Thermodynamics in mineral sciences: an introduction
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English German |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2005
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVI, 386 S. graph. Darst. |
| ISBN: | 354024364X 9783540243649 |
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Datensatz im Suchindex
| _version_ | 1805083685402181632 |
|---|---|
| adam_text |
LADISLAV CEMIC THERMODYNAMICS IN MINERAL SCIENCES AN INTRODUCTION WITH
82 FIGURES AND 23 TABLES 4UE SPRINGER CONTENTS CHAPTER 1 DEFINITION
OFTHERMODYNAMIC TERMS 1 1.1 SYSTEMS 1 1.2 PHASE 2 1.3 COMPONENTS 3 1.4
FUNCTIONS AND VARIABLES OF STATE 5 1.5 THE CONCEPT OFTHERMODYNAMIC
EQUILIBRIUM 7 1.6 TEMPERATURE 7 1.7PRESSURE 10 1.8 COMPOSITION 10 1.8.
1. GRAPHIC REPRESENTATION OF COMPOSITION 11 1.9 PROBLEMS 21 CHAPTER 2
VOLUME AS A STATE FUNCTION 23 2.1 VOLUME OF PURE PHASES 23 2.1.1 THERMAL
EXPANSION AND COMPRESSIBILITY 25 EXAMPLES OF CALCULATED THERMAL
EXPANSION AND COMPRESSIBILITY 28 2.1.2 VOLUME OF IDEAL GASES AS A STATE
FUNCTION 34 2.1.3 VOLUME OF REAL GASES 37 2.1.4 VOLUME OF SOLID PHASES
43 CALCULATION OF MOLAR VOLUME USING X-RAY DIFFRACTION DATA 46 2.2
VOLUME OF SOLUTIONS 47 2.2.1 PARTIAL MOLAR VOLUME 48 2.2.2 VOLUME
RELATIONSHIPS IN BINARY SOLUTIONS 51 2.2.3 VOLUME CHANGES ON MIXING 56
2.2.4 EXAMPLES FORTHE VOLUMES OF BINARY SOLUTIONS 60 2.2.5 VOLUME
OFREACTION 73 2.3 PROBLEMS 75 CHAPTER 3 THE FIRST LAW OF THERMODYNAMICS
78 3.1 THE RELATIONSHIP BETWEEN HEAT AND WORK 78 3.2 INTERNAL ENERGY 78
3.2.1 WORK 79 3.2.2 ENTHALPY 83 3.3 APPLICATION OF THE FIRST LAW OF
THERMODYNAMICS TO PURE PHASES 84 VIII CONTENTS 3.3.1 HEAT CAPACITIES C V
AND C P 86 THE TEMPERATURE DEPENDENCE OF HEAT CAPACITY 91 THE EMPIRICAL
REPRESENTATION OF HEAT CAPACITIES 98 3.3.2 ENTHALPY, H, OF PURE PHASES
AS A FUNCTION OF TEMPERATURE 101 3.4 ENTHALPY OF SOLUTIONS 106 3.4.1
ENTHALPY OF BINARY SOLUTION 107 3.4.2 EXAMPLES OF ENTHALPY OF MIXING IN
BINARY SOLUTIONS 110 3.5 ENTHALPY OFREACTION 116 3.5.1 TEMPERATURE
DEPENDENCE OF THE ENTHALPY OFREACTION 119 3.5.2 HESS'S LAW 122 3.6
PROBLEMS 124 CHAPTER 4 SECOND LAW OF THERMODYNAMICS 129 4.1 ENTROPY 130
4.2 CLASSICAL DEFINITION OF ENTROPY 130 4.2.1 ENTROPY OF PURE PHASES 131
4.2.2 ADIABATIC CHANGES 136 4.2.3 TEMPERATURE DEPENDENCE OF ENTROPY 137
4.2.4 ENTROPY CHANGES ASSOCIATED WITH IRREVERSIBLE PROCESSES 140 4.3
STATISTICAL INTERPRETATION OF ENTROPY 144 4.3.1 THERMAL ENTROPY 145
4.3.2 CONFIGURATIONAL ENTROPY (ENTROPY OF MIXING) 149 4.4 ENTROPY
OFREACTION 160 4.4.1 TEMPERATURE DEPENDENCE OF THE ENTROPY OFREACTION
160 4.5 PROBLEMS 163 CHAPTER 5 GIBBS FREE ENERGY AND HELMHOLTZ FREE
ENERGY 165 5.1 CHEMICAL POTENTIAL OF PURE PHASES 168 5.1.1 CHEMICAL
POTENTIAL OF IDEAL GASES 168 5.1.2 CHEMICAL POTENTIAL OF NON-IDEAL GASES
169 5.2 THE CHEMICAL POTENTIAL OF COMPONENTS IN SOLUTIONS 173 5.2.1
CHEMICAL POTENTIAL OF AN IDEAL GAS IN AN IDEAL SOLUTION 176 5.2.2
CHEMICAL POTENTIAL OF A REAL GAS IN IDEAL AND NON-IDEAL GAS MIXTURES.
177 5.2.3 CHEMICAL POTENTIAL OF COMPONENTS IN IDEAL SOLID SOLUTIONS 181
5.2.4 CHEMICAL POTENTIAL OF COMPONENTS IN NON-IDEAL SOLID SOLUTIONS 183
ACTIVITY AND ACTIVITY COEFFICIENT AS A FUNCTION OF COMPOSITION 184 5.2.5
THE STANDARD STATE 186 THE ACTIVITY COEFFICIENT AS A FUNCTION OF
TEMPERATURE AND PRESSURE 189 5.3 GIBBS FREE ENERGY OF MIXING 191 5.3.1
MIXING AND ACTIVITY MODELS 194 5.4 GIBBS FREE ENERGY OFREACTION 214
CONTENTS 5.4.1 STANDARD GIBBS FREE ENERGY OFREACTION 215 5.5 PROBLEMS
216 CHAPTER 6 THERMAL EQUILIBRIUM 218 6.1 STABILITY CONDITIONS FOR
PHASES IN ONE-COMPONENT SYSTEMS 220 6.1.1 PHASE EQUILIBRIA IN
ONE-COMPONENT SYSTEMS 223 6.1.2 CLASSIFICATION OF PHASE TRANSFORMATIONS
227 6.2 STABILITY CONDITIONS FOR SOLUTIONS 237 6.2.1 COHERENT EXSOLUTION
244 6.3 GIBBS FREE ENERGY AND PHASE DIAGRAMS OF BINARY SYSTEMS 249 6.3.1
CALCULATION OF PHASE DIAGRAMS FROM THERMODYNAMIC DATA 253 CRITICAL
MIXING CONDITIONS, BINODAL, SPINODAL 253 SIMPLE EUTECTIC SYSTEM 259
BINARY SYSTEM WITH COMPLETE MISCIBILITY OF THE COMPONENTS IN TWO PHAS-
ES 265 6.4 GIBBS PHASE RULE 272 6.5 PROBLEMS 275 CHAPTER 7 CHEMICAL
REACTIONS 277 7.1 PHASE EQUILIBRIA IN REACTING SYSTEMS 277 7.1.1
REACTIONS IN SYSTEMS CONTAINING PURE SOLID PHASES 278 7.1.2 REACTIONS IN
SYSTEMS CONTAINING SOLID SOLUTIONS 288 7.1.3 REACTIONS IN SYSTEMS
CONTAINING SOLID AND GAS PHASES 291 7.1.4 DISTRIBUTION COEFFICIENT, K D
306 RECIPROCAL SOLUTIONS 313 ENERGETICS OF ORDER-DISORDER 325 7.2
PROBLEMS 339 CHAPTER 8 GEOTHERMOMETRY AND GEOBAROMETRY 343 8.1 EXCHANGE
GEOTHERMOMETERS 345 8.2 SOLVUS THERMOMETRY 349 8.3 SOLID-SOLID REACTIONS
354 8.3.1 REACTIONS IN ONE-COMPONENT SYSTEM 354 8.3.2 REACTIONS IN
MULTICOMPONENT SYSTEMS 355 8.4 REACTIONS INVOLVING GASEOUS PHASES 358
SOLUTIONS TO PROBLEMS 365 REFERENCES 371 SUBJECT INDEX 381 |
| adam_txt |
LADISLAV CEMIC THERMODYNAMICS IN MINERAL SCIENCES AN INTRODUCTION WITH
82 FIGURES AND 23 TABLES 4UE SPRINGER CONTENTS CHAPTER 1 DEFINITION
OFTHERMODYNAMIC TERMS 1 1.1 SYSTEMS 1 1.2 PHASE 2 1.3 COMPONENTS 3 1.4
FUNCTIONS AND VARIABLES OF STATE 5 1.5 THE CONCEPT OFTHERMODYNAMIC
EQUILIBRIUM 7 1.6 TEMPERATURE 7 1.7PRESSURE 10 1.8 COMPOSITION 10 1.8.
1. GRAPHIC REPRESENTATION OF COMPOSITION 11 1.9 PROBLEMS 21 CHAPTER 2
VOLUME AS A STATE FUNCTION 23 2.1 VOLUME OF PURE PHASES 23 2.1.1 THERMAL
EXPANSION AND COMPRESSIBILITY 25 EXAMPLES OF CALCULATED THERMAL
EXPANSION AND COMPRESSIBILITY 28 2.1.2 VOLUME OF IDEAL GASES AS A STATE
FUNCTION 34 2.1.3 VOLUME OF REAL GASES 37 2.1.4 VOLUME OF SOLID PHASES
43 CALCULATION OF MOLAR VOLUME USING X-RAY DIFFRACTION DATA 46 2.2
VOLUME OF SOLUTIONS 47 2.2.1 PARTIAL MOLAR VOLUME 48 2.2.2 VOLUME
RELATIONSHIPS IN BINARY SOLUTIONS 51 2.2.3 VOLUME CHANGES ON MIXING 56
2.2.4 EXAMPLES FORTHE VOLUMES OF BINARY SOLUTIONS 60 2.2.5 VOLUME
OFREACTION 73 2.3 PROBLEMS 75 CHAPTER 3 THE FIRST LAW OF THERMODYNAMICS
78 3.1 THE RELATIONSHIP BETWEEN HEAT AND WORK 78 3.2 INTERNAL ENERGY 78
3.2.1 WORK 79 3.2.2 ENTHALPY 83 3.3 APPLICATION OF THE FIRST LAW OF
THERMODYNAMICS TO PURE PHASES 84 VIII CONTENTS 3.3.1 HEAT CAPACITIES C V
AND C P 86 THE TEMPERATURE DEPENDENCE OF HEAT CAPACITY 91 THE EMPIRICAL
REPRESENTATION OF HEAT CAPACITIES 98 3.3.2 ENTHALPY, H, OF PURE PHASES
AS A FUNCTION OF TEMPERATURE 101 3.4 ENTHALPY OF SOLUTIONS 106 3.4.1
ENTHALPY OF BINARY SOLUTION 107 3.4.2 EXAMPLES OF ENTHALPY OF MIXING IN
BINARY SOLUTIONS 110 3.5 ENTHALPY OFREACTION 116 3.5.1 TEMPERATURE
DEPENDENCE OF THE ENTHALPY OFREACTION 119 3.5.2 HESS'S LAW 122 3.6
PROBLEMS 124 CHAPTER 4 SECOND LAW OF THERMODYNAMICS 129 4.1 ENTROPY 130
4.2 CLASSICAL DEFINITION OF ENTROPY 130 4.2.1 ENTROPY OF PURE PHASES 131
4.2.2 ADIABATIC CHANGES 136 4.2.3 TEMPERATURE DEPENDENCE OF ENTROPY 137
4.2.4 ENTROPY CHANGES ASSOCIATED WITH IRREVERSIBLE PROCESSES 140 4.3
STATISTICAL INTERPRETATION OF ENTROPY 144 4.3.1 THERMAL ENTROPY 145
4.3.2 CONFIGURATIONAL ENTROPY (ENTROPY OF MIXING) 149 4.4 ENTROPY
OFREACTION 160 4.4.1 TEMPERATURE DEPENDENCE OF THE ENTROPY OFREACTION
160 4.5 PROBLEMS 163 CHAPTER 5 GIBBS FREE ENERGY AND HELMHOLTZ FREE
ENERGY 165 5.1 CHEMICAL POTENTIAL OF PURE PHASES 168 5.1.1 CHEMICAL
POTENTIAL OF IDEAL GASES 168 5.1.2 CHEMICAL POTENTIAL OF NON-IDEAL GASES
169 5.2 THE CHEMICAL POTENTIAL OF COMPONENTS IN SOLUTIONS 173 5.2.1
CHEMICAL POTENTIAL OF AN IDEAL GAS IN AN IDEAL SOLUTION 176 5.2.2
CHEMICAL POTENTIAL OF A REAL GAS IN IDEAL AND NON-IDEAL GAS MIXTURES.
177 5.2.3 CHEMICAL POTENTIAL OF COMPONENTS IN IDEAL SOLID SOLUTIONS 181
5.2.4 CHEMICAL POTENTIAL OF COMPONENTS IN NON-IDEAL SOLID SOLUTIONS 183
ACTIVITY AND ACTIVITY COEFFICIENT AS A FUNCTION OF COMPOSITION 184 5.2.5
THE STANDARD STATE 186 THE ACTIVITY COEFFICIENT AS A FUNCTION OF
TEMPERATURE AND PRESSURE 189 5.3 GIBBS FREE ENERGY OF MIXING 191 5.3.1
MIXING AND ACTIVITY MODELS 194 5.4 GIBBS FREE ENERGY OFREACTION 214
CONTENTS 5.4.1 STANDARD GIBBS FREE ENERGY OFREACTION 215 5.5 PROBLEMS
216 CHAPTER 6 THERMAL EQUILIBRIUM 218 6.1 STABILITY CONDITIONS FOR
PHASES IN ONE-COMPONENT SYSTEMS 220 6.1.1 PHASE EQUILIBRIA IN
ONE-COMPONENT SYSTEMS 223 6.1.2 CLASSIFICATION OF PHASE TRANSFORMATIONS
227 6.2 STABILITY CONDITIONS FOR SOLUTIONS 237 6.2.1 COHERENT EXSOLUTION
244 6.3 GIBBS FREE ENERGY AND PHASE DIAGRAMS OF BINARY SYSTEMS 249 6.3.1
CALCULATION OF PHASE DIAGRAMS FROM THERMODYNAMIC DATA 253 CRITICAL
MIXING CONDITIONS, BINODAL, SPINODAL 253 SIMPLE EUTECTIC SYSTEM 259
BINARY SYSTEM WITH COMPLETE MISCIBILITY OF THE COMPONENTS IN TWO PHAS-
ES 265 6.4 GIBBS PHASE RULE 272 6.5 PROBLEMS 275 CHAPTER 7 CHEMICAL
REACTIONS 277 7.1 PHASE EQUILIBRIA IN REACTING SYSTEMS 277 7.1.1
REACTIONS IN SYSTEMS CONTAINING PURE SOLID PHASES 278 7.1.2 REACTIONS IN
SYSTEMS CONTAINING SOLID SOLUTIONS 288 7.1.3 REACTIONS IN SYSTEMS
CONTAINING SOLID AND GAS PHASES 291 7.1.4 DISTRIBUTION COEFFICIENT, K D
306 RECIPROCAL SOLUTIONS 313 ENERGETICS OF ORDER-DISORDER 325 7.2
PROBLEMS 339 CHAPTER 8 GEOTHERMOMETRY AND GEOBAROMETRY 343 8.1 EXCHANGE
GEOTHERMOMETERS 345 8.2 SOLVUS THERMOMETRY 349 8.3 SOLID-SOLID REACTIONS
354 8.3.1 REACTIONS IN ONE-COMPONENT SYSTEM 354 8.3.2 REACTIONS IN
MULTICOMPONENT SYSTEMS 355 8.4 REACTIONS INVOLVING GASEOUS PHASES 358
SOLUTIONS TO PROBLEMS 365 REFERENCES 371 SUBJECT INDEX 381 |
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| discipline_str_mv | Chemie / Pharmazie Physik Geologie / Paläontologie Geographie |
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| illustrated | Illustrated |
| index_date | 2024-07-02T13:25:28Z |
| indexdate | 2024-07-20T07:52:29Z |
| institution | BVB |
| isbn | 354024364X 9783540243649 |
| language | English German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-014190760 |
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| physical | XVI, 386 S. graph. Darst. |
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| publisher | Springer |
| record_format | marc |
| spelling | Cemič, Ladislav Verfasser (DE-588)111611857 aut Thermodynamics in mineral sciences an introduction Ladislav Cemič Berlin [u.a.] Springer 2005 XVI, 386 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Mineralogia larpcal Minéralogie Termodinâmica larpcal Thermodynamique Mineralogy Textbooks Thermodynamics Textbooks Thermodynamik (DE-588)4059827-5 gnd rswk-swf Mineralogie (DE-588)4039457-8 gnd rswk-swf Mineralogie (DE-588)4039457-8 s Thermodynamik (DE-588)4059827-5 s DE-604 HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014190760&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Cemič, Ladislav Thermodynamics in mineral sciences an introduction Mineralogia larpcal Minéralogie Termodinâmica larpcal Thermodynamique Mineralogy Textbooks Thermodynamics Textbooks Thermodynamik (DE-588)4059827-5 gnd Mineralogie (DE-588)4039457-8 gnd |
| subject_GND | (DE-588)4059827-5 (DE-588)4039457-8 |
| title | Thermodynamics in mineral sciences an introduction |
| title_auth | Thermodynamics in mineral sciences an introduction |
| title_exact_search | Thermodynamics in mineral sciences an introduction |
| title_exact_search_txtP | Thermodynamics in mineral sciences an introduction |
| title_full | Thermodynamics in mineral sciences an introduction Ladislav Cemič |
| title_fullStr | Thermodynamics in mineral sciences an introduction Ladislav Cemič |
| title_full_unstemmed | Thermodynamics in mineral sciences an introduction Ladislav Cemič |
| title_short | Thermodynamics in mineral sciences |
| title_sort | thermodynamics in mineral sciences an introduction |
| title_sub | an introduction |
| topic | Mineralogia larpcal Minéralogie Termodinâmica larpcal Thermodynamique Mineralogy Textbooks Thermodynamics Textbooks Thermodynamik (DE-588)4059827-5 gnd Mineralogie (DE-588)4039457-8 gnd |
| topic_facet | Mineralogia Minéralogie Termodinâmica Thermodynamique Mineralogy Textbooks Thermodynamics Textbooks Thermodynamik Mineralogie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=014190760&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT cemicladislav thermodynamicsinmineralsciencesanintroduction |