Macromolecular nanostructured materials:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Berlin [u.a.]
Springer [u.a.]
2004
|
| Schriftenreihe: | Springer series in materials science
78 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVI, 335 S. Ill., graph. Darst. |
| ISBN: | 3540223274 4062112426 |
Internformat
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Datensatz im Suchindex
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N. UEYAMA A. HARADA (EDS.) MACROMOLECULAR NANOSTRUCTURED MATERIALS WITH
187 FIGURES, 59 SCHEMES AND 26 TABLES S\ KODANSHA 4Y SPRINGER CONTENTS
LIST OF CONTRIBUTORS V PREFACE IX 1 PRECISE SYNTHESIS OF SUPRAMOLECULES
1.1 AN INTEGRATED SYSTEMS-ORIENTED APPROACH TO MOLECULAR ELECTRONICS .
2 1.1.1 INTRODUCTION 2 1.1.2 CATENANE-BASED DEVICES 3 1.1.3 AMPHIPHILIC
SINGLE-STATION ROTAXANE-BASED DEVICES 10 1.1.4 AMPHIPHILIC BISTABLE
PSEUDOROTAXANE-BASED DEVICES 13 1.1.5 A SLOW AMPHIPHILIC BISTABLE
ROTAXANE-BASED DEVICE 15 1.1.6 A FAST AMPHIPHILIC BISTABLE
ROTAXANE-BASED DEVICE 18 1.1.7 THE BEST AMPHIPHILIC BISTABLE
ROTAXANE-BASED DEVICE TO DATE 20 1.1.8 CONCLUDING REMARKS 21 1.2
SUPRAMOLECULAR POLYMERS CONTAINING CYCLODEXTRIN 26 1.2.1 INTRODUCTION 26
1.2.2 CYCLODEXTRINS 27 1.2.3 ROTAXANES 28 1.2.4 POLYROTAXANES 30 1.2.5
MOLECULAR SHUTTLE 33 1.2.6 ELECTRONIC TRAP 34 1.2.7 SUPRAMOLECULAR
POLYMERS 34 A. INTRAMOLECULAR COMPLEXATION 34 B. INTERMOLECULAR
COMPLEXATION 35 C. SUPRAMOLECULAR POLYMERS 36 1.2.8 DAISY CHAIN NECKLACE
39 1.2.9 CONCLUSION 39 1.3 CUCURBITURIL: A VERSATILE "BEAD" FOR
POLYROTAXANE SYNTHESIS 41 1.3.1 INTRODUCTION 41 1.3.2 CUCURBITURIL 42
1.3.3 CONCLUSIONS 59 1.3.4 SUMMARY 59 REFERENCES 60 XII CONTENTS 2
MACROMOLECULAR ORGANIC ASSEMBLIES 2.1 NANOMETER-SIZE MULTISPIN
MACROMOLECULES AND THEIR MAGNETIC FORCE MICROSCOPIC IMAGES 66 2.1.1
INTRODUCTION 66 2.1.2 MACROMOLECULES BEARING RADICAL GROUPS 66 2.1.3
MAGNETIC FORCE MICROSCOPY 73 2.1.4 MAGNETIC FORCE MICROSCOPIC IMAGES OF
MAGNETICALLY RESPONSIVE MACROMOLECULES 74 2.2 SYNTHESIS AND
CHARACTERIZATION OF NEW HIGHLY SOLUBLE ORGANIC POLYIMIDES 80 2.2.1
INTRODUCTION 80 2.2.2 CHARACTERIZATION OF THE NOVEL POLYIMIDES 81 A.
MONOMER SYNTHESIS 81 B. PREPARATION OF NOVEL POLYIMIDES 83 C. SOLUBILITY
87 D. CRYSTALLINA^ 93 E. THERMAL PROPERTY 95 F. ELECTRICAL AND OPTICAL
PROPERTIES 98 2.3 "INORGANIC" COMBINATORIAL CHEMISTRY UTILIZING SOL-GEL
TRANSCRIPTION OF GELATINOUS ORGANIC SUPERSTRUCTURES 101 2.3.1
INTRODUCTION 101 2.3.2 SOL-GEL TRANSCRIPTION WITH DIFFERENT GEL
TEMPLATES 102 A. CHOLESTEROL-BASED GELS AS TEMPLATES 102 B. GELATORS
WITH AMIDE AND UREA MOIETIES AS TEMPLATES 106 2.3.3 COMBINATORIAL
APPROACH TO SOL-GEL TRANSCRIPTION 107 A. CARBOHYDRATE-BASED DERIVATIVES
AS A SOURCE FOR NOVEL GEL TEMPLATES . 109 B. SOL-GEL TRANSCRIPTION WITH
CARBOHYDRATE GELS AS TEMPLATES 112 2.3.4 SUMMARY AND OUTLOOK 116 2.4
DEVELOPMENT OF ORGANOGELATORS BASED ON SUPRAMOLECULAR CHEMISTRY 118
2.4.1 INTRODUCTION 118 2.4.2 LOW MOLECULAR WEIGHT ORGANOGELATORS 119
2.4.3 ORGANOGELATORS OF AMINO ACID DERIVATIVES 119 2.4.4 CYCLIC
DIPEPTIDES AS ORGANOGELATORS 126 2.4.5 01IGO(PEPTIDE)S AS ORGANOGELATORS
128 2.4.6 TWO-COMPONENT TYPE OF ORGANOGELATORS 129 2.4.7
RRA5-L,2-CYCLOHEXANEDIAMINE DERIVATIVES AS ORGANOGELATORS 131 2.4.8
TRIALKYL-L,3,5-BENZENETRICARBOXAMIDE AND TRIALKYL-CW-1,3,5-
CYCLOHEXANETRICARBOXAMIDE 135 2.4.9 ORGANOGELATORS BASED ON
2-AMINO-2-PHENYLETHANOL 136 CONTENTS 2.5 SYNTHESIS AND SELF-ASSOCIATION
OF STIMULI-RESPONSIVE BLOCK COPOLYMERS BY LIVING CATIONIC POLYMERIZATION
138 2.5.1 INTRODUCTION 138 2.5.2 RESULTS AND DISCUSSION 139 A. LIVING
CATIONIC POLYMERIZATION IN THE PRESENCE OF ADDED BASES AND SYNTHESIS OF
VARIOUS FUNCTIONAL POLYMERS 139 B. SYNTHESIS OF COPOLYMERS OF VARIOUS
SHAPES 142 C. SYNTHESIS AND SELF-ASSOCIATION OF STIMULI-RESPONSIVE BLOCK
COPOLYMERS 145 2.5.3 SUMMARY 148 REFERENCES 150 3 MACROMOLECULAR
INORGANIC ASSEMBLIES 3.1 SPHERICAL, FIBROUS ROCK- AND SHEET-LIKE
NONCOVALENT POLYMERS. 156 3.1.1 INTRODUCTION 156 3.1.2 SPHERES 156
3.1.3 FIBERS 160 3.1.4 NANOMETER ROCKS ON SMOOTH SURFACES 162 3.1.5
PLANAR SHEETS 165 3.1.6 CONCLUSION 166 3.1.7 SUMMARY 167 3.2
MACROMOLECULAR CONJUGATED COMPLEXES 168 3.2.1 INTRODUCTION 168 3.2.2
COMPLEXES WITH REDOX-ACTIVE 7T-CONJUGATED POLYMERS 170 3.2.3 COMPLEXES
WITH REDOX-ACTIVE 7T-CONJUGATED MOLECULES 174 3.2.4 REDOX-ACTIVE
RT-CONJUGATED SYSTEMS 179 3.2.5 CONCLUSIONS 181 3.3 POLYMER-CAPPED
BIMETALLIC NANOCIUSTERS AS ACTIVE AND SELECTIVE CATALYSTS 182 3.3.1
INTRODUCTION 182 3.3.2 PREPARATION AND STRUCTURE OF POLYMER-CAPPED
BIMETALLIC NANOCIUSTERS 183 A. COREDUCTION OF MIXED IONS OF PRECIOUS
METALS 186 B. COREDUCTION OF MIXED IONS OF LIGHT TRANSITION METALS AND
PRECIOUS METALS 189 C. SUCCESSIVE REDUCTION OF METAL IONS 189 D.
SACRIFICIAL HYDROGEN REDUCTION 191 E. MIXING OF TWO KINDS OF
MONOMETALLIC NANOCIUSTERS 193 3.3.3 CATALYSIS OF POLYMER-CAPPED
BIMETALLIC NANOCIUSTERS 193 A. HYDROGENATION 194 XIV CONTENTS B.
HYDRATION OF ACRYLONITRILE 195 C. PHOTO-INDUCED GENERATION OF HYDROGEN
FROM WATER 196 3.3.4 FUTURE ASPECTS 196 3.4 ORGANIC-INORGANIC HYBRID
MATERIALS BASED ON SILSESQUIOXANES . 197 3.4.1 INTRODUCTION 197 3.4.2
ORGANIC-INORGANIC HYBRID NANOCOMPOSITES USING FUNCTIONALIZED POSS AS AN
INITIATOR 198 A. SYNTHESIS OF HYBRID MICELLES USING POLYOXAZOLINES
INITIATED BY MONOFUNCTIONAL POSS 198 B. SYNTHESIS OF STAR-SHAPED
POLYOXAZOLINES USING OCTAFUNCTIONAL POSS INITIATOR 198 3.4.3
ORGANIC-INORGANIC HYBRID POLYMERS 200 A. SYNTHESIS OF HYBRID GELS HAVING
FUNCTIONALIZED POSS 200 B. SYNTHESIS OF LIQUID-CRYSTALLINE HYBRID
POLYMERS USING POSS AS A COMPONENT OF COPOLYMERIZATION 202 C. SYNTHESIS
OF LIQUID-CRYSTALLINE POSS 202 3.4.4 TRANSPARENT ORGANIC-INORGANIC
POLYMER HYBRIDS WITH FUNCTIONALIZED POSS 205 A. SYNTHESIS OF POLYMER
HYBRIDS USING POSS WITH HYDROXYL CROUPS 205 B. SYNTHESIS OF TERNARY
POLYMER HYBRIDS OF POSS AND ORGANIC POLYMERS UTILIZING THE SOL-GEL
REACTION 206 C. SYNTHESIS OF POLYMER HYBRIDS USING TWO PHYSICAL BONDING
INTERACTIONS IN ONE SYSTEM 207 3.4.5 CONCLUSIONS AND FUTURE PERSPECTIVES
208 3.5 PROTONATION-INDUCED INTRAMOLECULAR ELECTRON TRANSFER IN THE
FERROCENE-QUINONE CONJUGATED SYSTEM 209 3.5.1 INTRODUCTION 209 3.5.2
1:1-D/A COMPLEXES 210 3.5.3 2:1-D/A COMPLEXES 214 3.5.4 A F2-D/A COMPLEX
219 3.5.5 POLYMERIE 1:1-D/A COMPLEXES 221 3.5.6 CONCLUDING REMARKS 222
3.6 OLIGOMERS OF NON-NATURAL METAL COMPLEX AMINO ACIDS 224 3.6.1
INTRODUCTION 224 3.6.2 DESIGN OF NON-NATURAL AMINO ACID 225 3.6.3
OLIGOMERS OF FERROCENE AMINO ACID 226 3.6.4 FERROCENE-PEPTIDE COMPLEXES
230 3.6.5 BIPYRIDINE COMPLEX AMINO ACID 231 3.6.6 TERPYRIDINE COMPLEX
AMINO ACID 233 3.6.7 CONCLUDING REMARK 234 CONTENTS XV REFERENCES 235 4
BIOLOGICAL MACROMOLECULAR COMPLEXES 4.1 MACROMOLECULAR METAL COMPLEXES
IN BIOLOGICAL SYSTEMS 244 4.1.1 INTRODUCTION 244 4.1.2 SMALL LIGANDS AND
POLYMERIE LIGANDS PRESENT IN BIOLOGY 246 A. COORDINATION BEHAVIOR OF
LIGANDS TOWARDS METAL IONS 246 B. BRIEF OVERVIEW OF LIGAND GROUPS THAT
BIND TO METALS IN BIOLOGICAL SYSTEMS 247 4.1.3 REACTIVITY OF METALS
COORDINATED TO BIOLOGICAL LIGANDS GENERAL ASPECTS 249 A. METAL IONS MAY
HAVE ONLY A STRUCTURAL OR STRUCTURE-ORGANIZING ROLE . 250 B. TRANSPORT
AND STORAGE OF METAL IONS BY BIOMACROMOLECULES 250 C. CATALYSIS BY METAL
IONS PRESENT IN BIOMACROMOLECULES 251 D. TOXIC AND MEDICINAL FUNCTIONS
OF METAL IONS RELATED TO BIOMACROMOLECULES 252 E. BINDING OF
PT-ANTITUMOR DRUGS TO DNA 253 4.1.4 CONCLUDING REMARKS 255 4.2 DIRECT
OBSERVATION OF SUPRAMOLECULAR STRUCTURES OF BIORELATED MATERIALS BY
ATOMIC FORCE MICROSCOPY 258 4.2.1 INTRODUCTION 258 4.2.2 ANTIBODY
SUPRAMOLECULES 259 A. SINGLE MOLECULAR IMAGES OF ANTIBODIES 259 B.
DIRECT OBSERVATION OF SUPRAMOLECULES BETWEEN ANTIBODIES AND PORPHYRIN
261 C. ANTIBODY DENDRIMERS: COMBINATION OF IGG AND IGM 262 4.2.3 DNA
SUPRAMOLECULES 264 A. IMAGING OF INDIVIDUAL PLASMID DNA MOLECULES 264 B.
PREPARATION OF NICKED DNA BY THE ADDITION OF DNASE I TO PLASMID DNA
PBR322 267 C. CATENATION REACTION USING TOPOISOMERASE I 268 D. SINGLE
MOLECULAR IMAGES OF DNA CATENANES OBSERVED BY AFM 268 E. DNA
[RC]CATENANES PREPARED BY IRREVERSIBLE REACTION WITH ' DNA LIGASE 270
4.2.4 CONCLUSIONS AND SUMMARY 272 4.3 ANALYSES OF THE NANOSTRUCTURE OF
CALCIUM CARBONATE COMPOSITE IN BIOMINERALS OF PINCTADA FUCATA 273 4.3.1
INTRODUCTION 273 4.3.2 SOLID STATE 13 C-NMR ANALYSIS OF THE NACREOUS
LAYER 274 4.3.3 HIGH RESOLUTION TEM ANALYSIS OF THE NACREOUS LAYER 277
4.3.4 CONCLUSIONS 280 XVI CONTENTS 4.4 A NOVEL TRIPLE HELIX CONSISTING
OF ONE POLYNUCLEOTIDE AND TWO POLYSACCHARIDE CHAINS 281 4.4.1
INTRODUCTION 281 4.4.2 SPECTROSCOPIC CHANGES UPON THE COMPLEXATION 283
4.4.3 MOLECULAR SPECIFICITY IN THE COMPLEXATION 284 4.4.4 TEMPERATURE
AND COMPOSITION DEPENDENCES OF CIRCULAR DICHROISM FOR THE COMPLEX 285
4.4.5 CRITICAL MOLECULAR WEIGHT TO INDUCE THE COMPLEXATION 287 4.4.6
STOICHIOMETRY AND MOLECULAR MODELING 287 4.4.7 CATION-INDUCED
COMPLEXATION 292 4.4.8 SWITCHING THE COMPLEXATION ON/OFF 293 4.4.9
CHEMICAL MODIFICATION TO ENHANCE AFFINITY 294 4.4.10 SUMMARY 296 4.5
PHYSICOCHEMICAL PROPERTIES OF SPIDER SILK*AN APPROACH TO NANOSTRUCTURE
297 4.5.1 INTRODUCTION 297 4.5.2 MATERIALS AND METHODS 299 A. SPIDER
SILKS 299 B. S AMPLES FOR THERMAL, OPTICAL AND AGING MEASUREMENTS 301 C.
PREPARATION OF SAMPLES FOR MECHANICAL MEASUREMENTS 301 D. WEIGHT OF
NEPHILA CLAVATA SPIDERS 301 E. THERMAL MEASUREMENTS 303 F. DENSITY OF
DRAGLINES 303 G. SCANNING ELECTRON MICROSCOPY 303 H. ELASTIC MODULUS 304
I. ESR MEASUREMENTS 304 J. ULTRAVIOLET RAYS 304 K. AMINO ACID
COMPOSITION 304 4.5.3 RESULTS AND DISCUSSION 304 A. THERMAL PROPERTIES ,
304 B. MECHANICAL LIFELINE OF DRAGLINES 307 C. MECHANICAL LIFELINE FOR
IMMATURE SPIDERS 310 D. ELASTIC MODULUS 312 E. DEGRADATION OF DRAGLINES
BY UV RAYS 314 F. STRENGTHENING OF DRAGLINES BY UV RAYS 316 G. INFRARED
DICHROISM 317 H. FINE STRUCTURE OF DRAGLINE 319 4.5.4 CONCLUSION 319
REFERENCES 321 INDEX 325 |
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| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-013017072 |
| oclc_num | 890428819 |
| open_access_boolean | |
| owner | DE-19 DE-BY-UBM DE-526 DE-83 DE-188 |
| owner_facet | DE-19 DE-BY-UBM DE-526 DE-83 DE-188 |
| physical | XVI, 335 S. Ill., graph. Darst. |
| publishDate | 2004 |
| publishDateSearch | 2004 |
| publishDateSort | 2004 |
| publisher | Springer [u.a.] |
| record_format | marc |
| series | Springer series in materials science |
| series2 | Springer series in materials science |
| spelling | Macromolecular nanostructured materials N. Ueyama ... (eds.) Berlin [u.a.] Springer [u.a.] 2004 XVI, 335 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Springer series in materials science 78 Macromolécules Nanomatériaux Macromolecules Nanostructured materials Nanostrukturiertes Material (DE-588)4342626-8 gnd rswk-swf Makromolekül (DE-588)4037172-4 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Makromolekül (DE-588)4037172-4 s Nanostrukturiertes Material (DE-588)4342626-8 s DE-604 Ueyama, Norikazu Sonstige oth Springer series in materials science 78 (DE-604)BV000683335 78 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=013017072&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Macromolecular nanostructured materials Springer series in materials science Macromolécules Nanomatériaux Macromolecules Nanostructured materials Nanostrukturiertes Material (DE-588)4342626-8 gnd Makromolekül (DE-588)4037172-4 gnd |
| subject_GND | (DE-588)4342626-8 (DE-588)4037172-4 (DE-588)4143413-4 |
| title | Macromolecular nanostructured materials |
| title_auth | Macromolecular nanostructured materials |
| title_exact_search | Macromolecular nanostructured materials |
| title_full | Macromolecular nanostructured materials N. Ueyama ... (eds.) |
| title_fullStr | Macromolecular nanostructured materials N. Ueyama ... (eds.) |
| title_full_unstemmed | Macromolecular nanostructured materials N. Ueyama ... (eds.) |
| title_short | Macromolecular nanostructured materials |
| title_sort | macromolecular nanostructured materials |
| topic | Macromolécules Nanomatériaux Macromolecules Nanostructured materials Nanostrukturiertes Material (DE-588)4342626-8 gnd Makromolekül (DE-588)4037172-4 gnd |
| topic_facet | Macromolécules Nanomatériaux Macromolecules Nanostructured materials Nanostrukturiertes Material Makromolekül Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=013017072&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000683335 |
| work_keys_str_mv | AT ueyamanorikazu macromolecularnanostructuredmaterials |