYMER EXTRUSION WITH SUPERCRITICAL CARBON DIOXIDE 255 LEON P. B. M.
JANSSEN AND SAMEER P. NALAWADE INTRODUCTION 255 PRACTICAL BACKGROUND ON
EXTRUSION 256 SUPERCRITICAL CO2-ASSISTED E XTR USION 257 MIXING AND
HOMOGENIZATION 260 DISSOLUTION OF GAS INTO POLY M ER MELT 260 DIFFUSION
INTO THE POLYMER MELT 261 APPLICATIONS 262 POLYMER BLENDING 262
MICROCELLULAR FOAMING 265 PARTICLE PRODUCTION 268 REACTIVE EXTRUSION 269
CONCLUDING REMARKS 270 NOTATION 271 REFERENCES 271 CHEMICAL MODIFICATION
OF POLYMERS IN SUPERCRITICAL CARBON DIOXIDE 273 JESSE M. DE COOIJER UND
COR E. KONING INTRODUCTION 273 BRIEF REVIEW OF THE STATE OF THE ART 275
END-GROUP MODIFICATION OF POLYAMIDE G IN SUPERCRITICAL C02 277
BACKGROUND 277 SORPTION AND DIFFUSION 278 AMINE END-GROUP MODIFICATION
WITH SUCCINIC ANHYDRIDE 279 SORPTION MEASUREMENTS 28 1 MELT STABILITY OF
MODIFIED AND UNRNODIFIED PA4 285 CONCLUSIONS 286 AMINE AND CARBOXYLIC
ACID END-GROUP MODIFICATION WITH 1,2-EPOXYBUTANE 286 MELT STABILITY OF
MODIFIED AND UNMODIFIED PA-G 289 CONCLUSIONS 289 AMINE END-GROUP
MODIFICATION WITH DIKETENE AND DIKETENE ACETONE ADDUCT 289 MODIFICATION
OF PA-G GRANULES WITH DIKETENE AND DIKETENE ACETONE ADDUCT IN
SUPERCRITICAL AND SUBCRITICAL CO2 290 MOLECULAR CHARACTERIZATION 291
CONCLUSIONS 292 GENERAL CONCLUSIONS ON POLYAMIDE MODIFICATION 292
CARBOXYLIC ACID END-GROUP MODIFICATION OF POLY(BUTY1ENE TEREPHTHALATE)
WITH 1,2-EPOXYBUTANE IN SUPERCRITICAL CO2 292 BACKGROUND 292 CHERNICAL
MODIFICATION OF PBT WITH 1,2-EPOXYBUTANE 293 INFLUENCE OF ACID
END-GROUP CONCENTRATION ON HYDROLYTIC STABILITY 296 DETERMINATION OF
MOLECULAR WEIGHTS 296 GENERAL CONCLUSIONS CONCERNING PBT MODIFICATION
297 CONCLUDING REMARKS AND OUTLOOK 297 NOTATION 298 REFERENCES 299
REDUCTION OF RESIDUAL MONOMER IN LATEX PRODUCTS USING HIGH-PRESSURE
CARBON DIOXIDE 303 MAAR TJ E F. KEMMERE, MARCUS VAN SCHILT, MARC JACOBS,
AND JOS KEURENTJES INTRODUCTION 303 OVERVIEW OF TECHNIQUES FOR REDUCTION
OF RESIDUAL MONOMER 304 CONVERSION OF RESIDUAL MONOMER 305 REMOVAL OF
RESIDUAL MONOMER 305 ALTERNATIVE TECHNOLOGY HIGH-PRESSURE CARBON DIOXIDE
307 ENHANCED POLYMERIZATION IN HIGH-PRESSURE CARBON DIOXIDE 307
PROCEDURE FOR PULSED ELECTRON BEAM EXPERIMENTS 308 RESULTS AND
DISCUSSION 308 EXTRACTION CAPACITY OF CARBON DIOXIDE 3 10 MODELING PHASE
BEHAVIOR WITH THE PENG-ROBINSON EQUATION OF STATE 3 11 PROCEDURE FOR
MEASURING MONOMER PARTITION COEFFICIENTS 3 13 VALIDATION OF THE
EXPERIMENTAL DETERMINATION OF PARTITION COEFFICIENTS 3 15 MEASURED
PARTITION COEFFICIENTS OF MMA OVER WATER AND CO2 31 6 PREDICTION OF
PARTITION COEFFICIENTS OF MMA OVER WATER AND CO2 31 9 MODELING THE
TWO-COMPONENT SYSTEMS CO2-H20, MMA-CO2 AND MMA-H20 320 MODELING THE
THREE-COMPONENT SYSTEM CO2-H20-MMA 320 PROCESS DESIGN FOR THE REMOVAL OF
MMA FROM A PMMA LATEX USING COZ 323 EXTRACTION MODEL 323 DIFFUSION AND
MASS TRANSFER COEFFICIENTS 324 PARTITION COEFFICIENTS 326 INTERFACIAL
SURFACE AREAS 326 PROCESS FLOW DIAGRAM, EQUIPMENT SELECTION, AND
EQUIPMENT SIZING 326 ECONOMIC EVALUATION 328 CONCLUSION AND FUTURE
OUTLOO K 330 NOTATION 330 REFERENCES 332 SUBJECT INDEX 335 |
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ctrlnum | (OCoLC)254112794 (DE-599)BVBBV021250348 |
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discipline_str_mv | Chemie / Pharmazie Physik Chemie Werkstoffwissenschaften Chemie-Ingenieurwesen |
format | Book |
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genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
genre_facet | Aufsatzsammlung |
id | DE-604.BV021250348 |
illustrated | Illustrated |
index_date | 2024-07-02T13:39:15Z |
indexdate | 2024-07-09T20:33:51Z |
institution | BVB |
isbn | 9783527310920 3527310924 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-014571761 |
oclc_num | 254112794 |
open_access_boolean | |
owner | DE-29T DE-703 DE-M49 DE-BY-TUM DE-83 |
owner_facet | DE-29T DE-703 DE-M49 DE-BY-TUM DE-83 |
physical | XIX, 339 S. Ill., graph. Darst. |
publishDate | 2005 |
publishDateSearch | 2005 |
publishDateSort | 2005 |
publisher | Wiley-VCH |
record_format | marc |
series2 | Green chemistry |
spelling | Supercritical carbon dioxide in polymer reaction engineering ed. by Maartje F. Kemmere ... Weinheim Wiley-VCH 2005 XIX, 339 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Green chemistry Überkritischer Zustand - Kohlendioxid - Kunststoffverarbeitung Liquid carbon dioxide Polymerization Supercritical fluid extraction Kohlendioxid (DE-588)4031648-8 gnd rswk-swf Überkritischer Zustand (DE-588)4186602-2 gnd rswk-swf Kunststoffverarbeitung (DE-588)4114335-8 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Überkritischer Zustand (DE-588)4186602-2 s Kohlendioxid (DE-588)4031648-8 s Kunststoffverarbeitung (DE-588)4114335-8 s DE-604 Kemmere, Maartje F. 1971- Sonstige (DE-588)130461326 oth OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014571761&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Supercritical carbon dioxide in polymer reaction engineering Überkritischer Zustand - Kohlendioxid - Kunststoffverarbeitung Liquid carbon dioxide Polymerization Supercritical fluid extraction Kohlendioxid (DE-588)4031648-8 gnd Überkritischer Zustand (DE-588)4186602-2 gnd Kunststoffverarbeitung (DE-588)4114335-8 gnd |
subject_GND | (DE-588)4031648-8 (DE-588)4186602-2 (DE-588)4114335-8 (DE-588)4143413-4 |
title | Supercritical carbon dioxide in polymer reaction engineering |
title_auth | Supercritical carbon dioxide in polymer reaction engineering |
title_exact_search | Supercritical carbon dioxide in polymer reaction engineering |
title_exact_search_txtP | Supercritical carbon dioxide in polymer reaction engineering |
title_full | Supercritical carbon dioxide in polymer reaction engineering ed. by Maartje F. Kemmere ... |
title_fullStr | Supercritical carbon dioxide in polymer reaction engineering ed. by Maartje F. Kemmere ... |
title_full_unstemmed | Supercritical carbon dioxide in polymer reaction engineering ed. by Maartje F. Kemmere ... |
title_short | Supercritical carbon dioxide in polymer reaction engineering |
title_sort | supercritical carbon dioxide in polymer reaction engineering |
topic | Überkritischer Zustand - Kohlendioxid - Kunststoffverarbeitung Liquid carbon dioxide Polymerization Supercritical fluid extraction Kohlendioxid (DE-588)4031648-8 gnd Überkritischer Zustand (DE-588)4186602-2 gnd Kunststoffverarbeitung (DE-588)4114335-8 gnd |
topic_facet | Überkritischer Zustand - Kohlendioxid - Kunststoffverarbeitung Liquid carbon dioxide Polymerization Supercritical fluid extraction Kohlendioxid Überkritischer Zustand Kunststoffverarbeitung Aufsatzsammlung |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014571761&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT kemmeremaartjef supercriticalcarbondioxideinpolymerreactionengineering |