An introduction to plastics:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | German |
| Veröffentlicht: |
Weinheim
Wiley
2003
|
| Ausgabe: | 2., completely rev. ed. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XXII, 387 S. Ill., graph. Darst. |
| ISBN: | 3527296026 |
Internformat
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| 100 | 1 | |a Elias, Hans-Georg |d 1928- |e Verfasser |0 (DE-588)128433426 |4 aut | |
| 245 | 1 | 0 | |a An introduction to plastics |c Hans-Georg Elias |
| 250 | |a 2., completely rev. ed. | ||
| 264 | 1 | |a Weinheim |b Wiley |c 2003 | |
| 300 | |a XXII, 387 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
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| adam_text |
Contents XIII
Contents
Prefaces V
List of Symbols VII
Symbols for Languages VII
Symbols in Chemical Structures VII
Mathematical Symbols VII
Averages and Other Markings VII
Exponents and Superscripts VIII
Indices and Subscripts VIII
Physical Quantities IX
Table of Contents XIII
1 Introduction 1
1.1 Basic Terms 1
1.2 History of Plastics 4
1.3 Economic Importance 6
Literature 12
References 12
Polymers
2 Chemical Structure of Polymers 13
2.1 Constitution 13
2.1.1 Introduction 13
2.1.2 Linear Polymers 13
2.1.3 Branched Polymers 15
2.1.4 Unordered Networks 16
2.1.5 Ordered Chain Assemblies 17
2.1.6 Nomenclature 17
2.2 Molecular Weights 18
2.2.1 Molar Mass Averages 19
Number and Mass Averages 19
Absolute Methods 20
Viscometry 20
Rheometry 21
2.2.2 Molar Mass Distributions 22
2.3 Stereoisomerism 24
2.3.1 Configurational Isomerism 24
Definitions 24
Determination of Tacticity 26
2.3.2 Torsional Isomerism 26
2.3.3 Conformational Isomerism 27
Literature 28
XIV Contents
3 Polymer Syntheses 31
3.1 Introduction 31
3.1.1 Raw Materials for Polymers 31
3.1.2 Classification of Syntheses 32
3.1.3 Polymer Formation 33
3.1.4 Thermodynamics of Polymerization 34
3.1.5 Polymerization Reactors 35
Reactor Types 35
Effect on Molecular Weight Distribution 37
3.1.6 Source and Process Based Terms 39
Homopolymers 39
Copolymers 40
3.2 Chain Polymerization 41
3.2.1 Overview 41
3.2.2 Free-Radical Polymerization 42
Initiation 43
Propagation 43
Termination 44
Chain Transfer 44
Polymerization Kinetics 45
Crosslinking Polymerizations 45
Process Engineering 45
3.2.3 Anionic Polymerization 47
3.2.4 Cationic Polymerization 47
3.2.5 Coordination Polymerizations 48
3.2.6 Copolymerization 49
3.3 Polycondensation and Polyaddition 51
3.3.1 Introduction 51
3.3.2 Linear Polycondensation 52
3.3.3 Non-linear Polycondensation 54
3.3.5 Polyaddition 55
3.4 Polymer Reactions 55
3.4.1 Polymer Transformations 55
3.4.2 Formation of Block and Graft Copolymers 56
3.4.3 Crosslinking Reactions 57
3.4.4 Degradation Reactions 57
Literature 58
Reference 60
4 Physical Structure of Polymers 61
4.1 Solubility of Polymers 61
4.2 Dilute Solutions 62
4.2.1 Unperturbed Coils 62
4.2.2 Perturbed Coils 63
4.3 Concentrated Solutions and Melts 64
4.4 Non-crystalline States 66
Contents X V
4.4.1 Amorphous Polymers 66
4.4.2 Oriented Polymers 67
4.5 Crystalline Polymers 67
4.5.1 Introduction 67
4.5.2 Crystal Structure 68
4.5.3 Morphology 70
4.6 Mesophases 73
4.6.1 Introduction 73
4.6.2 Liquid Crystals 73
Mesogens 73
Thermotropic Liquid-Crystalline Polymers 75
Lyotropic Liquid-Crystalline Polymers 75
4.6.3 Block Copolymers 76
4.6.4 Acidic Copolymers and Ionomers 78
4.7 Gels 79
4.8 Polymer Surfaces 80
4.8.1 Structure 80
4.8.2 Interfacial Tension 80
4.8.3 Adsorption 81
Literature 82
References 84
Manufacture of Plastics
5 Polymer Adjuvants 85
5.1 Introduction 85
5.2 Compounding 86
5.2.1 Homogenization 86
5.2.2 Devolatilization, Drying, and Conditioning 87
5.3 Demixing 89
5.4 Modifiers 90
5.4.1 Extenders 90
5.4.2 Fibers 92
5.4.3 Coupling Agents 93
5.4.4 Plasticizers 94
5.4.5 Impact Modifiers 95
5.4.6 Compatibilizers 95
5.4.7 Antifogging Agents 96
5.5 Colorants 96
5.5.1 Dyes 96
5.5.2 Pigments 96
5.6 Stabilizing Agents 97
5.6.1 Aging 97
5.6.2 Chemofunctional Agents 98
5.6.3 Flame Retardants 100
XVI Contents
5.7 Processing Aids 101
5.7.1 Lubricants 102
5.7.2 Plasticating Agents 102
5.7.3 Parting Agents and Abherents 102
5.7.4 Nucleating Agents 102
Literature 103
References 105
6 Thermophysical Properties 107
6.1 Introduction 107
6.1.1 Overview 107
6.1.2 Methods 107
6.2 Thermal Transformations 110
6.2.1 Definitions 110
6.2.2 Crystallization 112
6.2.3 Melting 113
6.2.4 Liquid-Crystal Transitions 116
6.2.5 Glass Transformation 117
Phenomena 117
Static and Dynamic Glass Temperatures 118
Structure-Property Relationships 119
6.3 Molecular Motions 120
6.3.1 Thermal Expansion 120
6.3.2 Heat Capacity 121
6.3.3 Heat Conductivity 122
6.4 Transport 123
6.4.1 Self-Diffusion 123
6.4.2 Permeation 125
Literature 127
References 128
7 Flow Properties 129
7.1 Types of How 129
7.2 Newtonian Viscosities 130
7.2.1 Fundamentals 130
7.2.2 Melts 132
7.2.3 Concentrated Solutions 134
7.3 Non-Newtonian Shear Viscosities 135
7.3.1 Types 135
7.3.2 Shear Rate Dependence 136
7.3.3 Temperature Dependence 140
7.3.4 Melt Elasticity 141
7.4 Extensional Viscosities 142
7.4.1 Types 142
7.4.2 Uniaxial Extensional Viscosities 144
7.4.3 Melt Strengths 146
Contents XVII
Literature 147
References 148
8 Plastics Processing 149
8.1 Properties and Operations 149
8.1.1 Overview 149
8.1.2. Densities 150
8.1.3 Warehousing and Transportation 152
8.1.4 Heating and Melting 152
8.1.5 Cooling and Annealing 154
8.1.6 Processing Steps 155
8.2 Processing of Viscous Materials 158
8.2.1 Casting 158
8.2.2 Coating 159
Spread Coating 159
Roll Coating 160
Spray Processes 160
8.2.3 Laminating 161
8.2.4 Pressureless Molding 161
Hand Lay-up Molding 162
Fiber-spray Gun Molding 162
Filament Winding 162
Pultrusion 163
8.2.5 Pressure-Assisted Molding 163
Bag Molding Processes 163
Press Molding 164
Resin Transfer Molding 165
8.3 Processing of Viscoelastic Materials 166
8.3.1 Plasticating 167
Kneading 167
Rolling 167
Calendering 168
8.3.2 Extrusion Processes 169
Fiber Spinning 169
Extrusion 169
Cast Film Extrusion 170
Coextrusion 170
Netlon® Process 170
Film Blowing 170
Extrusion Blow Forming 170
8.3.3 Injection Molding 171
Sandwich Molding 173
Reaction Injection Molding 173
Injection Blow Molding 173
8.4 Solid-State Processing 174
8.4.1 Strengthening 174
XVIII Contents
8.4.2 Thermoforming 175
8.5 Fabricating 176
8.5.1 Transforming 176
8.5.2 Machining 176
8.5.3 Bonding 176
8.6 Surface Treatment 177
Literature 179
References 180
Properties of Plastics
9 Mechanical Properties 181
9.1 Basic Terms 181
9.1.1 Deformation of Plastics 181
9.1.2 Standard Testing 182
Standards 182
Influence of Processing 183
Influence of Performance 185
Influence of Polymer Structure 186
9.1.3 Classification of Plastics 187
9.2 Energy Elasticity 188
9.2.1 Tensile Properties 188
9.2.2 Theoretical Moduli 190
Moduli and Poisson's Ratio 190
Structural Effects 192
9.2.3 Real Moduli 193
9.2.4 Flexural Moduli 194
9.3 Entropy Elasticity 195
9.4 Viscoelasticity 197
9.4.1 Yielding 197
9.4.2 Mechanical Models 199
9.4.3 Time-Temperature Superposition 200
9.5 Dynamic Behavior 201
9.5.1 Fundamentals 201
9.5.2 Molecular Interpretation 202
9.6 Strength 204
9.6.1 Failure Modes 204
9.6.2 Fracture Strengths 204
Theoretical Fracture Strength 205
Experimental Fracture Strength 206
Stress-Intensity Factors 208
9.6.3 Impact Strength 210
9.6.4 Fatigue 213
9.7 Surface Mechanics 214
9.7.1. Hardness 214
Contents XIX
9.7.2 Friction 215
9.7.3 Abrasion and Wear 216
9.7.4 Stress Cracking 216
Literature 217
References 219
10 Electrical Properties 221
10.1 Fundamentals 221
10.2 Dielectric Properties 222
10.2.1 Relative Permittivity 222
10.2.2 Resistivity 224
10.2.3 Dielectric Loss 225
10.2.4 Dielectric Strength and Tracking Resistance 225
10.2.5 Electrostatic Charging 226
10.3 Electrical Conductivity 227
10.4 Photoconductivity 228
Literature 229
Reference 230
11 Optical Properties 231
11.1 Refraction 231
11.1.1 Refractive Index 231
11.1.2 Birefringence 232
11.1.3 Non-linear Optics 233
11.2 Reflection 233
11.3 Perviousness 235
11.3.1 Transmission 235
11.3.2 Transparency 236
11.3.3 Haze and Milkiness 237
Literature 238
Reference 238
Types of Plastics
12 Polymers for Plastics 239
12.1 Introduction 239
12.1.1 Classification 239
12.1.2 Designations 240
ISO System 240
ASTM System 242
12.1.3 Production 243
12.2 Carbon Chain Thermoplastics 244
12.2.1 Poly(ethylene)s 244
Syntheses 245
Properties 246
XX Contents
Modified Poly(ethylene)s 247
Copolymers 247
12.2.2 Poly(propylene)s 248
12.2.3 Other Poly(l-olefm)s 249
12.2.4 Styrenics 249
Atactic Poly(styrene)s 249
Stereoregular Poly(styrene)s 250
Copolymers and Impact-Resistant Grades 251
Substituted Poly(styrene)s 252
12.2.5 Vinyls 253
12.2.6 Acrylics 254
12.2.7 Fluoroplastics 255
12.2.8 Poly(cycloolefin)s 256
12.3 Carbon-Oxygen Chain Thermoplastics 258
12.3.1 Thermoplastic Polyesters 258
12.3.2 Polycarbonates 260
12.3.3 Liquid-Crystalline Polyesters 262
12.3.4 Acetal Polymers 263
12.3.5 Polyethers 264
12.4 Carbon-Sulfur Chain Thermoplastics 266
12.4.1 Poly(phenylene sulfide) 266
12.4.2 Polysulfones 266
12.5 Carbon-Nitrogen Chain Thermoplastics 268
12.5.1 Polyamides 268
Nomenclature 268
Syntheses 269
Properties 270
12.5.2 Polyimides 272
In-situ Polyimides 272
Preformed Imide Groups 273
12.5.3 Azole Polymers 274
12.6 Thermosets 275
12.6.1 Phenolics 275
12.6.2 Amino Resins 277
12.6.3 Alkyd Resins 278
12.6.4 Unsaturated Polyesters 278
12.6.5 Polyallyls 279
12.6.6 Epoxy Resins 279
12.6.7 Polyurethanes 280
12.6.8 Silicone Resins 281
12.7 Biopolymer-Based Plastics 281
12.7.1 Wood 281
12.7.2 Cellulosics 282
12.7.3 Starch-Based Plastics 283
12.7.4 Poly(hydroxybutyrate) 284
12.7.5 Poly(lactic acid) 284
Contents XXI
Literature 285
References 290
13 Polymer Composites 291
13.1 Basic Considerations 291
13.1.1 Terminology 291
13.1.2 Polymer Systems 292
13.1.3 Rules of Mixtures 293
13.1.4 Concentration Parameters 295
13.1.5 Interlayers 296
13.2 Moduli 298
13.2.1 Long Fibers 298
13.2.2 Short Fibers 300
13.2.3 Particulates 302
13.3 Strengths 304
13.3.1 Overview 304
13.3.2 Tensile Strength - Long Fibers 305
13.3.3 Tensile Strength - Short Fibers 306
13.3.4 Tensile and Tensile Yield Strength - Particulates 307
13.3.5 Flexural Strength 309
13.3.6 Tear Strength 310
13.3.7 Impact Strength 311
13.4 Fracture Elongation 312
13.5 Thermal Properties 313
13.5.1 Expansion Coefficient 313
13.5.2 Transformation Temperatures 314
13.5.3 Heat Capacity and Heat Conductivity 315
13.6 Rheological Properties 315
13.7 Macrocomposites 316
Literature 317
References 318
14 Polymer Blends 319
14.1 Overview 319
14.2 Plasticized Polymers 319
14.2.1 Molecular Plasticizer Efficiency 320
14.2.2 Technical Considerations 321
14.3 Polymer Blends 322
14.3.1 Overview 322
14.3.2 Miscibility 323
14.3.3 Blend Formation 326
14.3.4 Phase Morphology 327
14.3.5 Rubber Blends 328
14.3.6 Homogeneous Blends of Thermoplastics 329
14.3.7 Blends of Compatible Thermoplastics 329
14.3.8 Toughened Plastics 331
XXII Contents
Classes 331
Morphology 333
Deformation 333
14.4 Thermoplastic Elastomers 334
14.5 Expanded Plastics 336
14.5.1 Overview 336
14.5.2 Manufacture 336
14.5.3 Mechanical Properties 338
14.5.4 Thermal Conductivity 339
Literature 340
References 341
15 Disposal and Recycling 343
Literature 348
References 348
16 Appendix 349
16.1 Physical Quantities and Units 349
Table 16-1 Names and Symbols for Physical Quantities 349
Table 16.2 Derived SI Units 350
Table 16-3 Older Units 351
Table 16-4 SI Prefixes for SI Units 352
Table 16-5 Fundamental Constants 352
Table 16-6 Conversion of US and Outdated Units 353
16.2 Concentrations 357
16.3 Ratios of Physical Quantities 357
16.4 Polymer and Plastics Abbreviations and Acronyms 358
Table 16-7 Common Abbreviations and Acronyms 358
16.5 ISO Codes for Thermoplastic Materials 366
Table 16-8 ISO and DIN Codes for Data Block 1 366
Table 16-9 ISO Code for Items in Data Block 2 367
Table 16-10 ISO Codes for Data Block 4 367
17 Subject Index 369 |
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| id | DE-604.BV017579654 |
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| indexdate | 2024-12-29T04:07:30Z |
| institution | BVB |
| isbn | 3527296026 |
| language | German |
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| publishDate | 2003 |
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| title | An introduction to plastics |
| title_auth | An introduction to plastics |
| title_exact_search | An introduction to plastics |
| title_full | An introduction to plastics Hans-Georg Elias |
| title_fullStr | An introduction to plastics Hans-Georg Elias |
| title_full_unstemmed | An introduction to plastics Hans-Georg Elias |
| title_short | An introduction to plastics |
| title_sort | an introduction to plastics |
| topic | Plastics Kunststoff (DE-588)4033676-1 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Plastics Kunststoff Polymere |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010578811&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT eliashansgeorg anintroductiontoplastics |
Inhaltsverzeichnis
THWS Würzburg Zentralbibliothek Lesesaal
| Signatur: |
1000 ZM 5000 E42(2)st |
|---|---|
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THWS Würzburg Teilbibliothek Röntgenring - KV, Raum C.2.05
| Signatur: |
1300 ZM 5000 E42(2)st |
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| Exemplar 1 | nicht ausleihbar Verfügbar Bestellen |