Organic chemistry of photography: with 32 tables
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
Berlin [u.a.]
Springer
2004
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| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIX, 587 S. graph. Darst. |
| ISBN: | 3540209883 |
Internformat
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| 245 | 1 | 0 | |a Organic chemistry of photography |b with 32 tables |c Shinsaku Fujita |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 2004 | |
| 300 | |a XIX, 587 S. |b graph. Darst. | ||
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Datensatz im Suchindex
| _version_ | 1804132916311097344 |
|---|---|
| adam_text | Titel: Organic chemistry of photography
Autor: Fujita, Shinsaku
Jahr: 2004
Table of Contents
I Fundamentals of Photography 1
1. Photography Based on Silver Halides. An Overview 3
1.1 Photographic Processes.................... 3
1.1.1 Black-and-White Photographic Process ....... 3
1.1.2 Color Photographic Process.............. 5
1.2 Multilayer Structure of Photographic Materials........ 7
1.2.1 Multilayer Structure of Color Papers......... 7
1.2.2 Multilayer Structure of Color Films ......... 17
1.2.3 Other Multilayer Structure of Color Films...... 25
1.3 Chemicals for Color Photography............... 35
References............................... 37
2. Photographic Emulsions 39
2.1 Silver Halides—Fundamental Chemical Properties...... 39
2.1.1 Precipitation of Silver Halides............ 39
2.1.2 Silver Complexes................... 41
2.2 Gelatin—Fundamental Chemical Properties......... 44
2.2.1 Merits of Gelatin as Binder.............. 44
2.2.2 Manufacture of Gelatin................ 45
2.2.3 Side-Chain Groups of Gelatin............. 46
2.3 Preparation of Photographic Emulsions............ 47
2.3.1 Preparation With and Without Ammonia....... 47
2.3.2 Examples of Procedures................ 48
2.4 Precipitation.......................... 49
2.4.1 Crystal Growth.................... 49
2.5 Washing............................ 52
XII Table of Contents
2.6 After-Ripening and Chemical Sensitization.......... 52
2.6.1 Sulfur Sensitization.................. 53
2.6.2 Reduction Sensitization................ 54
2.6.3 Gold Sensitization................... 54
2.6.4 Example of Chemical Sensitization.......... 55
2.7 Industrial Manufacture of Silver Halide Emulsions...... 56
References............................... 57
3. Silver Halide Crystals. Fundamental Properties 59
3.1 Crystal Structures of Silver Halides.............. 59
3.1.1 Dimension of Crystal Lattices ............ 59
3.1.2 Solid Solutions.................... 61
3.2 Shapes of Silver Halide Crystals ............... 61
3.2.1 Representation of Shapes............... 61
3.2.2 Controlling Crystal Shapes of Silver Halides..... 63
3.3 Lattice Defects in Crystals................... 64
3.3.1 Kinds of Lattice Defects ............... 64
3.3.2 Intrinsic Point Defects................. 65
3.3.3 Extrinsic Point Defects................ 67
3.3.4 Linear Defects—Dislocations............. 67
3.3.5 Kink and Jog Sites .................. 69
3.3.6 Twinned Crystals................... 70
3.4 Spectral and Electronic Properties of Silver Halide Crystals . 71
3.4.1 Band Theory...................... 71
3.4.2 Optical Absorption.................. 72
References............................... 73
4. Silver Halide Crystals. Photo-Sensitivity 75
4.1 Mechanism of Latent-Image Formation............ 75
4.1.1 Mechanism for Electronic Process .......... 77
4.1.2 Mechanism for Ionic Process and Silver Clusters . . 80
4.1.3 Mechanism for Photo-Hole Process.......... 81
4.1.4 Formation of Photo-Electrons............. 81
4.1.5 Overall Chemical Sensitizations........... 82
4.2 Tabular Grains......................... 84
4.2.1 Tabular Grains for Color Negative Films....... 84
4.2.2 2-Grains....................... 87
4.2.3 Example for Preparing Tabular Grains........ 88
4.2.4 Crystal Habit Controlling Agents........... 89
References............................... 90
5. Photographic Development and Developers 93
5.1 Photographic Development.................. 93
5.2 Photographic Developers................... 94
5.2.1 Hydroquinones and Related Compounds....... 94
Table of Contents XIII
5.2.2 Aminophenols and Related Compounds....... 94
5.2.3 Hydrazine Derivatives................. 95
5.2.4 Hydroxylamine Derivatives.............. 95
5.2.5 Ascorbic Acid and Related Compounds....... 95
5.2.6 Heterocyclic Developers............... 96
5.2.7 Kendall s Rule..................... 96
5.3 Electrochemistry of Development............... 97
5.3.1 Redox Reactions ................... 97
5.3.2 The Silver Electrode Potential ............ 97
5.3.3 Developer Potential.................. 98
5.3.4 Effect of Semiquinone Formation........... 99
References............................... 101
II Principles of Color Photography 103
6. Color Reproduction 105
6.1 Color and Absorption..................... 105
6.2 Additive and Subtractive Color Reproduction......... 106
6.2.1 Additive Color Reproduction............. 106
6.2.2 Subtractive Color Reproduction............ 107
6.2.3 Negative and Positive Images............. 108
6.3 Color Image Formation.................... 109
6.3.1 Principles of Color Image Formation......... 109
6.3.2 Chromogenic (Dye-Forming) Process........ 110
6.3.3 Dye-Bleaching Process................ 110
6.3.4 Dye-Transfer Process................. 110
References............................... 112
7. Spectral Sensitizaron and Sensitizing Dyes 113
7.1 Background.......................... 113
7.2 Chromophoric Systems of Sensitizing Dyes ......... 114
7.3 CyanineDyes......................... 117
7.4 Mechanism of Spectral Sensitization............. 119
7.5 Syntheses of Sensitizing Dyes................. 121
7.5.1 Symmetrically Substituted Sensitizing Dyes..... 121
7.5.2 Unsymmetrical Sensitizing Dyes........... 123
7.5.3 Chains Incorporating a Heterocyclic Ring...... 123
7.6 Recent Topics......................... 125
7.6.1 Residual Color Due to Sensitizing Dyes....... 125
7.6.2 Additional Sensitizing Layer............. 126
7.6.3 Infrared-Sensitizing Dyes for Digital Printing .... 128
7.6.4 Sensitizing Dyes Applied to CD-R.......... 130
References............................... 132
XIV Table of Contents
III Chromogenic Photography 135
8. History of Color Development 137
8.1 Fischer s Pioneering Work................... 137
8.2 Diffusible Couplers...................... 139
8.3 Non-diffusible Couplers.................... 143
8.3.1 Hydrophilic Couplers................. 143
8.3.2 Oil- and Polymer-Protected Couplers......... 144
8.4 Syntheses of Non-diffusible Couplers............. 148
8.4.1 Syntheses of Hydrophilic Couplers.......... 148
8.4.2 Syntheses of Oil-Protected Couplers......... 150
References............................... 153
9. Color Developers 155
9.1 Syntheses and Basic Properties................ 155
9.2 Mechanism of Reactions.................... 157
9.2.1 Dye Formation .................... 157
9.2.2 Side Reactions..................... 160
References............................... 162
10. Couplers 163
10.1 Negative-Positive Process................... 163
10.2 Couplers and Azomethine Dyes................ 166
10.2.1 Dye-Forming Reactions................ 166
10.2.2 Properties of Dyes.................... 168
10.2.3 Ballast Groups for Oil-Protection........... 168
10.3 Cyan Couplers......................... 168
10.3.1 Naphthol Couplers.................. 169
10.3.2 Phenol Couplers.................... 173
10.3.3 Heterocyclic Cyan Couplers ............. 182
10.4 Magenta Couplers . ...................... 185
10.4.1 5-Pyrazolone Couplers................ 185
10.4.2 Pyrazolotriazole Magenta Couplers.......... 188
10.5 Yellow Couplers........................ 206
10.5.1 Benzoylacetanilide Couplers............. 206
10.5.2 Pivaloylacetanilide Couplers............. 210
10.5.3 Cyclopropanecarbonylacetanilide Couplers..... 212
10.5.4 Malondiamide Couplers................ 214
10.5.5 Pyrroloylacetanilides and Related Couplers..... 215
10.6 Polymer Couplers....................... 219
References............................... 220
11. Two-Equivalent Couplers 225
11.1 Merits of Two-Equivalent Couplers.............. 225
11.2 Two-Equivalent Cyan Couplers................ 226
Table of Contents XV
11.2.1 Two-Equivalent Cyan Couplers of Naphthol Type . . 226
11.2.2 Two-Equivalent Cyan Couplers of Other Types . . . 229
11.3 Two-Equivalent Magenta Couplers.............. 230
11.3.1 Two-Equivalent 5-Pyrazolone Couplers ....... 230
11.3.2 Two-Equivalent Magenta Couplers of Other Types . . 236
11.4 Two-Equivalent Yellow Couplers............... 238
11.4.1 Earlier Two-Equivalent Yellow Couplers....... 238
11.4.2 Acylacetanilide Couplers............... 239
References............................... 244
12. Colored Couplers 247
12.1 Color Masking......................... 247
12.1.1 Azomethine Dyes From Azo Dyes.......... 247
12.1.2 Azo Dyes as Colored Couplers............ 249
12.2 Colored Cyan Couplers.................... 252
12.2.1 Magenta-Colored Cyan Couplers........... 252
12.2.2 Yellow-Colored Cyan Couplers............ 260
12.3 Colored Magenta Couplers.................. 262
12.3.1 Yellow-Colored Magenta Couplers.......... 262
12.3.2 Hydrophilic Yellow-Colored Magenta Couplers . . . 264
12.4 Colored Yellow Couplers................... 266
12.4.1 Magenta-Colored Yellow Couplers for Movie Films . 266
12.4.2 Magenta-Colored Yellow Couplers for Color Negative
Films ......................... 267
References............................... 269
13. DIR Couplers and Related Compounds 271
13.1 Development-Inhibitor Releasing............... 271
13.1.1 Development Inhibitors................ 271
13.1.2 Timing and Imagewise Releasing........... 274
13.2 Effects of DIR Couplers.................... 278
13.2.1 Intralayer Effects................... 278
13.2.2 Interlayer Effects................... 279
13.3 DIR Couplers of Direct-Releasing Type............ 280
13.3.1 Releasing Thiolic Development Inhibitors...... 281
13.3.2 Releasing Heterocyclic Development Inhibitors . . . 283
13.3.3 Deactivatable DIR Couplers ............. 288
13.4 Timing DIR Couplers..................... 291
13.4.1 Timing Due to Hydrolysis............... 291
13.4.2 Timing Due to Intramolecular Attacks........ 293
13.4.3 Timing Due to Quinone-Methide Formation..... 296
13.4.4 Multi-Timing DIR Couplers ............. 300
13.5 DAR Couplers........................ . 303
13.6 BAR Couplers......................... 306
References............................... 308
XVI Table of Contents
14. DIR Hydroquinones and Related Compounds 311
14.1 DIR Hydroquinones...................... 311
14.1.1 DIR Hydroquinones for Reversal Color Process ... 311
14.2 DIR Hydroquinones with Additional Functions........ 315
14.2.1 Timing DIR Hydroquinones ............. 315
14.2.2 DIRR Couplers.................... 315
14.3 DIR Hydrazines........................ 321
14.3.1 Applications to Chromogenic Photography...... 321
14.3.2 Application to Graphic Arts Films.......... 321
References............................... 324
IV Diffusion Transfer Photography 327
15. Silver-Salt Diffusion Transfer Photography 329
15.1 B W Diffusion Transfer Process............... 329
15.1.1 DTR Copy Print.................... 329
15.1.2 Instant B W Photography.............. 330
15.1.3 DTR Plate....................... 332
15.2 Additive Color Photography.................. 334
15.2.1 Instant Color Movie.................. 334
15.2.2 Instant Color Slide .................. 338
References............................... 339
16. Chemistry in Instant Color Photography 341
16.1 Instant Color Photography vs. Conventional Color Photography 341
16.2 Classification of Imaging Compounds for Instant Color Photog-
raphy ........................... ... 344
16.2.1 Dye-Stopping and Dye-Releasing........... 344
16.2.2 Positive-and Negative-Working........... 345
16.3 Imaging Compounds of Three Categories........... 346
16.3.1 Dye Developers as Dye-Stopping and Positive-Working
Compounds (Category a)............... 346
16.3.2 Negative-Working Dye Releasers (Category b). . . . 346
16.3.3 Positive-Working Dye Releasers (Category c) .... 351
16.4 Reversal Mechanisms in Instant Color Photography..... 355
16.4.1 Direct Reversal Mechanism Based on Dye Developers 355
16.4.2 Direct Reversal Mechanisms for Negative-Working Dye
Releasers ....................... 357
16.4.3 Direct Reversal Mechanisms Based Upon Positive-
Working Dye Releasers................ 366
References............................... 372
17. Dye Developers 375
17.1 Chemical Processes and Multilayer Structure......... 375
Table of Contents XVII
17.1.1 Chemical Processes of Dye Developers........ 375
17.1.2 Multilayer Structure for Color Reproduction..... 376
17.2 Dye Moieties of Dye Developers............... 379
17.2.1 Azo and Anthraquinone Dye Developers....... 379
17.2.2 Temporarily Shifted Dye Developers......... 382
17.2.3 Metallized Dye Developers.............. 387
17.2.4 Xanthene Dye Developers .............. 394
17.3 Chemicals for Controlling Dye Transfer Processes...... 397
17.3.1 Chemicals Contained in Photo-Sensitive Layers . . . 397
17.3.2 Chemicals Contained in an Activator Fluid...... 399
17.4 Hybrid of Dye Developers and Thiazolidine Dye Releasers . 403
17.4.1 Single Use to Hybrid Use............... 403
17.4.2 Multilayered Hybrid Films.............. 405
17.5 Polymers............................ 408
17.5.1 Polymers for the Mordant Layer........... 408
17.5.2 Polymers for the Acid Layer............. 410
17.5.3 Polymers for the Timing Layer............ 411
References............................... 413
18. / -Sulfonamidonaphthol Dye Releasers 419
18.1 Chemical Processes and Multilayer Structure......... 419
18.1.1 Chemical Processes of p-Sulfonamidonaphthol Dye
Releasers....................... 419
18.1.2 Multilayer Structure for Color Reproduction..... 420
18.2 /7-Sulfonamidonaphthol Moieties............... 423
18.2.1 Ballasted p-Sulfonamidonaphthols .......... 423
18.2.2 Improved Dye-Releasing Efficiency......... 425
18.2.3 Change of Ballast Groups............... 427
18.3 Azo Dye Moieties....................... 428
18.3.1 Azo Dye as Ionic Species............... 428
18.3.2 Cyan Dye Moieties.................. 429
18.3.3 Magenta Dye Moieties................ 433
18.3.4 Yellow Dye Moieties................. 435
18.4 After-Chelation Dye Moieties................. 437
18.4.1 Cyan Dye Moieties of After-Chelation Type..... 437
18.4.2 Magenta Dye Moieties of After-Chelation Type . . . 437
18.4.3 Yellow Dye Moieties of After-Chelation Type .... 439
18.5 Chemicals for Controlling Dye Transfer Processes...... 440
18.5.1 Chemicals Contained in Photo-Sensitive Layers . . . 440
18.5.2 Chemicals Contained in an Activator Fluid...... 442
18.6 Polymers............................ 444
18.6.1 Polymers for the Mordant Layer........... 444
18.6.2 Polymers for the Acid Layer............. 446
18.6.3 Polymers for the Timing Layer............ 447
References............................... 448
XVIII Table of Contents
19. o-Sulfonamidophenol Dye Releasers 451
19.1 Chemical Processes and Multilayer Structure......... 451
19.1.1 Chemical Processes of o-Sulfonamidophenol Dye Re-
leasers ......................... 451
19.1.2 Multilayer Structure for Color Reproduction..... 452
19.1.3 Dynamic Processes of Image Formation....... 453
19.2 Design of Dye Releasers.................... 456
19.3 o-Sulfonamidophenol Moieties................ 458
19.3.1 Designing o-Sulfonamidophenol Moieties...... 458
19.3.2 o-Sulfonamidophenols Having Alkoxy Groups . . . . 459
19.3.3 Improved Dye-Releasing Efficiency......... 463
19.4 Azo Dye Moieties....................... 471
19.4.1 Cyan Dye Moieties.................. 471
19.4.2 Magenta Dye Moieties................ 475
19.4.3 Yellow Dye Moieties................. 480
19.5 Chemicals for Controlling Dye Transfer Processes...... 484
19.5.1 Chemicals Contained in Photo-Sensitive Layers . . . 484
19.5.2 Chemicals Contained in an Activator Fluid...... 488
19.6 Polymers............................ 490
19.6.1 Polymers for the Mordant Layer........... 490
19.6.2 Polymers for the Acid Layer............. 490
19.6.3 Polymers for the Timing Layer............ 492
19.7 Recent Innovations ...................... 494
19.7.1 Integrated Instant Color Films ............ 494
19.7.2 Peel-Apart Instant Color Films............ 498
19.8 Heat Development for Digital Printing............ 500
19.8.1 Incorporation of Activators in Layers......... 500
19.8.2 False Color Reproduction............... 503
19.8.3 Improvement of Light Stability............ 504
19.8.4 Direct Digital Color Proofs.............. 506
References............................... 508
20. Positive-Working Dye Releasers 513
20.1 Carquin Dye Releasers .................... 513
20.
20.
20.
20.
20.
20.
.1 Multilayer Structure for Color Reproduction..... 515
.2 Ballasted Quinone Moieties.............. 518
.3 Dye Moieties for Carquin Dye Releasers....... 522
.4 Chemicals Contained in Photo-Sensitive Layers . . . 522
.5 Chemicals Contained in an Activator Fluid...... 523
.6 Mordant Polymers for Carquin Dye Releasers .... 524
20.2 ROSET Dye Releasers..................... 525
20.2.1 Chemical Processes of ROSET Dye Releasers .... 525
20.2.2 Multilayer Structure for Color Reproduction..... 526
20.2.3 ROSET Moieties................... 528
20.2.4 Dye Moieties for ROSET Dye Releasers....... 531
Table of Contents XIX
20.2.5 Chemicals Contained in Photo-Sensitive Layers . . . 533
20.2.6 Mordant Polymers for Dyes from ROSET Dye Releasers 535
References............................... 535
V Dye Bleach Photography 539
21. Silver Dye Bleach Photography 541
21.1 Chemical Processes and Multilayer Structure......... 541
21.1.1 Chemical Processes of Dye Bleach Photography . . . 541
21.1.2 Multilayer Structure for Color Reproduction..... 542
21.1.3 Color Reproduction.................. 543
21.2 Azo Dyes for Silver Dye Bleach Photography........ 545
21.2.1 BisazoDyes...................... 545
21.2.2 Cyan Bisazo Dyes................... 546
21.2.3 Magenta Bisazo Dyes................. 547
21.2.4 Yellow Bisazo Dyes.................. 548
21.2.5 Colloidal Dispersion of Azo Dyes.......... 549
21.2.6 Masking by Development Inhibitors......... 550
21.3 Chemicals for Dye Bleach................... 551
21.3.1 Bleach Catalysts.................... 551
21.3.2 Other Additives for Bleach Baths........... 553
References............................... 554
Index 557
|
| any_adam_object | 1 |
| author | Fujita, Shinsaku 1944- |
| author_GND | (DE-588)11287987X |
| author_facet | Fujita, Shinsaku 1944- |
| author_role | aut |
| author_sort | Fujita, Shinsaku 1944- |
| author_variant | s f sf |
| building | Verbundindex |
| bvnumber | BV019524892 |
| ctrlnum | (OCoLC)883292775 (DE-599)BVBBV019524892 |
| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV019524892 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T20:00:25Z |
| institution | BVB |
| isbn | 3540209883 |
| language | German |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-012902896 |
| oclc_num | 883292775 |
| open_access_boolean | |
| owner | DE-210 DE-634 |
| owner_facet | DE-210 DE-634 |
| physical | XIX, 587 S. graph. Darst. |
| publishDate | 2004 |
| publishDateSearch | 2004 |
| publishDateSort | 2004 |
| publisher | Springer |
| record_format | marc |
| spelling | Fujita, Shinsaku 1944- Verfasser (DE-588)11287987X aut Organic chemistry of photography with 32 tables Shinsaku Fujita Berlin [u.a.] Springer 2004 XIX, 587 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Organische Verbindungen (DE-588)4043816-8 gnd rswk-swf Farbfotografie (DE-588)4016464-0 gnd rswk-swf Fotografischer Prozess (DE-588)4132126-1 gnd rswk-swf Farbfotografie (DE-588)4016464-0 s Fotografischer Prozess (DE-588)4132126-1 s Organische Verbindungen (DE-588)4043816-8 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012902896&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Fujita, Shinsaku 1944- Organic chemistry of photography with 32 tables Organische Verbindungen (DE-588)4043816-8 gnd Farbfotografie (DE-588)4016464-0 gnd Fotografischer Prozess (DE-588)4132126-1 gnd |
| subject_GND | (DE-588)4043816-8 (DE-588)4016464-0 (DE-588)4132126-1 |
| title | Organic chemistry of photography with 32 tables |
| title_auth | Organic chemistry of photography with 32 tables |
| title_exact_search | Organic chemistry of photography with 32 tables |
| title_full | Organic chemistry of photography with 32 tables Shinsaku Fujita |
| title_fullStr | Organic chemistry of photography with 32 tables Shinsaku Fujita |
| title_full_unstemmed | Organic chemistry of photography with 32 tables Shinsaku Fujita |
| title_short | Organic chemistry of photography |
| title_sort | organic chemistry of photography with 32 tables |
| title_sub | with 32 tables |
| topic | Organische Verbindungen (DE-588)4043816-8 gnd Farbfotografie (DE-588)4016464-0 gnd Fotografischer Prozess (DE-588)4132126-1 gnd |
| topic_facet | Organische Verbindungen Farbfotografie Fotografischer Prozess |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012902896&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT fujitashinsaku organicchemistryofphotographywith32tables |