Thermodynamics and introductory statistical mechanics:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, N.J.
Wiley-Interscience
2004
|
| Schlagworte: | |
| Online-Zugang: | Publisher description Table of contents Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | xvi, 209 S. graph. Darst. 25 cm |
| ISBN: | 0471474592 |
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| adam_text | THERMODYNAMICS AND INTRODUCTORY STATISTICAL MECHANICS BRUNO LINDER
DEPARTMENT OF CHEMISTRY AND BIOCHEMISTRY THE FLORIDA STATE UNIVERSITY
WILEY- INTERSCIENCE A JOHN WILEY & SONS, INC. PUBLICATION CONTENTS
PREFACE XV 1 INTRODUCTORY REMARKS 1 1.1 SCOPE AND OBJECTIVES / 1 1.2
LEVEL OF COURSE / 2 1.3 COURSE OUTLINE / 2 1.4 BOOKS / 3 PART I
THERMODYNAMICS 5 2 BASIC CONCEPTS AND DEFINITIONS 7 2.1 SYSTEMS AND
SURROUNDINGS / 8 2.2 STATE VARIABLES AND THERMODYNAMIC PROPERTIES / 8
2.3 INTENSIVE AND EXTENSIVE VARIABLES / 9 2.4 HOMOGENEOUS AND
HETEROGENEOUS SYSTEMS, PHASES / 9 2.5 WORK / 9 2.6 REVERSIBLE AND
QUASI-STATIC PROCESSES / 10 2.6.1 QUASI-STATIC PROCESS /11 2.6.2
REVERSIBLE PROCESS / 12 2.7 ADIABATIC AND DIATHERMAL WALLS /13 2.8
THERMAL CONTACT AND THERMAL EQUILIBRIUM /13 VII VIII CONTENTS 3 THE LAWS
OF THERMODYNAMICS I 14 3.1 THE ZEROTH LAW*TEMPERATURE /15 3.2 THE FIRST
LAW*TRADITIONAL APPROACH /16 3.3 MATHEMATICAL INTERLUDE I: EXACT AND
INEXACT DIFFERENTIALS /18 3.4 THE FIRST LAW*AXIOMATIC APPROACH /19 3.5
SOME APPLICATIONS OF THE FIRST LAW / 23 3.5.1 HEAT CAPACITY / 23 3.5.2
HEAT AND INTERNAL ENERGY / 23 3.5.3 HEAT AND ENTHALPY / 24 3.6
MATHEMATICAL INTERLUDE II: PARTIAL DERIVATIVES / 26 3.6.1 RELATIONS
BETWEEN PARTIALS OF DEPENDENT VARIABLES / 26 3.6.2 RELATIONS BETWEEN
PARTIALS WITH DIFFERENT SUBSCRIPTS / 27 3.7 OTHER APPLICATIONS OF THE
FIRST LAW / 27 3.7.1 CP-CY / 27 3.7.2 ISOTHERMAL CHANGE, IDEAL GAS / 28
3.7.3 ADIABATIC CHANGE, IDEAL GAS / 28 3.7.4 THE JOULE AND THE
JOULE-THOMSON COEFFICIENTS / 29 4 THE LAWS OF THERMODYNAMICS II 32 4.1
THE SECOND LAW*TRADITIONAL APPROACH / 32 4.2 ENGINE EFFICIENCY: ABSOLUTE
TEMPERATURE / 36 4.2.1 IDEAL GAS / 36 4.2.2 COUPLED CYCLES / 36 4.3
GENERALIZATION: ARBITRARY CYCLE / 38 4.4 THE CLAUSIUS INEQUALITY / 39
4.5 THE SECOND LAW*AXIOMATIC APPROACH (CARATHEODORY) / 41 4.6
MATHEMATICAL INTERLUDE III: PFAFFIAN DIFFERENTIAL FORMS / 43 4.7
PFAFFIAN EXPRESSIONS IN TWO VARIABLES / 44 4.8 PFAFFIAN EXPRESSIONS IN
MORE THAN TWO DIMENSIONS / 44 4.9 CARATHEODORY S THEOREM / 45 4.10
ENTROPY*AXIOMATIC APPROACH / 45 4.11 ENTROPY CHANGES FOR NONISOLATED
SYSTEMS / 48 4.12 SUMMARY / 49 4.13 SOME APPLICATIONS OF THE SECOND LAW
/ 50 4.13.1 REVERSIBLE PROCESSES (PV WORK ONLY) / 50 4.13.2 IRREVERSIBLE
PROCESSES /51 CONTENTS IX 5 USEFUL FUNCTIONS: THE FREE ENERGY FUNCTIONS
52 5.1 MATHEMATICAL INTERLUDE IV: LEGENDRE TRANSFORMATIONS / 53 5.1.1
APPLICATION OF THE LEGENDRE TRANSFORMATION / 54 5.2 MAXWELL RELATIONS /
55 5.3 THE GIBBS-HELMHOLTZ EQUATIONS / 55 5.4 RELATION OF AA AND AG TO
WORK: CRITERIA FOR SPONTANEITY / 56 5.4.1 EXPANSION AND OTHER TYPES OF
WORK / 56 5.4.2 COMMENTS / 57 5.5 GENERALIZATION TO OPEN SYSTEMS AND
SYSTEMS OF VARIABLE COMPOSITION / 58 5.5.1 SINGLE COMPONENT SYSTEM /58
5.5.2 MULTICOMPONENT SYSTEMS / 59 5.6 THE CHEMICAL POTENTIAL / 59 5.7
MATHEMATICAL INTERLUDE V: EULER S THEOREM / 60 5.8 THERMODYNAMIC
POTENTIALS /61 6 THE THIRD LAW OF THERMODYNAMICS 65 6.1 STATEMENTS OF
THE THIRD LAW / 66 6.2 ADDITIONAL COMMENTS AND CONCLUSIONS / 68 7
GENERAL CONDITIONS FOR EQUILIBRIUM AND STABILITY 70 7.1 VIRTUAL
VARIATIONS /71 7.2 THERMODYNAMIC POTENTIALS*INEQUALITIES / 73 7.3
EQUILIBRIUM CONDITION FROM ENERGY / 75 7.3.1 BOUNDARY FULLY HEAT
CONDUCTING, DEFORMABLE, PERMEABLE (NORMAL SYSTEM) / 75 7.3.2 SPECIAL
CASES: BOUNDARY SEMI-HEAT CONDUCTING, SEMI-DEFORMABLE, OR SEMI-PERMEABLE
/ 76 7.4 EQUILIBRIUM CONDITIONS FROM OTHER POTENTIALS / 77 7.5 GENERAL
CONDITIONS FOR STABILITY / 78 7.6 STABILITY CONDITIONS FROM E / 78 7.7
STABILITY CONDITIONS FROM CROSS TERMS / 80 7.8 STABILITY CONDITIONS FROM
OTHER POTENTIALS / 81 7.9 DERIVATIVES OF THERMODYNAMIC POTENTIALS WITH
RESPECT TO INTENSIVE VARIABLES / 82 X CONTENTS 8 APPLICATION OF
THERMODYNAMICS TO GASES, LIQUIDS, AND SOLIDS 83 8.1 GASES / 83 8.2
ENTHALPY, ENTROPY, CHEMICAL POTENTIAL, FUGACITY / 85 8.2.1 ENTHALPY / 85
8.2.2 ENTROPY / 86 8.2.3 CHEMICAL POTENTIAL / 87 8.2.4 FUGACITY / 88 8.3
STANDARD STATES OF GASES / 89 8.4 MIXTURES OF GASES / 90 8.4.1 PARTIAL
FUGACITY / 90 8.4.2 FREE ENERGY, ENTROPY, ENTHALPY, AND VOLUME OF MIXING
OF GASES / 90 8.5 THERMODYNAMICS OF CONDENSED SYSTEMS / 91 8.5.1 THE
CHEMICAL POTENTIAL / 92 8.5.2 ENTROPY / 93 8.5.3 ENTHALPY / 93 9 PHASE
AND CHEMICAL EQUILIBRIA 94 9.1 THE PHASE RULE / 94 9.2 THE CLAPEYRON
EQUATION / 96 9.3 THE CLAUSIUS-CLAPEYRON EQUATION / 97 9.4 THE
GENERALIZED CLAPEYRON EQUATION / 98 9.5 CHEMICAL EQUILIBRIUM / 99 9.6
THE EQUILIBRIUM CONSTANT / 100 10 SOLUTIONS*NONELECTROLYTES 102 10.1
ACTIVITIES AND STANDARD STATE CONVENTIONS / 102 10.1.1 GASES / 102
10.1.2 PURE LIQUIDS AND SOLIDS / 103 10.1.3 MIXTURES / 103 10.1.3.1
LIQUID-LIQUID SOLUTIONS*CONVENTION I (CON I) / 104 10.1.3.2 SOLID-LIQUID
SOLUTIONS*CONVENTION II (CON II) / 104 10.2 IDEAL AND IDEALLY DILUTE
SOLUTIONS; RAOULT S AND HENRY S LAWS / 104 CONTENTS XI 10.2.1 IDEAL
SOLUTIONS / 104 10.2.2 IDEALLY DILUTE SOLUTIONS / 105 10.3 THERMODYNAMIC
FUNCTIONS OF MIXING /107 10.3.1 FOR IDEAL SOLUTIONS / 107 10.3.2 FOR
NONIDEAL SOLUTIONS / 107 10.4 COLLIGATIVE PROPERTIES / 108 10.4.1
LOWERING OF SOLVENT VAPOR PRESSURE / 108 10.4.2 FREEZING POINT
DEPRESSION / 109 10.4.3 BOILING POINT ELEVATION /111 10.4.4 OSMOTIC
PRESSURE / 112 11 PROCESSES INVOLVING WORK OTHER THAN PRESSURE-VOLUME
WORK 114 11.1 P-V WORK AND ONE OTHER TYPE OF WORK /115 11.2 P-V, *** AND
FL WORK /116 12 PHASE TRANSITIONS AND CRITICAL PHENOMENA 119 12.1
STABLE, METASTABLE, AND UNSTABLE ISOTHERMS / 120 12.2 THE CRITICAL
REGION / 124 PART II INTRODUCTORY STATISTICAL MECHANICS 127 13
PRINCIPLES OF STATISTICAL MECHANICS 129 13.1 INTRODUCTION / 129 13.2
PRELIMINARY DISCUSSION*SIMPLE PROBLEM / 130 13.3 TIME AND ENSEMBLE
AVERAGES / 131 13.4 NUMBER OF MICROSTATES, 0 D , DISTRIBUTIONS D, / 132
13.5 MATHEMATICAL INTERLUDE VI: COMBINATORY ANALYSIS / 134 13.6
FUNDAMENTAL PROBLEM IN STATISTICAL MECHANICS / 136 13.7
MAXWELL-BOLTZMANN, FERMI-DIRAC, BOSE-EINSTEIN STATISTICS. CORRECTED
MAXWELL-BOLTZMANN STATISTICS /137 13.7.1 MAXWELL-BOLTZMANN STATISTICS /
137 13.7.2 FERMI-DIRAC STATISTICS / 137 13.7.3 BOSE-EINSTEIN STATISTICS
/ 137 13.7.4 CORRECTED MAXWELL-BOLTZMANN STATISTICS / 138 13.8 SYSTEMS
OF DISTINGUISHABLE (LOCALIZED) AND INDISTINGUISHABLE (NONLOCALIZED)
PARTICLES /139 XUE CONTENTS 13.9 MAXIMIZING FT D / 139 13.10 PROBABILITY
OF A QUANTUM STATE: THE PARTITION FUNCTION /140 13.10.1
MAXWELL-BOLTZMANN STATISTICS / 140 13.10.2 CORRECTED MAXWELL-BOLTZMANN
STATISTICS / 141 14 THERMODYNAMIC CONNECTION 143 14.1 ENERGY, HEAT, AND
WORK / 143 14.2 ENTROPY / 144 14.2.1 ENTROPY OF NONLOCALIZED SYSTEMS
(GASES) / 145 14.2.2 ENTROPY OF LOCALIZED SYSTEMS (CRYSTALLINE SOLIDS) /
145 14.3 IDENTIFICATION OF SS WITH 1/KT / 145 14.4 PRESSURE / 146 14.5
THE FUNCTIONS E, H, S, A, G, AND [I I 147 15 MOLECULAR PARTITION
FUNCTION 150 15.1 TRANSLATIONAL PARTITION FUNCTION / 151 15.2
VIBRATIONAL PARTITION FUNCTION: DIATOMICS /152 15.3 ROTATIONAL PARTITION
FUNCTION: DIATOMICS / 152 15.4 ELECTRONIC PARTITION FUNCTION / 154 15.5
NUCLEAR SPIN STATES / 154 15.6 THE ZERO OF ENERGY / 155 16 STATISTICAL
MECHANICAL APPLICATIONS 158 16.1 POPULATION RATIOS /158 16.2
THERMODYNAMIC FUNCTIONS OF GASES / 159 16.3 EQUILIBRIUM CONSTANTS / 161
16.4 SYSTEMS OF LOCALIZED PARTICLES: THE EINSTEIN SOLID /164 16.4.1
ENERGY / 164 16.4.2 HEAT CAPACITY / 165 16.4.3 ENTROPY / 165 16.5
SUMMARY /166 ANNOTATED BIBLIOGRAPHY 167 APPENDIX I HOMEWORK PROBLEM SETS
169 PROBLEM SET 1/169 PROBLEM SET 11/170 PROBLEM SET III / 171 PROBLEM
SET IV / 172 PROBLEM SET V / 173 PROBLEM SET VI / 173 PROBLEM SET VII /
174 PROBLEM SET VIII / 175 PROBLEM SET IX / 175 PROBLEM SET X / 176
APPENDIX II SOLUTIONS TO PROBLEMS SOLUTION TO SET 1/177 SOLUTION TO SET
II / 179 SOLUTION TO SET III / 181 SOLUTION TO SET IV / 185 SOLUTION TO
SET V / 187 SOLUTION TO SET VI / 189 SOLUTION TO SET VII / 191 SOLUTION
TO SET VIII / 194 SOLUTION TO SET IX / 195 SOLUTION TO SET X / 198 INDEX
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| spelling | Linder, Bruno Verfasser aut Thermodynamics and introductory statistical mechanics Bruno Linder Hoboken, N.J. Wiley-Interscience 2004 xvi, 209 S. graph. Darst. 25 cm txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Statistische mechanica gtt Thermodynamica gtt Thermodynamics Statistical mechanics Statistische Mechanik (DE-588)4056999-8 gnd rswk-swf Thermodynamik (DE-588)4059827-5 gnd rswk-swf (DE-588)4151278-9 Einführung gnd-content Thermodynamik (DE-588)4059827-5 s DE-604 Statistische Mechanik (DE-588)4056999-8 s b DE-604 http://www.loc.gov/catdir/description/wiley042/2004003022.html Publisher description http://www.loc.gov/catdir/toc/ecip0415/2004003022.html Table of contents GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=013222642&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
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| subject_GND | (DE-588)4056999-8 (DE-588)4059827-5 (DE-588)4151278-9 |
| title | Thermodynamics and introductory statistical mechanics |
| title_auth | Thermodynamics and introductory statistical mechanics |
| title_exact_search | Thermodynamics and introductory statistical mechanics |
| title_full | Thermodynamics and introductory statistical mechanics Bruno Linder |
| title_fullStr | Thermodynamics and introductory statistical mechanics Bruno Linder |
| title_full_unstemmed | Thermodynamics and introductory statistical mechanics Bruno Linder |
| title_short | Thermodynamics and introductory statistical mechanics |
| title_sort | thermodynamics and introductory statistical mechanics |
| topic | Statistische mechanica gtt Thermodynamica gtt Thermodynamics Statistical mechanics Statistische Mechanik (DE-588)4056999-8 gnd Thermodynamik (DE-588)4059827-5 gnd |
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