Femto- to nanosecond time-resolved pump-probe spectroscopy on electron transfer in ferrocenophanone oxazine-1, merocyanine-3 TiO 2 and acridine-modified DNA:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
2003
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | München, Techn. Univ., Diss., 2003 |
| Beschreibung: | 137 S. graph. Darst. |
Internformat
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| 245 | 1 | 0 | |a Femto- to nanosecond time-resolved pump-probe spectroscopy on electron transfer in ferrocenophanone oxazine-1, merocyanine-3 TiO 2 and acridine-modified DNA |c Reinhard Haselsberger |
| 246 | 1 | |a Femto- to nanosecond time resolved pump probe spectroscopy on electron transfer in ferrocenophanone/oxazine-1, merocyanine-3/TiO 2 and acridine-modified DNA | |
| 264 | 1 | |c 2003 | |
| 300 | |a 137 S. |b graph. Darst. | ||
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Datensatz im Suchindex
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|---|---|
| adam_text |
CONTENTS
1 INTRODUCTION 7
2 EXPERIMENTAL METHODS 11
2.1 THE PUMP-PROBE METHOD . 11
2.1.1 DEFINITIONS. 11
2.1.2 THE PUMP-PROBE SET-UP. 12
2.1.3 DIFFERENCE-ABSORPTION. 12
2.1.4 ANALYSIS. 15
2.2 FEMTOSECOND PUMP-PROBE MEASUREMENTS. 16
2.2.1 THE LASER-SYSTEM. 16
2.2.2 SYNCHRONIZATION AND DATA ACQUISITION . 19
2.3 NONLINEAR OPTICAL PROCESSES . 19
2.3.1 WAVE EQUATION IN NONLINEAR MEDIA. 20
2.3.2 PHASE-MATCHING CONDITION. 21
2.3.3 INDEX-ELLIPSOID. 22
2.3.4 EXCITATION. 25
2.3.5 IR GENERATION. 26
2.4 NANOSECOND PUMP-PROBE MEASUREMENTS. 29
2.4.1 EXCITATION BEAM. 29
2.4.2 PROBE BEAM. 31
2.4.3 SAMPLE CHAMBER . 32
2.4.4 DATA ACQUISITION.32
2.5 STEADY-STATE MEASUREMENTS.34
3 FS TIME-RESOLVED IR-SPECTROSCOPY 35
3.1 THE PHOTOLYASE REPAIR MECHANISM. 36
3.2 THE VIBRATIONAL STARK-EFFECT.40
3.3 THE FERROCENOPHANONE/OXAZIN-L-SYSTEM.43
3.3.1 THEORETICAL CALCULATIONS. 44
3.3.2 EXPERIMENTS IN THE VISIBLE.45
3.4 IR SPECTROSCOPY. 48
3
BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/968528481
3.4.1 STEADY-STATE SPECTRUM.48
3.4.2 MATERIALS AND METHODS.49
3.4.3 TRANSIENT SPECTRUM.50
3.4.4 TIME-RESOLVED DATA.51
3.4.5 DISCUSSION.52
3.5 CONCLUSIONS.53
4 DYE SENSITIZED TICVCOLLOIDS 55
4.1 DYE SENSITIZER FOR ELECTROCHEMICAL CELLS .55
4.2 MATERIALS AND METHODS.58
4.3 PURE DYE IN SOLUTION.59
4.4 MC3 ADSORBED ON TI02.65
4.4.1 STEADY-STATE ABSORPTION.66
4.4.2 STEADY-STATE FLUORESCENCE.67
4.4.3 GLYCEROL ADDITION.69
4.4.4 SPECTRUM ANALYSIS.71
4.4.5 LIGHT INDUCED EFFECTS.72
4.5 TIME-RESOLVED MEASUREMENTS.73
4.5.1 EXCITATION WAVELENGTHS . 74
4.5.2 MAGNETIC FIELD EFFECT (MFE) .80
4.5.3 DISCUSSION.82
5 ACTIVATED HOLE TRANSFER IN DNA 89
5.1 STRUCTURE AND FUNCTION.89
5.2 CHARGE TRANSFER THEORY.91
5.2.1 SUPEREXCHANGE .91
5.2.2 HOPPING MECHANISM.93
5.2.3 THE PARAMETER
/3
.95
5.3 ACMA-MODIFIED OLIGONUCLEOTIDES.96
5.4 MATERIALS AND METHODS.99
5.4.1 LASER DYES. 99
5.4.2 OLIGONUCLEOTIDES.100
5.5 HOLE TRAPPING BY G, GG AND GGG.100
5.5.1 DUPLEXES UNDER STUDY.101
5.5.2 HOLE TRANSFER IN DIFFERENT DIRECTIONS.102
5.5.3 ACTIVATION ENERGY .105
5.5.4 CONCLUSIONS.108
5.6 DISTANCE DEPENDENT ACTIVATION ENERGIES .109
5.6.1 RESULTS.HO
5.6.2 DISCUSSION.112
5.6.3 CONCLUSIONS.114
5
6 SUMMARY 1X1
6.1 ELECTRON TRANSFER IN THE FERROCENOPHANONE-OXAZINE-1 SYSTEM 117
6.2 INVESTIGATION OF THE HETEROGENOUS SYSTEM MC3/TI02 .118
6.3 ACTIVATED HOLE TRANSFER IN ACRIDINE MODIFIED DNA.119
BIBLIOGRAPHY
LIST OF PUBLICATIONS
DANKSAGUNG
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139 |
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| discipline | Physik Chemie |
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| indexdate | 2024-11-22T17:37:28Z |
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| language | English |
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| physical | 137 S. graph. Darst. |
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| spelling | Haselsberger, Reinhard 1970- Verfasser (DE-588)124899471 aut Femto- to nanosecond time-resolved pump-probe spectroscopy on electron transfer in ferrocenophanone oxazine-1, merocyanine-3 TiO 2 and acridine-modified DNA Reinhard Haselsberger Femto- to nanosecond time resolved pump probe spectroscopy on electron transfer in ferrocenophanone/oxazine-1, merocyanine-3/TiO 2 and acridine-modified DNA 2003 137 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Techn. Univ., Diss., 2003 Ultrakurzzeitspektroskopie (DE-588)4209051-9 gnd rswk-swf Pump-Probe-Technik (DE-588)4601119-5 gnd rswk-swf Elektronentransfer (DE-588)4151907-3 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Elektronentransfer (DE-588)4151907-3 s Pump-Probe-Technik (DE-588)4601119-5 s Ultrakurzzeitspektroskopie (DE-588)4209051-9 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010395547&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Haselsberger, Reinhard 1970- Femto- to nanosecond time-resolved pump-probe spectroscopy on electron transfer in ferrocenophanone oxazine-1, merocyanine-3 TiO 2 and acridine-modified DNA Ultrakurzzeitspektroskopie (DE-588)4209051-9 gnd Pump-Probe-Technik (DE-588)4601119-5 gnd Elektronentransfer (DE-588)4151907-3 gnd |
| subject_GND | (DE-588)4209051-9 (DE-588)4601119-5 (DE-588)4151907-3 (DE-588)4113937-9 |
| title | Femto- to nanosecond time-resolved pump-probe spectroscopy on electron transfer in ferrocenophanone oxazine-1, merocyanine-3 TiO 2 and acridine-modified DNA |
| title_alt | Femto- to nanosecond time resolved pump probe spectroscopy on electron transfer in ferrocenophanone/oxazine-1, merocyanine-3/TiO 2 and acridine-modified DNA |
| title_auth | Femto- to nanosecond time-resolved pump-probe spectroscopy on electron transfer in ferrocenophanone oxazine-1, merocyanine-3 TiO 2 and acridine-modified DNA |
| title_exact_search | Femto- to nanosecond time-resolved pump-probe spectroscopy on electron transfer in ferrocenophanone oxazine-1, merocyanine-3 TiO 2 and acridine-modified DNA |
| title_full | Femto- to nanosecond time-resolved pump-probe spectroscopy on electron transfer in ferrocenophanone oxazine-1, merocyanine-3 TiO 2 and acridine-modified DNA Reinhard Haselsberger |
| title_fullStr | Femto- to nanosecond time-resolved pump-probe spectroscopy on electron transfer in ferrocenophanone oxazine-1, merocyanine-3 TiO 2 and acridine-modified DNA Reinhard Haselsberger |
| title_full_unstemmed | Femto- to nanosecond time-resolved pump-probe spectroscopy on electron transfer in ferrocenophanone oxazine-1, merocyanine-3 TiO 2 and acridine-modified DNA Reinhard Haselsberger |
| title_short | Femto- to nanosecond time-resolved pump-probe spectroscopy on electron transfer in ferrocenophanone oxazine-1, merocyanine-3 TiO 2 and acridine-modified DNA |
| title_sort | femto to nanosecond time resolved pump probe spectroscopy on electron transfer in ferrocenophanone oxazine 1 merocyanine 3 tio 2 and acridine modified dna |
| topic | Ultrakurzzeitspektroskopie (DE-588)4209051-9 gnd Pump-Probe-Technik (DE-588)4601119-5 gnd Elektronentransfer (DE-588)4151907-3 gnd |
| topic_facet | Ultrakurzzeitspektroskopie Pump-Probe-Technik Elektronentransfer Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=010395547&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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