The organometallic chemistry of the transition metals:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, NJ
Wiley-Interscience
2005
|
| Ausgabe: | 4. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIII, 546 S. graph. Darst. |
| ISBN: | 0471662569 |
Internformat
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| 245 | 1 | 0 | |a The organometallic chemistry of the transition metals |c Robert H. Crabtree |
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Datensatz im Suchindex
| _version_ | 1804133252412211200 |
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| adam_text | THE ORGANOMETALLIC CHEMISTRY OF THE TRANSITION METALS FOURTH EDITION
ROBERT H. CRABTREE YALE UNIVERSITY, NEW HAVEN, CONNECTICUT WILEY-
INTERSCIENCE A JOHN WILEY & SONS, INC., PUBLICATION CONTENTS PREFACE IX
LIST OF ABBREVIATIONS XI 1 INTRODUCTION 1 1.1 WERNER COMPLEXES, 2 1.2
THE TRANS EFFECT, 6 1.3 SOFT VERSUS HARD LIGANDS, 8 1.4 THE CRYSTAL
FIELD, 9 1.5 THE LIGAND FIELD, 14 1.6 BACK BONDING, 15 1.7
ELECTRONEUTRALITY, 19 1.8 TYPES OF LIGAND, 21 2 GENERAL PROPERTIES OF
ORGANOMETALLIC COMPLEXES 29 2.1 THE 18-ELECTRON RULE, 30 2.2 LIMITATIONS
OF THE 18-ELECTRON RULE, 35 2.3 ELECTRON COUNTING IN REACTIONS, 37 2.4
OXIDATION STATE, 39 2.5 COORDINATION NUMBER AND GEOMETRY, 41 2.6 EFFECTS
OF COMPLEXATION, 45 2.7 DIFFERENCES BETWEEN METALS, 47 2.8 OUTER-SPHERE
COORDINATION, 49 VI CONTENTS 3 METAL ALKYLS, ARYLS, AND HYDRIDES AND
RELATED A -BONDED LIGANDS 53 3.1 TRANSITION METAL ALKYLS AND ARYLS, 53
3.2 RELATED A-BONDED LIGANDS, 68 3.3 METAL HYDRIDE COMPLEXES, 72 3.4 A
COMPLEXES, 75 3.5 BOND STRENGTHS FOR CLASSICAL A -BONDING LIGANDS, 79 4
CARBONYLS, PHOSPHINE COMPLEXES, AND LIGAND SUBSTITUTION REACTIONS 87 4.1
METAL COMPLEXES OF CO, RNC, CS, AND NO, 87 4.2 PHOSPHINES AND RELATED
LIGANDS, 99 4.3 DISSOCIATIVE SUBSTITUTION, 104 4.4 ASSOCIATIVE
MECHANISM, 109 4.5 REDOX EFFECTS, THE I MECHANISM, AND REARRANGEMENTS IN
SUBSTITUTION, 112 4.6 PHOTOCHEMICAL SUBSTITUTION, 115 4.7 STERIC AND
SOLVENT EFFECTS IN SUBSTITUTION, 118 5 COMPLEXES OF N -BOUND LIGANDS 125
5.1 ALKENE AND ALKYNE COMPLEXES, 125 5.2 ALLYL COMPLEXES, 131 5.3 DIENE
COMPLEXES, 136 5.4 CYCLOPENTADIENYL COMPLEXES, 140 5.5 ARENES AND OTHER
ALICYCLIC LIGANDS, 148 5.6 METALACYCLES AND ISOELECTRONIC AND ISOLOBAL
REPLACEMENT, 152 5.7 STABILITY OF POLYENE AND POLYENYL COMPLEXES, 154 6
OXIDATIVE ADDITION AND REDUCTIVE ELIMINATION 159 6.1 CONCERTED
ADDITIONS, 162 6.2 S N 2 REACTIONS, 165 6.3 RADICAL MECHANISMS, 166 6.4
IONIC MECHANISMS, 169 6.5 REDUCTIVE ELIMINATION, 170 6.6 CR-BOND
METATHESIS, 176 6.7 OXIDATIVE COUPLING AND REDUCTIVE CLEAVAGE, 177 7
INSERTION AND ELIMINATION 183 7.1 REACTIONS INVOLVING CO, 185 7.2
INSERTIONS INVOLVING ALKENES, 191 7.3 OTHER INSERTIONS, 197 7.4 A, P, Y,
AND 8 ELIMINATION, 199 CONTENTS VII 8 NUCLEOPHILIC AND ELECTROPHILIC
ADDITION AND ABSTRACTION 207 8.1 NUCLEOPHILIC ADDITION TO CO, 210 8.2
NUCLEOPHILIC ADDITION TO POLYENE AND POLYENYL LIGANDS, 213 8.3
NUCLEOPHILIC ABSTRACTION IN HYDRIDES, ALKYLS, AND ACYLS, 221 8.4
ELECTROPHILIC ADDITION, 222 8.5 ELECTROPHILIC ABSTRACTION OF ALKYL
GROUPS, 226 8.6 SINGLE-ELECTRON TRANSFER PATHWAYS, 228 8.7 REACTIONS OF
ORGANIC FREE RADICALS WITH METAL COMPLEXES, 229 9 HOMOGENEOUS CATALYSIS
235 9.1 ALKENE ISOMERIZATION, 239 9.2 ALKENE HYDROGENATION, 241 9.3
ALKENE HYDROFORMYLATION, 254 9.4 HYDROCYANATION OF BUTADIENE, 257 9.5
ALKENE HYDROSILATION AND HYDROBORATION, 261 9.6 COUPLING REACTIONS, 263
9.7 SURFACE AND SUPPORTED ORGANOMETALLIC CATALYSIS, 266 10 PHYSICAL
METHODS IN ORGANOMETALLIC CHEMISTRY 275 10.1 ISOLATION, 275 10.2 H NMR
SPECTROSCOPY, 276 10.3 13 C NMR SPECTROSCOPY, 281 10.4 3I P NMR
SPECTROSCOPY, 282 10.5 DYNAMIC NMR, 284 10.6 SPIN SATURATION TRANSFER,
288 10.7 T AND THE NUCLEAR OVERHAUSER EFFECT, 290 10.8 ISOTOPIC
PERTURBATION OF RESONANCE, 294 10.9 IR SPECTROSCOPY, 297 10.10
CRYSTALLOGRAPHY, 300 10.11 OTHER METHODS, 302 11 METAL-LIGAND MULTIPLE
BONDS 309 11.1 CARBENES, 309 11.2 CARBYNES, 325 11.3 BRIDGING CARBENES
AND CARBYNES, 327 11.4 /V-HETEROCYCLIC CARBENES, 330 11.5 MULTIPLE BONDS
TO HETEROATOMS, 334 12 APPLICATIONS OF ORGANOMETALLIC CHEMISTRY 343 12.1
ALKENE METATHESIS, 343 12.2 DIMERIZATION, OLIGOMERIZATION, AND
POLYMERIZATION OF ALKENES, 350 VIII CONTENTS 12.3 ACTIVATION OF CO AND
CO 2 , 360 12.4 CH ACTIVATION, 364 12.5 ORGANOMETALLIC MATERIALS AND
POLYMERS, 371 13 CLUSTERS AND THE METAL-METAL BOND 379 13.1 STRUCTURES,
380 13.2 THE ISOLOBAL ANALOGY, 393 13.3 SYNTHESIS, 397 13.4 REACTIONS,
399 13.5 GIANT CLUSTERS AND NANOPARTICLES, 407 13.6 GIANT MOLECULES, 411
14 APPLICATIONS TO ORGANIC SYNTHESIS 417 14.1 METAL ALKYLS ARYLS, AND
HYDRIDES, 418 14.2 REDUCTION, OXIDATION, AND CONTROL OF STEREOCHEMISTRY,
429 14.3 PROTECTION AND DEPROTECTION, 435 14.4 REDUCTIVE ELIMINATION AND
COUPLING REACTIONS, 438 14.5 INSERTION REACTIONS, 443 14.6 NUCLEOPHILIC
ATTACK ON A LIGAND, 447 14.7 HETEROCYCLES, 454 14.8 MORE COMPLEX
MOLECULES, 455 15 PARAMAGNETIC, HIGH-OXIDATION-STATE, AND
HIGH-COORDINATION-NUMBER COMPLEXES 463 15.1 MAGNETISM AND SPIN STATES,
464 15.2 POLY ALKY IS, 471 15.3 POLYHYDRIDES, 476 15.4 CYCLOPENTADIENYL
COMPLEXES, 479 15.5 /-BLOCK COMPLEXES, 481 16 BIOORGANOMETALLIC
CHEMISTRY 491 16.1 INTRODUCTION, 492 16.2 COENZYMEB|2, 497 16.3 NITROGEN
FIXATION, 503 16.4 NICKEL ENZYMES, 509 16.5 BIOMEDICAL APPLICATIONS, 517
USEFUL TEXTS ON ALLIED TOPICS 521 MAJOR REACTION TYPES 52^ SOLUTIONS TO
PROBLEMS 52! INDEX 53
|
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| isbn | 0471662569 |
| language | English |
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| physical | XIII, 546 S. graph. Darst. |
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| spelling | Crabtree, Robert H. Verfasser aut The organometallic chemistry of the transition metals Robert H. Crabtree 4. ed. Hoboken, NJ Wiley-Interscience 2005 XIII, 546 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 s Übergangsmetallorganische Verbindungen (DE-588)4417301-5 s 1\p DE-604 b DE-604 HEBIS Datenaustausch Darmstadt application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=013098049&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Crabtree, Robert H. The organometallic chemistry of the transition metals Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4417301-5 (DE-588)4131837-7 |
| title | The organometallic chemistry of the transition metals |
| title_auth | The organometallic chemistry of the transition metals |
| title_exact_search | The organometallic chemistry of the transition metals |
| title_full | The organometallic chemistry of the transition metals Robert H. Crabtree |
| title_fullStr | The organometallic chemistry of the transition metals Robert H. Crabtree |
| title_full_unstemmed | The organometallic chemistry of the transition metals Robert H. Crabtree |
| title_short | The organometallic chemistry of the transition metals |
| title_sort | the organometallic chemistry of the transition metals |
| topic | Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Übergangsmetallorganische Verbindungen Übergangsmetallkomplexe |
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