Soil and water chemistry: an integrative approach
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Boca Raton [u.a.]
CRC Press
2004
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index. |
| Beschreibung: | 534 S. graph. Darst. |
| ISBN: | 0849312582 |
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| 245 | 1 | 0 | |a Soil and water chemistry |b an integrative approach |c Michael E. Essington |
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Datensatz im Suchindex
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|---|---|
| adam_text | SOIL AND WATER CHEMISTRY AN INTEGRATIVE APPROACH MICHAEL E. ESSINGTON
CRC PRESS BOCA RATON LONDON NEW YORK WASHINGTON, D.C. TABLE OF CONTENTS
CHAPTER 1 THE SOIL CHEMICAL ENVIRONMENT: AN OVERVIEW 1 1.1 PHASES AND
CHEMICAL PROCESSES IN SOIL 1 1.1.1 INTRAPHASE SOIL PROCESSES 3 1.1.2
INTERPHASE SOIL PROCESSES I 4 1.2 ELEMENTS IN THE SOIL ENVIRONMENT:
THEIR CONCENTRATIONS AND IMPORTANT SPECIES 6 1.3 UNITS AND CONVERSIONS
14 1.4 HETEROGENEITY OF SOIL CHEMICAL CHARACTERISTICS 19 1.4.1
DESCRIPTIVE STATISTICAL PROPERTIES 21 1.4.2 GEOSTATISTICS 23 1.4.2.1
VARIOGRAMS 24 1.4.2.2 INTERPOLATION BY KRIGING 28 1.5 EXERCISES 31
REFERENCES 34 CHAPTER 2 SOIL MINERALS , 35 2.1 CHEMICAL BONDS 35 2.2
PAULING S RULES 38 2.3 CRYSTAL STRUCTURE 43 2.4 SILICATE CLASSES 45
2.4.1 NESOSILICATES 46 2.4.2 SOROSILICATES 48 2.4.3 CYCLOSILICATES 48
2.4.4 INOSILICATES 48 2.4.5 PHYLLOSILICATES 49 2.4.6 TECTOSILICATES 53
2.5 CLAY MINERALOGY 56 2.5.1 DIVISION 1:1 PHYLLOSILICATE MINERALS 61
2.5.2 DIVISION 2:1 PHYLLOSILICATE MINERALS 65 2.5.2.1 PYROPHYLLITE GROUP
65 2.5.2.2 SMECTITE GROUP 68 2.5.2.3 VERMICULITE GROUP 74 2.5.2.4 MICA
AND ILLITE GROUPS 75 2.5.2.5 CHLORITE GROUP 76 2.5.2.6 INTERSTRATIFIED
LAYER SILICATES 78 2.6 HYDROUS METAL OXIDES 80 2.6.1 HYDROUS ALUMINUM
OXIDES 80 2.6.2 HYDROUS IRON OXIDES 83 2.6.3 HYDROUS MANGANESE OXIDES 86
2.6.4 ALLOPHANE AND IMOGOLITE 88 2.7 X-RAY DIFFRACTION ANALYSIS 90 2.7.1
PRINCIPLES 90 2.7.2 CLAY MINERAL CHARACTERIZATION 93 2.8 EXERCISES 98
REFERENCES 100 CHAPTER 3 CHEMICAL WEATHERING 101 3.1 HYDROLYSIS AND
OXIDATION 101 3.2 BALANCING CHEMICAL REACTIONS 105 3.3 MINERAL
STABILITY: PRIMARY SILICATES IN THE SAND- AND SILT-SIZED FRACTIONS 109
3.4 MINERAL STABILITY: CLAY-SIZED FRACTION ILL 3.5 WEATHERING AND
FORMATION CHARACTERISTICS OF THE PHYLLOSILICATES 113 3.5.1 MICA 113
3.5.2 CHLORITE 120 3.5.3 VERMICULITE 122 3.5.4 SMECTITE 123 3.6 GENERAL
WEATHERING SCHEME FOR THE PHYLLOSILICATES 124 3.7 EXERCISES 125
REFERENCES 127 CHAPTER 4 ORGANIC MATTER IN SOIL 129 4.1 DETERMINATION OF
SOIL ORGANIC CARBON CONCENTRATIONS 131 4.2 ORGANIC FUNCTIONAL GROUPS: A
REVIEW 133 4.3 NONHUMIC SUBSTANCES 140 4.3.1 CARBOHYDRATES 140 4.3.2
NITROGEN, SULFUR, AND PHOSPHORUS COMPOUNDS 143 4.3.3 LIPIDS 150 4.3.4
LIGNINS 152 4.4 HUMIC SUBSTANCES 155 4.4.1 GENESIS OF HUMIC SUBSTANCES
157 4.4.2 CHEMICAL AND STRUCTURAL CHARACTERISTICS OF HUMIC SUBSTANCES
163 4.4.2.1 ELEMENTAL CONTENT 163 4.4.2.2 FUNCTIONAL GROUPS AND
STRUCTURAL COMPONENTS 167 4.4.2.3 MOLECULAR MASS AND CONFIGURATION 173
4.5 EXERCISES 178 REFERENCES 180 CHAPTER 5 SOIL WATER CHEMISTRY 183 5.1
NATURE OF WATER 183 5.2 ION HYDRATION 185 5.3 ELECTROLYTE SOLUTIONS 188
5.4 HYDROLYSIS OF CATIONS 195 5.5 LOWRY-BR0NSTED ACIDS AND BASES 198 5.6
COMPLEX IONS AND ION PAIRS 207 5.6.1 STABILITY OF SOLUBLE COMPLEXES 208
5.6.2 THE IRVING AND WILLIAMS SERIES 211 5.6.3 METAL-FULVATE
INTERACTIONS 212 5.7 THE ION ASSOCIATION MODEL 216 5.8 ION SPECIATION IN
SOIL SOLUTION 223 5.8.1 ACID SOIL SOLUTION 224 5.8.2 ALKALINE SOIL
SOLUTION 225 5.9 QUALITATIVE ASPECTS OF ION SPECIATION 227 5.10 SOIL
WATER SAMPLING METHODOLOGIES 232 5.10.1 IN SITU SOIL WATER SAMPLING 232
5.10.2 EX SITU SOIL WATER SAMPLING 236 5.11 METHODS OF CHEMICAL
ANALYSIS: ELEMENTAL ANALYSIS 238 5.11.1 ATOMIC SPECTROMETRY 238 5.11.1.1
FLAME ATOMIC ABSORPTION SPECTROPHOTOMETRY 238 5.11.1.2 ATOMIC EMISSION
SPECTROMETRY 243 5.11.1.3 GRAPHITE FURNACE ATOMIC ABSORPTION
SPECTROPHOTOMETRY 243 5.11.1.4 HYDRIDE GENERATION ATOMIC ABSORPTION
SPECTROPHOTOMETRY 245 5.11.2 INDUCTIVELY COUPLED (ARGON) PLASMA
SPECTROMETRY 246 5.12 EXERCISES 248 REFERENCES 251 CHAPTER 6 MINERAL
SOLUBILITY . 255 6.1 MINERAL SOLUBILITY: BASIC PRINCIPLES 255 6.1.1
MINERALOGICAL CONTROLS ON ION ACTIVITIES IN SOIL SOLUTIONS 257 6.1.2 THE
ION ACTIVITY PRODUCT AND RELATIVE SATURATION 260 6.2 APPLICATION OF
MINERAL SOLUBILITY PRINCIPLES: IMPEDIMENTS 263 6.2.1 THE ESTIMATION OF
STANDARD FREE ENERGIES OF FORMATION 264 6.2.2 METASTABILITY AND THE STEP
RULE 268 6.3 THE DEVIATION OF K SP FROM K DIS 269 6.3.1 POORLY
CRYSTALLINE AND MICROCRYSTALLINE SOLIDS 269 6.3.2 SOLID SOLUTIONS 271
6.4 MINERAL SOLUBILITY AND SOLUTION COMPOSITION 274 6.5 STABILITY
DIAGRAMS 276 6.5.1 ACTIVITY DIAGRAMS 277 6.5.2 ACTIVITY RATIO DIAGRAMS
280 6.5.3 THE TEMPERATURE DEPENDENCE OF THE EQUILIBRIUM CONSTANT 283
6.5.4 IN SITU STABILIZATION: OBSERVED AND PREDICTED TRANSFORMATIONS OF
METALLIC LEAD IN ALKALINE SOIL 290 6.5.5 PREDOMINANCE DIAGRAMS 297 6.6
PREDICTING SOLUTION COMPOSITION 302 6.7 EXERCISES 305 REFERENCES 308
CHAPTER 7 SURFACE CHEMISTRY AND ADSORPTION REACTIONS 311 7.1 SURFACE
FUNCTIONAL GROUPS AND COMPLEXES 311 7.1.1 INORGANIC SOIL PARTICLE
SURFACES AND THE SOURCE OF CHARGE 313 7.1.2 SURFACE COMPLEXES 321 7.2
THE SOLID-SOLUTION INTERFACE: A MICROSCOPIC VIEW 322 7.2.1 SURFACE
CHARGE DENSITY 322 7.2.2 POINTS OF ZERO CHARGE 327 7.2.3 THE ELECTRIC
DOUBLE-LAYER 330 7.3 QUANTITATIVE DESCRIPTION OF ADSORPTION 334 7.3.1
THE ADSORPTION ISOTHERM 335 7.3.2 LINEAR PARTITION THEORY 348 7.3.3
ADSORPTION KINETICS AND DESORPTION HYSTERESIS 358 7.4 SPECIFIC RETENTION
OF METALS AND LIGANDS 364 7.5 LIGAND EFFECTS ON METAL ADSORPTION 370 7.6
ORGANIC SURFACE FUNCTIONAL GROUPS AND ORGANIC MOLECULAR RETENTION
MECHANISMS 373 7.6.1 ORGANIC SURFACE FUNCTIONAL GROUPS 373 7.6.2
MOLECULAR RETENTION MECHANISMS 373 7.7 SURFACE COMPLEXATION MODELS 377
7.7.1 THE NONELECTROSTATIC MODEL 380 7.7.2 ELECTROSTATIC EFFECTS ON
ADSORPTION 386 7.7.2.1 THE CONSTANT CAPACITANCE MODEL 387 7.7.2.2 THE
MODIFIED TRIPLE LAYER MODEL 391 7.8 EXERCISES 394 REFERENCES 397 CHAPTER
8 CATION EXCHANGE 399 8.1 CATION EXCHANGE: A BEGINNING FOR SOIL
CHEMISTRY 399 8.2 QUALITATIVE ASPECTS OF CATION EXCHANGE 401 8.3 CATION
EXCHANGE CAPACITY AND EXCHANGE PHASE COMPOSITION 404 8.3.1 EXCHANGE
PHASE COMPOSITION 404 8.3.2 METHODS OF MEASURING THE CATION EXCHANGE
CAPACITY 407 8.3.2.1 AMMONIUM ACETATE (PH 7 OR 8.2) 407 8.3.2.2 CATION
EXCHANGE CAPACITY OF ARID LAND SOILS 408 8.3.2.3 CATION EXCHANGE
CAPACITY OF ACID SOILS 409 8.3.2.4 UNBUFFERED SALT EXTRACTION 409 8.4
QUANTITATIVE DESCRIPTION OF CATION EXCHANGE 409 8.4.1 CATION EXCHANGE
SELECTIVITY 410 8.4.1.1 KERR SELECTIVITY COEFFICIENT 410 8.3.1.2
VANSELOW SELECTIVITY COEFFICIENT 412 8.4.1.3 ROTHMUND AND KORNFELD
SELECTIVITY COEFFICIENT 416 8.4.1.4 GAPON SELECTIVITY COEFFICIENT 418
8.4.1.5 GAINES AND THOMAS SELECTIVITY COEFFICIENT 420 8.4.1.6 DAVIES
SELECTIVITY COEFFICIENT 421 8.4.1.7 REGULAR SOLUTION MODEL 422 8.4.2
EXCHANGE ISOTHERMS AND PREFERENCE 424 8.4.3 EXCHANGE EQUILIBRIUM
CONSTANT 430 8.5 EXERCISES 440 REFERENCES 442 CHAPTER 9
OXIDATION-REDUCTION REACTIONS IN SOILS 445 9.1 THE ELECTRON ACTIVITY 446
9.2 REDOX POTENTIAL MEASUREMENTS 449 9.3 REDOX STATUS IN SOILS 454 9.3.1
REDUCTION-OXIDATION SEQUENCES IN SOILS 455 9.3.2 REDOX ZONES 458 9.4
PE-PH PREDOMINANCE DIAGRAMS 459 9.4.1 CONSTRUCTION OF PE-PH DIAGRAMS:
THE CR-H 2 O SYSTEM 460 9.4.2 EXAMPLES OF PE-PH DIAGRAMS FOR
REDOX-SENSITIVE ELEMENTS 464 9.4.2.1 IRON AND MANGANESE 465 9.4.2.2
SELENIUM 467 9.4.2.3 ARSENIC 469 9.5 EXERCISES 471 REFERENCES 472
CHAPTER 10 ACIDITY IN SOIL MATERIALS 473 10.1 THE MEASUREMENT OF SOIL
SOLUTION PH 474 10.1.1 THE PH ELECTRODE SYSTEM 474 10.1.2 SOIL SOLUTION
PH 476 10.2 CHEMICAL AND BIOCHEMICAL PROCESSES THAT INFLUENCE SOIL
SOLUTION PH 477 10.3 ACID-NEUTRALIZING CAPACITY AND THE QUANTIFICATION
OF SOIL ACIDITY 483 10.4 NEUTRALIZATION OF SOIL ACIDITY 484 10.5 ACID
GENERATION AND MANAGEMENT IN MINE SPOILS: THE OXIDATION OF PYRITE 488
10.5.1 ACID GENERATION AND NEUTRALIZATION IN PYRITIC WASTES 488 10.5.2
PYRITIC MINE SPOIL RECLAMATION: CASE STUDY - 492 10.6 EXERCISES *. 495
REFERENCES 497 CHAPTER 11 SOIL SALINITY AND SODICITY 499 11.1 SOURCES OF
SALTS 500 11.2 DIAGNOSTIC CHARACTERISTICS OF SALINE AND SODIC SOILS 501
11.3 IRRIGATION WATER QUALITY PARAMETERS AND RELATIONSHIPS 504 11.4
GENESIS, MANAGEMENT, AND RECLAMATION OF SALT-AFFECTED SOILS 506 11.4.1
SALINE SOILS 507 11.4.2 SODIC SOILS 511 11.4.2.1 CLASSIFICATION OF SODIC
SOILS 511 11.4.2.2 FLOCCULATION AND DISPERSION IN COLLOIDAL SUSPENSIONS
513 11.4.2.3 GENESIS AND MANAGEMENT OF SODIC SOILS 516 11.4.3 SODIC MINE
SPOIL RECLAMATION 518 11.5 EXERCISES 519 REFERENCES 521 INDEX 523
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| indexdate | 2024-07-09T19:17:11Z |
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| language | English |
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| physical | 534 S. graph. Darst. |
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| spelling | Essington, Michael E. Verfasser aut Soil and water chemistry an integrative approach Michael E. Essington Boca Raton [u.a.] CRC Press 2004 534 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index. Bodemchemie gtt Bodemkunde gtt Eau - Chimie Grondwater gtt Hydrologie gtt Química aquática larpcal Química do solo larpcal Sols - Chimie Su kimyası Toprak kimyası Soil chemistry Water chemistry Bodenchemie (DE-588)4146134-4 gnd rswk-swf Bodenchemie (DE-588)4146134-4 s DE-604 GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010467290&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Essington, Michael E. Soil and water chemistry an integrative approach Bodemchemie gtt Bodemkunde gtt Eau - Chimie Grondwater gtt Hydrologie gtt Química aquática larpcal Química do solo larpcal Sols - Chimie Su kimyası Toprak kimyası Soil chemistry Water chemistry Bodenchemie (DE-588)4146134-4 gnd |
| subject_GND | (DE-588)4146134-4 |
| title | Soil and water chemistry an integrative approach |
| title_auth | Soil and water chemistry an integrative approach |
| title_exact_search | Soil and water chemistry an integrative approach |
| title_full | Soil and water chemistry an integrative approach Michael E. Essington |
| title_fullStr | Soil and water chemistry an integrative approach Michael E. Essington |
| title_full_unstemmed | Soil and water chemistry an integrative approach Michael E. Essington |
| title_short | Soil and water chemistry |
| title_sort | soil and water chemistry an integrative approach |
| title_sub | an integrative approach |
| topic | Bodemchemie gtt Bodemkunde gtt Eau - Chimie Grondwater gtt Hydrologie gtt Química aquática larpcal Química do solo larpcal Sols - Chimie Su kimyası Toprak kimyası Soil chemistry Water chemistry Bodenchemie (DE-588)4146134-4 gnd |
| topic_facet | Bodemchemie Bodemkunde Eau - Chimie Grondwater Hydrologie Química aquática Química do solo Sols - Chimie Su kimyası Toprak kimyası Soil chemistry Water chemistry Bodenchemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010467290&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT essingtonmichaele soilandwaterchemistryanintegrativeapproach |