The mechanisms of fast reactions in solution:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
IOS Press [u.a.]
2001
|
| Schlagworte: | |
| Online-Zugang: | Table of contents Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | xi, 329 p. ill. |
| ISBN: | 4274904091 1586031031 |
Internformat
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Datensatz im Suchindex
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|---|---|
| adam_text | THE MECHANISMS OF FAST REACTIONS IN SOLUTION BY E.F. CALDIN MA, D.PHIL.
LOTE PROFESSOR OFPHYSICAL CHEMISTRY UNIVERSITY OFKENT, CANTERBURY,
UNITED KINGDOM IOS PRESS *HL OHMSHA AMSTERDAM * BERLIN * OXFORD * TOKYO
* WASHINGTON, DC CONTENTS PREFACE V FOREWORD VII ACKNOWLEDGEMENTS VIII
PROLOGUE XI PART ONE CHAPTER 1. INTRODUCTION: ORIGINS, METHODS,
MECHANISMS, RATE CONSTANTS 1.1. INTRODUCTION 3 1.2. THE STRUCTURE OF
THIS BOOK 10 1.3. THEORY OF RATE CONSTANTS FOR DIFFUSION-COHTROLLED
REACTIONS 12 REFERENCES 18 CHAPTER 2. THE RATES OF DIFFUSION-CONTROLLED
REACTIONS 2.1. INTRODUCTION 21 2.2. APPLICATION OF THE DIFFUSION LAW TO
RATES OF ENCOUNTER AND OF CHEMICAL REAC- TION: DIE SMOLUCHOWSKI EQUATION
21 2.3. A MOLECULAR MODEL FOR TRANSLATIONAL DIFFUSION AND
DIFFUSION-INFLUENCED RATES OF REACTION: RANDOM-WALK THEORY 31 2.4.
ENCOUNTER IN SOLUTION: THE SOLVENT CAGE 33 2.5. THE COURSE OF AN
ENCOUNTER 36 2.6. ALTERNATIVE THEORETICAL APPROACHES: REFINEMENT OF
THEORY 45 REFERENCES 48 CHAPTER 3. THE MATHEMATICAL THEORY OF DIFFUSION
AND DIFFUSION-CONTROLLED REACTION RATES 3.1. INTRODUCTION 51 3.2. THEORY
OF RATES OF DIFFUSION, IN TERMS OF CONCENTRATION GRADIENTS 54 3.3.
CALCULATION OF DIFFUSION-CONTROLLED RATE CONSTANT 59 3.4. DIFFUSION
COEFFICIENTS: THEORY AND EXPERIMENT 65 REFERENCES 79 CHAPTER 4. FLASH
PHOTOLYSIS TECHNIQUES 4.1. INTRODUCTION 81 4.2. EXPERIMENTAL FLASH
TECHNIQUES 85 4.3. SOME APPLICATIONS OF FLASH TECHNIQUES 98 REFERENCES
115 CHAPTER 5. INITIATION BY HIGH-ENERGY RADIATION: PULSE RADIOLYSIS
5.1. INTRODUCTION 5.2. EXPERIMENTAL TECHNIQUES 119 122 X CONTENTS 5.3.
SOME APPLICATIONS OF PULSE RADIOLYSIS 125 REFERENCES 136 PARTTWO CHAPTER
6. FLUORESCENCE QUENCHING AND ENERGY-TRANSFER FROM EXCITED MOLECULES
6.1. GENERAL PRINCIPLES 141 6.2. THEORY OF FLUORESCENCE QUENCHING 142
6.3. EXPERIMENTAL INVESTIGATION OF FLUORESCENCE QUENCHING 151 6.4.
KINETIC AND MECHANISTIC APPLICATIONS OF FLUORESCENCE MEASUREMENTS 156
6.5. PHYSICAL MECHANISMS FOR NON-RADIATIVE ENERGY TRANSFER BETWEEN
MOLECULES 167 REFERENCES 187 CHAPTER 7. ULTRAFAST PROCESSES:
SUB-PICOSECOND AND FEMTOSECOND TECHNIQUES 7.1. INTRODUCTION 191 7.2.
FEMTOSECOND STUDIES OF THE ENTIRE REACTION PATH 192 7.3. SOME SYSTEMS
STUDIED BY SUB-PICOSECOND AND FEMTOSECOND TECHNIQUES 197 REFERENCES 221
PART THREE CHAPTER 8. PROTON-TRANSFER AND GROUP-TRANSFER REACTONS IN
SOLUTION: MARCUS THEORY (I) 8.1. MARCUS THEORY. INTRODUCTION 227 8.2.
APPLICATION OF MARCUS THEORY TO PROTON-TRANSFER REACTIONS IN SOLUTION
228 8.3. APPLICATION OF MARCUS THEORY TO GROUP TRANSFER 256 8.4.
REFINEMENTS AND EXTENSIONSOF THE MARCUS TREATMENT 261 REFERENCES 261
CHAPTER 9. ELECTRON-TRANSFER REACTIONS: MARCUS THEORY (II) 9.1.
INTRODUCTION 265 I. ELECTRON-TRANSFER IN OUTER-SPHERE REACTIONS OF METAL
IONS 266 9.2 292 II. ELECTRON-TRANSFER REACTIONS IN ORGANIC SYSTEMS 292
9.3. TAILPIECE: A BRIEF RE-CAPITULATION 317 REFERENCES 318 EPILOGUE 323
LIST OF SYMBOLS USED FREQUENTLY IN THE MARCUS THEORY OF REACTIONS 325
SUBJECT INDEX 327
|
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| illustrated | Illustrated |
| indexdate | 2024-07-09T19:58:06Z |
| institution | BVB |
| isbn | 4274904091 1586031031 |
| language | English |
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| oclc_num | 48231810 |
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| owner_facet | DE-703 |
| physical | xi, 329 p. ill. |
| publishDate | 2001 |
| publishDateSearch | 2001 |
| publishDateSort | 2001 |
| publisher | IOS Press [u.a.] |
| record_format | marc |
| spelling | Caldin, Edward Verfasser aut The mechanisms of fast reactions in solution by E. F. Caldin Amsterdam [u.a.] IOS Press [u.a.] 2001 xi, 329 p. ill. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Chemical kinetics Reaction mechanisms (Chemistry) Solution (Chemistry) Lösung Chemie (DE-588)4036159-7 gnd rswk-swf Reaktionsmechanismus (DE-588)4177123-0 gnd rswk-swf Schnelle Reaktion (DE-588)4179864-8 gnd rswk-swf Lösung Chemie (DE-588)4036159-7 s Reaktionsmechanismus (DE-588)4177123-0 s Schnelle Reaktion (DE-588)4179864-8 s DE-604 http://www.loc.gov/catdir/toc/fy022/00109666.html Table of contents GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012808968&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Caldin, Edward The mechanisms of fast reactions in solution Chemical kinetics Reaction mechanisms (Chemistry) Solution (Chemistry) Lösung Chemie (DE-588)4036159-7 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Schnelle Reaktion (DE-588)4179864-8 gnd |
| subject_GND | (DE-588)4036159-7 (DE-588)4177123-0 (DE-588)4179864-8 |
| title | The mechanisms of fast reactions in solution |
| title_auth | The mechanisms of fast reactions in solution |
| title_exact_search | The mechanisms of fast reactions in solution |
| title_full | The mechanisms of fast reactions in solution by E. F. Caldin |
| title_fullStr | The mechanisms of fast reactions in solution by E. F. Caldin |
| title_full_unstemmed | The mechanisms of fast reactions in solution by E. F. Caldin |
| title_short | The mechanisms of fast reactions in solution |
| title_sort | the mechanisms of fast reactions in solution |
| topic | Chemical kinetics Reaction mechanisms (Chemistry) Solution (Chemistry) Lösung Chemie (DE-588)4036159-7 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Schnelle Reaktion (DE-588)4179864-8 gnd |
| topic_facet | Chemical kinetics Reaction mechanisms (Chemistry) Solution (Chemistry) Lösung Chemie Reaktionsmechanismus Schnelle Reaktion |
| url | http://www.loc.gov/catdir/toc/fy022/00109666.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=012808968&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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