Acid-base chemistry:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New York
Macmillan [u.a.]
1986
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 273 S. Graph. Darst. |
| ISBN: | 0023499109 |
Internformat
MARC
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| 100 | 1 | |a Hand, Clifford W. |e Verfasser |4 aut | |
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| 264 | 1 | |a New York |b Macmillan [u.a.] |c 1986 | |
| 300 | |a X, 273 S. |b Graph. Darst. | ||
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| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Acid-base balance | |
| 650 | 7 | |a Säure-Base-Gleichgewicht |2 swd | |
| 650 | 4 | |a Acid-base chemistry | |
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Datensatz im Suchindex
| _version_ | 1804132949069660160 |
|---|---|
| adam_text | IMAGE 1
ACID-BASE CHEMISTRY
CLIFFORD W. HAND HARRY LYON BLEWITT
DEPARTMENT OF CHEMISTRY UNIVERSITY OF ALABAMA
J
MACMILLAN PUBLISHING COMPANY NEW YORK COLLIER MACMILLAN PUBLISHERS
LONDON
IMAGE 2
CONTENTS
1. INTRODUCTION TO THE STUDY OF ACID-BASE CHEMISTRY 1.1 WHAT IS
ACID-BASE CHEMISTRY? 1 1.2 CHEMICAL REACTIONS 1 1.3 BOND CLEAVAGE
PROCESSES 2
1.4 ENERGY AND STABILITY 3 1.5 IMPORTANCE OF ACID-BASE CHEMISTRY 5
2. GENERAL CONCEPTS OF ACIDS AND BASES
2.1 HISTORICAL BACKGROUND 6 2.2 PROPERTIES OF ACIDS AND BASES 7 2.3
ARRHENIUS CONCEPT 8 2.4 BR0NSTED-LOWRY THEORY 9 2.5 STRENGTH OF ACIDS
AND BASES 11 2.6 NATURE OF THE AQUEOUS PROTON 12 2.7 AMPHIPROTIC
SUBSTANCES 13 2.8 AUTOINOIZATION 17
2/9 THE LEVELING EFFECT OF SOLVENT 17 2.10 PREPARATION OF INORGANIC
ACIDS 18 2.11 PREPARATION OF SOME COMMON BASES 22 PROBLEMS 26
3. QUANTITATIVE ASPECTS OF ACIDITY
3.1 INTRODUCTION AND REVIEW OF ELEMENTARY CONCEPTS 29 3.2 STRONG ACIDS
36 3.3 WEAK ACIDS 37 3.4 CALCULATIONS OF ACID IONIZATION 41 3.5 WEAK
BASES 43
3.6 BASICITY 45
IMAGE 3
VIII CONTENTS
3.7 AUTOIONIZATION 45
3.8 AN APPROXIMATE METHOD 48 3.9 VERY DILUTE SOLUTIONS AND VERY WEAK
ACIDS 50 3.10 SUMMARY 53 PROBLEMS 54
4. LEWIS ACIDS AND BASES 4.1 INTRODUCTION 58 4.2 WHAT IS A LEWIS ACID?
58 4.3 STRENGTH OF LEWIS ACIDS 60 4.4 STRENGTH OF LEWIS BASES 60 4.5
TYPES OF LEWIS ACIDS 61 4.6 TYPES OF LEWIS BASES 63
4.7 DISPLACEMENT REACTIONS 64 4.8 COMPARISON OF LEWIS AND BR0NSTED-LOWRY
VIEWS 68 4.9 USANOVICH ACID-BASE THEORY 68 4.10 SOME GENERALIZATIONS 69
PROBLEMS 70
5. THE EFFECTS OF STRUCTURE ON ACID-BASE STRENGTH 5.1 INTRODUCTION 71
5.2 ELECTRONEGATIVITY 71 5.3 RESONANCE 72 5.4 INDUCTIVE EFFECT 78 5.5
SIZE OF THE ION 83
5.6 MAGNITUDE OF THE CHARGE 84 5.7 APPLICATIONS: HYDROGEN HALIDES AND
BORON TRIHALIDES 84 PROBLEMS 87
6. APPLICATIONS AND EXAMPLES IN ORGANIC CHEMISTRY 6.1 INTRODUCTION 89
6.2 HYDROCARBONS: THE EFFECT OF HYBRIDIZATION 89 6.3 ORGANIC OXYGEN
ACIDS 92 6.4 BASIC FUNCTIONAL GROUPS 99 6.5 AMIDES AND IMIDES 104 6.6
SULFONAMIDES AND THE HINSBERG TEST 105 6.7 CARBANIONS: THEIR USE IN
ORGANIC SYNTHESIS 107
6.8 ALKENES: THEIR FORMATION AND BASIC CHARACTER 111 6.9 BENZENE AS A
BASE 113 6.10 ACID-CATALYZED ESTER FORMATION 115 6.11 CONCLUSION 116
PROBLEMS 117
IMAGE 4
CONTENTS IX
7. SALT HYDROLYSIS AND BUFFER ACTION 124
7.1 HYDROLYSIS 124 7.2 THE RELATIONSHIP BETWEEN K H AND K A 127 7.3
BUFFER SOLUTIONS 130 7.4 BUFFER CALCULATIONS 132
7.5 BUFFER CAPACITY 136 7.6 PREPARATION OF BUFFERS 138 7.7 EXACT
TREATMENT 139 7.8 VALIDITY OF THE HENDERSON-HASSELBALCH EQUATION 141
7.9 ERRORS AND VALIDITY RANGES 142 PROBLEMS 144
8. TITRATIONS 148
8.1 INTRODUCTION AND DEFINITIONS 148 8.2 CALCULATIONS 152 8.3 WEAK ACID
TITRATION CURVES 159 8.4 INDICATORS 163 8.5 VERY WEAK ACIDS 167
PROBLEMS 167
9. POLYPROTIC ACIDS AND AMPHIPROTIC SUBSTANCES 169
9.1 POLYPROTIC ACIDS 169 9.2 POLYHYDRIC BASES 172 9.3 EXACT CALCULATIONS
172 9.4 CONCENTRATION VERSUS PH GRAPHS 176 9.5 APPROXIMATE CALCULATIONS
180 9.6 POLYPROTIC BUFFER SOLUTIONS 183 9.7 TITRATION AND TITRATION
CURVES 184 9.8 AMPHIPROTIC SUBSTANCES 187 9.9 AMPHIPROTIC SALTS 188 9.10
INNER SALTS 193
PROBLEMS 195
10. RELATION EQUILIBRIA 197
10.1 COMPLEXATION 197 10.2 SOLUBILITY 201 10.3 SIMULTANEOUS EQUILIBRIA
204 10.4 SUCCESSIVE APPROXIMATIONS 207 10.5 PRECIPITATION OF HYDROXIDES
BY PH CONTROL 209 10.6 PRECIPITATION OF SULFIDES BY PH CONTROL 211 10.7
OTHER PH-DEPENDENT PRECIPITATIONS 212
PROBLEMS 213
IMAGE 5
CONTENTS
11. EXPERIMENTAL DETERMINATION OF PK
11.1 WEAK ACIDS 215 11.2 POTENTIOMETRIE TITRATIONS 216 11.3
SPECTROPHOTOMETRIC METHODS 219 11.4 OTHER METHODS 221 11.5 STRONG ACIDS
222 11.6 NONAQUEOUS SOLVENTS 222 11.7 VERY WEAK ACIDS: CARBON ACIDS AND
CARBANIONS 225 11.8 GAS-PHASE ACIDITIES 226 11.9 CINCLUSION 226
215
APPENDIX I AUTOIONIZATION CONSTANT OF WATER APPENDIX II COMPUTER
PROGRAMS IN BASIC APPENDIX III LONIZATION CONSTANTS (25C) OF SELECTED
ACIDS AND BASES APPENDIX IV ACTIVITY COEFFICIENTS
APPENDIX V ABSORBANCE APPENDIX VI APPROXIMATIONS, ERRORS, AND THE EXACT
SOLUTION
227 228 246 255
258 260
INDEX
|
| any_adam_object | 1 |
| author | Hand, Clifford W. Blewitt, Harry L. |
| author_facet | Hand, Clifford W. Blewitt, Harry L. |
| author_role | aut aut |
| author_sort | Hand, Clifford W. |
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| building | Verbundindex |
| bvnumber | BV019589332 |
| callnumber-first | Q - Science |
| callnumber-label | QD477 |
| callnumber-raw | QD477 |
| callnumber-search | QD477 |
| callnumber-sort | QD 3477 |
| callnumber-subject | QD - Chemistry |
| classification_rvk | VE 6350 |
| ctrlnum | (OCoLC)11186221 (DE-599)BVBBV019589332 |
| dewey-full | 547/.037 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547/.037 |
| dewey-search | 547/.037 |
| dewey-sort | 3547 237 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV019589332 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-09T20:00:56Z |
| institution | BVB |
| isbn | 0023499109 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-012926124 |
| oclc_num | 11186221 |
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| owner | DE-M49 DE-BY-TUM |
| owner_facet | DE-M49 DE-BY-TUM |
| physical | X, 273 S. Graph. Darst. |
| publishDate | 1986 |
| publishDateSearch | 1986 |
| publishDateSort | 1986 |
| publisher | Macmillan [u.a.] |
| record_format | marc |
| spelling | Hand, Clifford W. Verfasser aut Acid-base chemistry Clifford W. Hand ; Harry Lyon Blewitt New York Macmillan [u.a.] 1986 X, 273 S. Graph. Darst. txt rdacontent n rdamedia nc rdacarrier Acid-base balance Säure-Base-Gleichgewicht swd Acid-base chemistry Säure-Base-Gleichgewicht (DE-588)4051270-8 gnd rswk-swf Säure-Base-Gleichgewicht (DE-588)4051270-8 s 1\p DE-604 Blewitt, Harry L. Verfasser aut GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012926124&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Hand, Clifford W. Blewitt, Harry L. Acid-base chemistry Acid-base balance Säure-Base-Gleichgewicht swd Acid-base chemistry Säure-Base-Gleichgewicht (DE-588)4051270-8 gnd |
| subject_GND | (DE-588)4051270-8 |
| title | Acid-base chemistry |
| title_auth | Acid-base chemistry |
| title_exact_search | Acid-base chemistry |
| title_full | Acid-base chemistry Clifford W. Hand ; Harry Lyon Blewitt |
| title_fullStr | Acid-base chemistry Clifford W. Hand ; Harry Lyon Blewitt |
| title_full_unstemmed | Acid-base chemistry Clifford W. Hand ; Harry Lyon Blewitt |
| title_short | Acid-base chemistry |
| title_sort | acid base chemistry |
| topic | Acid-base balance Säure-Base-Gleichgewicht swd Acid-base chemistry Säure-Base-Gleichgewicht (DE-588)4051270-8 gnd |
| topic_facet | Acid-base balance Säure-Base-Gleichgewicht Acid-base chemistry |
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