PEM fuel cells: theory and practice
Gespeichert in:
1. Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Amsterdam [u.a.]
Elsevier Acad. Press
2005
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Schriftenreihe: | Academic Press sustainable world series
|
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XV, 433 S. Ill., graph. Darst. |
ISBN: | 0120781425 |
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Datensatz im Suchindex
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adam_text | PEM FUEL CELLS THEORY AND PRACTICE FRANO BARBIR ELSEVIER ACADEMIC PRESS
AMSTERDAM BOSTON HEIDELBERG LONDON NEW YORK OXFORD PARIS SAN DIEGO SAN
FRANCISCO SINGAPORE SYDNEY TOKYO CONTENTS FOREWORD XI PREFACE AND
ACKNOWLEDGMENTS XIII 1. INTRODUCTION 1 1.1. WHAT IS A FUEL CELL? 1 1.2.
A VERY BRIEF HISTORY OF FUEL CELLS 4 1.3. TYPES OF FUEL CELLS 6 1.4. HOW
DOES A PEM FUEL CELL WORK? 10 1.5. WHY DO WE NEED FUEL CELLS? 12 1.6.
FUEL CELL APPLICATIONS 13 REFERENCES 16 2. FUEL CELL BASIC CHEMISTRY AND
THERMODYNAMICS 17 2.1. BASIC REACTIONS 17 2.2. HEAT OF REACTION 17 2.3.
HIGHER AND LOWER HEATING VALUE OF HYDROGEN 18 2.4. THEORETICAL
ELECTRICAL WORK 19 2.5. THEORETICAL FUEL CELL POTENTIAL 20 2.6. EFFECT
OF TEMPERATURE 21 2.7. THEORETICAL FUEL CELL EFFICIENCY 24 2.8. CARNOT
EFFICIENCY MYTH 26 2.9. EFFECT OF PRESSURE 27 2.10. SUMMARY 29
REFERENCES 30 PROBLEMS 30 QUIZ 31 3. FUEL CELL ELECTROCHEMISTRY 33 3.L
ELECTRODE KINETICS 33 3.1.1. REACTION RATE 33 3.1.2. REACTION
CONSTANTS,-TRANSFER COEFFICIENT 35 3.1.3. CURRENT POTENTIAL
RELATIONSHIP*BUTLER-VOLMER EQUATION 36 VI CONTENTS 3.1.4. EXCHANGE
CURRENT DENSITY 3.2. VOLTAGE LOSSES 3.2.1. ACTIVATION POLARIZATION
3.2.2. INTERNAL CURRENTS AND CROSSOVER LOSSES 3.2.3. OHMIC (RESISTIVE)
LOSSES 3.2.4. CONCENTRATION POLARIZATION 3.3. CELL
POTENTIAL*POLARIZATION CURVE 3.4. DISTRIBUTION OF POTENTIAL ACROSS A
FUEL CELL 3.5. SENSITIVITY OF PARAMETERS IN POLARIZATION CURVE 3.5.1.
EFFECT OF TRANSFER COEFFICIENT/TAFEL SLOPE 3.5.2. EFFECT OF EXCHANGE
CURRENT DENSITY 3.5.3. EFFECT OF HYDROGEN CROSSOVER AND INTERNAL CURRENT
LOSS 3.5.4. EFFECT OF INTERNAL RESISTANCE 3.5.5. EFFECT OF LIMITING
CURRENT DENSITY 3.5.6. EFFECT OF OPERATING PRESSURE 3.5.7. AIR VS OXYGEN
3.5.8. EFFECT OF OPERATING TEMPERATURE 3.6. FUEL CELL EFFICIENCY 3.7.
IMPLICATIONS AND USE OF FUEL CELL POLARIZATION CURVE 3.7.1. OTHER CURVES
RESULTING FROM POLARIZATION CURVE 3.7.2. LINEAR APPROXIMATION OF
POLARIZATION CURVE 3.7.3. USE OF POLARIZATION CURVE FOR FUEL CELL SIZING
REFERENCES PROBLEMS QUIZ 4. MAIN CELL COMPONENTS, MATERIALS PROPERTIES
AND PROCESSES 4.1. CELL DESCRIPTION 4.2. MEMBRANE 4.2.1. WATER UPTAKE
4.2.2. PHYSICAL PROPERTIES 4.2.3. PROTONIC CONDUCTIVITY 4.2.4. WATER
TRANSPORT 4.2.5. GAS PERMEATION 4.3. ELECTRODE 4.4. GAS DIFFUSION LAYER
4.4.1. TREATMENTS AND COATINGS 4.4.2. POROSITY 4.4.3. ELECTRICAL
CONDUCTIVITY 4.4.4. COMPRESSIBILITY 4.4.5. PERMEABILITY 4.5. BIPOLAR
PLATES 4.5.1. MATERIALS CONTENTS VII 4.5.2. PROPERTIES 102 REFERENCES
108 PROBLEMS 110 QUIZ 112 5. FUEL CELL OPERATING CONDITIONS 115 5.1.
OPERATING PRESSURE 115 5.2. OPERATING TEMPERATURE 115 5.3. REACTANTS
FLOW RATES 118 5.4. REACTANTS HUMIDITY 124 5.5. FUEL CELL MASS BALANCE
132 5.5.1. INLET FLOW RATES 132 5.5.2. OUTLET FLOW RATES 134 5.6. FUEL
CELL ENERGY BALANCE 137 REFERENCES 142 PROBLEMS 142 QUIZ 144 6. STACK
DESIGN 147 6.1. SIZING OF A FUEL CELL STACK 147 6.2. STACK CONFIGURATION
152 6.3. UNIFORM DISTRIBUTION OF REACTANTS TO EACH CELL 156 6.4. UNIFORM
DISTRIBUTION OF REACTANTS INSIDE EACH CELL 161 6.4.1. SHAPE OF THE FLOW
FIELD 161 6.4.2. FLOW FIELD ORIENTATION 162 6.4.3. CONFIGURATION OF
CHANNELS 162 6.4.4. CHANNEL S SHAPE, DIMENSIONS, AND SPACING 166 6.4.5.
PRESSURE DROP THROUGH THE FLOW FIELD 170 6.5. HEAT REMOVAL FROM A FUEL
CELL STACK 177 6.5.1. STACK HEAT BALANCE 178 6.5.2. HEAT CONDUCTION 179
6.5.3. ACTIVE HEAT REMOVAL 185 6.5.4. HEAT DISSIPATION FROM THE STACK BY
NATURAL CONVECTION AND RADIATION 190 6.5.5. ALTERNATIVE STACK COOLING
OPTIONS 192 6.6. STACK CLAMPING 197 REFERENCES 201 PROBLEMS 203 QUIZ 204
7. FUEL CELL MODELING 207 7.1. THEORY AND GOVERNING EQUATIONS 208 7.1.1.
CONSERVATION OF MASS 209 7.1.2. CONSERVATION OF MOMENTUM 210 7.1.3.
CONSERVATION OF ENERGY 211 VIII CONTENTS 7. 1.4. CONSERVATION OF SPECIES
2 7.1.5. CONSERVATION OF CHARGE 2 7.2. MODELING DOMAINS 2 7.3. MODELING
EXAMPLES 2 7.3.1. ONE-DIMENSIONAL THROUGH-THE-MEMBRANE MODEL
(BERNARDI-VERBRUGGE) 2 7.3.2. ONE-DIMENSIONAL CATALYST LAYER MODEL
(YOU-LIU) 2 7.3.3. TWO-DIMENSIONAL ABOVE-THE-CHANNEL MODEL (JENGETAL) 2
7.3.4. TWO-DIMENSIONAL ALONG-THE-CHANNEL MODEL (GURAU ET AL.) 1 7.3.5.
THREE-DIMENSIONAL MODELS 7.4. CONCLUSIONS REFERENCES PROBLEMS QUIZ 8.
FUEL CELL DIAGNOSTICS 8.1. POLARIZATION CURVE 8.2. CURRENT INTERRUPT
8.3. AC IMPEDANCE SPECTROSCOPY 8.4. PRESSURE DROP AS A DIAGNOSTIC TOOL
8.5. CURRENT DENSITY MAPPING 8.6. NEUTRON IMAGING REFERENCES PROBLEMS
QUIZ 9. FUEL CELL SYSTEM DESIGN 9.1. HYDROGEN-OXYGEN SYSTEMS 9.1.1.
OXYGEN SUPPLY 9.1.2. HYDROGEN SUPPLY 9.1.3. WATER AND HEAT
MANAGEMENT*SYSTEM INTEGRATION 9.2. HYDROGEN-AIR SYSTEMS 9.2.1. AIR
SUPPLY 9.2.2. PASSIVE AIR SUPPLY 9.2.3. HYDROGEN SUPPLY 9.2.4.
HUMIDIFICATION SCHEMES 9.2.5. WATER AND HEAT MANAGEMENT*SYSTEM
INTEGRATION 9.3. FUEL CELL SYSTEMS WITH FUEL PROCESSOR 9.3.1. BASIC
PROCESSES AND REACTIONS 9.3.2. STEAM REFORMING 9.3.3. PARTIAL OXIDATION
AND AUTOTHERMAL REFORMING CONTENTS IX 9.3.4. EFFECT OF REFORMATE ON FUEL
CELL PERFORMANCE 312 9.3.5. SYSTEM INTEGRATION 316 9.4. ELECTRICAL
SUBSYSTEM 322 9.5. SYSTEM EFFICIENCY 328 REFERENCES 332 PROBLEMS 334
QUIZ 335 0. FUEL CELL APPLICATIONS 337 10.1. TRANSPORTATION APPLICATIONS
337 10.1.1. AUTOMOBILES 337 10.1.2. BUSES 352 10.1.3. UTILITY VEHICLES
353 10.1.4. SCOOTERS AND BICYCLES 356 10.2. STATIONARY POWER 357 10.2.1.
CLASSIFICATION OF STATIONARY FUEL CELL SYSTEMS 357 10.2.2. SYSTEM
CONFIGURATION 360 10.2.3. EFFICIENCY OF ENTIRE FUEL CELL SYSTEM 363
10.2.4. ECONOMICS OF FUEL CELL SYSTEMS 363 10.3. BACKUP POWER 376 10.4.
FUEL CELLS FOR SMALL PORTABLE POWER 381 10.5. REGENERATIVE FUEL CELLS
AND THEIR APPLICATIONS 383 10.5.1. DESIGN TRADE-OFFS 384 10.5.2.
REGENERATIVE FUEL CELL APPLICATIONS 386 REFERENCES 390 PROBLEMS 393 QUIZ
395 11. FUEL CELLS AND HYDROGEN ECONOMY 399 11.1. INTRODUCTION 399 11.2.
TRANSITIONS IN ENERGY SUPPLY 399 11.3. HISTORY OF HYDROGEN AS FUEL 403
11.4. HYDROGEN ENERGY SYSTEM 405 11.5. HYDROGEN ENERGY TECHNOLOGIES 407
11.5.1. TECHNOLOGIES FOR HYDROGEN PRODUCTION 407 11.5.2. TECHNOLOGIES
FOR HYDROGEN STORAGE 408 11.5.3. TECHNOLOGIES FOR HYDROGEN UTILIZATION
409 11.5.4. SAFETY ASPECTS OF HYDROGEN AS FUEL 411 11.6. PREDICTING THE
FUTURE 416 11.7. TRANSITION TO HYDROGEN ECONOMY 420 11.8. COMING ENERGY
REVOLUTION? 421 11.9. CONCLUSIONS 423 REFERENCES 423 INDEX 427
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author | Barbir, Frano |
author_facet | Barbir, Frano |
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illustrated | Illustrated |
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language | English |
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publisher | Elsevier Acad. Press |
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spelling | Barbir, Frano Verfasser aut PEM fuel cells theory and practice Franco Barbir Amsterdam [u.a.] Elsevier Acad. Press 2005 XV, 433 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Academic Press sustainable world series Brennstoffzelle - Protonentransfer Ion-permeable membranes Proton exchange membrane fuel cells Design (DE-588)4011510-0 gnd rswk-swf Analyse (DE-588)4122795-5 gnd rswk-swf Energiequelle (DE-588)4014720-4 gnd rswk-swf Protonentransfer (DE-588)4176024-4 gnd rswk-swf Brennstoffzelle (DE-588)4008195-3 gnd rswk-swf Elektrochemische Energiequelle (DE-588)4151755-6 gnd rswk-swf Brennstoffzelle (DE-588)4008195-3 s Protonentransfer (DE-588)4176024-4 s DE-604 Energiequelle (DE-588)4014720-4 s Elektrochemische Energiequelle (DE-588)4151755-6 s 1\p DE-604 Design (DE-588)4011510-0 s Analyse (DE-588)4122795-5 s 2\p DE-604 HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=013314314&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
spellingShingle | Barbir, Frano PEM fuel cells theory and practice Brennstoffzelle - Protonentransfer Ion-permeable membranes Proton exchange membrane fuel cells Design (DE-588)4011510-0 gnd Analyse (DE-588)4122795-5 gnd Energiequelle (DE-588)4014720-4 gnd Protonentransfer (DE-588)4176024-4 gnd Brennstoffzelle (DE-588)4008195-3 gnd Elektrochemische Energiequelle (DE-588)4151755-6 gnd |
subject_GND | (DE-588)4011510-0 (DE-588)4122795-5 (DE-588)4014720-4 (DE-588)4176024-4 (DE-588)4008195-3 (DE-588)4151755-6 |
title | PEM fuel cells theory and practice |
title_auth | PEM fuel cells theory and practice |
title_exact_search | PEM fuel cells theory and practice |
title_full | PEM fuel cells theory and practice Franco Barbir |
title_fullStr | PEM fuel cells theory and practice Franco Barbir |
title_full_unstemmed | PEM fuel cells theory and practice Franco Barbir |
title_short | PEM fuel cells |
title_sort | pem fuel cells theory and practice |
title_sub | theory and practice |
topic | Brennstoffzelle - Protonentransfer Ion-permeable membranes Proton exchange membrane fuel cells Design (DE-588)4011510-0 gnd Analyse (DE-588)4122795-5 gnd Energiequelle (DE-588)4014720-4 gnd Protonentransfer (DE-588)4176024-4 gnd Brennstoffzelle (DE-588)4008195-3 gnd Elektrochemische Energiequelle (DE-588)4151755-6 gnd |
topic_facet | Brennstoffzelle - Protonentransfer Ion-permeable membranes Proton exchange membrane fuel cells Design Analyse Energiequelle Protonentransfer Brennstoffzelle Elektrochemische Energiequelle |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=013314314&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT barbirfrano pemfuelcellstheoryandpractice |