Stable isotope geochemistry: with 18 tables
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin ; Heidelberg ; New York ; Hong Kong ; London ; Milan ; Pa
Springer
2004
|
| Ausgabe: | 5., rev. and updated ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Literaturverz. S. 197 - 239 |
| Beschreibung: | XI, 244 S. graph. Darst. : 24 cm |
| ISBN: | 3540402276 |
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| 100 | 1 | |a Hoefs, Jochen |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Stable isotope geochemistry |b with 18 tables |c Jochen Hoefs |
| 250 | |a 5., rev. and updated ed. | ||
| 264 | 1 | |a Berlin ; Heidelberg ; New York ; Hong Kong ; London ; Milan ; Pa |b Springer |c 2004 | |
| 300 | |a XI, 244 S. |b graph. Darst. : 24 cm | ||
| 336 | |b txt |2 rdacontent | ||
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| 338 | |b nc |2 rdacarrier | ||
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Datensatz im Suchindex
| _version_ | 1804130376334966785 |
|---|---|
| adam_text | Contents
1 Theoretical and Experimental Principles.............. 1
1.1 General Characteristics of Isotopes................. 1
1.2 Isotope Effects............................. 3
1.3 Isotope Fractionation Processes................... 5
1.3.1 Isotope Exchange........................... 5
1.3.1.1 Fractionation Factor (a) ....................... 7
1.3.1.2 The Delta Value (6) .......................... 8
1.3.1.3 Evaporation-Condensation Processes................ 9
1.3.2 Kinetic Effects............................. 10
1.3.3 Diffusion................................ 11
1.3.4 Other Factors Influencing Isotopic Fractionations......... 13
1.3.4.1 Pressure ................................ 13
1.3.4.2 Chemical Composition........................ 14
1.3.4.3 Crystal Structure ........................... 14
1.3.4.4 Mass-Independent Isotope Effects.................. 15
1.3.5 Isotope Geothermometers ...................... 16
1.3.5.1 Theoretical Calculations ....................... 17
1.3.5.2 Experimental Calibrations...................... 18
1.4 Basic Principles of Mass Spectrometry ............... 21
1.4.1 Continuous Flow - Isotope Ratio Mass Spectrometers ...... 23
1.5 Standards ............................... 23
1.6 General Remarks on Sample Preparation Methods for Gases ... 26
1.7 New Microanalytical Techniques .................. 27
1.7.1 Laser Microprobe........................... 27
1.7.2 Continuous Flow Isotope Ratio Mass Spectrometry (IRMS) ... 28
1.7.3 Secondary Ion Mass Spectrometry (SIMS) ............. 28
1.8 Stable Isotope Variations of Heavier Elements........... 29
2 Isotope Fractionation Mechanisms of Selected Elements..... 31
2.1 Hydrogen ............................... 32
2.1.1 Preparation Techniques and Mass Spectrometric Measurements 33
2.1.2 Standards ............................... 34
2.1.3 Fractionation Mechanisms...................... 34
2.1.3.1 Equilibrium Exchange Reactions .................. 36
2.1.3.2 Kinetic Isotope Effects ........................ 38
VIII Contents
2.1.3.3 Other Fractionation Effects ..................... 38
2.2 Lithium ................................ 39
2.3 Boron.................................. 41
2.4 Carbon................................. 44
2.4.1 Preparation Techniques ....................... 44
2.4.2 Standards ............................... 45
2.4.3 Fractionation Mechanisms...................... 45
2.4.3.1 Inorganic Carbonate System..................... 45
2.4.3.2 Carbon Isotope Fractionations During Photosynthesis...... 46
2.4.4 Interactions Between the Carbonate-Carbon Reservoir
and Organic Carbon Reservoir.................... 48
2.5 Nitrogen................................ 49
2.6 Oxygen................................. 52
2.6.1 Preparation Techniques ....................... 53
2.6.2 Standards ............................... 55
2.6.3 Fractionation Mechanisms...................... 55
2.6.4 Fluid-Rock Interactions ....................... 60
2.7 Magnesium .............................. 62
2.8 Silicon ................................. 63
2.9 Sulfur.................................. 63
2.9.1 Preparation Techniques ....................... 64
2.9.2 Fractionation Mechanisms...................... 65
2.9.2.1 Dissimilatory Sulfate Reduction................... 65
2.9.2.2 Thermochemical Reduction of Sulfate ............... 67
2.9.2.3 Isotope Exchange Reactions ..................... 68
2.10 Chlorine ................................ 69
2.11 Calcium ................................ 71
2.12 Chromium............................... 72
2.13 Iron................................... 72
2.14 Copper................................. 74
2.15 Zinc .................................. 74
2.16 Selenium................................ 75
2.17 Molybdenum ............................. 75
2.18 Thallium................................ 76
3 Variations of Stable Isotope Ratios in Nature ........... 77
3.1 Extraterrestrial Materials....................... 77
3.1.1 Chondrites............................... 78
3.1.1.1 Hydrogen ............................... 80
3.1.1.2 Carbon................................. 80
3.1.1.3 Nitrogen................................ 81
3.1.1.4 Sulfur.................................. 82
3.1.2 Evolved Extraterrestrial Materials.................. 82
3.1.2.1 The Moon ............................... 83
3.1.2.2 Mars .................................. 84
3.1.2.3 Venus.................................. 86
Contents IX
3.2 Isotopic Composition of the Upper Mantle............. 86
3.2.1 Oxygen................................. 87
3.2.2 Hydrogen ............................... 88
3.2.3 Carbon................................. 90
3.2.4 Nitrogen................................ 91
3.2.5 Sulfur.................................. 92
3.3 Magmatic Rocks............................ 93
3.3.1 Fractional Crystallization ...................... 94
3.3.2 Differences Between Volcanic and Plutonic Rocks......... 94
3.3.3 Low-Temperature Alteration Processes............... 94
3.3.4 Assimilation of Crustal Rocks.................... 95
3.3.5 Basaltic Rocks from Different Tectonic Settings .......... 95
3.3.6 Ocean Water/Basaltic Crust Interactions .............. 96
3.3.7 Granitic Rocks............................. 97
3.4 Volatiles in Magmatic Systems.................... 97
3.4.1 Glasses................................. 98
3.4.1.1 Hydrogen ............................... 98
3.4.1.2 Carbon................................. 98
3.4.1.3 Nitrogen................................ 99
3.4.1.4 Sulfur.................................. 99
3.4.2 Volcanic Gases and Hot Springs................... 100
3.4.2.1 Water.................................. 100
3.4.2.2 Carbon................................. 101
3.4.2.3 Sulfur.................................. 102
3.4.3 Isotope Thermometers in Geothermal Systems .......... 103
3.5 Ore Deposits and Hydrothermal Systems.............. 103
3.5.1 Origin of Ore Fluids ......................... 105
3.5.1.1 Magmatic Water............................ 106
3.5.1.2 Metamorphic Water.......................... 107
3.5.1.3 Formation Waters........................... 107
3.5.2 Wall-Rock Alteration ......................... 107
3.5.3 Fossil Hydrothermal Systems .................... 108
3.5.4 Hydrothermal Carbonates ...................... 109
3.5.5 Sulfur Isotope Composition of Ore Deposits............ 110
3.5.5.1 Importance of Changing fO2 and pH ................ 110
3.5.5.2 Recent Sulfide Deposits at Midocean Ridges............ 112
3.5.5.3 Magmatic Ore Deposits........................ 112
3.5.5.4 Magmatic Hydrothermal Deposits ................. 113
3.5.5.5 Base-and Precious-Metal Vein Deposits .............. 113
3.5.5.6 Volcanic-Associated Massive Sulfide Deposits ........... 113
3.5.5.7 Shale/Carbonate-Hosted Massive Sulfide Deposits ........ 114
3.5.5.8 Mississippi Valley Type Deposits .................. 114
3.5.5.9 Biogenic Deposits........................... 114
3.5.5.10 Metamorphosed Deposits ...................... 115
3.6 Hydrosphere.............................. 115
3.6.1 Meteoric Water ............................ 116
3.6.1.1 6D-618O Relationship......................... 118
X Contents
3.6.1.2 Ancient Meteoric Waters....................... 119
3.6.2 Ice Cores................................ 119
3.6.3 Groundwater ............................. 121
3.6.4 Isotope Fractionations During Evaporation ............ 121
3.6.5 Ocean Water.............................. 122
3.6.6 Porewaters............................... 124
3.6.7 Formation Water ........................... 125
3.6.8 Water in Hydrated Salt Minerals................... 127
3.7 Isotopic Composition of the Ocean During Geologic History ... 128
3.7.1 Oxygen................................. 128
3.7.2 Carbon................................. 130
3.7.3 Sulfur.................................. 131
3.8 Isotopic Composition of Dissolved and Particulate Compounds
in Ocean and Freshwaters ...................... 133
3.8.1 Carbon Species in Water ....................... 133
3.8.1.1 Bicarbonate in Ocean Water ..................... 133
3.8.1.2 Particulate Organic Matter (POM) ................. 134
3.8.1.3 Carbon Isotope Composition of Porewaters ............ 135
3.8.1.4 Carbon in Freshwaters ........................ 136
3.8.2 Nitrogen................................ 137
3.8.3 Oxygen................................. 137
3.8.4 Sulfate ................................. 138
3.9 Atmosphere .............................. 139
3.9.1 Nitrogen................................ 140
3.9.2 Nitrous Oxide ............................. 140
3.9.3 Oxygen................................. 141
3.9.4 Carbon Dioxide............................ 142
3.9.4.1 Carbon................................. 142
3.9.4.2 Oxygen................................. 143
3.9.4.3 Long-Term Variations in the CO2 Concentration.......... 145
3.9.5 Carbon Monoxide........................... 147
3.9.6 Methane ................................ 147
3.9.7 Hydrogen ............................... 148
3.9.8 Sulfur.................................. 149
3.9.9 Mass-Independent Isotope Effects in Atmospheric Compounds 150
3.10 Biosphere ............................... 150
3.10.1 Living Organic Matter ........................ 151
3.10.1.1 Bulk Carbon.............................. 151
3.10.1.2 Hydrogen ............................... 152
3.10.1.3 Oxygen................................. 153
3.10.1.4 Nitrogen................................ 153
3.10.1.5 Sulfur.................................. 154
3.10.2 Stable Isotopes as Indicators of Diet and Metabolism....... 154
3.10.3 Tracing Anthropogenic Organic Contaminant Sources ...... 155
3.10.4 Fossil Organic Matter......................... 155
3.10.4.1 Isotope Composition of Individual Compounds.......... 156
3.10.4.2 Marine Versus Terrestrial Organic Matter ............. 157
Contents XI
3.10.5 Oil ................................... 157
3.10.6 Coal .................................. 159
3.10.7 Natural Gas .............................. 160
3.10.7.2 Thermogenic Gas........................... 161
3.10.7.1 BiogenicGas.............................. 161
3.10.7.3 Abiogenic Methane.......................... 162
3.11 Sedimentary Rocks.......................... 163
3.11.1 Clay Minerals ............................. 163
3.11.2 Clastic Sedimentary Rocks...................... 165
3.11.3 Biogenic Silica and Cherts ...................... 167
3.11.4 Marine Carbonates .......................... 168
3.11.4.1 Oxygen................................. 168
3.11.4.2 Carbon................................. 171
3.11.5 Diagenesis............................... 173
3.11.5.1 Meteoric Pathway........................... 173
3.11.5.2 Burial Pathway............................. 173
3.11.6 Dolomites ............................... 174
3.11.7 Freshwater Carbonates........................ 176
3.11.8 Phosphates............................... 177
3.11.9 Iron Oxides .............................. 178
3.11.10 Sedimentary Sulfur.......................... 178
3.12 Paleoclimatology ........................... 180
3.12.1 Continental Records ......................... 180
3.12.1.1 Ice Cores................................ 182
3.12.2 Marine Records............................ 185
3.12.2.1 Corals ................................. 186
3.12.3 Characteristic Climatic Events During the Last 65 Ma....... 186
3.13 Metamorphic Rocks ......................... 188
3.13.1 Contact Metamorphism ....................... 190
3.13.2 Regional Metamorphism....................... 191
3.13.3 Lower Crustal Rocks ......................... 192
3.13.4 Thermometry............................. 193
References.................................... 197
Subject Index .................................. 241
|
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| author | Hoefs, Jochen |
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| classification_tum | GEO 450f |
| ctrlnum | (OCoLC)249552589 (DE-599)BVBBV017624533 |
| dewey-full | 551.9 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 551 - Geology, hydrology, meteorology |
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| dewey-search | 551.9 |
| dewey-sort | 3551.9 |
| dewey-tens | 550 - Earth sciences |
| discipline | Chemie / Pharmazie Geowissenschaften Geologie / Paläontologie Physik Geographie |
| edition | 5., rev. and updated ed. |
| format | Book |
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| id | DE-604.BV017624533 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T19:20:03Z |
| institution | BVB |
| isbn | 3540402276 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-010601685 |
| oclc_num | 249552589 |
| open_access_boolean | |
| owner | DE-703 DE-12 DE-20 DE-19 DE-BY-UBM DE-91 DE-BY-TUM DE-29 DE-83 DE-11 DE-188 DE-B16 |
| owner_facet | DE-703 DE-12 DE-20 DE-19 DE-BY-UBM DE-91 DE-BY-TUM DE-29 DE-83 DE-11 DE-188 DE-B16 |
| physical | XI, 244 S. graph. Darst. : 24 cm |
| publishDate | 2004 |
| publishDateSearch | 2004 |
| publishDateSort | 2004 |
| publisher | Springer |
| record_format | marc |
| spelling | Hoefs, Jochen Verfasser aut Stable isotope geochemistry with 18 tables Jochen Hoefs 5., rev. and updated ed. Berlin ; Heidelberg ; New York ; Hong Kong ; London ; Milan ; Pa Springer 2004 XI, 244 S. graph. Darst. : 24 cm txt rdacontent n rdamedia nc rdacarrier Literaturverz. S. 197 - 239 Isotopengeochemie - Stabiles Isotop Stabiles Isotop (DE-588)4124245-2 gnd rswk-swf Isotopengeochemie (DE-588)4136262-7 gnd rswk-swf Isotopengeochemie (DE-588)4136262-7 s Stabiles Isotop (DE-588)4124245-2 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010601685&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Hoefs, Jochen Stable isotope geochemistry with 18 tables Isotopengeochemie - Stabiles Isotop Stabiles Isotop (DE-588)4124245-2 gnd Isotopengeochemie (DE-588)4136262-7 gnd |
| subject_GND | (DE-588)4124245-2 (DE-588)4136262-7 |
| title | Stable isotope geochemistry with 18 tables |
| title_auth | Stable isotope geochemistry with 18 tables |
| title_exact_search | Stable isotope geochemistry with 18 tables |
| title_full | Stable isotope geochemistry with 18 tables Jochen Hoefs |
| title_fullStr | Stable isotope geochemistry with 18 tables Jochen Hoefs |
| title_full_unstemmed | Stable isotope geochemistry with 18 tables Jochen Hoefs |
| title_short | Stable isotope geochemistry |
| title_sort | stable isotope geochemistry with 18 tables |
| title_sub | with 18 tables |
| topic | Isotopengeochemie - Stabiles Isotop Stabiles Isotop (DE-588)4124245-2 gnd Isotopengeochemie (DE-588)4136262-7 gnd |
| topic_facet | Isotopengeochemie - Stabiles Isotop Stabiles Isotop Isotopengeochemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010601685&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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