Inorganic and organometallic polymers:
"This textbook is intended to give an understanding of the basic principles that constitute the field of non-conventional polymers containing inorganic and organometallic units as the repeating units. Each chapter will be self-explanatory with a good background so that it can be easily understo...
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin [u. a.]
Springer
2005
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Zusammenfassung: | "This textbook is intended to give an understanding of the basic principles that constitute the field of non-conventional polymers containing inorganic and organometallic units as the repeating units. Each chapter will be self-explanatory with a good background so that it can be easily understood at the senior graduate level. The principles involved in the preparation of these polymers, their characterization and their applications will be discusses. Basic inorganic chemistry required for the understanding of each topic is presented so that the content of the chapter is readily understood. All the major inorganic and organometallic polymers such as polyphosphazenes, polysilanes, polysiloxanes, poly-thiazyl, poly-ferrocenes and other polymers containing main group elements will be dealt with."--BOOK JACKET. |
| Beschreibung: | XIII, 339 S. graph. Darst. |
| ISBN: | 3540225749 |
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| 100 | 1 | |a Chandrasekhar, Vadapalli |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Inorganic and organometallic polymers |c Vadapalli Chandrasekhar |
| 264 | 1 | |a Berlin [u. a.] |b Springer |c 2005 | |
| 300 | |a XIII, 339 S. |b graph. Darst. | ||
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| 520 | 1 | |a "This textbook is intended to give an understanding of the basic principles that constitute the field of non-conventional polymers containing inorganic and organometallic units as the repeating units. Each chapter will be self-explanatory with a good background so that it can be easily understood at the senior graduate level. The principles involved in the preparation of these polymers, their characterization and their applications will be discusses. Basic inorganic chemistry required for the understanding of each topic is presented so that the content of the chapter is readily understood. All the major inorganic and organometallic polymers such as polyphosphazenes, polysilanes, polysiloxanes, poly-thiazyl, poly-ferrocenes and other polymers containing main group elements will be dealt with."--BOOK JACKET. | |
| 650 | 7 | |a Anorganische polymeren |2 gtt | |
| 650 | 7 | |a Cyclofosfazenen |2 gtt | |
| 650 | 7 | |a Organometaalverbindingen |2 gtt | |
| 650 | 7 | |a Polyfosfazenen |2 gtt | |
| 650 | 7 | |a Polymeren |2 gtt | |
| 650 | 4 | |a Polymères inorganiques | |
| 650 | 4 | |a Polymères organométalliques | |
| 650 | 7 | |a Polysilanen |2 gtt | |
| 650 | 7 | |a Polysiloxanen |2 gtt | |
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| 650 | 4 | |a Organometallic polymers | |
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Datensatz im Suchindex
| _version_ | 1804133122349989888 |
|---|---|
| adam_text | CONTENTS
1 INORGANIC POLYMERS: PROBLEMS AND PROSPECTS 1
1.1 INTRODUCTION 1
1.2 PROCEDURES FOR SYNTHESIZING ORGANIC POLYMERS 2
1.3 INORGANIC POLYMERS: A REVIEW OF SYNTHETIC STRATEGIES 5
1.3.1 UNSATURATED INORGANIC COMPOUNDS 6
1.3.2 INORGANIC POLYMERS FROM ACYCLIC MONOMERS 7
1.3.3 RING-OPENING POLYMERIZATION OF CYCLIC INORGANIC
COMPOUNDS 16
1.3.4 POLYMERS CONTAINING INORGANIC RINGS OR MOTIFS AS
PENDANT GROUPS 21
1.4 SUMMARY OF POLYMERIZATION PROCEDURES FOR INORGANIC POLYMERS . 22
REFERENCES 25
2 ORGANIC POLYMERS - A BRIEF SURVEY 27
2.1 INTRODUCTION 27
2.2 NATURAL POLYMERS 28
2.3 SYNTHETIC POLYMERS 29
2.4 FREE-RADICAL POLYMERIZATION 30
2.4.1 INITIATORS 31
2.4.2 MECHANISM OF POLYMERIZATION 33
2.4.3 BRANCHING 34
2.4.4 CHAIN TRANSFER 35
2.4.5 SUMMARY OF THE MAIN FEATURES OF FREE-RADICAL
POLYMERIZATION 36
2.5 POLYMERIZATION BY IONIC INITIATORS 36
2.5.1 ANIONIC POLYMERIZATION 37
2.5.2 CATIONIC POLYMERIZATION 40
2.6 ZIEGLER-NATTA CATALYSIS 43
2.6.1 MECHANISM OF POLYMERIZATION OF OLEFINS USING THE
ZIEGLER-NATTA CATALYSTS 45
2.6.2 SUPPORTED ZIEGLER-NATTA CATALYSTS 50
2.6.3 RECENT DEVELOPMENTS IN ZIEGLER-NATTA CATALYSIS 50
2.6.4 SUMMARY OF THE ZIEGLER-NATTA CATALYSIS 55
X CONTENTS
2.7 OLEFM METATHESIS POLYMERIZATION 56
2.8 ATOM TRANSFER RADICAL POLYMERIZATION 58
2.9 RING-OPENING POLYMERIZATION 60
2.10 GROUP-TRANSFER POLYMERIZATION 62
2.11 CONDENSATION POLYMERS 63
2.11.1 POLYESTERS 64
2.11.2 POLYCARBONATES 67
2.11.3 POLYAMIDES 67
2.11.4POLYIMIDES 69
2.11.5 POLYSULFONES 71
2.11.6 THERMOSET RESINS 71
2.12 SOME BASIC FEATURES ABOUT POLYMERS 75
2.12.1 MOLECULAR WEIGHTS OF POLYMERS 75
2.12.2 GLASS TRANSITION TEMPERATURE OF POLYMERS 76
2.12.3 ELASTOMERS, FIBERS AND PLASTICS 77
REFERENCES 80
3 CYCLO- AND POLYPHOSPHAZENES 82
3.1 INTRODUCTION 82
3.2 CYCLOPHOSPHAZENES 83
3.2.1 PREPARATION OF CHLOROCYCLOPHOSPHAZENES 86
3.2.2 PREPARATION OF FLUOROCYCLOPHOSPHAZENES AND OTHER
HALOGENO- AND PSEUDOHALOGENOCYCLOPHOSPHAZENES 89
3.2.3 CHLORINE REPLACEMENT REACTIONS OF
CHLOROCYCLOPHOSPHAZENES 90
3.2.4 OTHER METHODS OF PREPARING P-C CONTAINING COMPOUNDS... 94
3.2.5 REACTIONS OF CHLOROCYCLOPHOSPHAZENES WITH DIFUNCTIONAL
REAGENTS 95
3.2.6 ISOMERISM IN CYCLOPHOSPHAZENES 99
3.2.7 MECHANISM OF THE NUCLEOPHILIC SUBSTITUTION REACTION 100
3.2.8 CYCLOPHOSPHAZENES AS LIGANDS FOR TRANSITION METAL
COMPLEXES 104
3.2.9 STRUCTURAL CHARACTERIZATION OF CYCLOPHOSPHAZENES 106
3.2.10 NATURE OF BONDING IN CYCLOPHOSPHAZENES 108
3.3 POLYPHOSPHAZENES 112
3.3.1 HISTORICAL 112
3.3.2 POLY(DICHLOROPHOSPHAZENE) 113
3.3.3 CONDENSATION POLYMERIZATION OF C1
3
P=N-P(O)C1
2
116
3.3.4 POLYMERIZATION OF CL
3
P=NSIME
3
118
3.3.5 ROP OF SUBSTITUTED CYCLOPHOSPHAZENES 123
PO1Y(ORGANOPHOSPHAZENE)S PREPARED BY
SUBSTITUTION OF [NPCL
2
]
N
126
CONTENTS XI
3.3.7 PREPARATION OF POLYPHOSPHAZENES CONTAINING P-C BONDS
BY THERMAL TREATMENT OF PHOSPHORANIMINES 131
3.3.8 MODIFICATION OF POLY(ORGANOPHOSPHAZENE)S 136
3.3.9 MODIFICATION OF POLY(ALKYL/ARYLPHOSPHAZENE)S 140
3.3.10 STRUCTURE AND PROPERTIES OF POLYPHOSPHAZENES 142
3.3.11 POTENTIAL APPLICATIONS OF POLYPHOSPHAZENES 150
REFERENCES 153
4 CYCLOPHOSPHAZENE-CONTAINING POLYMERS 155
4.1 INTRODUCTION 155
4.2 POLYMERS CONTAINING CYCLOPHOSPHAZENES AS PENDANT GROUPS 156
4.2.1 SYNTHESIS OF CYCLOPHOSPHAZENE MONOMERS CONTAINING
VINYL GROUPS 158
4.2.2 POLYMERIZATION OF CYCLOPHOSPHAZENE MONOMERS 165
4.2.3 OTHER WAYS OF MAKING POLYMERS CONTAINING
CYCLOPHOSPHAZENE PENDANT GROUPS 172
4.2.4 APPLICATIONS OF POLYMERS CONTAINING CYCLOPHOSPHAZENE
PENDANT GROUPS 173
4.3 CYCLOLINEAR AND CYCLOMATRIX POLYMERS 178
REFERENCES 181
5 OTHER INORGANIC POLYMERS THAT CONTAIN PHOSPHORUS, BORON
AND SULFUR 183
5.1 POLY(HETEROPHOSPHAZENE)S 183
5.2 POLY(CARBOPHOSPHAZENE)S 184
5.3 POLY(THIOPHOSPHAZENE)S 189
5.4 POLY(THIONYLPHOSPHAZENE)S 193
5.4.1 POLYMERIZATION OF [{NPC1
2
}
2
{NS(O)C1}] AND
[{NPC1
2
}
2
{NS(O)F}] 194
5.5 OTHER P-N-S POLYMERS 199
5.6 METALLACYCLOPHOSPHAZENES 200
5.7 OTHER PHOSPHORUS-CONTAINING POLYMERS 203
5.7.1 POLYPHOSPHINOBORANES 203
5.7.2 POLYMERS CONTAINING P=C BONDS 204
5.8 POLY(ALKYL/ARYLOXOTHIAZENES) 205
5.9 BORAZINE-BASED POLYMERS 206
REFERENCES 207
6 POLYSILOXANES 209
6.1 INTRODUCTION 209
6.2 HISTORICAL ASPECTS OF POLY(DIMETHYSILOXANE) 215
6.3 RING-OPENING POLYMERIZATION OF CYCLOSILOXANES 219
XII CONTENTS
6.3.1 CYCLOSILOXANES 220
6.3.2 RING-OPENING POLYMERIZATION OF CYCLOSILOXANES BY
IONIC INITIATORS 224
6.3.3 PREPARATION OF COPOLYMERS BY RING-OPENING
POLYMERIZATION 230
6.3.4 SUMMARY OF THE RING-OPENING POLYMERIZATION OF
CYCLOSILOXANES 231
6.4 CONDENSATION POLYMERIZATION 232
6.5 CROSSLINKING OF POLYSILOXANES 234
6.5.1 OTHER WAYS OF ACHIEVING CROSSLINKING 234
6.6 HYBRID POLYMERS 239
6.7 PROPERTIES OF POLYSILOXANES 241
6.7.1 GLASS-TRANSITION TEMPERATURES AND CONFORMATIONAL
FLEXIBILITY 241
6.8 APPLICATIONS OF POLYSILOXANES 244
REFERENCES 246
7 POLYSILANES AND OTHER SILICON-CONTAINING POLYMERS 249
7.1 INTRODUCTION 249
7.2 HISTORICAL 251
7.3 SYNTHESIS OF POLYSILANES 254
7.3.1 SYNTHESIS OF POLYSILANES BY WURTZ-TYPE COUPLING
REACTIONS 255
7.3.2 POLYMERIZATION BY ANIONIC INITIATORS 260
7.3.3 POLYSILANES OBTAINED BY CATALYTIC DEHYDROGENATION 265
7.3.4 SUMMARY OF THE SYNTHETIC PROCEDURES FOR POLYSILANES 268
7.4 MODIFICATION OF POLYSILANES 269
7.5 PHYSICAL PROPERTIES OF POLYSILANES 272
7.5.1 NMR OF POLYSILANES 273
7.5.2 ELECTRONIC SPECTRA OF POLYSILANES 276
7.6 OPTICALLY ACTIVE POLYSILANES 278
7.7 APPLICATIONS OF POLYSILANES 280
7.8 POLYSILYNES 281
7.9 POLYCARBOSILANES AND POLYSILOLES 284
7.9.1 POLYCARBOSILANES 284
7.9.2 POLYSILOLES 288
REFERENCES 292
8 ORGANOMETALLIC POLYMERS 296
8.1 INTRODUCTION 296
8.2 POLYGERMANES AND POLYSTANNANES 297
8.2.1 SYNTHESIS OF POLYGERMANES 298
CONTENTS XIII
8.2.2 SYNTHESIS OF POLYSTANNANES 300
8.2.3 ELECTRONIC PROPERTIES OF POLYGERMANES AND POLYSTANNANES.. 302
8.3 FERROCENE-CONTAINING POLYMERS 303
8.3.1 SYNTHETIC STRATEGIES 304
8.3.2 STRAINED FERROCENOPHANES 310
8.3.3 POLY(FERROCENYLSILANE)S 312
8.3.4 OTHER FERROCENYL POLYMERS PREPARED FROM STRAINED
FERROCENOPHANES 318
8.3.5 OTHER RELATED POLYMERS 320
8.3.6 PROPERTIES AND APPLICATIONS OF POLY(FERROCENYLSILANE)S
AND RELATED POLYMERS 321
8.4 POLYYNE RIGID-ROD ORGANOMETALLIC POLYMERS 324
8.4.1 PROPERTIES AND APPLICATIONS OF RIGID-ROD POLYYNES 332
REFERENCES 333
INDEX 337
|
| any_adam_object | 1 |
| author | Chandrasekhar, Vadapalli |
| author_facet | Chandrasekhar, Vadapalli |
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| dewey-ones | 541 - Physical chemistry |
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| dewey-search | 541/.2254 |
| dewey-sort | 3541 42254 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
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| publisher | Springer |
| record_format | marc |
| spelling | Chandrasekhar, Vadapalli Verfasser aut Inorganic and organometallic polymers Vadapalli Chandrasekhar Berlin [u. a.] Springer 2005 XIII, 339 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier "This textbook is intended to give an understanding of the basic principles that constitute the field of non-conventional polymers containing inorganic and organometallic units as the repeating units. Each chapter will be self-explanatory with a good background so that it can be easily understood at the senior graduate level. The principles involved in the preparation of these polymers, their characterization and their applications will be discusses. Basic inorganic chemistry required for the understanding of each topic is presented so that the content of the chapter is readily understood. All the major inorganic and organometallic polymers such as polyphosphazenes, polysilanes, polysiloxanes, poly-thiazyl, poly-ferrocenes and other polymers containing main group elements will be dealt with."--BOOK JACKET. Anorganische polymeren gtt Cyclofosfazenen gtt Organometaalverbindingen gtt Polyfosfazenen gtt Polymeren gtt Polymères inorganiques Polymères organométalliques Polysilanen gtt Polysiloxanen gtt Inorganic polymers Organometallic polymers Metallorganische Polymere (DE-588)4169616-5 gnd rswk-swf Anorganische Polymere (DE-588)4142565-0 gnd rswk-swf Anorganische Polymere (DE-588)4142565-0 s DE-604 Metallorganische Polymere (DE-588)4169616-5 s DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=013009810&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Chandrasekhar, Vadapalli Inorganic and organometallic polymers Anorganische polymeren gtt Cyclofosfazenen gtt Organometaalverbindingen gtt Polyfosfazenen gtt Polymeren gtt Polymères inorganiques Polymères organométalliques Polysilanen gtt Polysiloxanen gtt Inorganic polymers Organometallic polymers Metallorganische Polymere (DE-588)4169616-5 gnd Anorganische Polymere (DE-588)4142565-0 gnd |
| subject_GND | (DE-588)4169616-5 (DE-588)4142565-0 |
| title | Inorganic and organometallic polymers |
| title_auth | Inorganic and organometallic polymers |
| title_exact_search | Inorganic and organometallic polymers |
| title_full | Inorganic and organometallic polymers Vadapalli Chandrasekhar |
| title_fullStr | Inorganic and organometallic polymers Vadapalli Chandrasekhar |
| title_full_unstemmed | Inorganic and organometallic polymers Vadapalli Chandrasekhar |
| title_short | Inorganic and organometallic polymers |
| title_sort | inorganic and organometallic polymers |
| topic | Anorganische polymeren gtt Cyclofosfazenen gtt Organometaalverbindingen gtt Polyfosfazenen gtt Polymeren gtt Polymères inorganiques Polymères organométalliques Polysilanen gtt Polysiloxanen gtt Inorganic polymers Organometallic polymers Metallorganische Polymere (DE-588)4169616-5 gnd Anorganische Polymere (DE-588)4142565-0 gnd |
| topic_facet | Anorganische polymeren Cyclofosfazenen Organometaalverbindingen Polyfosfazenen Polymeren Polymères inorganiques Polymères organométalliques Polysilanen Polysiloxanen Inorganic polymers Organometallic polymers Metallorganische Polymere Anorganische Polymere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=013009810&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT chandrasekharvadapalli inorganicandorganometallicpolymers |