Industrial organic chemicals:
Updated and expanded, the Second Edition discusses how the majority of industrial organic chemicals and polymers are derived from seven major building blocks produced from petroleum and natural gas, these include ethylene, propylene, C4 olefins (butenes and butadiene), benzene toluene, the xylenes a...
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| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, NJ
Wiley-Interscience
2004
|
| Ausgabe: | 2. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Zusammenfassung: | Updated and expanded, the Second Edition discusses how the majority of industrial organic chemicals and polymers are derived from seven major building blocks produced from petroleum and natural gas, these include ethylene, propylene, C4 olefins (butenes and butadiene), benzene toluene, the xylenes and methane. The book goes on to describe the chemistry of these building block chemicals and their derivatives, as well as how they are manufactured. It also gives the uses and the economic importance of the substances, explaining the concerns and why one is preferred over another. Provides a thorough overview of the seven building block chemicals and their derivatives, including processing, uses, and economic importance Gives a broad description of the polymer industry and industrial catalysts Has a new section on the highly profitable specialty chemicals. |
| Beschreibung: | 1. Aufl. u.d.T.: Wittcoff, Harold A.: Industrial organic chemicals in pespective |
| Beschreibung: | XXXI, 662 S. graph. Darst. |
| ISBN: | 0471443859 |
Internformat
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| 100 | 1 | |a Wittcoff, Harold A. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Industrial organic chemicals |c Harold A. Wittcoff ; Bryan G. Reuben ; Jeffrey S. Plotkin |
| 250 | |a 2. ed. | ||
| 264 | 1 | |a Hoboken, NJ |b Wiley-Interscience |c 2004 | |
| 300 | |a XXXI, 662 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a 1. Aufl. u.d.T.: Wittcoff, Harold A.: Industrial organic chemicals in pespective | ||
| 520 | 3 | |a Updated and expanded, the Second Edition discusses how the majority of industrial organic chemicals and polymers are derived from seven major building blocks produced from petroleum and natural gas, these include ethylene, propylene, C4 olefins (butenes and butadiene), benzene toluene, the xylenes and methane. The book goes on to describe the chemistry of these building block chemicals and their derivatives, as well as how they are manufactured. It also gives the uses and the economic importance of the substances, explaining the concerns and why one is preferred over another. Provides a thorough overview of the seven building block chemicals and their derivatives, including processing, uses, and economic importance Gives a broad description of the polymer industry and industrial catalysts Has a new section on the highly profitable specialty chemicals. | |
| 650 | 4 | |a Composés organiques - Applications industrielles | |
| 650 | 7 | |a Industrie chimique |2 ram | |
| 650 | 7 | |a Produits pétrochimiques |2 ram | |
| 650 | 4 | |a Organic compounds |x Industrial applications | |
| 650 | 0 | 7 | |a Chemische Industrie |0 (DE-588)4009848-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Organische Verbindungen |0 (DE-588)4043816-8 |2 gnd |9 rswk-swf |
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| 689 | 1 | 0 | |a Technische organische Chemie |0 (DE-588)4184575-4 |D s |
| 689 | 1 | |5 DE-604 | |
| 700 | 1 | |a Reuben, Bryan G. |e Verfasser |4 aut | |
| 700 | 1 | |a Plotkin, Jeffrey S. |e Verfasser |4 aut | |
| 856 | 4 | 2 | |m OEBV Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012846675&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
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Datensatz im Suchindex
| _version_ | 1804132828852518912 |
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| adam_text | CONTENTS PREFACE PREFACE TO THE FIRST EDITION LIST OF ACRONYMS AND
ABBREVIATIONS CHAPTER 0 HOW TO USE INDUSTRIAL ORGANIC CHEMICALS, SECOND
EDITION 0.1 WHY THIS BOOK WAS WRITTEN AND HOW IT IS STRUCTURED / 1 0.2
NORTH AMERICAN INDUSTRY CLASSIFICATION / 3 0.3 UNITS AND NOMENCLATURE /
4 0.4 GENERAL BIBLIOGRAPHY / 4 0.4.1 ENCYCLOPEDIAS / 5 0.4.2 BOOKS / 6
0.4.3 JOURNALS / 9 0.4.4 PATENTS / 9 0.4.5 STATISTICS / 11 0.4.6 CD-ROM
AND ON-LINE DATABASES / 12 CHAPTER 1 THE CHEMICAL INDUSTRY 1.1 THE
NATIONAL ECONOMY / 15 1.2 SIZE OF THE CHEMICAL INDUSTRY / 20 XXIII XXV
XXVII 15 XI XII CONTENTS 1.3 CHARACTERISTICS OF THE CHEMICAL INDUSTRY /
21 1.3.1 MATURITY / 21 1.3.1.1 REALIGNMENT OF BUSINESS SEGMENTS / 26
1.3.2 PARTICIPATION IN INTERNATIONAL TRADE / 28 1.3.3 COMPETITION FROM
DEVELOPING COUNTRIES / 29 1.3.4 CAPITAL INTENSITY AND ECONOMIES OF SCALE
/ 32 1.3.5 CRITICALITY AND PERVASIVENESS / 33 1.3.6 FREEDOM OF MARKET
ENTRY / 35 1.3.7 STRONG HEALTH AND SAFETY REGULATION / 36 1.3.8 HIGH
RESEARCH AND DEVELOPMENT EXPENDITURES / 41 1.3.9 DISLOCATIONS / 46 1.4
THE TOP CHEMICAL COMPANIES / 48 1.5 THE TOP CHEMICALS / 50 NOTES AND
REFERENCES / 53 CHAPTER 2 CHEMICALS FROM NATURAL GAS AND PETROLEUM 57
2.1 PETROLEUM DISTILLATION / 61 2.2 PETROLEUM REFINING REACTIONS / 67
2.2.1 STEAM CRACKING / 67 2.2.1.1 CHOICE OF FEEDSTOCK / 70 2.2.1.2
ECONOMICS OF STEAM CRACKING / 71 2.2.1.3 MECHANISM OF CRACKING / 76
2.2.2 CATALYTIC CRACKING / 76 2.2.3 CATALYTIC REFORMING / 79 2.2.4
OLIGOMERIZATION / 82 2.2.5 ALKYLATION / 84 2.2.6 HYDROTREATING AND
COKING / 84 2.2.7 DEHYDROGENATION / 86 2.2.8 ISOMERIZATION / 87 2.2.9
METATHESIS / 87 2.2.9.1 METATHESIS OUTSIDE THE REFINERY / 89 2.2.9.2
MECHANISM OF METATHESIS / 90 2.3 THE REFINERY*A PERSPECTIVE / 92 2.3.1
THE FUNCTION OF THE REFINERY AND THE POTENTIAL PETROLEUM SHORTAGE / 92
2.3.2 UNLEADED GASOLINE AND THE CLEAN AIR ACT / 93 2.4 SEPARATION OF
NATURAL GAS / 96 NOTES AND REFERENCES / 96 CONTENTS XUI CHAPTER 3
CHEMICALS AND POLYMERS FROM ETHYLENE 100 3.1 ETHYLENE POLYMERS / 105
3.1.1 DISCOVERY OF LOW- AND HIGH-DENSITY POLYETHYLENES / 105 3.1.2
LOW-DENSITY POLYETHYLENE / 106 3.1.3 HIGH-DENSITY POLYETHYLENE / 107
3.1.4 LINEAR LOW-DENSITY POLYETHYLENE / 108 3.1.5 VERY HIGH MOLECULAR
WEIGHT POLYETHYLENE / 109 3.2 ETHYLENE COPOLYMERS / 109 3.2.1
CHLOROSULFONATED POLYETHYLENE / 109 3.2.2 ETHYLENE-VINYL ACETATE / 110
3.2.3 IONOMERS /111 3.2.4 COPOLYMER FROM INCOMPATIBLE POLYMER BLENDS
/111 3.2.5 ETHYLENE-PROPYLENE ELASTOMERS /111 3.2.6 ULTRA-LOW-DENSITY
POLYETHYLENE / 112 3.2.7 PHOTODEGRADABLE COPOLYMERS / 112 3.3
OLIGOMERIZATION / 113 3.3.1 DIMERIZATION / 113 3.3.2 ZIEGLER
OLIGOMERIZATION OF ETHYLENE / 114 3.3.3 OTHER ETHYLENE OLIGOMERIZATION
TECHNOLOGIES / 115 3.3.4 THE SHELL HIGHER OLEFINS PROCESS (SHOP) / 116
3.4 VINYL CHLORIDE / 119 3.5 ACETALDEHYDE / 121 3.6 VINYL ACETATE / 124
3.7 ETHYLENE OXIDE / 126 3.7.1 ETHYLENE GLYCOL / 127 3.7.2 PROPOSED
NON-ETHYLENE OXIDE PROCESSES FOR ETHYLENE GLYCOL PRODUCTION / 129 3.8
STYRENE / 132 3.9 ETHANOL / 135 3.10 MAJOR CHEMICALS FROM ETHYLENE*A
SUMMARY / 137 3.11 LESSER VOLUME CHEMICALS FROM ETHYLENE / 139 3.11.1
HYDROFORRNYLATION*PROPIONALDEHYDE, PROPIONIC ACID, AND N-PROPANOL / 140
3.11.2 ETHYL HALIDES / 141 3.11.3 ACETALDEHYDE CHEMISTRY / 142 3.11.4
METAL COMPLEXES / 146 3.11.5 ETHYLENEDIAMINE AND RELATED COMPOUNDS / 147
XIV CONTENTS 3.11.6 ETHYLENE OXIDE AND ETHYLENE GLYCOL DERIVATIVES / 149
3.11.6.1 OLIGOMERS / 149 3.11.6.2 GLY COL ETHERS AND ESTERS / 14 9
3.11.6.3 ETHYLENE CARBONATE / 150 3.11.6.4 AMINOETHYL ALCOHOLS
(ETHANOLAMINES) AND DERIVATIVES / 153 3.11.6.5 ETHYLENIMINE / 154
3.11.6.6 1,3-PWPANEDIOL / 155 3.11.6.7 ETHYLENE GLYCOL DERIVATIVES / 156
3.11.7 VINYL CHLORIDE AND ETHYLENE DICHLORIDE DERIVATIVES / 158 3.11.8
VINYL FLUORIDE AND VINYLIDENE FLUORIDE / 159 3.11.9 ETHYLENE DIBROMIDE /
160 3.11.10 ETHANOL DERIVATIVES / 161 3.11.11 VINYL ESTERS AND ETHERS /
162 NOTES AND REFERENCES / 163 CHAPTER 4 CHEMICALS AND POLYMERS FROM
PROPYLENE 167 4.1 ON-PURPOSE PROPYLENE PRODUCTION TECHNOLOGIES AND
PROPANE DEHYDROGENATION / 168 4.2 PROPYLENE VIA DEEP CATALYTIC CRACKING
/ 169 4.3 PROPYLENE VIA OLEFIN METATHESIS / 169 4.4 PROPYLENE VIA
SELECTIVE C 4 /C 5 CRACKING / 171 4.5 MAIN POLYMERS AND CHEMICALS FROM
PROPYLENE / 172 4.5.1 PROPYLENE POLYMERS AND COPOLYMERS / 172 4.6
OLIGOMERIZATION / 175 4.7 ACRYLIC ACID / 176 4.8 ACRYLONITRILE / 181
4.8.1 USES OF ACRYLONITRILE / 183 4.9 CUMENE, CUMENE HYDROPEROXIDE, AND
PHENOL / 184 4.10 ACETONE AND ISOPROPANOL / 187 4.10.1 METHYL
METHACRYLATE / 188 4.10.2 METHYL ISOBUTYL KETONE AND OTHER ACETONE
DERIVATIVES / 193 4.11 PROPYLENE OXIDE / 195 4.11.1 PROPYLENE OXIDE
APPLICATIONS / 198 4.11.2 PROJECTED PROPYLENE OXIDE-PROPYLENE GLYCOL
PROCESSES / 199 CONTENTS XV 4.11.3 OTHER NOVEL SYNTHESES OF PROPYLENE
OXIDE / 200 4.11.3.1 DIRECT OXIDATION / 200 4.11.3.2 USE OF PERACIDS OR
HYDROGEN PEROXIDE / 201 4.11.3.3 ELECTROCHEMICAL PROCESSES / 202
4.11.3.4 BIOTECHNOLOGICAL APPROACHES / 204 4.12 N-BUTYRALDEHYDE AND
LSOBUTYRALDEHYDE / 205 4.12.1 USES FOR BUTYRALDEHYDE AND
LSOBUTYRALDEHYDE / 207 4.12.2 OTHER OXO PRODUCTS / 208 4.13 MAJOR
CHEMICALS FROM PROPYLENE*A PERSPECTIVE / 209 4.14 LESSER VOLUME
CHEMICALS FROM PROPYLENE / 211 4.14.1 ALLYL CHLORIDE AND EPICHLOROHYDRIN
/ 211 4.14.2 GLYCEROL / 214 4.14.3 ACRYLAMIDE / 215 4.14.4 ACROLEIN /
216 4.14.5 ACRYLONITRILE DERIVATIVES / 218 NOTES AND REFERENCES / 218
CHAPTER 5 CHEMICALS AND POLYMERS FROM THE C 4 STREAM 223 5.1 CHEMICALS
AND POLYMERS FROM BUTADIENE / 226 5.1.1 ACRYLONITRILE-BUTADIENE-STYRENE
RESINS (ABS) / 230 5.1.2 HEXAMETHYLENEDIAMINE / 231 5.1.3 LESSER VOLUME
CHEMICALS FROM BUTADIENE / 236 5.1.3.1 CYDILATION / 236 5.1.3.2
DIMERIZATION AND TRIMERIZATION / 237 5.1.3.3 DIELS-ALDER REACTIONS / 239
5.1.3.4 ADIPIC ACID / 240 5.1.3.5 1,4-BUTANEDIOL / 241 5.1.3.6
TRANS-1,4-HEXADIENE / 241 5.1.3.7 DIMETHYL-2,6-NAPHTHALENE DICARBOXYLATE
/ 241 5.1.3.8 BUTADIENE MONOEPOXIDE / 241 5.2 CHEMICALS AND POLYMERS
FROM ISOBUTENE / 242 5.2.1 METHYL FERF-BUTYL ETHER / 243 5.2.2 BUTYL
RUBBER / 244 5.2.3 POLYISOBUTENES AND ISOBUTENE OLIGOMERS AND POLYMERS /
244 XVI CONTENTS 5.2.4 TERT-BUTMOL / 245 5.2.5 METHYL METHACRYLATE / 245
5.2.6 LESSER VOLUME CHEMICALS FROM ISOBUTENE / 245 5.3 CHEMICALS AND
POLYMERS FROM 1- AND 2-BUTENES / 248 5.4 CHEMICALS FROM N-BUTANE / 249
5.4.1 ACETIC ACID / 249 5.4.2 MALEIC ANHYDRIDE / 249 NOTES AND
REFERENCES / 251 CHAPTER 6 CHEMICALS AND POLYMERS FROM THE C 5 STREAM
6.1 SEPARATION OF THE C 5 STREAM / 256 6.2 ISOPRENE / 259 6.3
CYCLOPENTADIENE AND DICYCLOPENTADIENE / 263 6.4 PENTENE-1 AND PIPERYLENE
/ 265 NOTES AND REFERENCES / 266 255 CHAPTER 7 CHEMICALS AND POLYMERS
FROM BENZENE 267 7.1 PHENOL / 269 7.1.1 PHENOLIC RESINS / 275 7.1.2
BISPHENOLA / 276 7.1.2.1 EPOXY RESINS / 277 7.1.2.2 POLYCARBONATE RESINS
/ 277 7.1.2.3 LESSER VOLUME USES FOR BISPHENOLA / 280 7.1.3
CYCLOHEXANONE / 281 7.1.4 ALKYLPHENOLS / 283 7.1.5 CHLORINATED PHENOLS /
283 7.1.6 2,6-XYLENOL AND CRESOLS / 284 7.1.7 ANILINE FROM PHENOL / 284
7.2 CYCLOHEXANE / 285 7.2.1 ADIPICACID / 285 7.2.1.1 NYLONS FROM ADIPIC
ACID / 289 7.2.2 CAPROLACTAM / 290 7.3 ANILINE / 294 7.3.1
4,4 -DIPHENYLMETHANE DIISOCYANATE (MDI) / 296 7.4 ALKYLBENZENES / 299
7.5 MALEIC ANHYDRIDE / 301 7.6 CHLORINATED BENZENES / 301 CONTENTS XVII
7.7 DIHYDROXYBENZENES / 302 7.8 ANTHRAQUINONE / 308 NOTES AND REFERENCES
/ 309 CHAPTER 8 CHEMICALS AND POLYMERS FROM TOLUENE 312 8.1
HYDRODEALKYLATION AND DISPROPORTIONATION / 313 8.2 SOLVENTS / 314 8.3
DINITROTOLUENE AND TOLUENE DIISOCYANATE / 314 8.4 LESSER VOLUME
CHEMICALS FROM TOLUENE / 316 NOTES AND REFERENCES / 318 CHAPTER 9
CHEMICALS AND POLYMERS FROM XYLENES 320 9.1 A-XYLENE AND PHTHALIC
ANHYDRIDE / 322 9.1.1 USES OF PHTHALIC ANHYDRIDE / 323 9.2 M-XYLENE AND
ISOPHTHALIC ACID / 327 9.2.1 USES OF ISOPHTHALIC ACID / 328 9.3 P-XYLENE
AND TEREPHTHALIC ACID*DIMETHYL TEREPHTHALATE / 329 9.3.1 OXIDATION
OF/?-XYLENE / 329 9.3.2 ALTERNATE SOURCES FOR TEREPHTHALIC ACID / 331
9.3.3 POLYETHYLENE TEREPHTHALATE) / 332 9.3.4 LOWER VOLUME POLYMERS FROM
TEREPHTHALIC ACID / 334 9.4 MAJOR CHEMICALS FROM XYLENES: A SUMMARY /
335 NOTES AND REFERENCES / 336 CHAPTER 10 CHEMICALS FROM METHANE 10.1
HYDROCYANIC ACID / 338 10.2 HALOGENATED METHANES / 341 10.2.1
CHLOROMETHANE / 342 10.2.2 DICHLOROMETHANE / 343 10.2.3 TRICHLOROMETHANE
/ 343 10.2.4 TETRACHLOROMETHANE AND CARBON DISULFIDE / 344 10.2.5
BROMOMETHANE / 347 10.3 ACETYLENE / 347 10.3.1 1,4-BUTANEDIOL / 349
10.3.2 LESSER USES FOR ACETYLENE / 352 338 XVIII CONTENTS 10.4 SYNTHESIS
GAS / 353 10.4.1 STEAM REFORMING OF METHANE / 354 10.4.2 VARIANTS OF
STEAM REFORMING / 355 10.4.3 PARTIAL OXIDATION OF HYDROCARBONS / 356
10.4.4 SOLID FEEDSTOCKS / 357 10.4.5 HYDROGEN / 357 10.5 CHEMICALS FROM
SYNTHESIS GAS / 358 10.5.1 AMMONIA AND ITS DERIVATIVES / 358 10.5.1.1
UREA AND MELAMINE RESINS / 360 10.5.2 METHANOL / 362 10.5.2.1
FORMALDEHYDE / 364 10.5.2.2 ACETIC ACID / 365 10.5.2.3 ACETIC ANHYDRIDE
/ 368 10.5.2.4 METHANOL TO GASOLINE / 37 0 10.5.2.5 METHANOL TO OLEFINS
/ 371 10.5.2.6 LOWER VOLUME AND PROPOSED USES FOR METHANOL / 373
10.5.2.7 CJ-BASED DEVELOPMENT PROCESSES / 375 10.6 CARBON MONOXIDE
CHEMISTRY / 377 10.6.1 PROPOSED CHEMISTRY BASED ON CARBON MONOXIDE / 378
10.7 GAS-TO-LIQUID FUELS / 382 10.7.1 SASOL GTL TECHNOLOGY / 382 10.7.2
SHELL MIDDLE DISTILLATE SYNTHESIS / 383 10.7.3 OTHER GTL TECHNOLOGIES /
383 NOTES AND REFERENCES / 384 CHAPTER 11 CHEMICALS FROM ALKANES 387
11.1 FUNCTIONALIZATION OF METHANE / 388 11.1.1 METHANE TO
METHANOL-FORMALDEHYDE / 388 11.1.2 DIMERIZATION OF METHANE / 389 11.1.3
AROMATIZATION OF METHANE / 390 11.2 FUNCTIONALIZATION OF C 2 -C 4
ALKANES / 391 11.2.1 OXIDATION OF C 2 -C 4 ALKANES / 391 11.2.2
DEHYDROGENATION OF C 2 -C 4 ALKANES / 393 11.2.3 AROMATIZATION OF C 2 -C
4 ALKANES / 394 11.3 CARBON BLACK / 394 NOTES AND REFERENCES / 395
CONTENTS XIX CHAPTER 12 CHEMICALS FROM COAL 12.1 CHEMICALS FROM COKE
OVEN DISTILLATE / 400 12.2 THE FISCHER-TROPSCH REACTION / 404 12.3 COAL
HYDROGENATION / 406 12.4 SUBSTITUTE NATURAL GAS (SNG) / 407 12.5
SYNTHESIS GAS TECHNOLOGY / 407 12.6 CALCIUM CARBIDE / 408 12.7 COAL AND
THE ENVIRONMENT / 409 NOTES AND REFERENCES / 409 399 CHAPTER 13 FATS AND
OILS 13.1 13.2 13.3 13.4 13.5 411 FATTY ACIDS / 416 FATTY NITROGEN
COMPOUNDS / 419 DIMER ACID / 421 AMINOAMIDES AND IMIDAZOLINES / 423
AZELAIC, PELARGONIC, AND PETROSELINIC ACIDS / 423 13.6 FATTY ALCOHOLS /
424 13.7 EPOXIDIZED OILS / 426 13.8 RICINOLEIC ACID / 426 13.9 GLYCEROL
/ 428 13.10 ALCOHOLYSIS OF FATS AND OILS / 428 13.10.1 COCOA BUTTER /
429 13.11 THE FUTURE OF FAT AND OIL CHEMISTRY / 430 13.11.1 NON-CALORIC
FAT-LIKE SUBSTANCES / 430 13.11.2 ALKYL POLYGLYCOSIDES / 430 13.11.3
FATTY ACID-BASED FUELS AND LUBRICANTS / 431 NOTES AND REFERENCES / 432
CHAPTER 14 CARBOHYDRATES 14.1 SUGARS AND SORBITOL / 435 14.1.1 FURFURAL
/ 442 14.2 STARCH / 443 14.3 CELLULOSE / 446 14.4 GUMS / 449 14.5
FERMENTATION AND BIOTECHNOLOGY / 450 14.5.1 AMINO ACIDS / 453 435 XX
CONTENTS 14.5.2 POLYMERS / 454 14.5.3 PROTEINS BY RECOMBINANT DNA
TECHNOLOGY / 455 14.5.4 A FERMENTATION SCENARIO / 455 14.5.5 CAN ETHANOL
BE JUSTIFIED AS A FUEL? / 456 NOTES AND REFERENCES / 457 CHAPTER 15 HOW
POLYMERS ARE MADE 459 15.1 POLYMERIZATION / 464 15.2 FUNCTIONALITY / 465
15.3 STEP-AND CHAIN-GROWTH POLYMERIZATIONS / 469 15.3.1 FREE RADICAL
POLYMERIZATION / 471 15.3.2 CHAIN TRANSFER / 473 15.3.3
COPOLYRNERIZATION / 475 15.3.4 MOLECULAR WEIGHT / 477 15.3.5
POLYMERIZATION PROCEDURES / 478 15.3.6 IONIC POLYMERIZATION / 480 15.3.7
LIVING POLYMERS / 486 15.3.8 BLOCK COPOLYMERS / 486 15.3.9 GRAFT
COPOLYMERS / 489 15.3.10 METAL COMPLEX CATALYSTS / 489 15.3.11 METAL
OXIDE CATALYSTS / 493 15.3.12 METALLOCENE AND OTHER SINGLE-SITE
CATALYSTS / 494 15.3J2.1 SINGLE-SITE NONMETALLOCENE CATALYSTS / 498
15.3.12.2 LATE TRANSITION METAL CATALYSTS / 498 15.3.12.3 COMMERCIAL
PROSPECTS / 500 15.4 EXAMPLES OF STEP POLYMERIZATION / 501 15.4.1
PHENOPLASTS AND AMINOPLASTS / 501 15.4.2 POLYURETHANES / 503 15.4.3
EPOXY RESINS / 506 15.4.4 DENDRITIC AND HYPERBRANCHED POLYMERS / 508
15.5 POLYMER PROPERTIES / 512 15.5.1 CRYSTALLINITY / 512 CONTENTS XXI
15.5.2 GLASS TRANSITION TEMPERATURE, CRYSTALLINE MELTING POINT, AND
SOFTENING TEMPERATURE / 516 15.5.3 MOLECULAR COHESION / 517 15.5.4
STRESS-STRAIN DIAGRAMS / 518 15.6 CLASSES OF POLYMERS / 520 NOTES AND
REFERENCES / 521 CHAPTER 16 INDUSTRIAL CATALYSIS 527 16.1 CATALYST
CHOICE / 528 16.1.1 REACTION VELOCITY AND SELECTIVITY / 529 16.1.2
RECOVERY OF UNCHANGED CATALYST / 531 16.1.3 CATALYST DEACTIVATION / 532
16.1.4 ACCESS TO NONEQUILIBRIUM PRODUCTS / 532 16.2 HOMOGENEOUS AND
HETEROGENEOUS CATALYSIS / 533 16.2.1 REACTORS FOR HETEROGENEOUS
CATALYSTS / 534 16.2.2 IMMOBILIZATION OF HOMOGENEOUS CATALYSTS / 535
16.3 CATALYST MARKETS / 536 16.4 CATALYSIS BY ACIDS AND BASES / 539 16.5
DUAL FUNCTION CATALYSIS / 543 16.6 CATALYSIS BY METALS, SEMICONDUCTORS,
AND INSULATORS / 544 16.6.1 CATALYSTS FOR AUTOMOBILE EMISSION CONTROL /
545 16.7 COORDINATION CATALYSIS / 546 16.7.1 CATALYSTS FOR STEREOREGULAR
COMPOUNDS / 547 16.7.2 ASYMMETRIC SYNTHESIS / 549 16.8 ENZYMES / 550
16.8.1 CATALYTIC ANTIBODIES / 552 16.9 SHAPE-SELECTIVE CATALYSTS / 553
16.10 PHASE-TRANSFER AND FLUOROUS BIPHASE CATALYSIS / 556 16.11
CATALYSTS OF THE FUTURE / 558 16.11.1 CATALYST DESIGN / 558 16.11.2
HIGHER SELECTIVITIES / 559 16.11.3 CATALYSTS WITH GREATER ACTIVITY / 559
16.11.4 POLLUTION PROBLEMS / 560 16.11.5 CATALYSTS FOR NEW REACTIONS /
560 16.11.6 CATALYSTS THAT MIMIC NATURAL CATALYSTS / 560 XXII CONTENTS
16.11.7 CATALYST DISCOVERY VIA HIGH THROUGHPUT EXPERIMENTATION / 561
NOTES AND REFERENCES / 562 CHAPTER 17 SUSTAINABJUTY AND GREEN CHEMISTRY
567 17.1 ENERGY SOURCES / 569 17.1.1 WIND POWER / 570 17.1.2 WAVE POWER
/ 570 17.1.3 SOLAR POWER / 571 17.1.3.1 PHOTOVOLTAIC CELLS / 571
17.1.3.2 ARTIFICIAL PHOTOSYNTHESIS / 572 17.1.4 METHANE HYDRATE / 574
17.1.5 THE HYDROGEN ECONOMY / 575 17.1.5.1 FUEL CELLS / 576 17.2
POLLUTION / 580 17.2.1 THE OZONE LAYER / 581 17.2.2 GLOBAL WARMING / 585
17.2.3 TRACE CHEMICALS / 587 17.2.3.1 PESTICIDES / 587 17.2.3.2
NONPESTICIDE LIPOPHILES / 588 17.2.4 AIR POLLUTION / 589 17.2.4.1 SULFUR
DIOXIDE AND PANICULATES / 589 17.2.4.2 AUTOMOBILE EXHAUST EMISSIONS /
590 17.2.5 WATER TREATMENT / 593 17.2.6 SOLID WASTES / 594 17.2.6.1
WASTE PREVENTION / 595 17.2.6.2 RECYCLING / 595 17.2.6.3 COMBUSTION *
INCINERATION / 596 17.2.6.4 SANITARY LANDFILL / 598 17.2.7 PETROCHEMICAL
INDUSTRY WASTES / 599 17.2.8 OTHER ENVIRONMENTAL PROBLEMS / 600 17.3
GREEN CHEMISTRY / 601 17.3.1 THE DECLINE IN ACETYLENE CHEMISTRY / 602
17.3.2 NYLON / 603 17.3.3 REPLACEMENT OF PHOSGENE / 603 17.3.4
MONOMETHYLATION BY DIMETHYL CARBONATE / 604 17.3.5 LIQUID AND
SUPERCRITICAL CARBON DIOXIDE AND WATER / 605 CONTENTS XXIII 17.3.6 IONIC
LIQUIDS / 607 17.3.7 PHOTOCATALYSTS / 608 17.3.8 PAIRED ELECTROSYNTHESIS
/ 608 17.3.9 SERTRALINE SYNTHESIS / 609 17.3.10 CATALYTIC
DEHYDROGENATION OF DIETHANOLAMINE / 61 1 17.3.11 GENETIC MANIPULATION /
611 17.3.12 POLYHYDROXYALKANOATES / 612 17.4 VALEDICTION / 633 NOTES AND
REFERENCES / 614 APPENDIX 1 A NOTE ON COST CALCULATIONS 620 APPENDIX 2
UNITS AND CONVERSION FACTORS 624 APPENDIX 3 SPECIAL UNITS IN THE
CHEMICAL INDUSTRY 626 INDEX 629
|
| any_adam_object | 1 |
| author | Wittcoff, Harold A. Reuben, Bryan G. Plotkin, Jeffrey S. |
| author_facet | Wittcoff, Harold A. Reuben, Bryan G. Plotkin, Jeffrey S. |
| author_role | aut aut aut |
| author_sort | Wittcoff, Harold A. |
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| building | Verbundindex |
| bvnumber | BV019383701 |
| callnumber-first | T - Technology |
| callnumber-label | TP247 |
| callnumber-raw | TP247 |
| callnumber-search | TP247 |
| callnumber-sort | TP 3247 |
| callnumber-subject | TP - Chemical Technology |
| classification_rvk | VN 5400 VN 5401 |
| classification_tum | CIT 700f CIT 450f |
| ctrlnum | (OCoLC)53307689 (DE-599)BVBBV019383701 |
| dewey-full | 661.8 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 661 - Technology of industrial chemicals |
| dewey-raw | 661.8 |
| dewey-search | 661.8 |
| dewey-sort | 3661.8 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Werkstoffwissenschaften Chemie-Ingenieurwesen |
| edition | 2. ed. |
| format | Book |
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| id | DE-604.BV019383701 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T19:59:02Z |
| institution | BVB |
| isbn | 0471443859 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-012846675 |
| oclc_num | 53307689 |
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| owner_facet | DE-91G DE-BY-TUM DE-703 DE-19 DE-BY-UBM |
| physical | XXXI, 662 S. graph. Darst. |
| publishDate | 2004 |
| publishDateSearch | 2004 |
| publishDateSort | 2004 |
| publisher | Wiley-Interscience |
| record_format | marc |
| spelling | Wittcoff, Harold A. Verfasser aut Industrial organic chemicals Harold A. Wittcoff ; Bryan G. Reuben ; Jeffrey S. Plotkin 2. ed. Hoboken, NJ Wiley-Interscience 2004 XXXI, 662 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier 1. Aufl. u.d.T.: Wittcoff, Harold A.: Industrial organic chemicals in pespective Updated and expanded, the Second Edition discusses how the majority of industrial organic chemicals and polymers are derived from seven major building blocks produced from petroleum and natural gas, these include ethylene, propylene, C4 olefins (butenes and butadiene), benzene toluene, the xylenes and methane. The book goes on to describe the chemistry of these building block chemicals and their derivatives, as well as how they are manufactured. It also gives the uses and the economic importance of the substances, explaining the concerns and why one is preferred over another. Provides a thorough overview of the seven building block chemicals and their derivatives, including processing, uses, and economic importance Gives a broad description of the polymer industry and industrial catalysts Has a new section on the highly profitable specialty chemicals. Composés organiques - Applications industrielles Industrie chimique ram Produits pétrochimiques ram Organic compounds Industrial applications Chemische Industrie (DE-588)4009848-5 gnd rswk-swf Organische Verbindungen (DE-588)4043816-8 gnd rswk-swf Technische organische Chemie (DE-588)4184575-4 gnd rswk-swf Organische Verbindungen (DE-588)4043816-8 s Chemische Industrie (DE-588)4009848-5 s DE-604 Technische organische Chemie (DE-588)4184575-4 s Reuben, Bryan G. Verfasser aut Plotkin, Jeffrey S. Verfasser aut OEBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012846675&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Wittcoff, Harold A. Reuben, Bryan G. Plotkin, Jeffrey S. Industrial organic chemicals Composés organiques - Applications industrielles Industrie chimique ram Produits pétrochimiques ram Organic compounds Industrial applications Chemische Industrie (DE-588)4009848-5 gnd Organische Verbindungen (DE-588)4043816-8 gnd Technische organische Chemie (DE-588)4184575-4 gnd |
| subject_GND | (DE-588)4009848-5 (DE-588)4043816-8 (DE-588)4184575-4 |
| title | Industrial organic chemicals |
| title_auth | Industrial organic chemicals |
| title_exact_search | Industrial organic chemicals |
| title_full | Industrial organic chemicals Harold A. Wittcoff ; Bryan G. Reuben ; Jeffrey S. Plotkin |
| title_fullStr | Industrial organic chemicals Harold A. Wittcoff ; Bryan G. Reuben ; Jeffrey S. Plotkin |
| title_full_unstemmed | Industrial organic chemicals Harold A. Wittcoff ; Bryan G. Reuben ; Jeffrey S. Plotkin |
| title_short | Industrial organic chemicals |
| title_sort | industrial organic chemicals |
| topic | Composés organiques - Applications industrielles Industrie chimique ram Produits pétrochimiques ram Organic compounds Industrial applications Chemische Industrie (DE-588)4009848-5 gnd Organische Verbindungen (DE-588)4043816-8 gnd Technische organische Chemie (DE-588)4184575-4 gnd |
| topic_facet | Composés organiques - Applications industrielles Industrie chimique Produits pétrochimiques Organic compounds Industrial applications Chemische Industrie Organische Verbindungen Technische organische Chemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012846675&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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